Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure :: Электронная библиотека попечительского совета мехмата МГУ

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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Dimerization of dienes      1091
Dimerization of Grignard reagents      938
Dimerization of ketenes      1249
Dimerization of lithium organoaluminates      940
Dimerization of nitrenes      254
Dimerization of organocuprates      939
Dimerization of radicals      242
Dimerization photochemical      321
Dimers of dialkylamides bases      348
Dimesitylethenol, enol content      74
Dimethyl (methylthio) sulfonium fluoroborate      1058
Dimethyl dioxirane and oxidation of aromatic diols      1518
Dimethyl dioxirane oxidation of alkenes      1533
Dimethyl dioxirane oxidation of thiols      1540
Dimethyl dioxirane oxidative cleavage of diamines      1520
Dimethyl dioxirane reaction with isocyanates      1540
Dimethyl malonate, $pK_{\alpha}$       347
Dimethyl sulfide      also see “Thioethers”
Dimethyl sulfide complex with dichloroborane      1014
Dimethyl sulfide reaction with base      572
Dimethyl sulfide reaction with phenol      722
Dimethyl sulfoxide      see “DMSO”
Dimethylalkylidine cation      220
Dimethylaluminum chloride, and the Prins reaction      1242
Dimethylamine, and base strength      349
Dimethylaminofluorene      347
Dimethylaminophenanthrenes      347
Dimethyldioxirane, oxidation of ketones      916
Dimethylformamide      see “DMF”
Dimethylformamide, dimethyl acetal      480
Dimethylhydrazones elimination reactions      1348
Dimethylhydrazones oxidation of      1519
Dimethyloxosulfonium methylid reaction with aldehydes or ketones      1247
Dimethyloxosulfonium methylid reaction with aromatic nitro compounds      872
Dimethylsulfonium methylid reaction with aldehydes or ketones      1247
Dimethyltitanium dichloride reaction with aldehydes or ketones      1210
Dimethyltitanocene      1238
Dinitriles by the Thorpe reaction      1238
Dinitriles from nitrites      1238
Dinitriles from ortho-diamines      1527
Dinitriles reaction with ammonia      1192
Dinitromethane, $pK_{\alpha}$       230
Diol, gem      see “Hydrates”
Diols and the pinacol rearrangement      1384
Diols aromatic, oxidation with chromium      1517
Diols by Gomberg — Bachmann pinacol synthesis      1560
Diols by photochemical dimerization      1560
Diols by the Prevost method      1049
Diols by the Prins reaction      1241
Diols by the Tollens’ reaction      1230
Diols cyclic, from dialdehydes      1560
Diols dehydration to cyclic ethers      480
Diols formation of cyclopropanes      544
Diols fragmentation reactions      1346
Diols from alkenes      290
Diols from alkenes and formaldehyde      1241
Diols from anhydrides      1551
Diols from aromatic compounds      1050
Diols from epoxides      468 1463
Diols from Grignard reactions      1208
Diols from ketones or aldehydes      1230
Diols from lactones      1551
Diols from reductive coupling of aldehydes or ketones      1559—1561
Diols hydrogenolysis      527
Diols oxidation to lactones      1537
Diols oxidative cleavage      1519—1521
Diols reaction with       544
Diols reaction with organolithium reagents      1340
Diols reaction with thiophosgene      1340
Diols rearrangements with acid      1396—1398
Dioxane, participation in substitution reactions      402
Dioxanes and a homoanomeric interaction      176
Dioxanes conformation      175—176
Dioxirane and ozonolysis      1525
Dioxirane oxidation of ethers      1525
Diphenylacetaldehyde      1384
Diphenylmethyl cation      222
Diphenylpicrylhydrazyl radical      242
Diphenylsulfimide      1057
Diphenyltetrabenz[a,c,h,j]anthracene      44
Dipleiadiene      69
Dipolar compounds, and [3+2]-cycloadditions      1060
Dipole moment      15—16
Dipole moments, and hyperconjugation      71—72
Dipotassium nitrosodisulfonate      see “Fremy’s salt”
Diradicals      244 (also see “Radicals”)
Diradicals and Bergman cyclization      1432
Diradicals and cyclopropyl rearrangements      1400
Diradicals and dioxirane oxidation      1525
Diradicals and ozonolysis      1525
Diradicals and rearrangement      1390
Diradicals and remote oxidation      1513
Diradicals and singlet oxygen reaction with alkenes      922
Diradicals and the Cope rearrangement      1447
Diradicals and the Paterno — Bilchi reaction      1249
Diradicals in [2+2]-cycloadditions      1080
Directed aldol reaction      1222
Disfavored, and Baldwin’s rules      283—284
Disiamylborane      1012
Disodium tetracarbonylferrate      see “Tetracarbonylferrate”
