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| Авторизация |
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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Aromatic compounds from aryl iodides 1657
Aromatic compounds from aryl nitriles 1657
Aromatic compounds from aryl organometallics 736
Aromatic compounds from aryl sulfonic acids 734—735
Aromatic compounds from arylboranes 1658
Aromatic compounds from benzylic alcohols 1657
Aromatic compounds from benzylic ethers 1657
Aromatic compounds from benzylic halides 1657
Aromatic compounds from cleavage of alkyl arenes 1657
Aromatic compounds from cleavage of aryl ketones 1657
Aromatic compounds from cleavage of tertiary alkoxides 1657
Aromatic compounds from cyclic hydrocarbons 1510
Aromatic compounds from diazonium salts 1657
Aromatic compounds from dimerization of arenes 1658
Aromatic compounds from dimerization of diazonium salts 1657
Aromatic compounds from ene-diynes 1432
Aromatic compounds from Grignard reagents 1658
Aromatic compounds from hydrogenolysis of benzyl alcohols 1657
Aromatic compounds from hydrolysis of organometallic compounds 1657
Aromatic compounds from ketones 1657
Aromatic compounds from methylation of diazonium salts 1658
Aromatic compounds from organocuprates 868
Aromatic compounds from organometallic compounds 1657 1658
Aromatic compounds from oxidation of hydrazines 1658
Aromatic compounds from peroxides 1657
Aromatic compounds from phenolic esters 1657
Aromatic compounds from phenols 866 1657
Aromatic compounds from photochemical arylation 1657
Aromatic compounds from rearrangement of alkyl arenes 1657
Aromatic compounds from stilbenes 1658
Aromatic compounds from substituted aromatic compounds 730—731
Aromatic compounds from sulfur compounds 1658
Aromatic compounds from trimerization of alkynes 1089 1658
Aromatic compounds haloalkylation 721
Aromatic compounds halogenation of 704
Aromatic compounds hydrogenation of 1009
Aromatic compounds in the Diels — Alder reaction 1063
Aromatic compounds methyl, oxidation of 1533
Aromatic compounds monosubstituted, electrophilic aromatic substitution 681—687
Aromatic compounds oxidation to phenols, reagents for 916
Aromatic compounds oxidative cleavage 1526
Aromatic compounds polycyclic, oxidation of 1535
Aromatic compounds radical substitution on side chains 902
Aromatic compounds reaction with  703
Aromatic compounds reaction with acid 730
Aromatic compounds reaction with acyl halides 712
Aromatic compounds reaction with acyl peroxides 932
Aromatic compounds reaction with alkenes 708
Aromatic compounds reaction with alkyl halides 707
Aromatic compounds reaction with anhydrides 713
Aromatic compounds reaction with aryl diazonium salts 700 928
Aromatic compounds reaction with bromine 704
Aromatic compounds reaction with carbenes 1087
Aromatic compounds reaction with chlorine 704
Aromatic compounds reaction with chlorosulfuric acid 703
Aromatic compounds reaction with dichloromethyl methyl ether 717
Aromatic compounds reaction with formaldehyde and HCl 721
Aromatic compounds reaction with formamides 715
Aromatic compounds reaction with Grignard reagents 1030
Aromatic compounds reaction with hexamethylenetetramine 717
Aromatic compounds reaction with hydrazoic acid 701
Aromatic compounds reaction with hydroxamic acid 702
Aromatic compounds reaction with isocyanates 719
Aromatic compounds reaction with isothiocyanates 719
Aromatic compounds reaction with ketones 719
Aromatic compounds reaction with mercury fulminate 723
Aromatic compounds reaction with metals 793
Aromatic compounds reaction with nitric acid 696
Aromatic compounds reaction with nitriles 722
Aromatic compounds reaction with organolithium reagents 791 872
Aromatic compounds reaction with peroxy acids 724
Aromatic compounds reaction with phosgene 718
Aromatic compounds reaction with sulfonyl chlorides 704
