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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Ïðåäìåòíûé óêàçàòåëü |
Rearrangements Tiffeneau — Demyanov 1399
Rearrangements transannular 1388
Rearrangements vinylcyclobutane 1444
Rearrangements vinylcyclopropane 1443
Rearrangements vinylcyclopropane, and formation of heterocycles 1443
Rearrangements vinylcyclopropane, and homodienyl [1,5] shifts 1444
Rearrangements von Richter rearrangement 876
Rearrangements Wallach 1464
Rearrangements Wallach, photochemical 14
Rearrangements Whitmore 1,2 shift 1378
Rearrangements Wittig 1421
Rearrangements Wittig rearrangement 558
Rearrangements Wittig, migratory aptitudes 1421
Rearrangements Wolff 252 1250 1405—1406
Rearrangements Wolff, and the Arndt — Eistert synthesis 1405
Rearrangements Wolff, photochemical 1406
Rearrangements, allylic 421 771
Rearrangements, allylic and allylic alcohols 544
Rearrangements, allylic and autoxidation 921
Rearrangements, allylic and Grignard reactions 546
Rearrangements, allylic and propargyl compounds 423
Rearrangements, allylic Meyer — Schuster rearrangement 423
Rearrangements, allylic of propargylic halides with  525
Rearrangements, allylic radical chlorination 914
Rearrangements, allylic with nucleophilic substitution 421—424
Rearrangements, allylic with vinyl epoxides and Grignard reagents 547
Rearrangements, electrocyclic 1426—1436
Rearrangements, electrocyclic and NMR 1435
Rearrangements, electrocyclic and super acids 1435
Rearrangements, electrocyclic conrotatory and disrotatory 1427
Rearrangements, electrocyclic frontier orbital method 1428
Rearrangements, electrocyclic Mobius — Hiickel method 1429
Rearrangements, electrocyclic orbital symmetry rues 1434
Rearrangements, electrophilic 1377 1392
Rearrangements, electrophilic ab initio studies 1392
Rearrangements, Wagner — Meerwein 1384 1393—1396
Rearrangements, Wagner — Meerwein and adamantanes 1396
Rearrangements, Wagner — Meerwein and Lewis acids 1394
Rearrangements, Wagner — Meerwein and Nametkin rearrangements 1395
Rearrangements, Wagner — Meerwein and norbornyl cations 1394
Rearrangements, Wagner — Meerwein and retro pinacol rearrangements 1395
Rearrangements, Wagner — Meerwein and stabilomers 1396
Rearrangements, Wagner — Meerwein and the Stieglitz rearrangement 1416
Rearrangements, Wagner — Meerwein andZaitsev’s rule 1393 1394
Rearrangements, Wagner — Meerwein hydride ion migration 1394
Rearrangements, Wagner — Meerwein in terpenes 1394
Red-AI and reduction of esters 1552
Red-AI eduction of epoxides 529
Reduction see “Oxidation-reduction”
Reduction and Grignard reagents 1207
Reduction and organolithium reagents 1209
Reduction and the Bouveault — Blanc reaction 1199
Reduction conjugate, of conjugated systems, reagents for 1008—1009
Reduction definition 1506
Reduction dissolving metal 1199
Reduction ease of reduction of functional groups 1545—1546
Reduction hydrogenolysis 524
Reduction Meerwein — Ponndorf — Verley reduction 1199
Reduction of alkyl halides 525
Reduction of aromatic compounds 1009—1012
Reduction of hydrazones 1203
Reduction of ketones and aldehydes 1197—1203
Reduction of ketones, and Cram’s rule 1201
Reduction of nitriles 1204
Reduction of Schiff bases 1203
Reduction ofimines 1203
Reduction with optically active boranes 1210—1211
Reduction-oxidation see “Oxidation-reduction”
Reductions, selectivity 1544—1564
Reductive acylation, of ketones 1182
Reductive alkylation of amines 1188
Reductive alkylation of lactams 513
Reductive animation 1188
Reductive coupling, of aldehydes and ketones 1559—1561
Reed reaction 924
Reformatsky reaction 1212
Reformatsky reaction and ketene-imine cycloaddition 1250
Reformatsky reaction and the Claisen reaction 1224
Reformatsky reaction and the Wittig reaction 1232
Reformatsky reaction with other metals 1212
Regiochemistry, of  -elimination 1314—1317
Regioselectivity and reaction of sulfur ylids with aldehydes or ketones 1247
Regioselectivity and the ortho/para ratio 685
Regioselectivity definition 458
Regioselectivity electrophilic substitution, monosubstituted benzenes 681—687
Regioselectivity electrophilic substitution, polycyclic aromatics 689—690
Regioselectivity in alkene addition reactions 984
