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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Mechanisms and bromomum ions      971
Mechanisms and catalysis      289
Mechanisms and electrofuge      385
Mechanisms and emission spectroscopy      321
Mechanisms and equilibrium      293
Mechanisms and first order reaction      291
Mechanisms and formation of thioethers      496
Mechanisms and half-life      294—295
Mechanisms and heterolytic bond cleavage      274
Mechanisms and homolytic bond cleavage      275
Mechanisms and isotopic effects      297—300
Mechanisms and isotopic labeling      289—290
Mechanisms and kinetics      290—296
Mechanisms and leaving group      275
Mechanisms and Marcus theory      286—287
Mechanisms and microscopic reversibility      285—286
Mechanisms and molecularlity      291
Mechanisms and nucleofuge      275 385
Mechanisms and phenonium ions      411 413
Mechanisms and primary isotope effects      298
Mechanisms and product determination      287
Mechanisms and rate constants      291
Mechanisms and rate determining step      291—292
Mechanisms and rate law      290
Mechanisms and second order reaction      291
Mechanisms and secondary isotope effects      298
Mechanisms and solvent isotope effects      299
Mechanisms and steady state approximation      292
Mechanisms and stereochemistry      290
Mechanisms and symproportionation      1017
Mechanisms and the Hammond postulate      285
Mechanisms and third order reactions      291
Mechanisms anhydride hydrolysis      469
Mechanisms arenium ion mechanism      675—680
Mechanisms arenium ion, mercuration of aryl compounds      793
Mechanisms aromatic compound cleavage      731
Mechanisms aromatic compounds and acyl peroxides      932
Mechanisms aromatic formylation      715
Mechanisms aromatic radical substitution      898
Mechanisms aromatic sulfonation      702
Mechanisms aryl halides with alkoxides      862
Mechanisms arylation of aryl diazonium salts      929
Mechanisms azides with active methylene compounds      781
Mechanisms Baeyer — Villager rearrangement      1418
Mechanisms Bamberger rearrangement      879
Mechanisms Bamford — Stevens reaction      1335
Mechanisms Barton reaction      1463
Mechanisms Beckmann rearrangement      1416
Mechanisms benzidine rearrangement      1455—1456
Mechanisms benzoin condensation      1243
Mechanisms benzyne, and aromatic substitution      854
Mechanisms bimolecular      759—763
Mechanisms bimolecular, $S_N2$      390
Mechanisms biradical, for Diels — Alder reactions      1067
Mechanisms Birch reduction of aromatic compounds      1010
Mechanisms bisdecarboxylation of dicarboxylic acids      1530
Mechanisms borane and hydroperoxide anion      797
Mechanisms borane reaction with halo carbonyls      560
Mechanisms boranes, elimination with alkenes      1339
Mechanisms Bucherer reaction      865
Mechanisms Cannizzaro reaction      1565
Mechanisms carbamate hydrolysis      474
Mechanisms carbanion, elimination      1308—1312
Mechanisms carbene disproportionation      790
Mechanisms carbene insertion      789 1086 1087
Mechanisms carbocations and hydrocarbons      786
Mechanisms Chapman rearrangement      1464
Mechanisms Claisen condensation      570
Mechanisms Claisen reaction      1224
Mechanisms Claisen rearrangement      1449—1450
Mechanisms concentration of reactants      293—294
Mechanisms conducted tour mechanism      766
Mechanisms conducted tour, and double bond migration      771
Mechanisms conversion of isocyanates to carbodiimides      1246
Mechanisms Cope elimination      1333
Mechanisms Cope rearrangement      1446—1447
Mechanisms coupling of boranes      939
Mechanisms Criegee, for ozonolysis      1523—1525
Mechanisms Curtius rearrangement      1412
