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| Авторизация |
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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Peroxides from dienes 1054
Peroxides from hydrocarbons 922
Peroxides from ozonides 1523
Peroxides hydro see “Hydroperoxides”
Peroxides reaction with Grignard reagents 796
Peroxides reaction with organometallic compounds 796
Peroxides reduction of 1558
Peroxides silyl, reaction with vmyllithium reagents 796
Peroxides thermal cleavage 245
Peroxyacids and the Baeyer-VUliger rearrangement 1417
Peroxyacids and the Tamao-Fleming oxidation 482
Peroxyacids from anhydrides 492
Peroxyacids from carboxylic acids 1542
Peroxyacids from oxidation of carboxylic acids 1684
Peroxyacids oxidation of boranes 1016
Peroxyacids reaction with alkenes 1051—1052
Peroxyacids reaction with amines 1541
Peroxyacids reaction with aromatic compounds 724
Peroxyacids reaction with ketones 1417
Peroxyacids reaction with oximes 1539
Peroxyesters, reaction with hydrocarbons 922—923
Perpendicular disymmetric planes see “Chiral axes”
Pes see “Photoelectron spectroscopy”
Petasis alkenylation 1237—1238
Petasis reagent 1238
Peterson alkenylation reaction 1228
Peterson reaction 1219
PH, and  335
Phase transfer and alkylation of amines 501
Phase transfer and azide formation 515
Phase transfer and carbene reactions with alkenes 1085
Phase transfer and cleavage of ethers with HBr 520
Phase transfer and dehydration of amides 1350
Phase transfer and diazo transfer reactions 781
Phase transfer and enolate amon alkylation 548
Phase transfer and ester hydrolysis 470
Phase transfer and oxidation of amines to imines 1536
Phase transfer and oxidation of nitro compounds 1537
Phase transfer and permanganate oxidation of alcohols 1515
Phase transfer and reactions of alkyl halides and cyanide 562
Phase transfer and the Darzens glycidic ester condensation 1230
Phase transfer and the Gomberg reaction 928
Phase transfer catalysis 454—456
Phase transfer catalysis interfacial mechanism 455
Phase transfer catalysis triphase catalysts 456
Phase transfer catalysts alkylation with carboxylic acid salts 488
Phase transfer catalysts ammonium salts 454—455
Phase transfer catalysts and transesterification 487
Phase transfer catalysts crown ethers 455
Phase transfer catalysts cryptands 455
Phase transfer catalysts phosphonium salts 454
Phase transfer catalysts podands 456
Phenacenes, and aromaticity 67
Phenalene, and aromaticity 50
Phenanthrenes and aromaticity 49
Phenanthrenes from photocyclization of stilbenes 1436
Phenanthrenes reaction with oxygen 1054
Phenanthrenes resonance energy 49
Phenol anions see “phenoxides
Phenol, reaction with dimethyl sulfide 722
Phenol-dienone rearrangement 1402
Phenol-keto tautomerism 75—76 (also see “Tautomerism”)
Phenolic esters, from arylmethyl ketones 1528
Phenols acidity of 345
Phenols allyl, by Claisen rearrangement 1449
Phenols allyl, from allyl aryl ethers 1449
Phenols and Friedel — Crafts alkylation 709
Phenols by Fenton’s reagent 916
Phenols by rearrangement of allylic aryl ethers 1685
Phenols by rearrangement of aralkyl peroxides 1685
Phenols by rearrangement of azoxy compounds 1685
Phenols by rearrangement of N-hydroxylamines 1685
Phenols by rearrangement of phenolic esters 1685
Phenols by the Baeyer — Villiger rearrangement 1685
Phenols by the Bucherer reaction 861
Phenols by the Claisen rearrangement 1685
Phenols by the Dakin reaction 1528
Phenols by the dienone-phenol rearrangement 1685
Phenols by the Fries rearrangement 727 1685
Phenols by the Wallach rearrangement 1685
Phenols by Udenfriend’s reagent 916
Phenols coupling with diazonium salts 700
Phenols formylation by the Duff reaction 717
Phenols formylation of 716
Phenols from alkali fusion of sulfonate ions 1685
Phenols from aromatic compounds 724 916 1685
Phenols from aromatization of cyclic ketones 1685
Phenols from aryl diazonium salts 874
Phenols from aryl halides 861
Phenols from aryl ketones 1685
Phenols from aryl organometallic compounds 1685
Phenols from cyclohexadienones 1402
Phenols from esters 727 1685
Phenols from hydrolysis of aryl halides 1685
Phenols from hydrolysis of diazonium salts 1685
Phenols from hydrolysis of phenolic esters 1685
Phenols from phenolic esters 1685
Phenols from phenols 1685
Phenols from quinones 1685
