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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Peroxides from dienes      1054
Peroxides from hydrocarbons      922
Peroxides from ozonides      1523
Peroxides hydro      see “Hydroperoxides”
Peroxides reaction with Grignard reagents      796
Peroxides reaction with organometallic compounds      796
Peroxides reduction of      1558
Peroxides silyl, reaction with vmyllithium reagents      796
Peroxides thermal cleavage      245
Peroxyacids and the Baeyer-VUliger rearrangement      1417
Peroxyacids and the Tamao-Fleming oxidation      482
Peroxyacids from anhydrides      492
Peroxyacids from carboxylic acids      1542
Peroxyacids from oxidation of carboxylic acids      1684
Peroxyacids oxidation of boranes      1016
Peroxyacids reaction with alkenes      1051—1052
Peroxyacids reaction with amines      1541
Peroxyacids reaction with aromatic compounds      724
Peroxyacids reaction with ketones      1417
Peroxyacids reaction with oximes      1539
Peroxyesters, reaction with hydrocarbons      922—923
Perpendicular disymmetric planes      see “Chiral axes”
Pes      see “Photoelectron spectroscopy”
Petasis alkenylation      1237—1238
Petasis reagent      1238
Peterson alkenylation reaction      1228
Peterson reaction      1219
PH, and $H_o$      335
Phase transfer and alkylation of amines      501
Phase transfer and azide formation      515
Phase transfer and carbene reactions with alkenes      1085
Phase transfer and cleavage of ethers with HBr      520
Phase transfer and dehydration of amides      1350
Phase transfer and diazo transfer reactions      781
Phase transfer and enolate amon alkylation      548
Phase transfer and ester hydrolysis      470
Phase transfer and oxidation of amines to imines      1536
Phase transfer and oxidation of nitro compounds      1537
Phase transfer and permanganate oxidation of alcohols      1515
Phase transfer and reactions of alkyl halides and cyanide      562
Phase transfer and the Darzens glycidic ester condensation      1230
Phase transfer and the Gomberg reaction      928
Phase transfer catalysis      454—456
Phase transfer catalysis interfacial mechanism      455
Phase transfer catalysis triphase catalysts      456
Phase transfer catalysts alkylation with carboxylic acid salts      488
Phase transfer catalysts ammonium salts      454—455
Phase transfer catalysts and transesterification      487
Phase transfer catalysts crown ethers      455
Phase transfer catalysts cryptands      455
Phase transfer catalysts phosphonium salts      454
Phase transfer catalysts podands      456
Phenacenes, and aromaticity      67
Phenalene, and aromaticity      50
Phenanthrenes and aromaticity      49
Phenanthrenes from photocyclization of stilbenes      1436
Phenanthrenes reaction with oxygen      1054
Phenanthrenes resonance energy      49
Phenol anions      see “phenoxides
Phenol, reaction with dimethyl sulfide      722
Phenol-dienone rearrangement      1402
Phenol-keto tautomerism      75—76 (also see “Tautomerism”)
Phenolic esters, from arylmethyl ketones      1528
Phenols acidity of      345
Phenols allyl, by Claisen rearrangement      1449
Phenols allyl, from allyl aryl ethers      1449
Phenols and Friedel — Crafts alkylation      709
Phenols by Fenton’s reagent      916
Phenols by rearrangement of allylic aryl ethers      1685
Phenols by rearrangement of aralkyl peroxides      1685
Phenols by rearrangement of azoxy compounds      1685
Phenols by rearrangement of N-hydroxylamines      1685
Phenols by rearrangement of phenolic esters      1685
Phenols by the Baeyer — Villiger rearrangement      1685
Phenols by the Bucherer reaction      861
Phenols by the Claisen rearrangement      1685
Phenols by the Dakin reaction      1528
Phenols by the dienone-phenol rearrangement      1685
Phenols by the Fries rearrangement      727 1685
Phenols by the Wallach rearrangement      1685
Phenols by Udenfriend’s reagent      916
Phenols coupling with diazonium salts      700
Phenols formylation by the Duff reaction      717
Phenols formylation of      716
Phenols from alkali fusion of sulfonate ions      1685
Phenols from aromatic compounds      724 916 1685
Phenols from aromatization of cyclic ketones      1685
Phenols from aryl diazonium salts      874
Phenols from aryl halides      861
Phenols from aryl ketones      1685
Phenols from aryl organometallic compounds      1685
Phenols from cyclohexadienones      1402
Phenols from esters      727 1685
Phenols from hydrolysis of aryl halides      1685
Phenols from hydrolysis of diazonium salts      1685
Phenols from hydrolysis of phenolic esters      1685
Phenols from phenolic esters      1685
Phenols from phenols      1685
Phenols from quinones      1685
Phenols hydrogenation of      1009
