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                    | Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |  
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                    | Предметный указатель |  
                    | | Grignard reagents reaction withimines      1216 Grignard reagents reaction withketones      1205—1209
 Grignard reagents rearrangement of      1416
 Grignard reagents stability of      806
 Grignard reagents stabilization by ethers      235
 Grignard reagents structure of      234—235
 Ground states, and photochemistry      306
 Grovenstein — Zimmerman rearrangement      1396
 Grunwald — Winstein equation      452
 Grunwald — Winstein relationship      371
 Guanidine, from cyanamide and ammonia      1192
 Guest, and crown ethers      105
 Guest-host, and resolution      152
 Ha worth reaction      714
 Half-chair conformation      178
 Half-life, and mechanism      294—295
 Half-life, definition      294
 Halide exchange reactions      517
 Halide exchange, with aryl halides      866
 Halide ions reaction with alkyl halides      517
 Halide ions reaction with sulfonate esters      518
 Halides 1,1,1-trihalides conversion to esters      463
 Halides 1,1,1-trihalides hydrolysis of      463
 Halides, acyl
  -halo, elimination reactions      1344 Halides, acyl alcoholysis, reagents for      482
 Halides, acyl and the Rosenmund reduction      532
 Halides, acyl conversion to Reissert compounds      533
 Halides, acyl coupling and ultrasound      568
 Halides, acyl decarbonylation      944
 Halides, acyl elimination reactions and rhodium catalysts      1339
 Halides, acyl from 1,1,1-trihalides and
  1642 Halides, acyl from acid derivatives      1642
 Halides, acyl from acyl halides      523 1643
 Halides, acyl from alcohols      1643
 Halides, acyl from aldehydes      914 1643
 Halides, acyl from alkenes      1643
 Halides, acyl from carboxylic acids      523 1642
 Halides, acyl from hydrogen halides      1643
 Halides, acyl from ketenes      992 1643
 Halides, acyl hydrogenation of      532
 Halides, acyl hydrogenolysis of      532
 Halides, acyl hydrolysis of      468
 Halides, acyl reaction with alcohols      482
 Halides, acyl reaction with aldehydes      1182
 Halides, acyl reaction with alkenes      1048
 Halides, acyl reaction with alkyl hydroperoxides      493
 Halides, acyl reaction with amides      514
 Halides, acyl reaction with ammonia      506
 Halides, acyl reaction with aromatic compounds      714
 Halides, acyl reaction with azide ion      515
 Halides, acyl reaction with carbanions      569
 Halides, acyl reaction with carboxylate salts      490
 Halides, acyl reaction with carboxylic acids      523
 Halides, acyl reaction with CuCN      573
 Halides, acyl reaction with diazomethane      573 1405
 Halides, acyl reaction with enamines      788
 Halides, acyl reaction with enolate anions      569
 Halides, acyl reaction with epi- sulfides      521
 Halides, acyl reaction with epoxides      521
 Halides, acyl reaction with Grignard reagents      567
 Halides, acyl reaction with HF      524
 Halides, acyl reaction with hydrazine      507
 Halides, acyl reaction with hydride reagents      532
 Halides, acyl reaction with hydrogen peroxide      492
 Halides, acyl reaction with hydrogen sulfide      497
 Halides, acyl reaction with hydroxylamine      507
 Halides, acyl reaction with hydroxylamine O-sulfonic acid      1413
 Halides, acyl reaction with ketones      1182
 Halides, acyl reaction with lithium nitride      507
 Halides, acyl reaction with lithium tri-t-butoxyaluminum hydride      532
 Halides, acyl reaction with organocadmium reagents      566
 Halides, acyl reaction with organocuprates      566
 Halides, acyl reaction with organometallic reagents      566
 Halides, acyl reaction with pyrophoric lead      568
 Halides, acyl reaction with thiols      497
 Halides, acyl reagents for preparation from RCOOH      523
