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| Авторизация |
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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Dimerization of dienes 1091
Dimerization of Grignard reagents 938
Dimerization of ketenes 1249
Dimerization of lithium organoaluminates 940
Dimerization of nitrenes 254
Dimerization of organocuprates 939
Dimerization of radicals 242
Dimerization photochemical 321
Dimers of dialkylamides bases 348
Dimesitylethenol, enol content 74
Dimethyl (methylthio) sulfonium fluoroborate 1058
Dimethyl dioxirane and oxidation of aromatic diols 1518
Dimethyl dioxirane oxidation of alkenes 1533
Dimethyl dioxirane oxidation of thiols 1540
Dimethyl dioxirane oxidative cleavage of diamines 1520
Dimethyl dioxirane reaction with isocyanates 1540
Dimethyl malonate,  347
Dimethyl sulfide also see “Thioethers”
Dimethyl sulfide complex with dichloroborane 1014
Dimethyl sulfide reaction with base 572
Dimethyl sulfide reaction with phenol 722
Dimethyl sulfoxide see “DMSO”
Dimethylalkylidine cation 220
Dimethylaluminum chloride, and the Prins reaction 1242
Dimethylamine, and base strength 349
Dimethylaminofluorene 347
Dimethylaminophenanthrenes 347
Dimethyldioxirane, oxidation of ketones 916
Dimethylformamide see “DMF”
Dimethylformamide, dimethyl acetal 480
Dimethylhydrazones elimination reactions 1348
Dimethylhydrazones oxidation of 1519
Dimethyloxosulfonium methylid reaction with aldehydes or ketones 1247
Dimethyloxosulfonium methylid reaction with aromatic nitro compounds 872
Dimethylsulfonium methylid reaction with aldehydes or ketones 1247
Dimethyltitanium dichloride reaction with aldehydes or ketones 1210
Dimethyltitanocene 1238
Dinitriles by the Thorpe reaction 1238
Dinitriles from nitrites 1238
Dinitriles from ortho-diamines 1527
Dinitriles reaction with ammonia 1192
Dinitromethane, 230
Diol, gem see “Hydrates”
Diols and the pinacol rearrangement 1384
Diols aromatic, oxidation with chromium 1517
Diols by Gomberg — Bachmann pinacol synthesis 1560
Diols by photochemical dimerization 1560
Diols by the Prevost method 1049
Diols by the Prins reaction 1241
Diols by the Tollens’ reaction 1230
Diols cyclic, from dialdehydes 1560
Diols dehydration to cyclic ethers 480
Diols formation of cyclopropanes 544
Diols fragmentation reactions 1346
Diols from alkenes 290
Diols from alkenes and formaldehyde 1241
Diols from anhydrides 1551
Diols from aromatic compounds 1050
Diols from epoxides 468 1463
Diols from Grignard reactions 1208
Diols from ketones or aldehydes 1230
Diols from lactones 1551
Diols from reductive coupling of aldehydes or ketones 1559—1561
Diols hydrogenolysis 527
Diols oxidation to lactones 1537
Diols oxidative cleavage 1519—1521
Diols reaction with  544
Diols reaction with organolithium reagents 1340
Diols reaction with thiophosgene 1340
Diols rearrangements with acid 1396—1398
Dioxane, participation in substitution reactions 402
Dioxanes and a homoanomeric interaction 176
Dioxanes conformation 175—176
Dioxirane and ozonolysis 1525
Dioxirane oxidation of ethers 1525
Diphenylacetaldehyde 1384
Diphenylmethyl cation 222
Diphenylpicrylhydrazyl radical 242
Diphenylsulfimide 1057
Diphenyltetrabenz[a,c,h,j]anthracene 44
Dipleiadiene 69
Dipolar compounds, and [3+2]-cycloadditions 1060
Dipole moment 15—16
Dipole moments, and hyperconjugation 71—72
Dipotassium nitrosodisulfonate see “Fremy’s salt”
Diradicals 244 (also see “Radicals”)
Diradicals and Bergman cyclization 1432
Diradicals and cyclopropyl rearrangements 1400
Diradicals and dioxirane oxidation 1525
Diradicals and ozonolysis 1525
Diradicals and rearrangement 1390
Diradicals and remote oxidation 1513
Diradicals and singlet oxygen reaction with alkenes 922
Diradicals and the Cope rearrangement 1447
Diradicals and the Paterno — Bilchi reaction 1249
Diradicals in [2+2]-cycloadditions 1080
Directed aldol reaction 1222
Disfavored, and Baldwin’s rules 283—284
Disiamylborane 1012
Disodium tetracarbonylferrate see “Tetracarbonylferrate”
Displacement, and oxidation-reduction 1509
