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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Isonitriles and the Passerini reaction      1252
Isonitriles and the Ugi reaction      1252
Isonitriles from $Me_3SiCN$      1677
Isonitriles from alkyl halides      562 1677
Isonitriles from amides      1350
Isonitriles from amines      506 1677
Isonitriles from chloroform      1677
Isonitriles from epoxides      1677
Isonitriles from formamides      1350
Isonitriles from isocyanates      1557 1677
Isonitriles from N-alkylformamides      1677
Isonitriles from oxetanes      1677
Isonitriles from substitution reactions with cyanide      459
Isonitriles reaction with carbonyls and carboxylic acids      1251
Isonitriles reaction with Grignard reagents      1252
Isonitriles reaction with organolithium reagents      1252
Isonitriles reaction with Schwartz’s reagent      1038
Isonitriles reaction with water      1251
Isonitriles rearrangement of      1421
Isonitriles reduction of      1204
Isopentane, bond energy      23
Isopropenyl formate, reaction with amines      511
Isopropyl acetate, reaction with ketones      487
Isopropyl fluoroantimonate      786
Isopropylbenzene      see “Cumene”
Isopropyllithium      236
Isoquinolines, by the Bischler-Napieralski reaction      721
Isoracemization      765
Isothiocyanates from alkyl halides      516
Isothiocyanates from amines      507 1192 1677
Isothiocyanates from diazonium salts      1677
Isothiocyanates from thiocyanate ion      1677
Isothiocyanates from thiophosgene      1677
Isothiocyanates hydrolysis of      1178
Isothiocyanates reaction with alcohols      1183
Isothiocyanates reaction with amines      1191
Isothiocyanates reaction with aromatic compounds      719
Isothiocyanates reaction with Grignard reagents      1218
Isothiocyanates reduction of      1203
Isothiocyanates reduction with $LiAlH_4$      1555
Isothiouronium salts, from thiourea and alkyl halides      495 1677
Isotope effects and $S_N1$ mechanisms for aromatic compounds      853
Isotope effects and electrophilic aromatic substitution      676
Isotope effects and ester hydrolysis      472
Isotope effects and hyperconjugation      299
Isotope effects and mechanism      297—300
Isotope effects and solvent      299
Isotope effects deuterium      297
Isotope effects deuterium, on nucleophilic substitution      438
Isotope effects for $S_N2$ and $S_N1$ reactions      299
Isotope effects in carbocations      220
Isotope effects in Diels — Alder reactions      1067
Isotope effects in enol ether hydrolysis      468
Isotope effects in the $S_N Ar$ mechanism      852
Isotope effects in the e2 elimination      1304
Isotope effects inverse      298
Isotope effects primary      298
Isotope effects secondary      298
Isotopic exchange isoracemization      765
Isotopic exchange rate, for carbanions      765
Isotopic labeling      see “Labeling”
Isotopic labeling and mechanism      289—290
Isovalent hyperconjugation      73
IUPAC mechanism nomenclature $S_E1$      681
IUPAC mechanism nomenclature $S_E2$      760
IUPAC mechanism nomenclature $S_Ei$      760
IUPAC mechanism nomenclature $S_{RN}1$      856
IUPAC mechanism nomenclature amide hydrolysis      476
IUPAC mechanism nomenclature and carbocations      219
IUPAC mechanism nomenclature arenium ion      675
IUPAC mechanism nomenclature ester formation      485
IUPAC mechanism nomenclature ester hydrolysis      471—472
IUPAC mechanism nomenclature nucleophilic addition to alkenes      975
IUPAC mechanism nomenclature pyrolytic eliminations      1323
IUPAC nomenclature for mechanisms      384
IUPAC nomenclature for transformations      382
Jablonski diagram      313—314
Jacobsen reaction      734
Jacobsen — Katsuki epoxidation      1053
Japp — Klingemann reaction      779
Johnson polyene cyclization      1019
Jones reagent      1514 1531
Jones reagent with $OsO_4$, and oxidative cleavage      1526
Journals in chemistry      1608—1609
Journals review      1620
K      see “Equilibrium constant”
Katritzky pyrylium-pyridinium method      447 489 499
Katritzky pyrylium-pyridinium method and enolate anions      551
Katritzky pyrylium-pyridinium method, preparation of alkyl iodides      522
Katritzky pyrylium-pyridinium method, reduction of amines      530
KCN      see “Cyanide potassium”
Kekulene, and aromaticity      66
Keryls and Gomberg — Bachmann pinacol synthesis      1560
Keryls and radical ions      247
Keryls dimerization of      1560
Keryls in reduction of aldehydes or ketones with Na/EtOH      1199
