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| Авторизация |
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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Thioethers from amides 1689
Thioethers from aromatic compounds 1689
Thioethers from aryl halides 1689
Thioethers from diazonium salts 1689
Thioethers from disulfides 1689
Thioethers from dithioacetals 1689
Thioethers from enolate anions 783
Thioethers from esters 1689
Thioethers from Grignard reagents 797 1689
Thioethers from ketones 783 1689
Thioethers from phenols 722
Thioethers from rearrangement of sulfonium salts 1689
Thioethers from rearrangements of sulfur ylids 1689
Thioethers from sulfenyl chlorides 1689
Thioethers from sulfones 1689
Thioethers from sulfonium salts 1420
Thioethers from sulfoxides 1557 1689
Thioethers from sulfur 1689
Thioethers from thioaldehydes 1689
Thioethers from thioethers 1689
Thioethers from thioketones 1689
Thioethers from thiol esters 1550 1689
Thioethers from thiolate ions 1689
Thioethers from thiols 494 998 1689
Thioethers halo and the Ramberg — Backlund reaction 1343
Thioethers hydrogenolysis, reagents for 531
Thioethers methylthiomethyl phenols 722
Thioethers oxidation of 1541
Thioethers reaction with  531
Thioethers reaction with alkyl halides 497
Thioethers reduction 940
Thioethers vinyl see “Vinyl sulfides”
Thioformamides, from isothiocyanates 1203
Thiohydroxamic esters, radical dimerization 942
Thioketenes, reaction with imines 1250
Thioketones from ketones 1184
Thioketones in Diels — Alder reactions 1075
Thioketones intermediate in episufide formation 1248
Thioketones reaction with diazoalkanes 1248
Thiol esters, from acyl halides 483
Thiol, anions, reaction with aryl halides 863
Thiolate ions and demethylation of ethers 496
Thiolate ions reaction with alkyl halides 496
Thiols by the Herz reaction 1689
Thiols cleavage of esters and lactones 496
Thiols coupling with peroxides 1543
Thiols from alcohols 496
Thiols from alkenes 1689
Thiols from alkyl halides 1689
Thiols from aromatic compounds 1689
Thiols from aryl halides 1689
Thiols from cleavage of isothiuronium salts 1689
Thiols from diazonium salts 1689
Thiols from disulfides 1559 1690
Thiols from dithiocarboxylic acids 1215 1690
Thiols from Grignard reagents 797 1689
Thiols from hydrolysis of thiol esters 1689
Thiols from Lawesson’s reagent 496
Thiols from organocuprates 1215 1690
Thiols from sulfonic acids 1690
Thiols from sulfonyl halides 1556 1690
Thiols from sulfur 1689
Thiols hydrogenolysis, reagents for 531
Thiols oxidation of 1540
Thiols radical addition to norbornene 1390
Thiols reaction with 531
Thiols reaction with acyl halides 497
Thiols reaction with aldehydes 1181
Thiols reaction with alkenes 998
Thiols reaction with alkyl halides 495
Thiols reaction with epoxides 481
Thiols reaction with ketones 1182
Thiols reaction with ketones or aldehydes 1185
Thiols reduction 940
Thiono ethers, reduction of 529
Thionocarbonates cyclic, pyrolysis of 1340
Thionocarbonates from thiophosgene and diols 1340
Thionolactones, reaction with butyllithium 1215
Thionyl chloride and dehydration of keto oximes 1349
Thionyl chloride reaction with 2-buten- l-ol 422
Thionyl chloride reaction with 3-buten-2-ol 422
Thionyl chloride reaction with alcohols 493 518
Thionyl chloride reaction with alkyl sulfonic aids 944
Thionyl chloride reaction with aromatic compounds 703
Thionyl chloride reaction with carboxylic acids 523
Thionyl chloride reaction with malic acid 391
Thionyl chloride reaction with sulfonic acids 577
Thiophenes alkylation of 531
Thiophenes and aromaticity 51
Thiophenes desulfurization 531
Thiophenes desulfurization, to alkenes 531
Thiophenes electrophilic aromatic substitution 688
Thiophenes hydrogenation of 941
Thiophenes resonance energy 51
Thiophenols from aryl diazonium salts 875
Thiophenols from aryl halides 863
Thiophosgene reaction with amines 507
Thiophosgene reaction with diols 1340
Thioureas from amines and  1192
Thioureas from isothiocyanates 1191
Thioureas reaction with alkyl halides 495
Third order reactions 291
Thorium oxide, reaction with carboxylic acids 573
Thorpe reaction 1219 1238
Thorpe reaction intramolecular 1238