Regioselectivity in reactions of organolithium reagents 792
Regioselectivity in the Diels — Alder reaction 1063
Regioselectivity in the Mannich reaction 1190
Regioselectivity in the pinacol rearrangement 1397
Regioselectivity in the Stork enamine reaction 787
Regioselectivity of borane addition to alkenes 1013
Regioselectivity of di- -methane rearrangements 1460
Regioselectivity of epoxide reduction 529
Regioselectivity of ketone enolate alkylations 554
Regioselectivity of pyrolytic eliminations 1325
Regioselectivity of radical bromination 899
Registry number, CAS 1632
Reilly — Hickinbottom rearrangement 729
Reimer — Tiemann reaction 716
Reimer — Tiemann reaction and carbenes 716
Reimer — Tiemann reaction and the Kolbe — Schmitt reaction 718
Reimer — Tiemann reaction ring expansion 717
Reissert compounds, reduction to aldehydes 533
Resins, exchange, and acetal hydrolysis 467
Resolution also see “Kinetic resolution”
Resolution and biochemical processes 153
Resolution and chiral recognition 152
Resolution and chromatography 152
Resolution and crystallization 153
Resolution and deracemization 154
Resolution and diastereomers 151—152
Resolution and differential absorption 152
Resolution and gas chromatography 156
Resolution and guest-hosts 152
Resolution and mechanical separation 153
Resolution kinetic 149 153—154
Resolution of enantiomers 126 151—155
Resonance also see “Mesomeric effect”
Resonance and aromatic radical substitution 898
Resonance and captodative compounds 159
Resonance and conjugate addition 980
Resonance and principle of least motion 1011
Resonance and radicals 241—242
Resonance and strain 43—45
Resonance and Wheland intermediates 676
Resonance captodative effect 60
Resonance effects 42
Resonance effects and acid strength 343—345
Resonance effects and electrophilic aromatic substitution 681
Resonance effects and free energy 365
Resonance effects and hyperconjugation 363
Resonance effects and structure 363
Resonance effects and vinylogy 553
Resonance effects aromatic amides 364—365
Resonance effects table 364
Resonance energy 32
Resonance energy benzene and fused ring aromatics 49
Resonance energy heterocycles 51
Resonance in amides and thioamides 158—159
Resonance in aniline 42
Resonance in aryl diazonium compounds 816
Resonance in benzene 32
Resonance in benzynes 855
Resonance in butadiene 37
Resonance in carboxylate anions 344
Resonance in chlorobenzene 41
Resonance in push-pull compounds 159
Resonance integral 35
| Resonance interaction, and electrophilic aromatic substitution 682
Resonance nitro group, and base strength 344
Resonance push-pull effect 60
Resonance rules 40—42
Resonance steric inhibition of 43—45 699
Retro aldol see “Aldol retro”
Retro aldol reaction 1220
Retro Claisen condensation see “Qaisen condensation retro”
Retro Diels — Alder reaction see “Diels — Alder reactions retro”
Retro pinacol rearrangement 1395
Retro — Claisen rearrangement 1450
Retro — Gatterman — Koch reaction 732
Retro-ene reaction 1022
Reversibility and radical addition to alkenes 981
Reversibility microscopic, and ElcB elimination 1310
Review journals 1620
Rhodium catalysts also see “Wilkinson’s catalyst”
Rhodium catalysts and addition of aldehydes to alkenes 1038
Rhodium catalysts and carbene addition reaction 1086
Rhodium catalysts and carbonylation of halides 565
Rhodium catalysts and the Bamford — Stevens reaction 1335
Rhodium catalysts chiral, and reduction of oximes 1554
Rhodium catalysts elimination with acyl halides 1339
Rhodium, and insertion reactions of carbenes 251
Ring chain tautomerism see “Tautomerism”
Ring closure alkene addition to alkenes 1019
Ring closure and Baldwin’s rules 282—284
Ring closure and entropy 280
Ring closure and Friedel — Crafts acylation 713
Ring closure and the Bischler — Napieralski reaction 720
Ring closure and the Bradsher reaction 720
Ring closure and the Friedlander quinoline synthesis 1186
Ring closure and the Haworth reaction 714
Ring closure and the Robinson annulation 1222
Ring closure by Friedel — Crafts acylation with ketones 720
Ring closure by radical addition to dienes 878
Ring closure by the aldol reaction 1222
Ring closure by the Wittig reaction 1236
Ring closure Pschorr 929
Ring closure with aryl halides 869
