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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Thioethers from amides      1689
Thioethers from aromatic compounds      1689
Thioethers from aryl halides      1689
Thioethers from diazonium salts      1689
Thioethers from disulfides      1689
Thioethers from dithioacetals      1689
Thioethers from enolate anions      783
Thioethers from esters      1689
Thioethers from Grignard reagents      797 1689
Thioethers from ketones      783 1689
Thioethers from phenols      722
Thioethers from rearrangement of sulfonium salts      1689
Thioethers from rearrangements of sulfur ylids      1689
Thioethers from sulfenyl chlorides      1689
Thioethers from sulfones      1689
Thioethers from sulfonium salts      1420
Thioethers from sulfoxides      1557 1689
Thioethers from sulfur      1689
Thioethers from thioaldehydes      1689
Thioethers from thioethers      1689
Thioethers from thioketones      1689
Thioethers from thiol esters      1550 1689
Thioethers from thiolate ions      1689
Thioethers from thiols      494 998 1689
Thioethers halo and the Ramberg — Backlund reaction      1343
Thioethers hydrogenolysis, reagents for      531
Thioethers methylthiomethyl phenols      722
Thioethers oxidation of      1541
Thioethers reaction with $LiAlH_4$      531
Thioethers reaction with alkyl halides      497
Thioethers reduction      940
Thioethers vinyl      see “Vinyl sulfides”
Thioformamides, from isothiocyanates      1203
Thiohydroxamic esters, radical dimerization      942
Thioketenes, reaction with imines      1250
Thioketones from ketones      1184
Thioketones in Diels — Alder reactions      1075
Thioketones intermediate in episufide formation      1248
Thioketones reaction with diazoalkanes      1248
Thiol esters, from acyl halides      483
Thiol, anions, reaction with aryl halides      863
Thiolate ions and demethylation of ethers      496
Thiolate ions reaction with alkyl halides      496
Thiols by the Herz reaction      1689
Thiols cleavage of esters and lactones      496
Thiols coupling with peroxides      1543
Thiols from alcohols      496
Thiols from alkenes      1689
Thiols from alkyl halides      1689
Thiols from aromatic compounds      1689
Thiols from aryl halides      1689
Thiols from cleavage of isothiuronium salts      1689
Thiols from diazonium salts      1689
Thiols from disulfides      1559 1690
Thiols from dithiocarboxylic acids      1215 1690
Thiols from Grignard reagents      797 1689
Thiols from hydrolysis of thiol esters      1689
Thiols from Lawesson’s reagent      496
Thiols from organocuprates      1215 1690
Thiols from sulfonic acids      1690
Thiols from sulfonyl halides      1556 1690
Thiols from sulfur      1689
Thiols hydrogenolysis, reagents for      531
Thiols oxidation of      1540
Thiols radical addition to norbornene      1390
Thiols reaction with $LiAlH_4$      531
Thiols reaction with acyl halides      497
Thiols reaction with aldehydes      1181
Thiols reaction with alkenes      998
Thiols reaction with alkyl halides      495
Thiols reaction with epoxides      481
Thiols reaction with ketones      1182
Thiols reaction with ketones or aldehydes      1185
Thiols reduction      940
Thiono ethers, reduction of      529
Thionocarbonates cyclic, pyrolysis of      1340
Thionocarbonates from thiophosgene and diols      1340
Thionolactones, reaction with butyllithium      1215
Thionyl chloride and dehydration of keto oximes      1349
Thionyl chloride reaction with 2-buten- l-ol      422
Thionyl chloride reaction with 3-buten-2-ol      422
Thionyl chloride reaction with alcohols      493 518
Thionyl chloride reaction with alkyl sulfonic aids      944
Thionyl chloride reaction with aromatic compounds      703
Thionyl chloride reaction with carboxylic acids      523
Thionyl chloride reaction with malic acid      391
Thionyl chloride reaction with sulfonic acids      577
Thiophenes alkylation of      531
Thiophenes and aromaticity      51
Thiophenes desulfurization      531
Thiophenes desulfurization, to alkenes      531
Thiophenes electrophilic aromatic substitution      688
Thiophenes hydrogenation of      941
Thiophenes resonance energy      51
Thiophenols from aryl diazonium salts      875
Thiophenols from aryl halides      863
Thiophosgene reaction with amines      507
Thiophosgene reaction with diols      1340
Thioureas from amines and $CS_2$      1192
Thioureas from isothiocyanates      1191
Thioureas reaction with alkyl halides      495
Third order reactions      291
Thorium oxide, reaction with carboxylic acids      573
Thorpe reaction      1219 1238
Thorpe reaction intramolecular      1238