Thorpe — Ziegler reaction 1239
Three-center hydrogen bonds 99—100
Threo diastereomers, from electrophilic addition to alkenes 971
Threo nomenclature 146—147
Tiffeneau — Demyanov rearrangement 1399
Tiffeneau — Demyanov ring expansion 1399
Tight ion pairs 398
Tin chloride, and the Stephen reduction 1204
Tishchenko reaction 1565
Titanium  , and reduction of amines 1548
Titanium cyclopentadienide 1238
Titanium reagent, low valent, and McMurry coupling 1561
Titanium tetrachloride and rearrangement of hydroxy ketones 1398
Titanium tetrachloride and the Simmons — Smith reaction 1088
Titanium tetrachloride in the Mukaiyama aldol reaction 1223
Titanium tetraisopropoxide, and Sharpless asymmetric epoxidation 1053
Titanium trichloride, in coupling reactions of alcohols 544
Titanocene dichloride and reduction of epoxides 1552
Titanocene dichloride and reduction of esters 1552
TMEDA see “Tetramethyl(N
Tolanes, from dibromotoluenes 1543
Tollens’ reaction 1219 1230
Toluene chlorination and the ortho/para ratio 685
Toluene dipole moment 16
Toluene electrophilic aromatic substitution, product distributions 693
Toluene nitration and the ortho/para ratio 686
Toluene oxidation of 1527
Topological stereoisomers, and catenanes 114
Torquoselectiviry 1120 (ref. 537)
Torsion angle and conformation 168
Torsional diastereomers 133
Tosyl azide reaction with active methylene compounds 780
Tosyl azide reaction with organolithium reactions 799
Tosyl cyanide, reaction with enolate anions 786
Tosylates, alkyl,  reaction rates 434
Tosylates, di-, elimination reactions 1340
Tosylates, ionization and solvent effects 451
Tosylates, leaving group 446
Tosylates, reaction with 526
Tosylhydrazide, reaction with alkyl halides 499
Tosylhydrazones and the Bamford — Stevens reaction 1335
Tosylhydrazones and the Knoevenagel reaction 1227
Tosylhydrazones and the Shapiro reaction 1334
Tosylhydrazones elimination reactions 1334
Tosylhydrazones reaction with Na and ethylene glycol 1335
| Tosylhydrazones reaction with organolithium reagents 1334
Tosylhydrazones reduction of 1548
Tosylmethylisocyanide, and the Knoevenagel reaction 1226
TPAP, oxidation of alcohols 1515
Trans isomers 156—153
trans-Cyclooctene 134 186
trans-Cyclooctene and resolution 151—152
Transacetalation 1181
Transamidation 503 512
Transamination 503
Transannular interactions 184
Transannular rearrangements 1388
Transannular rearrangements, in radicals 1392
Transannular stain 184
Transesterification 486
Transesterification and Montmorillonite K10 clay 486
Transesterification and phase transfer catalysis 487
Transesterification enzymatic 487
Transesterification of lactones 487
Transesterification reagents for 486
Transetherification 480
Transetherification and alkoxytrimethylsilanes 481
Transetherification of acetals 480
Transetherification of ethers 480
Transetherification of ortho esters 480
Transfer hydrogenation 1008
Transformations, IUPAC nomenclature 382
Transition states amide hydrolysis 365
Transition states and activated complexes 279
Transition states and equilibria 279
Transition states and kinetics 279
Transition states and solvent effects 450
Transition states and the Hammond postulate 285
Transition states for  reactions 390
Transition states for E2 reactions 1300
Transition states for free radical substitution 897
Transition states for Meerwein — Ponndorf — Verley reduction 1199
Transition states for the Cope rearrangement 1446
Transition states radicals, ab initio 900
Transition states types 450
Transmetallation and higher order cuprates 804
Transmetallation and Markovnikov’s rule 803
Transmetallation and metallocenes 803
Transmetallation and organocuprates 803
Transmetallation of organometallic compounds 803—804
Transoid conformation, of dienes, and the Diels — Alder reaction 1063
Trger’s base 130
Tri(pentafluorophenyl)methane,  343
Tri-t-butylamine 190
Tri-t-butylcarbinol 190
Tri-t-butylmethane, formal steric enthalpy 190
Triacylamines, from acyl halides 507
Triarylmethyl cations 225
Triarylmethyl radicals 242
Triazenes aryl, from diazonium coupling 700
Triazenes from alkenes and azides 1059
Triazenes from amines and diazonium salts 1690
Triazenes from aromatic amines and diazonium salts 1690