Displacement, and oxidation-reduction      1509
Disproportionation and radicals      246
Disproportionation and the Cannizzaro reaction      1564
Disproportionation in reduction of carbonyls      1202
Disproportionation of aldehydes      1564
Disproportionation of carbenes      790
Disrotatory rotation, in electrocyclic rearrangements      1427
Dissociation energy of carbocations      224
Dissociation energy table, of radicals      243
Dissolving metal reductions      1200
Dissolving metal reductions and Birch reduction      1010
Dissolving metal reductions of aldehydes or ketones      1199
Dissolving metal reductions of aromatic compounds      1009
Dissolving metal reductions of carboxylic acids      532
Dissolving metal reductions of esters      529
Dissolving metal reductions ofalkynes      1008
Dissolving metal reductions with nitrites      815
Distance, bond, delocalized bonds      35—36
Distillation, azeotropic and formation of acetals or ketals      1180
Distillation, azeotropic and formation of enamines      1187
Distillation, azeotropic and formation of imines      1186
Disulflde ion, reaction with alkyl halides      498
Disulfldes by the Smiles rearrangement      1667
Disulfldes from addition of ArSSCl to alkenes      1667
Disulfldes from alkyl halides      498 1667
Disulfldes from aryl halides      1667
Disulfldes from Bunte salts      498
Disulfldes from reduction of sulfonyl halides      1667
Disulfldes from thiols      1543 1667
Disulfldes reaction with alkenes      1055
Disulfldes reaction with enolate anions      783
Disulfldes reaction with zinc and acid      1559
Dithiane anions reaction with alkyl halides      556
Dithiane anions reaction with epoxides      557
Dithianes and conformation      176
Dithianes anions      556
Dithianes formation from aldehydes      556
Dithianes reaction with organolithium reagents      556
Dithianes reaction with Raney nickel      557
Dithioacetals alkylation      557
Dithioacetals from acetals      1667
Dithioacetals from aldehydes      1181 1667
Dithioacetals from dihalides      1667
Dithioacetals from ketones      1667
Dithioacetals fromalkynes      1667
Dithiocarbamic acid salts, from amines and       1192
Dithiocarboxylic acids, from Grignard reagents and       1215
Dithiocarboxylic esters, from carboxylic acids      1184
Dithioketals from ketones and thiols      1182
Dithioketals, alkylation      557

Dithiols from alkenes      1667
Dithiols from carbonyl compounds      1667
Dithiols from disulfides      1667
Dithiols from imines      1667
Ditosylamines, reaction with iodide ion      522
Divinylcyclobutanes, Cope rearrangement      1445
Divinylcyclopropanes, Cope rearrangement      1445 1446
Diynes and the Cadiot — Chodkiewicz reaction      927
Diynes by the Eglinton reaction      927
Diynes by the Glaser reaction      927
Diynes from alkynes      561 927
Diynes from alkynylboranes      939
Diynes reaction with amines      1000
Diynes reaction with zirconium complexes      1020
DME      see “Dimethyl (l
DMF and formation of thiophenols      863
DMF and monoalkylation of amines      502
DMF and nucleophilic substitution      441
DMF and reaction of organomercury compounds      800
DMF as a solvent      450
DMF influence on acidity      351
DMSO and for coupling silyl enol ethers      1543
DMSO and Cope elimination      1333
DMSO and electrophilic aromatic substitution      705
DMSO and epoxide hydrolysis      468
DMSO and formation of thiophenols      863
DMSO and oxidation of alcohols      1515
DMSO and oxidation of alkyl halides      1535
DMSO and reactions of cyanide and alkyl halides      562
DMSO and reactivity haloaromatic compounds with anions      856
DMSO and the Ramberg — Backlund reaction      1342
DMSO as a solvent      450
DMSO as a solvent for       764
DMSO carbanion, reaction with aromatic nitro compounds      872
DMSO reaction with base      572
DMSO reaction with phenols and DMSO      722
DMSO-based reagents for oxidation of alcohols      1516
Dodecahedrane      1514
Dodecahedryl cation      224—225
Doebner modification, of the Knoevenagel reaction      1226
Double asymmetric synthesis      150 1222
Double bond migration, in alkenes      770
Double bond shifts, and electrophilic substitution      766
Double carbonylations      565
Double hyperconjugation      220
Double-asymmetric synthesis, and hydroboration      1015
Doublets in ESR      239
Dppe, and reduction of acid chlorides      533
Dry ice      see “Carbon dioxide”
Drying agents and formation of acetals or ketals      1180
Drying agents and formation of enamines      1187
