Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure :: Электронная библиотека попечительского совета мехмата МГУ

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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

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Lactones from cyclic anhydrides      1681
Lactones from cyclic ethers      1680
Lactones from cyclic ketones      1680
Lactones from cyclic peroxides      1680
Lactones from dialdehydes      1564 1681
Lactones from halo acids      488 1680
Lactones from hydroxy acids      484 1680
Lactones from ketenes      1249 1680
Lactones from ketones      1249 1680
Lactones from lactones      1465
Lactones from manganese(III) acetate      1680
Lactones from N-iodoamines      1463
Lactones from peroxides      1355
Lactones from phosphoranes      1680
Lactones from rearrangement of N-halo amides      1680
Lactones from unsaturated alcohols      1680
Lactones fromalkenes      1036 1059 1680
Lactones fromdiols      1537 1681
Lactones hydrolysis      470
Lactones macrocyclic      484
Lactones pyrolysis of      1330
Lactones reaction with alcohols      487
Lactones reaction with amides      510
Lactones reactions with silanes      535
Lactones reduction to cyclic ethers      1548
Lactones reduction to diols      1551
Lactones reduction to ethers      1550
Lactonization      484
Lactonization and kinetics      281
Lactonization and the Mukaiyama reagent      485
Lactonization halo- and iodo-      1043
Lanosterol      1019
Lanthanide catalysts, reaction of i mines and diazoalkanes      1217
Lanthanide shift reagents, and diastereotopic atoms      165
Lanthanides, as chiral shift reagents      156
Lanthanum triflate, in the Diels — Alder reaction      1065
Large rings, and strain      185
Large-angle strain      184
Lariat ethers      107 (also see “Cryptands”)
Lawesson’s reagent and amide formation      509
Lawesson’s reagent and cleavage of phosphonate esters      1331
Lawesson’s reagent reaction with alcohols      496
Lawesson’s reagent reaction with aldehydes or ketones      1184
LCAO model      5
LDA      see “Lithium diisopropylamide”
Lead tetraacetate and formation of aryl esters      870
Lead tetraacetate oxidative cleavage of diols      1520
Lead tetraacetate reaction with alcohols      919
Lead tetraacetate reaction with alkenes and disulfides      1055
Lead tetraacetate reaction with amines      1417
Lead tetraacetate reaction with carboxylic acids, and cupric acetate      1528
Lead tetraacetate reaction with dicarboxylic acids      1530
Lead tetraacetate reaction with hydrazones      870
Lead, pyrophoric, reaction with acyl halides      568
Leaving group effects and El elimination      1307
Leaving group effects and electrophilic aromatic substitution      695
Leaving group effects and nucleophilic aromatic substitution      860
Leaving group effects in elimination reactions      1321
Leaving groups amine ditosylates      447
Leaving groups and basicity      445
Leaving groups and mechanism      275
Leaving groups and reactivity of acid derivatives      449
Leaving groups and ring strain      446
Leaving groups and the reaction      764
Leaving groups and the reaction      860
Leaving groups at acyl carbon      448
Leaving groups effect on reactions      768
Leaving groups effect on substitution reactions      445—449
Leaving groups halonium ions      446
Leaving groups order of ability to leave      449
Leaving groups the nucleofuge      389
Lederer — Manasse reaction      719
Lemieux — von Rudloff reagent      1526
Leuckart reaction      1188
Levo isomers, and chirality      125
Lewis acid catalysts acylation of aldehydes or ketones      1245
Lewis acid catalysts and acylation of alkenes      784
Lewis acid catalysts and Claisen rearrangement      1452
Lewis acid catalysts and diazomethane homologation of aldehydes or ketones      1408
Lewis acid catalysts and dithioketal formation      1182
Lewis acid catalysts and formation of acetals or ketals      1180
Lewis acid catalysts and formation of keto esters      785
Lewis acid catalysts and Friedel — Crafts acylation      712—714
Lewis acid catalysts and Friedel — Crafts alkylation      707
Lewis acid catalysts and heteroatom Diels — Alder reactions      1075
Lewis acid catalysts and reaction of aldehydes with allylsilanes      1211
Lewis acid catalysts and reaction of alkyl halides with alkenes      1047
Lewis acid catalysts and the aldol reaction      1221
Lewis acid catalysts and the Beckmann rearrangement      1415
Lewis acid catalysts and the Curtius rearrangement      1412
Lewis acid catalysts and the Fischer indole synthesis      1452
Lewis acid catalysts and the Prins reaction      1242
Lewis acid catalysts and [2+2]-cycloadditions      1083
Lewis acid catalysts for Friedel — Crafts reactions      708
Lewis acid catalysts in the Diels — Alder reaction      1065
Lewis acid catalysts with aldehydes and allyl silanes      1239
Lewis acid catalysts with ketenes and aldehydes or ketones      1249
Lewis acid, definition      339