Ring contraction, Demyanov 1398—1400
Ring current definition 46—47
Ring current paracyclophane 47
Ring expansion and the Beckmann rearrangement 1415
Ring expansion and the Stevens rearrangement 1419
Ring expansion by alkene metathesis 1458
Ring expansion by diazomethane homologation of cyclic ketones 1408
Ring expansion by radicals 1400
Ring expansion Demyanov 1398—1400
Ring expansion of aryl azides 1413
Ring expansion of carbenes 250—251
Ring expansion of cyano ketones 813
Ring expansion of cycloalkyl azides 1413
Ring expansion Tiffeneau — Demyanov 1399
Ring formation, by the Thorpe — Ziegler reaction 1239
Ring nitrosation 699
Ring opening, cyclopropyl cations 1434
Ring strain and ester hydrolysis 473
Ring strain and leaving groups 446
Ring strain and the Dieckmann condensation 570
Ring strain by coupling with nickel tetracarbonyl 542
Ring strain by the Story synthesis 1355
Ring strain by the Wurtz reaction 536
Ring strain closure by Friedel — Crafts alkylation 710
Ring strain closure with sulfur 704
Ring strain conformations 172—178
Ring strain cyclic amines, from amines 501
Ring strain from malonate and dihalides 550
Ring strain heterocyclic, from sulfides and dihalides 497
Ring strain other than 3or 4, stain 184—186
Ring strain puckering 172
Ring strain six-membered, conformations 172—177
Ring strain small rings and strain 180—184
Ring strain small-ring polycyclic and strain 182—183
Ring strain strain and reactivity 366
Ring strain unsaturated, and strain 186—188
Rings and cis/trans isomers 158 160—161
Ritter reaction 1244
Ritter reaction and the Beckmann rearrangement 1416
Robinson annulation reaction 1222 1224
Rosenmund catalyst 1005
Rosenmund reduction 532
Rosenmund — von Braun reaction 867
Rotamer, definition 167
Rotation and NMR 295
Rotation and rings 160
Rotation around single bonds 168—169
Rotation optical see “Optical rotation”
Rotation restricted, and allenes 133—134
Rotation restricted, and cis/trans isomers 156—157 159
Rotation restricted, torsional diastereomers 133—134
Rotation specific, and optical purity 155—156
Rotaxanes 113—114
Rotaxanes and chirality 136
Rotaxanes and fullerene 114
Rotaxanes and inclusion compounds 114
Rotaxanes and isomers 113
Rotaxanes and molecular shuttles 114
Rotaxanes definition 113
Rule  200
Ruthenium catalysts and hydrogenation of aldehydes or ketones 1198
Ruthenium catalysts and reaction of amines with nitriles 1192
Ruthenium oxide, reaction with alkynes 1540
Ruthenium tetroxide and oxidation of alcohols 1515
Ruthenium tetroxide oxidation of ethers 1534
Ruzicka cyclization 574
s character and carbanions 228 231
s character and strain 181
S states see “Singlet state”
Sacrificial hyperconjugation 73
Sadtler Index 1618
Sakurai reaction 1024
Salen manganese, and oxidation of ketones 1531
Salen, cobalt catalysts 468
Salen, cobalt complex, and epoxidation of alkenes 1053
Salen, manganese catalyst and formation of aziridines 1058
Salen, manganese catalyst and oxidation of ketones 1533
Salt effects 395 451
Salt effects and the  reaction 763
Salt effects in the Wittig reaction 1235
Salt effects special 399 452
Salts, hydrocarbon 230
Samarium iodide and reduction of isothiocyanates 1203
Samarium iodide and the Knoevenagel reaction 1226
Samarium iodide and the Prins reaction 1242
Samarium iodide and the Wurtz reaction 536
Samarium iodide and [2,3] Wittig rearrangement 1454
Samarium iodide coupling acyl halides 568
Samarium iodide reduction of nitriles 528
Samarium iodide reduction of pyridine 1011
Samarium iodide ring expansion of bicyclic ketones 1408
Samarium, and reduction of nitro compounds 1552
Sanderson electronegativity 14
Sandmeyer reaction 874 875 936
SANDRA 1629
Sandwich compounds see “Metallocenes”
Saponification see “Esters hydrolysis”
Saponification, of esters 470
Schiemann reaction 875
Schiff bases 1186
Schiff bases and organolithium reagents 547
Schiff bases hydrolysis of 1177
Schiff bases reaction with HCN 1240
Schiff bases reduction of 1203
Schlenk equilibrium 234
Schleyer adamantization 1396
Schmidt reaction 1413—1415
Schmidt rearrangement 1380
Schmidt rearrangement and the Beckmann rearrangement 1416
Scholl reaction 711
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