Drying agents and formation of imines      1186
Dual substituent parameter equation      373
Duff reaction      717
Dyes, azo, by diazonium coupling      700
Dyotropic rearrangements      1465
E/Z isomers and enolate anions      237
E/Z isomers and the Wittig reaction      1235
E/Z nomenclature      157
E1 elimination      see “Elimination E1”
E1cB elimination      see “Elimination”
E2 elimination      see “Eliminations E2”
E2C elimination      see “Elimination”
EDA complexes      also see “Complexes electron donor-acceptor”
EDA complexes $\eta$ prefix      104
EDA complexes and reactions      763
EDA complexes and charge-transfer bonding      104
EDA complexes benzene      103
EDA complexes hapto prefix      104
EDA complexes in photochemical [2+2]-cycloadditions      1082
EDA complexes metallocenes      103
EDA complexes norbornadienone      103
EDA complexes of picric acid      104
EDA complexes spectra      102—103
EDTA and oxidation of cyclic amines      1535
Eglinton reaction      927
Elbs reaction      724
Electrochemistry and dehalogenation of aryl halides      735
Electrochemistry and dehydration of oximes      1348
Electrochemistry and dimerization of ketones      1560
Electrochemistry and the Kolbe reaction      941—942
Electrochemistry and the Wacker process      1538
Electrochemistry conpling of dichlorides      537
Electrochemistry oxidation of alkynes      1540
Electrochemistry reduction of alkyl halides      525
Electrochemistry reduction of nitro compounds      1564
Electrocyclic rearrangements      1426—1436
Electrocyclic rearrangements and NMR      1435
Electrocyclic rearrangements and super acids      1435
Electrocyclic rearrangements conrotatory/disrotatory rotation      1427
Electrocyclic rearrangements frontier orbital method      1428
Electrocyclic rearrangements Mobius — Hueckel method      1429
Electrocyclic rearrangements orbital symmetry rules      1434
Electrofuge      385
Electrofuges and electrophilic aromatic substitution      675
Electrofuges and the reaction      769
Electromagnetic spectrum      307
Electron affinity and electronegativity      15
Electron diffraction and bond distance      18
Electron donating groups      17
Electron donating groups, a values      369—370
Electron donor-acceptor complexes      102—104 (also see “Complexes”)
Electron paramagnetic resonance      see “ESR”
Electron releasing groups, $\sigma$ values      369—370 372
Electron spin resonance      see “ESR”
Electron transfer and oxidation — reduction      1508
Electron transfer and oxidation-reduction      1508
Electron withdrawing groups      17
Electron withdrawing groups and aryl radicals      905
Electron withdrawing groups and nucleophilic addition to alkenes      982
Electron-donating field effect      see “I effect”
Electronegativity      14—15
Electronegativity of substituents      15
Electronegativity Pauling and Sanderson      14
Electronic configuration      6—8
Electronic effects and migratory aptitude in carbocations      1386
Electronic effects and radical formation      902
Electronic effects in epoxidation of alkenes      1052
Electronic effects in the Claisen rearrangement      1451
Electronic structures of molecules      12—13
Electrons as waves      3
Electrons lone pairs and bond angles      22
Electrons lone pairs, steric demands      22
Electrons valence      12—13
Electrophilic aromatic substitution      see “Substitution”
Electrophilic radicals      897
Electrophilic rearrangements      1392
Electrophilic substitution      see “Substitution electrophilic”
Electrophilic, mechanism      275
Element effect      429
Elimination $\beta$ -      1299
Elimination $\beta$ -, kinetic classifications      1309
Elimination $\rho$ values      1313 1321
Elimination and acidity of $\beta$ -hydrogen      1316
Elimination and Bredt’s rule      188 1314
Elimination and Grignard formation from dihalides      805
Elimination and heat of combustion      1315
Elimination and Hofmann’s rule      1320
Elimination and ketone enolate anions with alkyl halides      552
Elimination and leaving group effects      1316 1321
Elimination and reactivity at bridgehead carbons      1314
Elimination and regiochemistey      1314—1317
Elimination and steric effects      1316 1319
Elimination and substrate structure      1319—1320
Elimination and Zaitsev’s rule      1314 1315
Elimination anti      1300
Elimination by fragmentation reactions      1345
Elimination competition with substitution      1320
Elimination conjugate      1326
Elimination Cope      1333

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