Lewis acids ab initio study      339
Lewis acids and aromatic halogenation      706
Lewis acids and ate complexes      339
Lewis acids and cleavage of aromatic compounds      731
Lewis acids and cleavage of ethers      520
Lewis acids and reaction of ketones with silyl enol ethers      552
Lewis acids and the periodic table      345
Lewis acids and the Schmidt reaction      1413
Lewis acids and Wagner — Meerwein rearrangements      1396
Lewis acids coordination and conformational effects      348
Lewis acids hard-soft acid bases      338—342
Lewis acids reaction with acetals      467
Lewis acids reaction with alkyl halides      710
Lewis acids strengths      340
Lewis bases and ate complexes      339
Lewis bases hard-soft, acid-basses      338—342
Lewis bases Lewis structures      12 32
LFER      see “Linear free energy relationship”
LIDAKOR, reaction with epoxides      1329
Light and chemical reactions      306
Light circularly polarized, and reactions      150
Limiting reaction      394
Limonene and reduction of nitrites with Pd-C      1556
Limonene reaction with singlet oxygen      921
Limonylborane      1015
Lindlar catalyst, and hydrogenation of alkynes      1004
Linear free energy relationship      370
Lithiation of thioethers      941
Lithiation ortho      792
Lithium aluminum hydride and in coupling reactions      544
Lithium aluminum hydride and reduction of aldehydes or ketones      1197
Lithium aluminum hydride complex with carbonyls      1202
Lithium aluminum hydride disproportionation in reduction of carbonyls      1202
Lithium aluminum hydride ease of reduction of functional groups      1545
Lithium aluminum hydride reaction with amides      533
Lithium aluminum hydride reaction with ammonium salts      530
Lithium aluminum hydride reaction with epoxides      529
Lithium aluminum hydride reaction with imidazoles      534
Lithium aluminum hydride reaction with propargylic halides      525
Lithium aluminum hydride reaction with tosylates      526
Lithium aluminum hydride rednction of nitriles      1204
Lithium aluminum hydride rednction of sulfoxides      1557
Lithium aluminum hydride reduction of amines      1549
Lithium aluminum hydride reduction of anhydrides      1551
Lithium aluminum hydride reduction of aryl nitro compound      1563
Lithium aluminum hydride reduction of azides      1555
Lithium aluminum hydride reduction of azo compounds      1556
Lithium aluminum hydride reduction of carboxylic acids      1549
Lithium aluminum hydride reduction of diazonium salts      1556
Lithium aluminum hydride reduction of esters      1551
Lithium aluminum hydride reduction of imhies      1203
Lithium aluminum hydride reduction of iminium salts      1203

Lithium aluminum hydride reduction of iodo azides      1046
Lithium aluminum hydride reduction of isocyanates      1555
Lithium aluminum hydride reduction of isothiocyanates      1555
Lithium aluminum hydride reduction of N-nitroso amines      1556
Lithium aluminum hydride reduction of oximes      1554—1555
Lithium aluminum hydride reduction of sulfone carbanions      1355
Lithium aluminum hydride reduction of sulfonyl halides      1556
Lithium aluminum hydride reduction of the C-S bond      531
Lithium aluminum hydride reduction to hydroperoxides      1558
Lithium and amines, reduction of carboxylic acids      532
Lithium and amines, reduction of esters      529
Lithium and Birch reduction      1012
Lithium and reduction of aromatic compounds      1009
Lithium borohydride, and reactions of borane and CO      1424
Lithium dicyclohexylamide, with dihalides and carbonyl compounds      1207
Lithium diisopropylamide and formation of ketone enolates      551
Lithium diisopropylamide formation of enolate anions      793
Lithium diisopropylamide reaction with aldehydes and then immes      1222
Lithium diisopropylamide reaction with aziridino hydrazones      1335
Lithium diisopropylamide reaction with esters      1224
Lithium diisopropylamide reaction with ketones      786
Lithium diisopropylamide structure      348
Lithium diphenylphosphide, elimination of epoxides      1341
Lithium ditrifylamide      1155 (ref. 1223)
Lithium hexamethyldisilazide, structure      349
Lithium iodide, reaction with esters      521
Lithium naphthalenide, reaction with thioethers      941
Lithium nitride, reaction with acyl halides      507
Lithium perchlorate in ether, and the Diels — Alder reaction      1066
Lithium perchlorate special salt effect      399 452
Lithium phenoxide, and structure      349
Lithium tetramethylpiperidide, structure      348
Lithium tri-f-butoxyaluminum hydride, reaction with acyl halides      532
Lithium triethylborohydride, reaction with alkyl halides      525
Long range nucleophilic rearrangements      1387—1388
Loose ion pairs      398
Lossen rearrangement      1380 1413
Lowest unoccupied molecular orbital      see “LUMO”
LUMO alkenes      1070
LUMO and Diels — Alder reactions      1070
Lyonium ion      335
M effect      see “$esonance effect”
m-Aminoanisole, from o-bromoanisole      854
