Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure :: Электронная библиотека попечительского совета мехмата МГУ

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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Rearrangements Tiffeneau — Demyanov      1399
Rearrangements transannular      1388
Rearrangements vinylcyclobutane      1444
Rearrangements vinylcyclopropane      1443
Rearrangements vinylcyclopropane, and formation of heterocycles      1443
Rearrangements vinylcyclopropane, and homodienyl [1,5] shifts      1444
Rearrangements von Richter rearrangement      876
Rearrangements Wallach      1464
Rearrangements Wallach, photochemical      14
Rearrangements Whitmore 1,2 shift      1378
Rearrangements Wittig      1421
Rearrangements Wittig rearrangement      558
Rearrangements Wittig, migratory aptitudes      1421
Rearrangements Wolff      252 1250 1405—1406
Rearrangements Wolff, and the Arndt — Eistert synthesis      1405
Rearrangements Wolff, photochemical      1406
Rearrangements, allylic      421 771
Rearrangements, allylic and allylic alcohols      544
Rearrangements, allylic and autoxidation      921
Rearrangements, allylic and Grignard reactions      546
Rearrangements, allylic and propargyl compounds      423
Rearrangements, allylic Meyer — Schuster rearrangement      423
Rearrangements, allylic of propargylic halides with       525
Rearrangements, allylic radical chlorination      914
Rearrangements, allylic with nucleophilic substitution      421—424
Rearrangements, allylic with vinyl epoxides and Grignard reagents      547
Rearrangements, electrocyclic      1426—1436
Rearrangements, electrocyclic and NMR      1435
Rearrangements, electrocyclic and super acids      1435
Rearrangements, electrocyclic conrotatory and disrotatory      1427
Rearrangements, electrocyclic frontier orbital method      1428
Rearrangements, electrocyclic Mobius — Hiickel method      1429
Rearrangements, electrocyclic orbital symmetry rues      1434
Rearrangements, electrophilic      1377 1392
Rearrangements, electrophilic ab initio studies      1392
Rearrangements, Wagner — Meerwein      1384 1393—1396
Rearrangements, Wagner — Meerwein and adamantanes      1396
Rearrangements, Wagner — Meerwein and Lewis acids      1394
Rearrangements, Wagner — Meerwein and Nametkin rearrangements      1395
Rearrangements, Wagner — Meerwein and norbornyl cations      1394
Rearrangements, Wagner — Meerwein and retro pinacol rearrangements      1395
Rearrangements, Wagner — Meerwein and stabilomers      1396
Rearrangements, Wagner — Meerwein and the Stieglitz rearrangement      1416
Rearrangements, Wagner — Meerwein andZaitsev’s rule      1393 1394
Rearrangements, Wagner — Meerwein hydride ion migration      1394
Rearrangements, Wagner — Meerwein in terpenes      1394
Red-AI and reduction of esters      1552
Red-AI eduction of epoxides      529
Reduction      see “Oxidation-reduction”
Reduction and Grignard reagents      1207
Reduction and organolithium reagents      1209
Reduction and the Bouveault — Blanc reaction      1199
Reduction conjugate, of conjugated systems, reagents for      1008—1009
Reduction definition      1506
Reduction dissolving metal      1199
Reduction ease of reduction of functional groups      1545—1546
Reduction hydrogenolysis      524
Reduction Meerwein — Ponndorf — Verley reduction      1199
Reduction of alkyl halides      525
Reduction of aromatic compounds      1009—1012
Reduction of hydrazones      1203
Reduction of ketones and aldehydes      1197—1203
Reduction of ketones, and Cram’s rule      1201
Reduction of nitriles      1204
Reduction of Schiff bases      1203
Reduction ofimines      1203
Reduction with optically active boranes      1210—1211
Reduction-oxidation      see “Oxidation-reduction”
Reductions, selectivity      1544—1564
Reductive acylation, of ketones      1182
Reductive alkylation of amines      1188
Reductive alkylation of lactams      513
Reductive animation      1188
Reductive coupling, of aldehydes and ketones      1559—1561
Reed reaction      924
Reformatsky reaction      1212
Reformatsky reaction and ketene-imine cycloaddition      1250
Reformatsky reaction and the Claisen reaction      1224
Reformatsky reaction and the Wittig reaction      1232
Reformatsky reaction with other metals      1212
Regiochemistry, of $\beta$ -elimination      1314—1317
Regioselectivity and reaction of sulfur ylids with aldehydes or ketones      1247
Regioselectivity and the ortho/para ratio      685
Regioselectivity definition      458
Regioselectivity electrophilic substitution, monosubstituted benzenes      681—687
Regioselectivity electrophilic substitution, polycyclic aromatics      689—690
Regioselectivity in alkene addition reactions      984