Aromatic compounds reaction with sulfuric acid 702 734
Aromatic compounds reaction with thiocyanates 722
Aromatic compounds reaction with trichloroacetonitrile 722—723
Aromatic compounds reaction with zinc cyanide 715
Aromatic compounds reactivity with radicals 904
Aromatic compounds reduction of 1009—1012
Aromatic compounds UV spectra 311
Aromatic electrophilic substitution see “Substitution”
Aromatic hydrocarbons distorted 44
Aromatic hydrocarbons fused strained rings 45
Aromatic rings expansion, and the Reimer — Tiemann reaction 717
Aromatic rings neighboring group participation 411
Aromatic rings stabilization of carbanions 231
Aromatic sextet 34 46
Aromatic substitution see “Substitution”
Aromaticity 46—71 (also see “Antiaromaticity”)
Aromaticity and annellation 50
Aromaticity and annulenes 57 62—69
Aromaticity and fullerenes 70—71
Aromaticity and fused ring aromatics 54—56
Aromaticity and hardness 52
Aromaticity and heterocycles 51
Aromaticity and Huckel’s rule 57—58
Aromaticity and Hund’s rule 57
Aromaticity and medium-ring derivatives 48—54
Aromaticity and mesoionic compounds 69—70
Aromaticity and NMR 46—47
Aromaticity and ring current 46—47
Aromaticity and squaric acid 70
Aromaticity and syndones 70
Aromaticity and [10]annulene 62
Aromaticity conjugated circuit model 48
Aromaticity criteria for 58
Aromaticity definition 46
Aromaticity diatopic compounds 46—47
Aromaticity fused ring aromatics 48—50
Aromaticity hardness model 48
Aromaticity Herndon model 48
Aromaticity Hess — Schaad model 47—48
Aromaticity heterocycles 48
Aromaticity homoaromatic compounds 70
Aromaticity nitrogen heterocycles 48
Aromaticity other than six electrons 57—69
Aromaticity oxygen heterocycles 48
Aromaticity pentalene dianion 55
Aromaticity super aromaticity 66
Aromaticity tetramethylcyclooctatetraene dication 54
Aromaticity two-electron systems 58
Aromaticity unusual criteria 69—71
Aromatization and hydrogenation catalysts 1510
Aromatization of ene-diynes 1433
Aromatization with S and Se 1511
Aroxide ion 1464
Arsenite, sodium, reaction with aryl nitro compounds 1563
Arsines, triaryl, reaction with alkyl halides 1233
Arykhallium compounds, reaction with CuCN 802
Aryl aldehydes see “Aldehydes”
Aryl cations 929
Aryl diazonium compounds see “Diazonium”
Aryl diazonium salts see “Diazonium salts aryl”
Aryl fluorides see “Fluorides”
Aryl groups, migratory aptitude and carbocations 1386
Aryl halides see “Halides aryl”
Aryl radicals see “Radicals aryl”
Aryl sulfides see “Thioethers aryl”
Aryl sulfonic acids see “Sulfonic acids”
Aryl thioethers see “Thioethers aryl”
Arylammonium salts, reaction with HCl 729
Arylation by the Pschorr ring closure 929
Arylation Friedel — Crafts 711
Arylation intramolecular 929
Arylation Meerwein 929—930
Arylation of active methylene compounds 869
Arylation of acyl peroxides 932
Arylation of amines 501
Arylation of aryl diazonium compounds 928
Arylation of aryl iodides 933
| Arylation with aryllead tricarboxylates 932
Arylazo(N-) amines, rearrangement of 728
Arylhydrazones, cyclization with Lewis acids 1452
Arylidene bisamides 1187
Aryllead tricarboxylates, arylation reactions 932
Arylsulfonic trifluoromethanesulfonic anhydride, reaction with aromatic compounds 704
Arylthallium reagents, reaction with alcohols and CO 801
Aryltin, reaction with haloalkynes 561
Arynes 855; see “Benzynes”
Ascaridole, from terpinene 1055
Ascorbic acid and oxidation of aromatic compounds 916
Ascorbic acid and Udenfriend’s reagent 916
Aspartic acid, specific rotation 127
Asymmetric boranes 1014
Asymmetric carbon see “Stereogenic carbon”
Asymmetric induction 150
Asymmetric induction and reduction of ketones 1200
Asymmetric induction in the Baylis-Hillman reaction 1212
Asymmetric induction with sparteine 537
Asymmetric radicals 244
Asymmetric synthesis see “Synthesis”