 Halides, acyl reduction to aldehydes      532
 Halides, acyl reduction with
  , or  1551 Halides, acyl reduction, mechanism      532
 Halides, alkyl addition to alkenes      1047
 Halides, alkyl addition to conjugated compounds      1032
 Halides, alkyl addition to dienes      1047
 Halides, alkyl alkylation      477
 Halides, alkyl alkylation of alkenes by the Prins reaction      1047
 Halides, alkyl and ketone enolates, elimination      552
 Halides, alkyl and the Menshutkin reaction      499
 Halides, alkyl and the Sommelet reaction      1536
 Halides, alkyl and the Williamson reaction      477
 Halides, alkyl and the Wurtz reaction      535
 Halides, alkyl by radical substitution      907
 Halides, alkyl by the Finkelstein reaction      517 1650
 Halides, alkyl by the Hunsdiecker reaction      942—943 1651
 Halides, alkyl by the Simonini reaction      943
 Halides, alkyl by the von Braun reaction      523 1651
 Halides, alkyl carbonylation of      565
 Halides, alkyl conversion to carbamates      489
 Halides, alkyl conversion to carboxylic acids      564
 Halides, alkyl coupling with Grignard reagents      537
 Halides, alkyl coupling with organoaluminum compounds      541
 Halides, alkyl coupling with organocuprates      538
 Halides, alkyl coupling with organolithium reagents      537
 Halides, alkyl coupling with organometallics      536 540—541
 Halides, alkyl coupling with propargyl halides      543
 Halides, alkyl electrochemical reduction      525
 Halides, alkyl elimination and enantioselectivity      1338
 Halides, alkyl elimination and Zaitsev’s rule      1337
 Halides, alkyl elimination reactions      1336—1338
 Halides, alkyl elimination with DBN or DBU      1337
 Halides, alkyl elimination, and Hofmann’s rule      1337
 Halides, alkyl elimination, solvent effects      1337
 Halides, alkyl from alcohols      518 1650
 Halides, alkyl from aldehydes      1651
 Halides, alkyl from alkanes      907 1047 1651
 Halides, alkyl from alkyl halides      517
 Halides, alkyl from allylic halogenation      1651
 Halides, alkyl from amides      1651
 Halides, alkyl from amines      1651
 Halides, alkyl from aromatic compounds      1651
 Halides, alkyl from arylsilanes      1650
 Halides, alkyl from carbon tetrachloride      1651
 Halides, alkyl from carboxylic acids, reagents for      943
 Halides, alkyl from decarboxylative halogenation      1651
 Halides, alkyl from epoxides      1651
 Halides, alkyl from esters      1651
 Halides, alkyl from ethers      519 1651
 Halides, alkyl from Grignard reagents      798
 Halides, alkyl from halide exchange      1650
 Halides, alkyl from homologation of alkyl halides      1651
 Halides, alkyl from hydrogen halides      1650 1651
 Halides, alkyl from inorganic acid halides      1650
 Halides, alkyl from inorganic esters      1650
 Halides, alkyl from ketones      1651
 Halides, alkyl from methylniobium reagents      1651
 Halides, alkyl from organometallic compounds      798 1651
 Halides, alkyl from radical halogenation      1651
 Halides, alkyl from reduction of dihalides      1651
 Halides, alkyl from sulfonate esters      518
 Halides, alkyl fromalkynes      1651
 Halides, alkyl hydrogenation of      525
 Halides, alkyl hydrogenolysis of      524—525
 Halides, alkyl hydrolysis of      462
 Halides, alkyl hydrolysis to cation      366
 Halides, alkyl hydrolysis, rates      365
 Halides, alkyl ionization to carbocations      564
 Halides, alkyl oxidation with DMSO      1535
 Halides, alkyl preparation and microwaves      518
 Halides, alkyl preparation in HMPA      518
 Halides, alkyl radial addition to alkenes      1039
 Halides, alkyl rate of solvolysis      432
 Halides, alkyl, reaction with
  and  565 
 | Halides, alkyl, reaction with  and alcohols      564 Halides, alkyl, reaction with acetoacetic ester anions      549
 Halides, alkyl, reaction with acid salts      493
 Halides, alkyl, reaction with alcohols and CO      564
 Halides, alkyl, reaction with alcohols and tetramethylthiourea      496