Regioselectivity in reactions of organolithium reagents      792
Regioselectivity in the Diels — Alder reaction      1063
Regioselectivity in the Mannich reaction      1190
Regioselectivity in the pinacol rearrangement      1397
Regioselectivity in the Stork enamine reaction      787
Regioselectivity of borane addition to alkenes      1013
Regioselectivity of di- $\pi$ -methane rearrangements      1460
Regioselectivity of epoxide reduction      529
Regioselectivity of ketone enolate alkylations      554
Regioselectivity of pyrolytic eliminations      1325
Regioselectivity of radical bromination      899
Registry number, CAS      1632
Reilly — Hickinbottom rearrangement      729
Reimer — Tiemann reaction      716
Reimer — Tiemann reaction and carbenes      716
Reimer — Tiemann reaction and the Kolbe — Schmitt reaction      718
Reimer — Tiemann reaction ring expansion      717
Reissert compounds, reduction to aldehydes      533
Resins, exchange, and acetal hydrolysis      467
Resolution      also see “Kinetic resolution”
Resolution and biochemical processes      153
Resolution and chiral recognition      152
Resolution and chromatography      152
Resolution and crystallization      153
Resolution and deracemization      154
Resolution and diastereomers      151—152
Resolution and differential absorption      152
Resolution and gas chromatography      156
Resolution and guest-hosts      152
Resolution and mechanical separation      153
Resolution kinetic      149 153—154
Resolution of enantiomers      126 151—155
Resonance      also see “Mesomeric effect”
Resonance and aromatic radical substitution      898
Resonance and captodative compounds      159
Resonance and conjugate addition      980
Resonance and principle of least motion      1011
Resonance and radicals      241—242
Resonance and strain      43—45
Resonance and Wheland intermediates      676
Resonance captodative effect      60
Resonance effects      42
Resonance effects and acid strength      343—345
Resonance effects and electrophilic aromatic substitution      681
Resonance effects and free energy      365
Resonance effects and hyperconjugation      363
Resonance effects and structure      363
Resonance effects and vinylogy      553
Resonance effects aromatic amides      364—365
Resonance effects table      364
Resonance energy      32
Resonance energy benzene and fused ring aromatics      49
Resonance energy heterocycles      51
Resonance in amides and thioamides      158—159
Resonance in aniline      42
Resonance in aryl diazonium compounds      816
Resonance in benzene      32
Resonance in benzynes      855
Resonance in butadiene      37
Resonance in carboxylate anions      344
Resonance in chlorobenzene      41
Resonance in push-pull compounds      159
Resonance integral      35

Resonance interaction, and electrophilic aromatic substitution      682
Resonance nitro group, and base strength      344
Resonance push-pull effect      60
Resonance rules      40—42
Resonance steric inhibition of      43—45 699
Retro aldol      see “Aldol retro”
Retro aldol reaction      1220
Retro Claisen condensation      see “Qaisen condensation retro”
Retro Diels — Alder reaction      see “Diels — Alder reactions retro”
Retro pinacol rearrangement      1395
Retro — Claisen rearrangement      1450
Retro — Gatterman — Koch reaction      732
Retro-ene reaction      1022
Reversibility and radical addition to alkenes      981
Reversibility microscopic, and ElcB elimination      1310
Review journals      1620
Rhodium catalysts      also see “Wilkinson’s catalyst”
Rhodium catalysts and addition of aldehydes to alkenes      1038
Rhodium catalysts and carbene addition reaction      1086
Rhodium catalysts and carbonylation of halides      565
Rhodium catalysts and the Bamford — Stevens reaction      1335
Rhodium catalysts chiral, and reduction of oximes      1554
Rhodium catalysts elimination with acyl halides      1339
Rhodium, and insertion reactions of carbenes      251
Ring chain tautomerism      see “Tautomerism”
Ring closure alkene addition to alkenes      1019
Ring closure and Baldwin’s rules      282—284
Ring closure and entropy      280
Ring closure and Friedel — Crafts acylation      713
Ring closure and the Bischler — Napieralski reaction      720
Ring closure and the Bradsher reaction      720
Ring closure and the Friedlander quinoline synthesis      1186
Ring closure and the Haworth reaction      714
Ring closure and the Robinson annulation      1222
Ring closure by Friedel — Crafts acylation with ketones      720
Ring closure by radical addition to dienes      878
Ring closure by the aldol reaction      1222
Ring closure by the Wittig reaction      1236
Ring closure Pschorr      929
Ring closure with aryl halides      869