Phenols hydrogenation of 1009
Phenols nitrosation of 699
Phenols reaction with chloroacetamides 722
Phenols reaction with diazo compounds 479
Phenols reaction with DMSO and DCC 722
Phenols reaction with formaldehyde and amines 722
Phenols reaction with zinc metal 866
Phenols reduction to aromatic compounds 866
Phenols sulfonate esters, reduction of 867
Phenols thioalkylation of 722
Phenonium ions 411 413
Phenonium ions and NMR 413
Phenonium ions benzene, charge distribution 685
Phenoxides as ambident nucleophiles 459
Phenoxides from aryl sulfonic acids 862
Phenoxides reaction with  718
Phenoxides reaction with chloroform 716
Phenyl cation 223
Phenyl chloroformate, cleavage of amines 522
Phenyl radicals, reactions rates with substituted benzenes 905
Phenylhydrazine and the Fischer indole synthesis 1453
Phenylhydrazine reaction with aldehydes or ketones 1453
Phenyliodosyl bis(trifluoroacetate), and Hofmann rearrangement 1412
Phenyllithium 236
Phenyllithium from bromobenzene 699
Phenyllithium reaction with carbamates 1215
Phenyllithium reaction with thiobenzophenone 1172
Phenylselenyl bromide, reaction with enolate anions 783
Phenylselenyl chloride, reaction with enolate anions 783
Phosgene and aromatic formylations 715
Phosgene reaction with alcohols 483
Phosgene reaction with amines 507
Phosgene reaction with aromatic compounds 718
Phosgene reaction with formamides 1350
Phosphates, aryl diethyl, reaction with potassium amide and K 866
Phosphine oxides bonding 45
Phosphine oxides reaction with isocyanates 1246
Phosphines from alkyl halides 1685
Phosphines from Grignard reagents 1685
Phosphines from phosphonium salts 1685
Phosphines from phosphorus halides 1685
Phosphines reaction with alkyl halides 501 1231
Phosphines reaction with epoxides 1235
Phosphines reaction with methylpyridinium salts 501
Phosphite, triphenyl, reaction with aldehydes and bromine 1196
Phosphonate esters see “Esters”
Phosphonate ylids see “Ylids”
Phosphonates, by the Arbuzov reaction 1234
Phosphonic esters, coupling with Grignard reagents 544
Phosphonium salts as phase transfer catalysts 454—455
Phosphonium salts from Michael alkenes 1231
| Phosphonium salts from phosphines and alkyl halides 1231
Phosphonium salts reaction with bases 1231
Phosphonium salts reaction with organolithium reagents 793
Phosphonium ylids, from phosphonium salts 793
Phosphoranes see “Ylids phosphorus”
Phosphorescence 315
Phosphoric acids, anhydrides 494
Phosphorous pentoxide, dehydration agent 491
Phosphorus halides, reaction with alcohols 518
Phosphorus oxychloride and formylation of alkenes 785
Phosphorus oxychloride and formylation of aromatic compounds 715
Phosphorus oxychloride and the Bischler — Napieralski reaction 721
Phosphorus oxychloride reaction with alcohols 493
Phosphorus pentachloride and valence electrons 13
Phosphorus pentachloride reaction with aldehydes or ketones 1195
Phosphorus pentachloride reaction with amides 1464
Phosphorus pentachloride reaction with malic acid 391
Phosphorus pentachloride reaction with oximes 1349 1415
Phosphorus pentachloride reaction with sulfonic acids 577
Phosphorus pentoxide, dehydration of amides 1350
Phosphorus tribromide, reaction with carboxylic acids 777
Phosphorus ylids see “Ylids phosphorus”
Phosphorus ylids, and the Wittig reaction 1231—1237
Phosphorus, stabilization of carbanions 231
Photo — Fries rearrangement 727
Photo — Fries rearrangement relation to photolysis of arylamines 730
Photochemical decarboxylation 811
Photochemical reactions 306
Photochemical Wallach rearrangement 1465
Photochemistry addition of alcohols to alkenes 997
Photochemistry alkylation of quinolines 934
Photochemistry and absorption 308
Photochemistry and an actinometer 322
Photochemistry and angular momentum 315
Photochemistry and auxochromes 310
Photochemistry and chromophores 308 310
Photochemistry and circularly polarized light 150
Photochemistry and cis/trans isomerization 320
Photochemistry and conjugation 310
Photochemistry and dimerization of ketones 1560
Photochemistry and extinction coefficient 307
Photochemistry and extrusion reactions of pyrazolines 1353
Photochemistry and fluorescence 313—314
Photochemistry and forbidden transitions 308
Photochemistry and Hund’s rule 308
Photochemistry and intersystem crossing 315
Photochemistry and Jablonski diagrams 313—314