 Halides, alkyl, reaction with alkane diazotates      516
 Halides, alkyl, reaction with alkoxides      477
 Halides, alkyl, reaction with alkoxides, MOM and MEM      478
 Halides, alkyl, reaction with alkyl halides      548
 Halides, alkyl, reaction with alkyne anions      561
 Halides, alkyl, reaction with alkynes      561 1026
 Halides, alkyl, reaction with allyl silamines      534
 Halides, alkyl, reaction with aluminum hydride reagents      525
 Halides, alkyl, reaction with amide anions      513
 Halides, alkyl, reaction with amines      499—501
 Halides, alkyl, reaction with aromatic compounds      707
 Halides, alkyl, reaction with azide ion      515
 Halides, alkyl, reaction with carbanions      548—551
 Halides, alkyl, reaction with carboxylic acid salts      488 555
 Halides, alkyl, reaction with cyanamide      501
 Halides, alkyl, reaction with cyanate ion      516
 Halides, alkyl, reaction with cyanide and phase transfer      562
 Halides, alkyl, reaction with cyanide and ultrasound      562
 Halides, alkyl, reaction with cyanide ion      561—562
 Halides, alkyl, reaction with cyanohydrins      553
 Halides, alkyl, reaction with cyclopentadienyl anion      550
 Halides, alkyl, reaction with dianion of carboxylic acids      555
 Halides, alkyl, reaction with disulfide ion      498
 Halides, alkyl, reaction with dithiane anions      556
 Halides, alkyl, reaction with enamines      555 787
 Halides, alkyl, reaction with enolate anions and vinylogy      552
 Halides, alkyl, reaction with ethers      492
 Halides, alkyl, reaction with halide ions      517
 Halides, alkyl, reaction with hexamethylenetetramme      501
 Halides, alkyl, reaction with hydrazone anions      555
 Halides, alkyl, reaction with hydrogen sulfide      495
 Halides, alkyl, reaction with hydroperoxide anion      492
 Halides, alkyl, reaction with hydroxide      463
 Halides, alkyl, reaction with ketone enolate anions      551
 Halides, alkyl, reaction with ketones      492
 Halides, alkyl, reaction with lithium      806
 Halides, alkyl, reaction with lithium triethylborohydride      525
 Halides, alkyl, reaction with magnesium      805
 Halides, alkyl, reaction with malonate anions      549
 Halides, alkyl, reaction with metals      805
 Halides, alkyl, reaction with NaSH      495
 Halides, alkyl, reaction with organocuprates      538—540
 Halides, alkyl, reaction with organolithium reagents      807
 Halides, alkyl, reaction with organolithium reagents, and CIDNP      808
 Halides, alkyl, reaction with organometallic compounds      807
 Halides, alkyl, reaction with organotin, CO, and palladium catalyst      801
 Halides, alkyl, reaction with oxazine anions      558 559
 Halides, alkyl, reaction with oximes      495
 Halides, alkyl, reaction with phosphines      501 1231
 Halides, alkyl, reaction with potassium phthalimide      513
 Halides, alkyl, reaction with sodium metal      535
 Halides, alkyl, reaction with sodium nitrite      515
 Halides, alkyl, reaction with sodium sulfide      497
 Halides, alkyl, reaction with sulfinic acid salts      498
 Halides, alkyl, reaction with sulfonamide salts      514
 Halides, alkyl, reaction with sulfone anions      555
 Halides, alkyl, reaction with sulfur      498
 Halides, alkyl, reaction with tetracarbonylferrate      562
 Halides, alkyl, reaction with thiocyanate      499 516
 Halides, alkyl, reaction with thioethers      497
 Halides, alkyl, reaction with thiol anions      496
 Halides, alkyl, reaction with thiosulfate ion      498
 Halides, alkyl, reaction with thiourea      495
 Halides, alkyl, reaction with tosylhydrazide      499
 Halides, alkyl, reaction with triarylarsines      1233
 Halides, alkyl, reaction with triarylphosphines      1233
 Halides, alkyl, reaction with vinyl sulfide anions      557
 Halides, alkyl, reactivity of halogen in Friedel — Crafts reactions      707
 Halides, alkyl, reagents for halide exchange      517