m-Chloronitrobenzene, chlorination and the ortho effect      688
m-Chloroperoxybenzoic acid and formation of isocyanates      516
m-Chloroperoxybenzoic acid reaction with alkenes      1051
Magnesium and elimination of dihalides      1343
Magnesium and Grignard reagents      1205
Magnesium and pinacol coupling      1560
Magnesium and the Barbier reaction      1205
Magnesium monoperoxyphthalate      1054
magnesium, reaction with ketones      1229
Maleic acid properties      159
Maleic acid reaction with bromine      972
Maleic acid reaction with thionyl chloride      391
Maleic anhydride, in the Diels — Alder reaction      1062
Malic acid reaction with       391
Malonate      see “Malonic ester”
Malonate esters, reaction with dihalides      550
Malonic acids      491
Malonic acids dimethyl ester,       347
Malonic acids oxidative decarboxylation      1530
Malonic ester synthesis      549
Malonic ester synthesis an alternative      556
Malonic ester synthesis aryl derivatives      720
Malonic ester, reaction with diazonium salts      779
Malonic esters, alkylation      549
Manganese (III) acetate, reaction with alkenes      1059
Manganese dioxide and microwaves      1572 (ref. 53)
Manganese dioxide oxidation of thioethers      1542
Manganese salen and epoxidation of alkenes      1053
Manganese salen and oxidation of ketones      1531 1533
Mannich bases      1189
Mannich bases and enolate anion alkylation      550
Mannich bases and Michael reactions      1023
Mannich bases as a leaving group      550
Mannich bases reaction with aldehydes      1189
Mannich bases with leaving groups      447
Mannich reaction      1189
Mannich reaction and aminoalkylation      722
Mannich reaction and Eschenmoser’s salt      1191
Mannich reaction and the Strecker synthesis      1240
Mannich reaction diastereoselectivity      1191
Mannich reaction mechanism of      1190
Mannich reaction regioselectivity      1190
Marcus equation      337
Marcus equation and the Bronsted law      338
Marcus theory      286—287
Marcus theory and the Swain — Scott equation      444
Markovnikov, anti      see “Anti-Markovnikov”
Markovnikov’s rule      984 (also see “Regioselectivity”)
Markovnikov’s rule addition of carboxylic acids to alkenes      997
Markovnikov’s rule and acylation of alkenes      784
Markovnikov’s rule and addition of alcohols to alkenes      996
Markovnikov’s rule and addition of borane to alkenes      1013
Markovnikov’s rule and addition of HX to alkenes      991
Markovnikov’s rule and addition to cyclopropanes      989
Markovnikov’s rule and Friedel — Crafts alkylation with alkenes      710
Markovnikov’s rule and reaction of alkenes with alkyl halides      1047
Markovnikov’s rule and reaction of alkenes with anhydrides      1059
Markovnikov’s rule and reaction of alkenes with hypohalous acids      1044
Markovnikov’s rule and reaction of alkenes with NOCl      1046
Markovnikov’s rule and reactions of alkenes, CO, and water      1036
Markovnikov’s rule and the Prins reaction      1242
Markovnikov’s rule and the Wacker process      1538
Markovnikov’s rule and transmetallation      803
Markovnikov’s rule reaction of alkynes with HX      992
Masked reagents      1216
Masochistic steric effects      1080
Mass law effect      395
Mass spectrometry, and the reaction      392
Matrix trapping, of cyclobutadiene      59
McFadyen — Stevens reduction      534
McMurry reaction      1561
Mcpba      see “Chloro(m-)peroxybenzoic acid”
Mechanical separation, and resolution      153
Mechanisms reduction of aldehydes and ketones      1202
Mechanisms       763—766
Mechanisms , and carboxylate ion decarboxylation      733
Mechanisms , and electrophilic aromatic substitution      676
Mechanisms , and electropliilic aromatic substitution      681
Mechanisms , and ion pairs      768
Mechanisms , H-D exchange in hydrocarbons      770
Mechanisms       759—763
Mechanisms       760
Mechanisms       759—763
Mechanisms $\alpha$ -oxidation of ketones with       1531
Mechanisms $\pi$ -allyl complex      772
Mechanisms $\sigma$ -substitution      702
Mechanisms acetal and ketal formation      1180
Mechanisms acid catalyzed rearrangement of hydroperoxides      1418
Mechanisms acid chromate oxidation of alcohols      1517
Mechanisms acyl halide hydrolysis      469
Mechanisms acylation of alkenes      784
Mechanisms acylation of amines      511
Mechanisms acyloin condensation      1563
Mechanisms acyloxylation of hydrocarbons      923
Mechanisms addition      276
Mechanisms addition of alkanes to alkenes      1017—1018
Mechanisms addition of boranes to alkenes      1016
Mechanisms addition of protons to alkenes      974
Mechanisms aldehyde oxidation      917
Mechanisms aldol reaction      1220
Mechanisms alkene metathesis      1458—1459
Mechanisms alkenes, and nickel tetracarbonyl      1036
Mechanisms alkyl halides with alkoxides      477
Mechanisms alkyne trimerization      1090
Mechanisms amide hydrolysis      475
Mechanisms and anchimeric assistance      404
Mechanisms and arenium ions      411

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