Ketals and enol ether formation      1181
Ketals and transacetalation      1181
Ketals by the Prins reaction      1642
Ketals by transetherification      1642
Ketals from $\alpha$-halo ethers      1642
Ketals from $\beta$-hydroxy ethers      1642
Ketals from alcohols      1180 1642
Ketals from aldehydes      1642
Ketals from alkenes      1642
Ketals from alkoxides      1642
Ketals from alkynes      1642
Ketals from diazoalkanes      1642
Ketals from dihalides      1642
Ketals from Grignard reagents      1642
Ketals from ketones      1180 1642
Ketals from ortho esters      1642
Ketals from phenols      1642
Ketals hydrogenolysis, reagents for      528
Ketene acetals      see “Acetals ketene”
Ketene dimerization of      1249
Ketene photolysis of      250 319
Ketene reaction with cyclopentadiene      1080
Ketenes by the Wolff rearrangement      1677
Ketenes from dehalogenation of $\alpha$-halo acyl halides      1677
Ketenes from dehydrohalogenation of acyl halides      1677
Ketenes from halo acyl halides      1344
Ketenes from pyrolysis of carboxylic acids      1677
Ketenes from rearrangement of diazo ketones      1677
Ketenes from sulfonyl halides      1338
Ketenes in [2+2]-cycloadditions      1077
Ketenes reaction with aldehydes or ketones      1249
Ketenes reaction with alkenes      1077
Ketenes reaction with allenes      1077
Ketenes reaction with amines      1001
Ketenes reaction with HX      992
Ketenes reaction with hydrazones      1250
Ketenes reaction with imines      1250
Ketenes reaction with phosphorus ylids      1237
Ketenimines      see “Imines”
Keto acids, from ketones      1229
Keto aldehydes and internal Cannizzaro reactions      1565
Keto aldehydes oxidative cleavage      1520
Keto esters acyl cleavage      812
Keto esters aryl, photolysis of      1532
Keto esters by the Blaise reaction      1213
Keto esters from aldehydes      785
Keto esters from alkenes      1058
Keto esters from bromo esters      1213
Keto esters from diazo esters      785
Keto esters from esters      1213
Keto esters reaction with hydrazines      1193
Keto oximes, dehydration      1349
Keto sulfoxides, alkylation of      549
Keto-enol tautomerism      73—75 773—775 976
Keto-enol tautomerism and the Bucherer reaction      865
Ketocarbene intermediates in Wolff rearrangement      1407
Ketol rearrangement      1401
Ketone dithioketals, hydrolysis of      468
Ketone enolate anions, reaction with esters      571
Ketone esters      567
Ketone, halo      see “Halo ketones”
Ketone, methyl vinyl and the Robinson annulation      1222
Ketone, methyl vinyl, reaction with borane      1031
Ketone-alkenes, from keto acids      944
Ketones $\alpha$-dithiomethylene      1229
Ketones $\alpha$-oxidation      1531
Ketones $\alpha$-oxidation with selenium dioxide      1531
Ketones acylation of      569
Ketones acyloxy      1643
Ketones acyloxylation of      923
Ketones addition of boranes      1210
Ketones and Gomberg — Bachmann pinacol synthesis      1560
Ketones and hydroxyalkylation of aromatic rings      719
Ketones and keto-enol tautomerism      774
Ketones and radical cyclization      1244
Ketones and reduction to form a chiral center      1200
Ketones and the Baeyer — Villiger rearrangement      1417
Ketones and the Barbier reaction      1205
Ketones and the BouveauIt — Blanc reaction      1199
Ketones and the Claisen reaction      1224
Ketones and the Darzen’s glycidic ester condensation      1230
Ketones and the Eschweiler — Clarke reaction      1188
Ketones and the Fischer indole synthesis      1453
Ketones and the Friedlander quinoline synthesis      1186
Ketones and the Knoevenagel reaction      1225—1228
Ketones and the Leuckart reaction      1188
Ketones and the Meerwein — Ponndorf — Verley reduction      1199
Ketones and the Passerini reaction      1252
Ketones and the Paterno — Buchi reaction      1249
Ketones and the Robins on annulation      1222
Ketones and the Wallach reaction      1188
Ketones aryl methyl, oxidation to phenolic esters      1528
Ketones aryl, from aromatic compounds      722
Ketones aryl, from nitriles      722
Ketones aryl, oxidation of      1528
Ketones asymmetric induction during reduction      1200
Ketones asymmetric reduction with Alpine-borane      1201
Ketones by Friedel — Crafts acylation      1678
Ketones by Friedel — Crafts ring closure      720
Ketones by Oppenauer oxidation      1516
Ketones by oxidation with Bacillus stearvthermophilus      1517
Ketones by radical cyclization      1244