Mechanisms cyanoborohydride reduction of tosylhydrazones      1548
Mechanisms cyclic, and addition to alkenes      979
Mechanisms cyclic, and the Prins reaction      1242
Mechanisms cyclobutane cycloreversion      1081
Mechanisms Dakin reaction      1528
Mechanisms decarbonylation of aldehydes      945
Mechanisms decarboxylation of aryl carboxylic acids      733
Mechanisms decarboxylation of carboxylate ions      733
Mechanisms decarboxylation of glycidic acids      809
Mechanisms decarboxylation of keto acids      810
Mechanisms definition      274
Mechanisms dehydration of oxime tosylates      1349
Mechanisms detection of intermediates      288—289
Mechanisms determination of      287—300
Mechanisms di-$\pi$- methane rearrangements      1461
Mechanisms diazo transfer with active methylene compounds      781
Mechanisms diazoalkanes and alcohols      479
Mechanisms diazomethane homologation of aldehydes and ketones      1407
Mechanisms diazotization of aromatic amines      817
Mechanisms dichromate oxidation of aldehydes      918
Mechanisms Dieckmann condensation      570
Mechanisms Diels — Alder reactions      1066—1067
Mechanisms dihydroxylation of alkenes with $H_2O_2$      1049
Mechanisms diimide reduction of alkenes      1007
Mechanisms diion, and ketene-imine cycloaddition      1250
Mechanisms diion, for [2+2]-cycloadditions      1080
Mechanisms dimer mechanism and $S_NAr$      852
Mechanisms diradical, and carbene insertion to alkenes      1087
Mechanisms diradical, and Cope rearrangement      1447
Mechanisms diradical, and cyclobutane cycloreversion      1081
Mechanisms diradical, for [2+2]-cycloadditions      1080
Mechanisms DMSO oxidation of alkyl halides      1536
Mechanisms E1      1306—1308
Mechanisms E1cB      1308—1312
Mechanisms E2      1300—1306
Mechanisms E2C      1313
Mechanisms Eglinton reaction      928
Mechanisms electrocyclic rearrangements      1427
Mechanisms electrophilic      274
Mechanisms electrophilic addition to alkenes      970—975
Mechanisms electrophilic addition to cyclopropanes      989
Mechanisms elimination      276
Mechanisms elimination of alkyl halides      1337
Mechanisms elimination of epoxides with $PPh_3$      1341
Mechanisms elimination-addition, at vinyl carbon      430
Mechanisms ene reaction      1022
Mechanisms enol ester hydrolysis      474
Mechanisms enolate anion alkylations      550
Mechanisms ester formation      485
Mechanisms ester formation with DCC      485
Mechanisms ester hydrolysis      470—473
Mechanisms Etard reaction      1534
Mechanisms Favorskii rearrangement      1403
Mechanisms Fischer indole synthesis      1453
Mechanisms flash photolysis      321
Mechanisms fragmentation of alkene alcohols      1351
Mechanisms free radical      275
Mechanisms free radical substitution      896
Mechanisms Friedel — Crafts acylation      714
Mechanisms Friedel — Crafts alkylation      710—711
Mechanisms Fries rearrangement      727
Mechanisms gem-dichloride formation from aldehydes or ketones      1196
Mechanisms Glaser reaction      928
Mechanisms Gomberg — Bachmann pinacol synthesis      1560
Mechanisms Grignard reaction with aldehydes and ketones      1208
Mechanisms haloform reaction      813
Mechanisms halogenation of enolate anions      776
Mechanisms halogenation of ketones and aldehydes      776
Mechanisms halogenation of organometallic compounds      799
Mechanisms Heck reaction      931
Mechanisms heterogeneous catalytic hydrogenation of alkenes      1005
Mechanisms Hofmann elimination      1332
Mechanisms Hofmann rearrangement      1411
Mechanisms Hofmann — Loffler reaction      1462
Mechanisms homogeneous catalytic hydrogenation of alkenes      1006
Mechanisms Hunsdiecker reaction      943
Mechanisms hydrate formation      1176
