Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure :: Электронная библиотека попечительского совета мехмата МГУ

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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures

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Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

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Предметный указатель

Radicals from radicals      246
Radicals generation of      245—247
Radicals homocubyl      1390
Radicals hydrogen atom abstraction, and the Hammett equation      903
Radicals hydrogen atom abstraction, and the Hammett equation abstraction of a halogen, reactivity order      903
Radicals hydrogen atom abstraction, and the Hammett equation abstraction of hydrogen and stereoselectivity      903
Radicals hydrogen atom abstraction, and the Hammett equation abstraction reactions      246 896
Radicals hydrogen atom abstraction, and the Hammett equation abstraction, and bond angles      903
Radicals hydrogen atom abstraction, and the Hammett equation activation energy of      906
Radicals hydrogen atom abstraction, and the Hammett equation acyl, cyclization      1040
Radicals hydrogen atom abstraction, and the Hammett equation addition of silanes to alkenes      1039
Radicals hydrogen atom abstraction, and the Hammett equation addition reactions      246
Radicals hydrogen atom abstraction, and the Hammett equation addition to cyclopropanes      990
Radicals hydrogen atom abstraction, and the Hammett equation allylic, bromination      911
Radicals hydrogen atom abstraction, and the Hammett equation allylic, from alkenes      902
Radicals hydrogen atom abstraction, and the Hammett equation allylic, rearrangement of      902
Radicals in reduction of nitro compounds      531
Radicals in the Orton rearrangement      729
Radicals in [2+2]-cycloadditions      1080
Radicals isobutyl      1390
Radicals nucleophilic      903
Radicals nucleophilic, addition to alkenes      983
Radicals order of stability      241
Radicals oxygenation of alkenes      914
Radicals phenyl, reaction with substituted benzenes      905
Radicals polar      902
Radicals propeller shaped      244
Radicals pyramidal structure      244
Radicals radical ions      247
Radicals reaction at bridgehead carbons      904
Radicals reaction with alkenes      901
Radicals reaction with hydrocarbons      901
Radicals reaction with side chains of aromatic compounds      902
Radicals reaction with silanes      895
Radicals reaction with tributyltin hydride      895
Radicals reactivity with aliphatic substrates      900
Radicals reactivity with aromatic substrates      904
Radicals rearrangements      246 1389—1392
Radicals rearrangements 1,2phenyl migration      1389
Radicals rearrangements, and decarbonylation of aldehydes      1389
Radicals rearrangements, labeling experiments      1389
Radicals selectivity      905
Radicals solvent effects      906
Radicals spin traps      239
Radicals stability of      238—245 985
Radicals stable      242—243
Radicals stereoelectronic effects      903
Radicals structure of      238—245
Radicals substitution reactions and neighboring group effects      899
Radicals substitution reactions with hydrocarbons      899
Radicals succinimidyl      913
Radicals t-butyl      1390
Radicals transannular rearrangements      1392
Radicals triarylmethyl      242
Radicals tricyanomethyl      242
Radicals triphenylmethyl, stability of      905
Radicals vinyl, and rearrangements      1391
Radical’s field effects      906
Radiolabeling      see “Labeling”
Ramberg — Backlund reaction      1342
Ramberg — Backlund reaction and cheletropic reactions      1342
Ramberg — Backlund reaction and orbital symmetry rales      1342
Ramberg — Backlund reaction suprafacial vs. antarafacial processes      1342
Ramberg — Backlund reaction with $\alpha$ -halo sulfides      1343
Raney nickel and dehalogenation of aryl halides      735
Raney nickel and reduction of nitriles      1204
Raney nickel catalyst for hydrogenation      1003
Raney nickel reaction with dithianes      557