Disproportionation and radicals 246
Disproportionation and the Cannizzaro reaction 1564
Disproportionation in  reduction of carbonyls 1202
Disproportionation of aldehydes 1564
Disproportionation of carbenes 790
Disrotatory rotation, in electrocyclic rearrangements 1427
Dissociation energy of carbocations 224
Dissociation energy table, of radicals 243
Dissolving metal reductions 1200
Dissolving metal reductions and Birch reduction 1010
Dissolving metal reductions of aldehydes or ketones 1199
Dissolving metal reductions of aromatic compounds 1009
Dissolving metal reductions of carboxylic acids 532
Dissolving metal reductions of esters 529
Dissolving metal reductions ofalkynes 1008
Dissolving metal reductions with nitrites 815
Distance, bond, delocalized bonds 35—36
Distillation, azeotropic and formation of acetals or ketals 1180
Distillation, azeotropic and formation of enamines 1187
Distillation, azeotropic and formation of imines 1186
Disulflde ion, reaction with alkyl halides 498
Disulfldes by the Smiles rearrangement 1667
Disulfldes from addition of ArSSCl to alkenes 1667
Disulfldes from alkyl halides 498 1667
Disulfldes from aryl halides 1667
Disulfldes from Bunte salts 498
Disulfldes from reduction of sulfonyl halides 1667
Disulfldes from thiols 1543 1667
Disulfldes reaction with alkenes 1055
Disulfldes reaction with enolate anions 783
Disulfldes reaction with zinc and acid 1559
Dithiane anions reaction with alkyl halides 556
Dithiane anions reaction with epoxides 557
Dithianes and conformation 176
Dithianes anions 556
Dithianes formation from aldehydes 556
Dithianes reaction with organolithium reagents 556
Dithianes reaction with Raney nickel 557
Dithioacetals alkylation 557
Dithioacetals from acetals 1667
Dithioacetals from aldehydes 1181 1667
Dithioacetals from dihalides 1667
Dithioacetals from ketones 1667
Dithioacetals fromalkynes 1667
Dithiocarbamic acid salts, from amines and  1192
Dithiocarboxylic acids, from Grignard reagents and 1215
Dithiocarboxylic esters, from carboxylic acids 1184
Dithioketals from ketones and thiols 1182
Dithioketals, alkylation 557
| Dithiols from alkenes 1667
Dithiols from carbonyl compounds 1667
Dithiols from disulfides 1667
Dithiols from imines 1667
Ditosylamines, reaction with iodide ion 522
Divinylcyclobutanes, Cope rearrangement 1445
Divinylcyclopropanes, Cope rearrangement 1445 1446
Diynes and the Cadiot — Chodkiewicz reaction 927
Diynes by the Eglinton reaction 927
Diynes by the Glaser reaction 927
Diynes from alkynes 561 927
Diynes from alkynylboranes 939
Diynes reaction with amines 1000
Diynes reaction with zirconium complexes 1020
DME see “Dimethyl (l
DMF and formation of thiophenols 863
DMF and monoalkylation of amines 502
DMF and nucleophilic substitution 441
DMF and reaction of organomercury compounds 800
DMF as a solvent 450
DMF influence on acidity 351
DMSO and  for coupling silyl enol ethers 1543
DMSO and Cope elimination 1333
DMSO and electrophilic aromatic substitution 705
DMSO and epoxide hydrolysis 468
DMSO and formation of thiophenols 863
DMSO and oxidation of alcohols 1515
DMSO and oxidation of alkyl halides 1535
DMSO and reactions of cyanide and alkyl halides 562
DMSO and reactivity haloaromatic compounds with anions 856
DMSO and the Ramberg — Backlund reaction 1342
DMSO as a solvent 450
DMSO as a solvent for  764
DMSO carbanion, reaction with aromatic nitro compounds 872
DMSO reaction with base 572
DMSO reaction with phenols and DMSO 722
DMSO-based reagents for oxidation of alcohols 1516
Dodecahedrane 1514
Dodecahedryl cation 224—225
Doebner modification, of the Knoevenagel reaction 1226
Double asymmetric synthesis 150 1222
Double bond migration, in alkenes 770
Double bond shifts, and electrophilic substitution 766
Double carbonylations 565
Double hyperconjugation 220
Double-asymmetric synthesis, and hydroboration 1015
Doublets in ESR 239
Dppe, and reduction of acid chlorides 533
Dry ice see “Carbon dioxide”
Drying agents and formation of acetals or ketals 1180
Drying agents and formation of enamines 1187