Photochemistry and phosphorescence 315
Photochemistry and photolysis 312
Photochemistry and photosensitization 316
Photochemistry and Planck’s constant 306
Photochemistry and quantum yield 322
Photochemistry and radicals 245 312
Photochemistry and spectrophotometers 306
Photochemistry and the Barton reaction 1463
Photochemistry and the Diels — Alder reaction 1065
Photochemistry and the electromagnetic spectrum 307
Photochemistry and the Kolbe reaction 942
Photochemistry and the Orton rearrangement 729
Photochemistry and the Wolff rearrangements 1406
Photochemistry and triplet state reactivity 317
Photochemistry and triplet states 311
Photochemistry and vibrational levels 307—308
Photochemistry and [2+2]-cycloadditions 1081
Photochemistry benzene with alkenes 1093
Photochemistry cleavage 312
Photochemistry cleavage to radicals 318
Photochemistry cyclization of stilbenes 1436
Photochemistry decomposition 318
Photochemistry dehydrohalogenation 1513
Photochemistry dimerization 321
Photochemistry exciplex formation in [2+2]-cycloadditions 1082
Photochemistry flash photolysis 321
Photochemistry halogenation of hydrocarbons 907
Photochemistry hydrogen atom abstraction 321
Photochemistry internal conversions 313
Photochemistry intramolecular [2+2]-cycloadditions 1082
Photochemistry mechanism determination 231
Photochemistry Norrish Type I cleavage 318—319
Photochemistry Norrish Type II cleavage 318—319
Photochemistry of 1,4-dienes 1460
Photochemistry of 2,5-cyclohexadienones 1461
Photochemistry of aryl keto esters 1532
Photochemistry of cyclobutanones 1354
Photochemistry of dienes and trienes 1426
Photochemistry of ketene 319
Photochemistry of ketones 1560
Photochemistry of N-iodoamides 1463
Photochemistry of pyrazoles 1353
Photochemistry of thiohydroxamic esters 942
Photochemistry of triazolines 1057
Photochemistry photo Fries rearrangement 727
Photochemistry photosensitizers 316
Photochemistry physical processes of excited molecules 315
Photochemistry reactions 318
Photochemistry rearrangements 319
Photochemistry singlet and triplet states 308—309 316
Photochemistry singlet states 311
Photochemistry spin-forbidden transitions 309
Photochemistry symmetry-forbidden transitions 209
Photochemistry the Franck — Condon principle 312
Photochemistry types of excitation 309
Photochemistry Wallach rearrangement 1465
Photochemistry Wigner spin-conservation rule 316
Photodimerization 321
Photoelectron spectroscopy 10—12
Photoelectron spectroscopy and carbocations 224
Photoisomerization 319—30
Photolysis, definition 312
Photolytic halogenation 899
Photooxygenation, of alkenes 1054
Photosensitization 316
Photosensitization and the Paterno — Buchi reaction 1250
Photosensitization in [2+2]-cycloadditions 1081
Photosensitization of mercury, and alkane dimerization 926
Photosensitization of oxygen 921
Photosensitizers 316
Photosensitizers and reaction of oxygen with dienes 1054
Photosensitizers mercury, and dimerization of alkenes 1021
Phthalamic acid, hydrolysis of 427
Phthalate ion, rearrangement of 733
Phthalic anhydride, from naphthalene 1527
Phthalimide, potassium reaction with alkyl halides 513
Phthalimide, potassium reaction with aryl halides 865
Phthalimides reaction with hydrazine 513
Phthalimides reagents for hydrolysis 514
Picric acid acidity in DMF 351
Picric acid electron donor-acceptor complexes 104
Picryl chloride, reaction with hydroxide,  -complex 852
Picryl iodide, bond lengths 43
Pig liver ester esterase, hydrolysis of esters 470
Pig liver esterase, and Meinwald rearrangement 1398
Pimm sativum, oxidation of ketones 1533
Pinacol coupling 1560—1561
Pinacol rearrangement 1384 1396—1398
Pinacol rearrangement and quasi-Favorskii rearrangement 1405
Pinacol rearrangement migratory aptitudes 1384—1385
Pinacol rearrangement regioselectivity 1397
Pinacol rearrangement with epoxides 1398
Pinacols see “Diols”
Pinacols from aldehydes or ketones 1559—1561
Pinacols side products of Clemmensen reduction 1547
Pinene, reaction with borane 1014
Pinner synthesis 1183
Pinocolate, titanium 1562
Piperidine catalyst for the Doebner modification 1226
Piperidine reaction with cyclopropylmethyl halides 423
Piperidines, by the Hofrnann — Loeffler reaction 1462
Pitzer strain 184
Planck’s constant 3 306
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