Thorpe — Ziegler reaction      1239
Three-center hydrogen bonds      99—100
Threo diastereomers, from electrophilic addition to alkenes      971
Threo nomenclature      146—147
Tiffeneau — Demyanov rearrangement      1399
Tiffeneau — Demyanov ring expansion      1399
Tight ion pairs      398
Tin chloride, and the Stephen reduction      1204
Tishchenko reaction      1565
Titanium $(TiCl_3/Li/THF)$, and reduction of amines      1548
Titanium cyclopentadienide      1238
Titanium reagent, low valent, and McMurry coupling      1561
Titanium tetrachloride and rearrangement of hydroxy ketones      1398
Titanium tetrachloride and the Simmons — Smith reaction      1088
Titanium tetrachloride in the Mukaiyama aldol reaction      1223
Titanium tetraisopropoxide, and Sharpless asymmetric epoxidation      1053
Titanium trichloride, in coupling reactions of alcohols      544
Titanocene dichloride and reduction of epoxides      1552
Titanocene dichloride and reduction of esters      1552
TMEDA      see “Tetramethyl(N
Tolanes, from dibromotoluenes      1543
Tollens’ reaction      1219 1230
Toluene chlorination and the ortho/para ratio      685
Toluene dipole moment      16
Toluene electrophilic aromatic substitution, product distributions      693
Toluene nitration and the ortho/para ratio      686
Toluene oxidation of      1527
Topological stereoisomers, and catenanes      114
Torquoselectiviry      1120 (ref. 537)
Torsion angle and conformation      168
Torsional diastereomers      133
Tosyl azide reaction with active methylene compounds      780
Tosyl azide reaction with organolithium reactions      799
Tosyl cyanide, reaction with enolate anions      786
Tosylates, alkyl, $S_N1$reaction rates      434
Tosylates, di-, elimination reactions      1340
Tosylates, ionization and solvent effects      451
Tosylates, leaving group      446
Tosylates, reaction with $LiAlH_4$      526
Tosylhydrazide, reaction with alkyl halides      499
Tosylhydrazones and the Bamford — Stevens reaction      1335
Tosylhydrazones and the Knoevenagel reaction      1227
Tosylhydrazones and the Shapiro reaction      1334
Tosylhydrazones elimination reactions      1334
Tosylhydrazones reaction with Na and ethylene glycol      1335
Tosylhydrazones reaction with organolithium reagents      1334
Tosylhydrazones reduction of      1548
Tosylmethylisocyanide, and the Knoevenagel reaction      1226
TPAP, oxidation of alcohols      1515
Trans isomers      156—153
trans-Cyclooctene      134 186
trans-Cyclooctene and resolution      151—152
Transacetalation      1181
Transamidation      503 512
Transamination      503
Transannular interactions      184
Transannular rearrangements      1388
Transannular rearrangements, in radicals      1392
Transannular stain      184
Transesterification      486
Transesterification and Montmorillonite K10 clay      486
Transesterification and phase transfer catalysis      487
Transesterification enzymatic      487
Transesterification of lactones      487
Transesterification reagents for      486
Transetherification      480
Transetherification and alkoxytrimethylsilanes      481
Transetherification of acetals      480
Transetherification of ethers      480
Transetherification of ortho esters      480
Transfer hydrogenation      1008
Transformations, IUPAC nomenclature      382
Transition states amide hydrolysis      365
Transition states and activated complexes      279
Transition states and equilibria      279
Transition states and kinetics      279
Transition states and solvent effects      450
Transition states and the Hammond postulate      285
Transition states for $S_N2$ reactions      390
Transition states for E2 reactions      1300
Transition states for free radical substitution      897
Transition states for Meerwein — Ponndorf — Verley reduction      1199
Transition states for the Cope rearrangement      1446
Transition states radicals, ab initio      900
Transition states types      450
Transmetallation and higher order cuprates      804
Transmetallation and Markovnikov’s rule      803
Transmetallation and metallocenes      803
Transmetallation and organocuprates      803
Transmetallation of organometallic compounds      803—804
Transoid conformation, of dienes, and the Diels — Alder reaction      1063
Trger’s base      130
Tri(pentafluorophenyl)methane, $pK_a$      343
Tri-t-butylamine      190
Tri-t-butylcarbinol      190
Tri-t-butylmethane, formal steric enthalpy      190
Triacylamines, from acyl halides      507
Triarylmethyl cations      225
Triarylmethyl radicals      242
Triazenes aryl, from diazonium coupling      700
Triazenes from alkenes and azides      1059
Triazenes from amines and diazonium salts      1690