Drying agents and formation of imines 1186
Dual substituent parameter equation 373
Duff reaction 717
Dyes, azo, by diazonium coupling 700
Dyotropic rearrangements 1465
E/Z isomers and enolate anions 237
E/Z isomers and the Wittig reaction 1235
E/Z nomenclature 157
E1 elimination see “Elimination E1”
E1cB elimination see “Elimination”
E2 elimination see “Eliminations E2”
E2C elimination see “Elimination”
EDA complexes also see “Complexes electron donor-acceptor”
EDA complexes  prefix 104
EDA complexes and  reactions 763
EDA complexes and charge-transfer bonding 104
EDA complexes benzene 103
EDA complexes hapto prefix 104
EDA complexes in photochemical [2+2]-cycloadditions 1082
EDA complexes metallocenes 103
EDA complexes norbornadienone 103
EDA complexes of picric acid 104
EDA complexes spectra 102—103
EDTA and oxidation of cyclic amines 1535
Eglinton reaction 927
Elbs reaction 724
Electrochemistry and dehalogenation of aryl halides 735
Electrochemistry and dehydration of oximes 1348
Electrochemistry and dimerization of ketones 1560
Electrochemistry and the Kolbe reaction 941—942
Electrochemistry and the Wacker process 1538
Electrochemistry conpling of dichlorides 537
Electrochemistry oxidation of alkynes 1540
Electrochemistry reduction of alkyl halides 525
Electrochemistry reduction of nitro compounds 1564
Electrocyclic rearrangements 1426—1436
Electrocyclic rearrangements and NMR 1435
Electrocyclic rearrangements and super acids 1435
Electrocyclic rearrangements conrotatory/disrotatory rotation 1427
Electrocyclic rearrangements frontier orbital method 1428
Electrocyclic rearrangements Mobius — Hueckel method 1429
Electrocyclic rearrangements orbital symmetry rules 1434
Electrofuge 385
Electrofuges and electrophilic aromatic substitution 675
Electrofuges and the reaction 769
Electromagnetic spectrum 307
Electron affinity and electronegativity 15
Electron diffraction and bond distance 18
Electron donating groups 17
Electron donating groups, a values 369—370
Electron donor-acceptor complexes 102—104 (also see “Complexes”)
Electron paramagnetic resonance see “ESR”
Electron releasing groups,  values 369—370 372
Electron spin resonance see “ESR”
Electron transfer and oxidation — reduction 1508
Electron transfer and oxidation-reduction 1508
Electron withdrawing groups 17
Electron withdrawing groups and aryl radicals 905
Electron withdrawing groups and nucleophilic addition to alkenes 982
Electron-donating field effect see “I effect”
Electronegativity 14—15
Electronegativity of substituents 15
Electronegativity Pauling and Sanderson 14
Electronic configuration 6—8
Electronic effects and migratory aptitude in carbocations 1386
Electronic effects and radical formation 902
Electronic effects in epoxidation of alkenes 1052
Electronic effects in the Claisen rearrangement 1451
Electronic structures of molecules 12—13
Electrons as waves 3
Electrons lone pairs and bond angles 22
Electrons lone pairs, steric demands 22
Electrons valence 12—13
Electrophilic aromatic substitution see “Substitution”
Electrophilic radicals 897
Electrophilic rearrangements 1392
Electrophilic substitution see “Substitution electrophilic”
Electrophilic, mechanism 275
Element effect 429
Elimination  - 1299
Elimination -, kinetic classifications 1309
Elimination  values 1313 1321
Elimination and acidity of -hydrogen 1316
Elimination and Bredt’s rule 188 1314
Elimination and Grignard formation from dihalides 805
Elimination and heat of combustion 1315
Elimination and Hofmann’s rule 1320
Elimination and ketone enolate anions with alkyl halides 552
Elimination and leaving group effects 1316 1321
Elimination and reactivity at bridgehead carbons 1314
Elimination and regiochemistey 1314—1317
Elimination and steric effects 1316 1319
Elimination and substrate structure 1319—1320
Elimination and Zaitsev’s rule 1314 1315
Elimination anti 1300
Elimination by fragmentation reactions 1345
Elimination competition with substitution 1320
Elimination conjugate 1326
Elimination Cope 1333
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