Raney nickel reaction with sulfur compound      532
Raney nickel reduction of thiols and thioethers      940
Raney nickel reduction of thiono esters      1550
Rate constant, definition      291
Rate constants      also see “Kinetics”
Rate constants, and the Hammett equation      369
Rate controlling      see “Rate determining”
Rate determining step      291—292
Rate determining step, electrophilic aromatic substitution      694
Rate law      290
Rate law,       394
Rate limiting      see “Rate determining”
Rate of reaction acceleration, in Diels — Alder reactions      1065—1066
Rate of reaction alkyl halide hydrolysis      365
Rate of reaction alkyl halide solvolysis      366
Rate of reaction amide hydrolysis      475
Rate of reaction and $\sigma$ values      371—372
Rate of reaction and dual substituent parameter equation      373
Rate of reaction and enantiomers      126
Rate of reaction and isotope effects      297
Rate of reaction and kinetic resolution      153—154
Rate of reaction and mechanisms      290—296
Rate of reaction and size of anions      451
Rate of reaction and solvent effects      451
Rate of reaction and solvent polarity      450
Rate of reaction and substituents in aryl radicals      904
Rate of reaction and the reaction      390
Rate of reaction and the ortho effect      375
Rate of reaction diazomethane decomposition      1087
Rate of reaction electrophilic addition to allcenes      983
Rate of reaction electrophilic aromatic substitution      688 694
Rate of reaction for reactions      394
Rate of reaction for reactions of allyl tosylates      434
Rate of reaction for reactions, effect of $\beta$ -unsaturation      434
Rate of reaction for reactions, effect of $\alpha$ -substituents      436
Rate of reaction for reactions, for alkyl substrates      432
Rate of reaction for reactions      851
Rate of reaction for E1 elimination      1307
Rate of reaction for E2 elimination      1300 1302
Rate of reaction for ortho/para substitution      690
Rate of reaction for solvolysis of alkyl halides      432
Rate of reaction for solvolysis of bicyclic compounds      1435
Rate of reaction forE1cB elimination      1310
Rate of reaction haloform reaction      813
Rate of reaction halogenation of ketones an aldehydes      776
Rate of reaction heterocycles and electrophilic aromatic substitution      689
Rate of reaction hydrolysis of acetals and structure      466
Rate of reaction in aqueous Diels — Alder reactions      1066
Rate of reaction isotopic exchange for carbanions      765
Rate of reaction nucleophilic addition and conjugation      1174
Rate of reaction organomercury bromides and bromine      768
Rate of reaction pH and oxime formation      1194
Rate of reaction phenyl radicals with substituted benzenes      905
Rate of reaction pyrolytic eliminations      1324
Rate of reaction radical reactions with alkanes      901
Rate of reaction radicals with tin hydride or silanes      895
Rate of reaction substituent effects and the Diels — Alder reaction      1065
re nomenclature      166
re/si nomenclature      166
Reaction coordinate, and kinetics      279
Reaction medium, and nucleophilic substitution      450—454
Reaction order      291
Reaction rate      see “Rate of reaction”
Reaction, types      275—277
Reactions and asymmetric induction      150
Reactions and circularly polarized light      150
Reactions and kinetics      278—282
Reactions enantioselective      150
Reactions photochemical      306 318
Reactions self-immolative      150
Reactions synthetic, nucleophilic substitution      440—441
Reactions thermodynamic requirements      277—278
Reactions with intermediates      281—282
Reactivity order, radical abstraction of halogen      903
Reagents for acetal hydrolysis      468
Reagents for ester hydrolysis      470
Reagents for Organic Synthesis      1627
Reagents nucleophilic strength      444
Rearrangements $\alpha$ -ketol      1401
Rearrangements $\sigma$ -bond      1459 1465
Rearrangements $\sigma$ -bond, and carbocations      1460
Rearrangements 1,2-methyl shift      1383