Triazenes from azide addition to alkenes 1057
Triazenes from trimerization of nitriles 1246
Triazenes photolysis of 1057
Triazoles, from alkynes and azides 1061
Triazolines and extrusion reactions 1353
Tribromomethane see “Bromoform”
Tributyltin hydride and radical cyclization 1040
Tributyltin hydride and radical cyclization of dialdehydes 1561
Tributyltin hydride and radical cyclization to C=N and C=O 1244
Tributyltin hydride and the Barton — McCombie reaction 528
Tributyltin hydride reaction with radicals 895
Tributyltin oxide, and hydrolysis of alkyl halides 463
Trications 222 (also see “Carbocations”)
Trichloroacetic acid, thermodynamic ionization values 350
Trichloroacetonitrile, reaction with aromatic compounds 722—723
Trichloroamme, and electrophilic aromatic substitution 701
Trichloromethane see “Chloroform”
Trichloropropene, reaction with bromine radical 1391
Tricyanomethane, 344
Tricyanomethyl radicals 242
Tricyclic compounds, out-in isomers 163
Tricyclo![$[4.2.0.0^{2.5}]$](/math_tex/cb35031aa5de8558dcefc5e122b0a78c82.gif) octa-3,7-diene 1434
Tricyclobutanes 183
Tricyclohexylcarbinol 1422
Tricyclooctanes 183
Tricyclopentanes 183
Trienes by the Ramberg — Backlund reaction 1342
Trienes photolysis of 1426
Triethyl phosphite, reaction with epoxides 1341
Triethylcarboxide, lithium 1423
Triethylsilane, reaction with radicals 895
Triflates and the Heck reaction 930
Triflates aryl, reaction with boronic acids 868
Triflates aryl, reaction with zinc cyanide 724
Triflates leaving group 446
Triflates vinyl, and the Stille reaction 931
Triflates vinyl, reaction with vinyltin compounds 931
Triflic anhydride and the Ritter reaction 1245
Triflic anhydride reaction with alcohols 493
Trifluoroacetic acid, as a solvent 412
Trifluoroacetic anhydride and DMSO, for oxidation of alcohols 1516
Trifluoroacetic anhydride dehydrating agent 491
Trifluoroacetyl anilines, hydrolysis 475
Trifluoromethanesulfonate anhydride see “Triflic anhydride”
Trifluoromethanesulfonate leaving group 446
Trifluoroperoxyacetic acid reaction with aromatic compounds 724
Trifluoroperoxyacetic acid trig, and Baldwin’s rules 283—284
Trigonal carbon, and the tetrahedral mechanism 424
Trigonal molecules diastereotopic atoms 166
Trigonal molecules enantiotopic atoms 166
Triketones, from dlketones 572
Trimerization of aldehydes 1245
Trimerization of alkynes 1090
Trimerization of nitriles 1246
Trimerization ofdlenes 1091
Trimethyl phosphite, reaction with cyclic thionocarbonates 1340
Trimethylaluminum reaction with alcohols 544
Trimethylaluminum reaction with aldehydes or ketones 1210
Trimethylaluminum reaction with carboxylic acids 1214
Trimethylaluminum reaction with esters 567
Trimethylaluminum reaction with ketones 1214
Trimethylamine oxide, bonding 13
Trimethylamine, and base strength 349
Trimethylenemethane diradical 244
Trimethyloxonium tetrafluoroborate, reaction with amides 488
Trimethylsilyl azide, reaction with aromatic compounds 701
Trimethylsilyl cyanide and the Strecker synthesis 1240
Trimethylsilyl cyanide reaction with aldehydes or ketones 1240
Trimethylsilyl cyanide reaction with oxetanes 506
Trimethylsilylmethyl potassium 791
Trinitrophenol 2,4,6-trinitro see “Picric acid”
Trioxane 1245
Triphase catalysts 456
Triphenylchloromethane, ionization 222
Triphenylene, and aromaticity 50
Triphenylmethane, 343
Triphenylmethyl cation 222
Triphenylmethyl radical, stability of 905
Triphenylmethyl radicals 241
Triphenylphosphine and dehydration of alcohols 1327
Triphenylphosphine and elimination of halo acyl halides 1344
Triphenylphosphine and reduction of sulfonyl halides 1557
Triphenylphosphine and the Staudinger reaction 1555
Triphenylphosphine dibromide, reaction with amino alcohols 502
Triphenylphosphine oxide 1234
Triphenylphosphine reaction with  and alcohols 519
Triphenylphosphine reaction with alkyl halides 1233
Triphenylphosphine reaction with epoxides. 1341
Triphenylphosphine reduction of amine oxides 1557
Triphenylphosphine reduction of azoxy compound 1557
Triphenylphosphine reduction of hydroperoxides 1558
Triphenylphosphine reduction of nitro compound 1563
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