Ketones by retro-aldol condensation      808
Ketones by sulfene intermediates      1338
Ketones by Swern oxidation      1516
Ketones by the Dakin — West reaction      1678
Ketones by the Dess — Martin periodinane      1516
Ketones by the Fries rearrangement      1678
Ketones by the Hoesch reaction      1678
Ketones by the Hofmann rearrangement      1679
Ketones by the Michael reaction      1679
Ketones by the Nef reaction      1178 1679
Ketones by the Oppenauer oxidation      1199
Ketones by the pinacol rearrangement      1679
Ketones by the Stork enamine synthesis      1678
Ketones by the Tiffeneau — Demyanov reaction      1679
Ketones by the Wacker process      1538
Ketones by [1,3] sigmatropic rearrangements      1679
Ketones catalytic hydrogenation      1198
Ketones chemoselective reduction      1198
Ketones chiral, in the aldol reaction      1222
Ketones chloro, and Favorskii rearrangement      1403
Ketones chloro, rearrangement with base      1403
Ketones cleavage of      813
Ketones cleavage with amide bases      814
Ketones diastereoselectivity in reduction      1201
Ketones diazo, hydrolysis of      465
Ketones dissolving metal reductions      1199—1200
Ketones enolates      also see “Enolate anions”
Ketones enzymatic oxidation      1533
Ketones from $\alpha$-hydroxy or $\alpha$-halo amides and NaOBr      1679
Ketones from $\beta$-diketones      1678
Ketones from $\beta$-keto acids      1678
Ketones from $\beta$-keto esters      1678
Ketones from $\gamma$-amino halides      1679
Ketones from $\gamma$-hydroxy halides      1679
Ketones from 1,2-or 1,3-diols      1679
Ketones from acetoacetic ester synthesis      1678
Ketones from acid derivatives      567 1678
Ketones from active methylene compounds      1678 1680
Ketones from acyl halides      566 1678
Ketones from alcohols      487 1514—1517
Ketones from aldehydes      556 785 1033 1038 1678 1679
Ketones from alkene-alcohols      773
Ketones from alkoxides      1678
Ketones from alkyl halides      787 1678 1679 1680
Ketones from alkyne ketones      1031
Ketones from allenes      996
Ketones from allylic alcohols      1678
Ketones from allylic vinylic ethers      1679
Ketones from amines      1680
Ketones from amino acids      1678
Ketones from anhydrides      1678
Ketones from aromatic compounds      1678
Ketones from aryl diazonium salts      938
Ketones from aryl iodides      1678
Ketones from aryl nitriles      1530
Ketones from boranes      1678 1679
Ketones from boron-stabilized carbanions      1678
Ketones from bromohydrins      1399
Ketones from carbamates      1215
Ketones from carboxylic acid salts      1678
Ketones from carboxylic acids      568 573 1213 1327
Ketones from conjugated ketones      1027
Ketones from cycloalkenes      1539
Ketones from dialkylamino nitriles      1531
Ketones from dialkylchloroboranes      1679
Ketones from diarylmethanes      1680
Ketones from diazo ketones      1678
Ketones from diazonium salts      1679
Ketones from dimetallic compounds      1678
Ketones from dithianes      556 1678
Ketones from enamines      787 1678
Ketones from enol ethers      487
Ketones from epoxides      1398
Ketones from esters      549
Ketones from glycols      1679
Ketones from Grignard reagents      1679
Ketones from halo ketones      1678
Ketones from heterocycles      1678
Ketones from homologation of aldehydes      1679
Ketones from homologation of ketones      1679
Ketones from hydration of alkynes      1679
Ketones from hydration of allenes      1679
Ketones from hydrolysis of bicyclo[4.1.0]heptanes      1679
Ketones from hydrolysis of C=N compounds      1679
Ketones from hydrolysis of dihalides      1678
Ketones from hydrolysis of enol esters      1678
Ketones from hydrolysis of enol esters of inorganic acids      1678
Ketones from hydrolysis of enol ethers      1678
Ketones from hydrolysis of epoxy silanes      1679
Ketones from hydrolysis of hydrazones      1679
Ketones from hydrolysis of imines      1536 1679
Ketones from hydrolysis of ketals      1678
Ketones from hydrolysis of nitro compounds      1679
Ketones from hydrolysis of oximes      1679
Ketones from hydrolysis of thioketals      1678
Ketones from hydrolysis of unsaturated boranes      1679
Ketones from hydrolysis of vinylic halides      1678
Ketones from hydroperoxides      1418 1679
Ketones from hydroxy amines      1399
Ketones from imines      1177 1679
Ketones from keto sulfoxides      549
Ketones from ketone rearrangements      1679
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