Phenols nitrosation of      699
Phenols reaction with chloroacetamides      722
Phenols reaction with diazo compounds      479
Phenols reaction with DMSO and DCC      722
Phenols reaction with formaldehyde and amines      722
Phenols reaction with zinc metal      866
Phenols reduction to aromatic compounds      866
Phenols sulfonate esters, reduction of      867
Phenols thioalkylation of      722
Phenonium ions      411 413
Phenonium ions and NMR      413
Phenonium ions benzene, charge distribution      685
Phenoxides as ambident nucleophiles      459
Phenoxides from aryl sulfonic acids      862
Phenoxides reaction with $CO_2$      718
Phenoxides reaction with chloroform      716
Phenyl cation      223
Phenyl chloroformate, cleavage of amines      522
Phenyl radicals, reactions rates with substituted benzenes      905
Phenylhydrazine and the Fischer indole synthesis      1453
Phenylhydrazine reaction with aldehydes or ketones      1453
Phenyliodosyl bis(trifluoroacetate), and Hofmann rearrangement      1412
Phenyllithium      236
Phenyllithium from bromobenzene      699
Phenyllithium reaction with carbamates      1215
Phenyllithium reaction with thiobenzophenone      1172
Phenylselenyl bromide, reaction with enolate anions      783
Phenylselenyl chloride, reaction with enolate anions      783
Phosgene and aromatic formylations      715
Phosgene reaction with alcohols      483
Phosgene reaction with amines      507
Phosgene reaction with aromatic compounds      718
Phosgene reaction with formamides      1350
Phosphates, aryl diethyl, reaction with potassium amide and K      866
Phosphine oxides bonding      45
Phosphine oxides reaction with isocyanates      1246
Phosphines from alkyl halides      1685
Phosphines from Grignard reagents      1685
Phosphines from phosphonium salts      1685
Phosphines from phosphorus halides      1685
Phosphines reaction with alkyl halides      501 1231
Phosphines reaction with epoxides      1235
Phosphines reaction with methylpyridinium salts      501
Phosphite, triphenyl, reaction with aldehydes and bromine      1196
Phosphonate esters      see “Esters”
Phosphonate ylids      see “Ylids”
Phosphonates, by the Arbuzov reaction      1234
Phosphonic esters, coupling with Grignard reagents      544
Phosphonium salts as phase transfer catalysts      454—455
Phosphonium salts from Michael alkenes      1231
Phosphonium salts from phosphines and alkyl halides      1231
Phosphonium salts reaction with bases      1231
Phosphonium salts reaction with organolithium reagents      793
Phosphonium ylids, from phosphonium salts      793
Phosphoranes      see “Ylids phosphorus”
Phosphorescence      315
Phosphoric acids, anhydrides      494
Phosphorous pentoxide, dehydration agent      491
Phosphorus halides, reaction with alcohols      518
Phosphorus oxychloride and formylation of alkenes      785
Phosphorus oxychloride and formylation of aromatic compounds      715
Phosphorus oxychloride and the Bischler — Napieralski reaction      721
Phosphorus oxychloride reaction with alcohols      493
Phosphorus pentachloride and valence electrons      13
Phosphorus pentachloride reaction with aldehydes or ketones      1195
Phosphorus pentachloride reaction with amides      1464
Phosphorus pentachloride reaction with malic acid      391
Phosphorus pentachloride reaction with oximes      1349 1415
Phosphorus pentachloride reaction with sulfonic acids      577
Phosphorus pentoxide, dehydration of amides      1350
Phosphorus tribromide, reaction with carboxylic acids      777
Phosphorus ylids      see “Ylids phosphorus”
Phosphorus ylids, and the Wittig reaction      1231—1237
Phosphorus, stabilization of carbanions      231
Photo — Fries rearrangement      727
Photo — Fries rearrangement relation to photolysis of arylamines      730
Photochemical decarboxylation      811
Photochemical reactions      306
Photochemical Wallach rearrangement      1465
Photochemistry addition of alcohols to alkenes      997
Photochemistry alkylation of quinolines      934
Photochemistry and absorption      308
Photochemistry and an actinometer      322
Photochemistry and angular momentum      315
Photochemistry and auxochromes      310
Photochemistry and chromophores      308 310
Photochemistry and circularly polarized light      150
Photochemistry and cis/trans isomerization      320
Photochemistry and conjugation      310
Photochemistry and dimerization of ketones      1560
Photochemistry and extinction coefficient      307
Photochemistry and extrusion reactions of pyrazolines      1353
Photochemistry and fluorescence      313—314
Photochemistry and forbidden transitions      308
Photochemistry and Hund’s rule      308
Photochemistry and intersystem crossing      315
Photochemistry and Jablonski diagrams      313—314