Mechanisms hydration of alkenes      993
Mechanisms hydrolysis of $\beta$-lactones      473
Mechanisms hydrolysis of $\gamma$-lactones      473
Mechanisms hydrolysis of C=N compounds      1177
Mechanisms hydrolysis of enamines      1178
Mechanisms interfacial, phase transfer catalysis      455
Mechanisms ion pairs and [2,3] sigmatropic rearrangement      1454
Mechanisms ion-pair and substitution      400
Mechanisms ion-pair and the Sommelet — Hauser rearrangement      878
Mechanisms ketene-imine cycloaddition      1250
Mechanisms keto-enol tautomerism, catalyzed      774
Mechanisms ketones and diazonium salts      780
Mechanisms Kolbe reaction      942
Mechanisms lead tetraacetate oxidation of alcohols      919
Mechanisms Lossen rearrangement      1413
Mechanisms Mannich reaction      1190
Mechanisms Meerwein arylation      930
Mechanisms metal hydride addition-elimination      772
Mechanisms mixed $S_N1-S_N2$      400—402
Mechanisms Neber rearrangement      1410
Mechanisms Nef reaction      1178
Mechanisms neighboring-group      404—407
Mechanisms nonsynchronous, and [3+2]-cycloadditions      1061
Mechanisms nucleophilic      275
Mechanisms nucleophilic addition to alkenes      975—976
Mechanisms nucleophilic rearrangements      1378—1388
Mechanisms organocuprate conjugate addition      1030
Mechanisms organolithium reagents and alkyl halides      807
Mechanisms organolithiums with aldehydes or ketones      1209
Mechanisms oxidation of alkyl side chains on aromatic rings      1528
Mechanisms oxidation of aromatic amides with Caro’s acid      1539
Mechanisms oxidation of aromatic diols      1518
Mechanisms oxidation of hydroquinones      1511
Mechanisms oxidation of selenoxides to selenones      1542
Mechanisms oxidation with Fenton’s reagent      917
Mechanisms oxidation-reduction      277
Mechanisms oxidation-reduction, addition-elimination      1509
Mechanisms oxidation-reduction, and direct electron transfer      1508
Mechanisms oxidation-reduction, and ester intermediates      1508
Mechanisms oxidation-reduction, displacement      1509
Mechanisms oxidation-reduction, hydride transfer      1508
Mechanisms oxidation-reduction, hydrogen atom transfer      1508
Mechanisms oxidative cleavage of alkenes      1526
Mechanisms oxidative cleavage of diols with lead tetraacetate      1520—1521
Mechanisms oxidative decarboxylation of carboxylic acids      1529
Mechanisms ozonolysis of alkenes      1523—1525
Mechanisms Passerini reaction      1252
Mechanisms pericyclic      275 1427
Mechanisms pericyclic and the Prins reaction      1242
Mechanisms permanganate oxidation of aldehydes      918
Mechanisms peroxide coupling of thiols to disulfides      1544
Mechanisms peroxide oxidation of tertiary amines      1541
Mechanisms photochemical dimerization of ketones      1560
Mechanisms photochemical Wolff rearrangement      1406
Mechanisms photochemical [2+2]-cycloadditions      1082
Mechanisms photolysis of 2,5-cyclohexadienones      1461
Mechanisms photolysis of pyrazoles      1353
Mechanisms pinacol rearrangement      1397
Mechanisms Prevost reaction      1050
Mechanisms Prins reaction      1241
Mechanisms pseudo first order      293
Mechanisms Pummerer rearrangement      1566
Mechanisms pyrolytic eliminations      1322—1326
Mechanisms quasi-Favorskii rearrangement      1405
Mechanisms radical addition of aldehydes to alkenes      1034
Mechanisms radical addition to alkenes      977
Mechanisms radical allylic bromination      912
Mechanisms radical halogenation of hydrocarbons      909
Mechanisms radical ring enlargement      1400
Mechanisms radical, addition of HBr to alkenes      992
Mechanisms radical, and oxidative decarboxylation      1529
Mechanisms radical, and reduction of nitro compounds      531