Ring contraction, Demyanov      1398—1400
Ring current definition      46—47
Ring current paracyclophane      47
Ring expansion and the Beckmann rearrangement      1415
Ring expansion and the Stevens rearrangement      1419
Ring expansion by alkene metathesis      1458
Ring expansion by diazomethane homologation of cyclic ketones      1408
Ring expansion by radicals      1400
Ring expansion Demyanov      1398—1400
Ring expansion of aryl azides      1413
Ring expansion of carbenes      250—251
Ring expansion of cyano ketones      813
Ring expansion of cycloalkyl azides      1413
Ring expansion Tiffeneau — Demyanov      1399
Ring formation, by the Thorpe — Ziegler reaction      1239
Ring nitrosation      699
Ring opening, cyclopropyl cations      1434
Ring strain and ester hydrolysis      473
Ring strain and leaving groups      446
Ring strain and the Dieckmann condensation      570
Ring strain by coupling with nickel tetracarbonyl      542
Ring strain by the Story synthesis      1355
Ring strain by the Wurtz reaction      536
Ring strain closure by Friedel — Crafts alkylation      710
Ring strain closure with sulfur      704
Ring strain conformations      172—178
Ring strain cyclic amines, from amines      501
Ring strain from malonate and dihalides      550
Ring strain heterocyclic, from sulfides and dihalides      497
Ring strain other than 3or 4, stain      184—186
Ring strain puckering      172
Ring strain six-membered, conformations      172—177
Ring strain small rings and strain      180—184
Ring strain small-ring polycyclic and strain      182—183
Ring strain strain and reactivity      366
Ring strain unsaturated, and strain      186—188
Rings and cis/trans isomers      158 160—161
Ritter reaction      1244
Ritter reaction and the Beckmann rearrangement      1416
Robinson annulation reaction      1222 1224
Rosenmund catalyst      1005
Rosenmund reduction      532
Rosenmund — von Braun reaction      867
Rotamer, definition      167
Rotation and NMR      295
Rotation and rings      160
Rotation around single bonds      168—169
Rotation optical      see “Optical rotation”
Rotation restricted, and allenes      133—134
Rotation restricted, and cis/trans isomers      156—157 159
Rotation restricted, torsional diastereomers      133—134
Rotation specific, and optical purity      155—156
Rotaxanes      113—114
Rotaxanes and chirality      136
Rotaxanes and fullerene      114
Rotaxanes and inclusion compounds      114
Rotaxanes and isomers      113
Rotaxanes and molecular shuttles      114
Rotaxanes definition      113
Rule       200
Ruthenium catalysts and hydrogenation of aldehydes or ketones      1198
Ruthenium catalysts and reaction of amines with nitriles      1192
Ruthenium oxide, reaction with alkynes      1540
Ruthenium tetroxide and oxidation of alcohols      1515
Ruthenium tetroxide oxidation of ethers      1534
Ruzicka cyclization      574
s character and carbanions      228 231
s character and strain      181
S states      see “Singlet state”
Sacrificial hyperconjugation      73
Sadtler Index      1618
Sakurai reaction      1024
Salen manganese, and oxidation of ketones      1531
Salen, cobalt catalysts      468
Salen, cobalt complex, and epoxidation of alkenes      1053
Salen, manganese catalyst and formation of aziridines      1058
Salen, manganese catalyst and oxidation of ketones      1533
Salt effects      395 451
Salt effects and the reaction      763
Salt effects in the Wittig reaction      1235
Salt effects special      399 452
Salts, hydrocarbon      230
Samarium iodide and reduction of isothiocyanates      1203
Samarium iodide and the Knoevenagel reaction      1226
Samarium iodide and the Prins reaction      1242
Samarium iodide and the Wurtz reaction      536
Samarium iodide and [2,3] Wittig rearrangement      1454
Samarium iodide coupling acyl halides      568
Samarium iodide reduction of nitriles      528
Samarium iodide reduction of pyridine      1011
Samarium iodide ring expansion of bicyclic ketones      1408
Samarium, and reduction of nitro compounds      1552
Sanderson electronegativity      14
Sandmeyer reaction      874 875 936
SANDRA      1629
Sandwich compounds      see “Metallocenes”
Saponification      see “Esters hydrolysis”
Saponification, of esters      470
Schiemann reaction      875
Schiff bases      1186
Schiff bases and organolithium reagents      547
Schiff bases hydrolysis of      1177
Schiff bases reaction with HCN      1240
Schiff bases reduction of      1203
Schlenk equilibrium      234
Schleyer adamantization      1396
Schmidt reaction      1413—1415
Schmidt rearrangement      1380
Schmidt rearrangement and the Beckmann rearrangement      1416
Scholl reaction      711

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