Photochemistry and phosphorescence      315
Photochemistry and photolysis      312
Photochemistry and photosensitization      316
Photochemistry and Planck’s constant      306
Photochemistry and quantum yield      322
Photochemistry and radicals      245 312
Photochemistry and spectrophotometers      306
Photochemistry and the Barton reaction      1463
Photochemistry and the Diels — Alder reaction      1065
Photochemistry and the electromagnetic spectrum      307
Photochemistry and the Kolbe reaction      942
Photochemistry and the Orton rearrangement      729
Photochemistry and the Wolff rearrangements      1406
Photochemistry and triplet state reactivity      317
Photochemistry and triplet states      311
Photochemistry and vibrational levels      307—308
Photochemistry and [2+2]-cycloadditions      1081
Photochemistry benzene with alkenes      1093
Photochemistry cleavage      312
Photochemistry cleavage to radicals      318
Photochemistry cyclization of stilbenes      1436
Photochemistry decomposition      318
Photochemistry dehydrohalogenation      1513
Photochemistry dimerization      321
Photochemistry exciplex formation in [2+2]-cycloadditions      1082
Photochemistry flash photolysis      321
Photochemistry halogenation of hydrocarbons      907
Photochemistry hydrogen atom abstraction      321
Photochemistry internal conversions      313
Photochemistry intramolecular [2+2]-cycloadditions      1082
Photochemistry mechanism determination      231
Photochemistry Norrish Type I cleavage      318—319
Photochemistry Norrish Type II cleavage      318—319
Photochemistry of 1,4-dienes      1460
Photochemistry of 2,5-cyclohexadienones      1461
Photochemistry of aryl keto esters      1532
Photochemistry of cyclobutanones      1354
Photochemistry of dienes and trienes      1426
Photochemistry of ketene      319
Photochemistry of ketones      1560
Photochemistry of N-iodoamides      1463
Photochemistry of pyrazoles      1353
Photochemistry of thiohydroxamic esters      942
Photochemistry of triazolines      1057
Photochemistry photo Fries rearrangement      727
Photochemistry photosensitizers      316
Photochemistry physical processes of excited molecules      315
Photochemistry reactions      318
Photochemistry rearrangements      319
Photochemistry singlet and triplet states      308—309 316
Photochemistry singlet states      311
Photochemistry spin-forbidden transitions      309
Photochemistry symmetry-forbidden transitions      209
Photochemistry the Franck — Condon principle      312
Photochemistry types of excitation      309
Photochemistry Wallach rearrangement      1465
Photochemistry Wigner spin-conservation rule      316
Photodimerization      321
Photoelectron spectroscopy      10—12
Photoelectron spectroscopy and carbocations      224
Photoisomerization      319—30
Photolysis, definition      312
Photolytic halogenation      899
Photooxygenation, of alkenes      1054
Photosensitization      316
Photosensitization and the Paterno — Buchi reaction      1250
Photosensitization in [2+2]-cycloadditions      1081
Photosensitization of mercury, and alkane dimerization      926
Photosensitization of oxygen      921
Photosensitizers      316
Photosensitizers and reaction of oxygen with dienes      1054
Photosensitizers mercury, and dimerization of alkenes      1021
Phthalamic acid, hydrolysis of      427
Phthalate ion, rearrangement of      733
Phthalic anhydride, from naphthalene      1527
Phthalimide, potassium reaction with alkyl halides      513
Phthalimide, potassium reaction with aryl halides      865
Phthalimides reaction with hydrazine      513
Phthalimides reagents for hydrolysis      514
Picric acid acidity in DMF      351
Picric acid electron donor-acceptor complexes      104
Picryl chloride, reaction with hydroxide, $\pi$-complex      852
Picryl iodide, bond lengths      43
Pig liver ester esterase, hydrolysis of esters      470
Pig liver esterase, and Meinwald rearrangement      1398
Pimm sativum, oxidation of ketones      1533
Pinacol coupling      1560—1561
Pinacol rearrangement      1384 1396—1398
Pinacol rearrangement and quasi-Favorskii rearrangement      1405
Pinacol rearrangement migratory aptitudes      1384—1385
Pinacol rearrangement regioselectivity      1397
Pinacol rearrangement with epoxides      1398
Pinacols      see “Diols”
Pinacols from aldehydes or ketones      1559—1561
Pinacols side products of Clemmensen reduction      1547
Pinene, reaction with borane      1014
Pinner synthesis      1183
Pinocolate, titanium      1562
Piperidine catalyst for the Doebner modification      1226
Piperidine reaction with cyclopropylmethyl halides      423
Piperidines, by the Hofrnann — Loeffler reaction      1462
Pitzer strain      184
Planck’s constant      3 306
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