 Halides, alkyl, rearrangement in preparation from alcohols      518
 Halides, alkyl, reduction of      525
 Halides, alkyl, regioselectivity with ketone enolate anions      554
 Halides, alkyl, SET mechanism and reaction with LiAlKt      526
 Halides, alkyl, solvolysis rates      366
 Halides, alkyl, test for      494
 Halides, allylic coupling with nickel tetracarbonyl      541
 Halides, allylic reagents for coupling      542
 Halides, aryl and the halogen dance      735
 Halides, aryl and the Hurtley reaction      869
 Halides, aryl and the Rosenmund — von Braun reaction      867
 Halides, aryl and the Wurtz — Fittig reaction      535
 Halides, aryl by the Gatterman reaction      936
 Halides, aryl by the Hunsdiecker reaction      1658
 Halides, aryl by the Orton rearrangement      1658
 Halides, aryl by the Sandmeyer reaction      936 1658
 Halides, aryl by the Schiemann reaction      1658
 Halides, aryl catalysts for preparation of      502
 Halides, aryl coupling      870
 Halides, aryl dehalogenation, reagents for      735
 Halides, aryl from acyl halides      1658
 Halides, aryl from aromatic amines      936
 Halides, aryl from aromatic compounds      1658
 Halides, aryl from aryl diazonium salts      875 935—936
 Halides, aryl from aryl halide exchange      1658
 Halides, aryl from aryl halides      866
 Halides, aryl from aryl halo-de-hydroxylation      1658
 Halides, aryl from aryl halo-de-nitration      1658
 Halides, aryl from decarboxylative halogenation      1658
 Halides, aryl from diazonium salts      1658
 Halides, aryl from migration of halogen      1658
 Halides, aryl from organometallic compounds      1658
 Halides, aryl from rearrangement of N-haloamines      1658
 Halides, aryl from replacement of aromatic
  1658 Halides, aryl from replacement of aromatic COOH      1658
 Halides, aryl halide exchange      866
 Halides, aryl reaction with active methylene compounds      869
 Halides, aryl reaction with alcohols and CO      870
 Halides, aryl reaction with alkenes      930
 Halides, aryl reaction with alkoxides      862
 Halides, aryl reaction with amide anions      513
 Halides, aryl reaction with amines      501 864
 Halides, aryl reaction with amines, benzyne mechanism      864
 Halides, aryl reaction with ammonia      864
 Halides, aryl reaction with aromatic compounds      933
 Halides, aryl reaction with copper acetylides      868
 Halides, aryl reaction with copper metal      870
 Halides, aryl reaction with CuCN      867
 Halides, aryl reaction with enolate anions      860 869
 Halides, aryl reaction with halide ions      866
 Halides, aryl reaction with HS anion      863
 Halides, aryl reaction with hydroxide      861
 Halides, aryl reaction with Lewis acids      735
 Halides, aryl reaction with lithium      806
 Halides, aryl reaction with magnesium      805
 Halides, aryl reaction with metals      805
 Halides, aryl reaction with organocuprates      539 868
 Halides, aryl reaction with potassium phthalimide      865
 Halides, aryl reaction with sodium      535
 Halides, aryl reaction with sulfur nucleophiles      863
 Halides, aryl reaction with thiol anions      863
 Halides, aryl reagents for alkylation      868
 Halides, benzylic and the Krohnke reaction      1536
 Halides, benzylic from aromatic compounds      721
 Halides, benzylic oxidation of      1536
 Halides, benzylic substitution-elimination      1543
 Halides, di-      see “Dihalides”
 Halides, propargyl, coupling      543
 Halides, sulfonyl by the Reed reaction      1688
 Halides, sulfonyl elimination with amines      1338
 Halides, sulfonyl from aromatic compounds      1688
 Halides, sulfonyl from diazonium salts      1688
 Halides, sulfonyl from Grignard reagents      797 1688
 Halides, sulfonyl from radical halosulfonation      1688
 Halides, sulfonyl from sulfonic acid derivatives      1688
 Halides, sulfonyl from sulfonic acids      577 1688
 
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