Triazenes from aromatic amines and diazonium salts      1690
Triazenes from azide addition to alkenes      1057
Triazenes from trimerization of nitriles      1246
Triazenes photolysis of      1057
Triazoles, from alkynes and azides      1061
Triazolines and extrusion reactions      1353
Tribromomethane      see “Bromoform”
Tributyltin hydride and radical cyclization      1040
Tributyltin hydride and radical cyclization of dialdehydes      1561
Tributyltin hydride and radical cyclization to C=N and C=O      1244
Tributyltin hydride and the Barton — McCombie reaction      528
Tributyltin hydride reaction with radicals      895
Tributyltin oxide, and hydrolysis of alkyl halides      463
Trications      222 (also see “Carbocations”)
Trichloroacetic acid, thermodynamic ionization values      350
Trichloroacetonitrile, reaction with aromatic compounds      722—723
Trichloroamme, and electrophilic aromatic substitution      701
Trichloromethane      see “Chloroform”
Trichloropropene, reaction with bromine radical      1391
Tricyanomethane, $pK_a$      344
Tricyanomethyl radicals      242
Tricyclic compounds, out-in isomers      163
Tricyclo$[4.2.0.0^{2.5}]$octa-3,7-diene      1434
Tricyclobutanes      183
Tricyclohexylcarbinol      1422
Tricyclooctanes      183
Tricyclopentanes      183
Trienes by the Ramberg — Backlund reaction      1342
Trienes photolysis of      1426
Triethyl phosphite, reaction with epoxides      1341
Triethylcarboxide, lithium      1423
Triethylsilane, reaction with radicals      895
Triflates and the Heck reaction      930
Triflates aryl, reaction with boronic acids      868
Triflates aryl, reaction with zinc cyanide      724
Triflates leaving group      446
Triflates vinyl, and the Stille reaction      931
Triflates vinyl, reaction with vinyltin compounds      931
Triflic anhydride and the Ritter reaction      1245
Triflic anhydride reaction with alcohols      493
Trifluoroacetic acid, as a solvent      412
Trifluoroacetic anhydride and DMSO, for oxidation of alcohols      1516
Trifluoroacetic anhydride dehydrating agent      491
Trifluoroacetyl anilines, hydrolysis      475
Trifluoromethanesulfonate anhydride      see “Triflic anhydride”
Trifluoromethanesulfonate leaving group      446
Trifluoroperoxyacetic acid reaction with aromatic compounds      724
Trifluoroperoxyacetic acid trig, and Baldwin’s rules      283—284
Trigonal carbon, and the tetrahedral mechanism      424
Trigonal molecules diastereotopic atoms      166
Trigonal molecules enantiotopic atoms      166
Triketones, from dlketones      572
Trimerization of aldehydes      1245
Trimerization of alkynes      1090
Trimerization of nitriles      1246
Trimerization ofdlenes      1091
Trimethyl phosphite, reaction with cyclic thionocarbonates      1340
Trimethylaluminum reaction with alcohols      544
Trimethylaluminum reaction with aldehydes or ketones      1210
Trimethylaluminum reaction with carboxylic acids      1214
Trimethylaluminum reaction with esters      567
Trimethylaluminum reaction with ketones      1214
Trimethylamine oxide, bonding      13
Trimethylamine, and base strength      349
Trimethylenemethane diradical      244
Trimethyloxonium tetrafluoroborate, reaction with amides      488
Trimethylsilyl azide, reaction with aromatic compounds      701
Trimethylsilyl cyanide and the Strecker synthesis      1240
Trimethylsilyl cyanide reaction with aldehydes or ketones      1240
Trimethylsilyl cyanide reaction with oxetanes      506
Trimethylsilylmethyl potassium      791
Trinitrophenol 2,4,6-trinitro      see “Picric acid”
Trioxane      1245
Triphase catalysts      456
Triphenylchloromethane, ionization      222
Triphenylene, and aromaticity      50
Triphenylmethane, $pK_a$      343
Triphenylmethyl cation      222
Triphenylmethyl radical, stability of      905
Triphenylmethyl radicals      241
Triphenylphosphine and dehydration of alcohols      1327
Triphenylphosphine and elimination of halo acyl halides      1344
Triphenylphosphine and reduction of sulfonyl halides      1557
Triphenylphosphine and the Staudinger reaction      1555
Triphenylphosphine dibromide, reaction with amino alcohols      502
Triphenylphosphine oxide      1234
Triphenylphosphine reaction with $CBr_4$ and alcohols      519
Triphenylphosphine reaction with alkyl halides      1233
Triphenylphosphine reaction with epoxides.      1341
Triphenylphosphine reduction of amine oxides      1557
Triphenylphosphine reduction of azoxy compound      1557
Triphenylphosphine reduction of hydroperoxides      1558
Triphenylphosphine reduction of nitro compound      1563
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