Rearrangements 1,2-shifts, in aromatic compound cleavage      731
Rearrangements 1,3 hydride      1387
Rearrangements 1,3 migration of bromine      1387
Rearrangements 1.2 shifts and stereochemistry      1380
Rearrangements alkynes to allenes      771
Rearrangements and reactions      1381
Rearrangements and concertedness      1381
Rearrangements and crossover experiments      1378
Rearrangements and Friedel — Crafts alkylation      709
Rearrangements and ipso substitution      687
Rearrangements and neighboring group effects      1381
Rearrangements and preparation of alkyL halides from alcohols      518
Rearrangements and stabilomers      1396
Rearrangements and the Arndt — Eistert synthesis      1405—1407
Rearrangements and the Henkel reaction      733
Rearrangements and the Jacobsen reaction      734
Rearrangements and the Schmidt reaction      1413—1415
Rearrangements anionotropic      1377
Rearrangements aza-Cope      1445
Rearrangements aza-Wittig      1422
Rearrangements azo-Cope      1452
Rearrangements Baeyer — Vifliger      1417
Rearrangements Barton reaction      1463
Rearrangements Beckmann      1349 1381 1384 1415—1416
Rearrangements Beckmann, and the Ritter reaction      1416
Rearrangements Beckmann, and the Schmidt rearrangement      1416
Rearrangements benzidine      1455—1456
Rearrangements benzidine, labeling experiments      1456
Rearrangements benzidine, semidine formation      1455
Rearrangements benzil-benzilic acid      1403
Rearrangements borane oxidation to alcohols      797
Rearrangements boron migration      1409
Rearrangements cationotropic      1377
Rearrangements Chapman      1464
Rearrangements circumambulatory      1440
Rearrangements Claisen      1449—1452 1454
Rearrangements Cope      1444—1449
Rearrangements Cope, and bullvalene      1448
Rearrangements Cope, nonconcerted      1447
Rearrangements Curtius      1380 1384 1406 1412
Rearrangements cyclopropane carbenes to allenes      1400
Rearrangements cyclopropyl, and diradicals      1400
Rearrangements cyclopropyl, conservation of orbital symmetry      1400
Rearrangements degenerate      1380
Rearrangements Demyanov      1398—1400
Rearrangements deuterated anilines      727
Rearrangements di- $\pi$ -methane      1460
Rearrangements diazoketones      1414
Rearrangements dienone-phenol      1402
Rearrangements double bond migration in alkenes      770
Rearrangements double bond shifts and electrophilic substitution      766
Rearrangements dyotropic      1465
Rearrangements enolene      1450
Rearrangements Favorskii      1403—1405
Rearrangements Favorskii, labeling experiments      1404
Rearrangements Favorskii, quasi-Favorskii      1405
Rearrangements Fischer — Hepp      728
Rearrangements Fries      726
Rearrangements Grovenstein — Zimmerman      1396
Rearrangements Hofmann      1380 1384 1411
Rearrangements in aromatic compound cleavage      731
Rearrangements in aromatic compounds      876—880
Rearrangements in aryl carboxylic acid decarboxylation      733
Rearrangements in bicyclic systems      1386
Rearrangements in borane reactions with halo carbonyls      560
Rearrangements in diradicals      1390
Rearrangements in polyhalobenzenes      735
Rearrangements intermolecular      1378
Rearrangements intramolecular      1378
Rearrangements Ireland — Claisen      1452
Rearrangements Lossen      1380 1413
Rearrangements mechanism      276
Rearrangements Meinwald      1398
Rearrangements Meisenheimer      1420
Rearrangements Meyer — Schuster      423
Rearrangements Michaelis — Arbuzov      1289 (ref. 750)
Rearrangements Mislow — Evans      1455
Rearrangements Nametkin      1395
Rearrangements Neber      288 1410
Rearrangements nucleophilic      1378—1388
Rearrangements nucleophilic, and carbocations      1378
Rearrangements nucleophilic, and nitrenes      1378
Rearrangements nucleophilic, long range      1387—1388
Rearrangements nucleophilic, migratory aptitudes      1384—1386
Rearrangements of $\alpha$ -hydroxy aldehydes or ketones      1401
Rearrangements of aldehydes      1401
Rearrangements of alkyl carbenes      1084
Rearrangements of allylic radicals      902
Rearrangements of amine oxides      1420
Rearrangements of aryl hydroxylamines      878
Rearrangements of aryl radicals, as intermediates      1390
Rearrangements of carbenes      252 1392
Rearrangements of carbocations      227 407—420 786 1379
Rearrangements of carbocations, and NMR      419
Rearrangements of cations and cyclopropane      1382
Rearrangements of cyclobutylmethyl cations      418
Rearrangements of cyclopropylmethyl cation      417
Rearrangements of Grignard reagents and vinyl epoxides      547
Rearrangements of hydroperoxides      1418
Rearrangements of isonitriles      1421
Rearrangements of ketones      1401
Rearrangements of N,N-dichloroamines      1410
Rearrangements of N-arylazo amines      728
Rearrangements of N-azo amines      728
Rearrangements of N-chloro acetamides      728
Rearrangements of N-nitro amines      727
Rearrangements of N-nitroso amines      728
Rearrangements of nitrenes      254
Rearrangements of phthalate ion      733
Rearrangements of radicals      246 1377 1389—1392
Rearrangements of radicals 1,2phenyl migration      1389
Rearrangements of radicals, and decarbonylation of aldehydes      1389
Rearrangements of radicals, labeling experiments      1389
Rearrangements of radicals, migratory aptitudes      1389
Rearrangements of radicals, transannular      1392
Rearrangements of vinyl groups in radicals      1391
Rearrangements Orton      728
Rearrangements oxa-di- $\pi$ - methane      1461
Rearrangements oxy-Cope      1445
Rearrangements para-Claisen      1449
Rearrangements Payne rearrangement      481
Rearrangements phenol-dienone      1402
Rearrangements photo-Fries      727
Rearrangements photochemical induced      319
Rearrangements pinacol      1384 1396—1398
Rearrangements pinacol, migratory aptitudes      1384—1385
Rearrangements pinacol, regioselectivity      1397
Rearrangements pinacol, with epoxides      1398
Rearrangements prototropic      771 1377
Rearrangements Pummerer      1566
Rearrangements quasi-Favorskii      1405
Rearrangements Reilly-Hickinbottom      729
Rearrangements retro pinacol      1395
Rearrangements retro-Claisen      1450
Rearrangements Schmidt      1380
Rearrangements Schmidt, and the Beckmann rearrangement      1416
Rearrangements semipinacol      1397
Rearrangements sigmatropic      1436—1456
Rearrangements sigmatropic, circumambulatory      1440
Rearrangements sigmatropic, definition      1436
Rearrangements Smiles rearrangement      879
Rearrangements Sommelet-Hauser      877 1420 1455
Rearrangements Sommelet-Hauser, and the Stevens rearrangement      1420
Rearrangements Stevens      1419—1421
Rearrangements Stevens, and sulfur ylids      1420
Rearrangements Stevens, and the Sommelet — Hauser rearrangement      1420
Rearrangements Stevens, labeling experiments      1419
Rearrangements Stieglitz      1416
Rearrangements Stieglitz, and Wagner — Meerwein rearrangement      1416
Rearrangements thio-Claisen      1452

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