Mechanisms radical, and the Gif systems      1533
Mechanisms radical, and the Hofmann — Loeffler reaction      1462
Mechanisms radical, in autoxidation of aromatic diols      1518
Mechanisms radical, Stevens rearrangement      1420
Mechanisms Ramberg — Backlund reaction      1342
Mechanisms reaction of alkenes and peroxyacids      1052
Mechanisms reaction of alkenes with hypohalous acids      1044
Mechanisms reaction of alkenes, CO, and water      1036
Mechanisms reaction of carboxylate salts with BrCN      1247
Mechanisms reaction of diazomethane with aldehydes or ketones      1248
Mechanisms reaction of Grignard reagents with nitriles      1217
Mechanisms reaction of isonitriles and water      1251
Mechanisms reaction of nitroso compounds and hydroxylamines      819
Mechanisms reaction of organometallics and alkenes      792
Mechanisms reaction with boranes with CO      1422
Mechanisms rearrangement      276
Mechanisms rearrangement of aldehydes and ketones      1401
Mechanisms rearrangement of N-nitro amines      727
Mechanisms reduction of acyl halides      532
Mechanisms reduction of aldehydes or ketones with Na/EtOH      1199
Mechanisms reduction of aromatic nitro compound      1553
Mechanisms Sandmeyer reaction      936
Mechanisms Schiemann reaction      875
Mechanisms Schmidt reaction      1414
Mechanisms semi-benzilic mechanism      1405
Mechanisms, IUPAC $S_E1$      763
Mechanisms, IUPAC $S_E2$      760
Mechanisms, IUPAC $S_Ei$      760
Mechanisms, IUPAC $S_NAr$      851
Mechanisms, IUPAC $S_Ni$      420
Mechanisms, IUPAC $S_{RN}1$      855
Mechanisms, IUPAC allylic rearrangement      421
Mechanisms, IUPAC and ester hydrolysis      471—472
Mechanisms, IUPAC arenium ion      675
Mechanisms, IUPAC E1      1307
Mechanisms, IUPAC E2      1300
Mechanisms, IUPAC electrophilic addition to alkenes      970
Mechanisms, IUPAC leaving groups      445
Mechanisms, IUPAC nomenclature, and ester formation      485
Mechanisms, IUPAC nucleophilic addition to alkenes      975
Mechanisms, IUPAC pyrolytic eliminations      1323
Mechanisms, IUPAC radical substitution      897
Mechanisms, IUPAC rules      384
Mechanisms, IUPAC tetrahedral mechanism      424
Mechanisms, SET      402—404
Mechanisms, SET $S_N1$      393—400 420
Mechanisms, SET $S_N1$, and aromatic compounds      853
Mechanisms, SET $S_N1$, hydrolysis of acetals      466
Mechanisms, SET $S_N1$, ion pairing      397—400
Mechanisms, SET $S_N2$      390—393
Mechanisms, SET $S_N2$, and stereochemistry      142
Mechanisms, SET $S_NAr$      850—853 857
Mechanisms, SET $S_{ON}2$, and formation of aryl ethers      862
Mechanisms, SET $S_{RN}1$      855—856
Mechanisms, SET and coupling of organometallics with RX      537
Mechanisms, SET and electrophilic aromatic substitution      694
Mechanisms, SET and enolate anion alkylations      550—551
Mechanisms, SET and enolate anions with aryl halides      870
Mechanisms, SET and formation of Grignard reagents      806
Mechanisms, SET and sulfur nucleophiles      495
Mechanisms, SET and the Williamson reaction      478
Mechanisms, SET Shapiro reaction      1334
Mechanisms, SET Simmons-Smith reaction      1088
Mechanisms, SET Sommelet — Hauser rearrangement      878
Mechanisms, SET Stevens rearrangement      1419—1420
Mechanisms, SET substitution      275
Mechanisms, SET sulfite reduction of diazonium salts      1556
Mechanisms, SET sulfonyloxaziridine oxidation of ketones      916
Mechanisms, SET sulfur ylids with aldehydes or ketones      1247
Mechanisms, SET tetrahedral      424—428 (also see “Tetrahedral mechanism”)
Mechanisms, SET tetrahedral, and nucleophilic addition to carbonyls      1173
Mechanisms, SET transannular rearrangement      1388
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