Asymmetric synthesis and enantiomeric composition 143
Asymmetric synthesis double 150
Asymmetric synthesis general principles 147—150
Ate complexes and reduction of alkyl halides 525
Ate complexes definition 339
Atomic orbitals see “Orbitals atomic”
Atropisomers 132
Austin model 1 method 34
Autoxidation and allylic rearrangement 921
Autoxidation and radicals 921
Autoxidation of alkanes 920
Autoxidation of aromatic diols 1518
Autoxidation of hydrocarbons 920
Auxochrome, definition 310
Axes, chiral see “Chiral axes”
Axial bonds 172
Axis of symmetry, alternating 127—128
Aza-Cope rearrangement 1445
Aza-Wittig rearrangement 1422
Azaadamantanones 185
Azabullvalenes 1493 (ref. 521)
Azadienes, in Diels-Alder reactions 1075
Azeotropic distillation and ester formation 484
Azeotropic distillation and formation of acetals or ketals 1180
Azeotropic distillation and formation of enamines 1187
Azeotropic distillation and formation of i mines 1186
Azetidines, preparation of 501
Azetidines, reaction with  494
Azide amides, from azidation of amides 1659
Azide ion reaction with acyl halides 515
Azide ion reaction with alkenes 1046
Azide ion reaction with alkyl halides 515
Azides acyl, and the Curtius rearrangement 1412
Azides acyl, from acylhydrazines and HONO 1412
Azides acyl, thermolysis of 1412
Azides alkyl, and the diazonium leaving group 447
Azides alkyl, thermolysis of 1412
Azides aryl, reaction with amines 1413
Azides as 1,3-dipoles 1060
Azides cycloalkyl, ring expansion by Curtius rearrangement 1413
Azides from acyl peroxide 1658
Azides from alcohols 1658
Azides from aldehydes 516
Azides from alkenes 1002 1046 1658
Azides from alkyl halides 515
Azides from amides 1658
Azides from amine N-oxides 1557
Azides from azide ions 1658
Azides from hydrazides 1658
Azides from hydrazines 817 1658
Azides hydrolysis of 799
Azides iodo, conversion to aziridines 1046
Azides iodo, from alkenes 1046
Azides reaction with alkenes 1057 1059
Azides reaction with alkynes 1061
Azides reaction with amides 781
Azides reaction with tin hydride and radicals 1389
Azides reagents for preparation of 515—516
Azides reduction of, reagents 1555
Azides thermal decomposition to nitrenes 253
Azides tosyl, reaction with active methylene compounds 780
Azides tosyl, reaction with organolithium reagents 799
Azides trimethylsilyl, reaction with aromatic compounds 701
Azido amides, from amides 781
Azidochloromethylene dimethylammonium 701
Azine, from hydrazones and aldehydes 1193
Azines from addition of hydrazine to aldehydes 1659
Azines from addition of hydrazine to ketones 1659
Azines reaction with hydrazine and NaOH 1193
Azinic acids 76; see “Nitro compounds”
Azirene intermediate 288
Azirene intermediate in the Neber rearrangement 1410
Aziridines ambident substrates 461
Aziridines and the Darzens glycidic ester synthesis 1230
Aziridines by extrusion reactions 1353
Aziridines from  -iodo azides 1659
Aziridines from a-halo carbonyl compounds 1659
Aziridines from amino alcohols 502
Aziridines from azides 1057
Aziridines from azido alcohols 515
Aziridines from bromo-amines 500
Aziridines from carbenes 1659
Aziridines from conjugated amides 501
Aziridines from cyclization of -azido alcohols 1659
Aziridines from cyclization of amino alcohols 1659
Aziridines from cyclization of haloamines 1659
Aziridines from diazoalkanes 1659
Aziridines from epoxides 515 1659
Aziridines from epoxy amines 504
Aziridines from imines 1659
Aziridines from imines and diazoalkanes 1217
Aziridines from imines and halo esters 1230
Aziridines from iodo azides 1046
Aziridines from oximes 1555
Aziridines from reduction of oximes 1659
Aziridines from triazolines 1057 1659
Aziridines fromalkenes 1057 1659
Aziridines reaction with 494
Aziridines reaction with alkoxides 481
Aziridines reaction with alkynes 1062
Aziridines reaction with amines 505
Aziridines reaction with ammonia 504
Aziridines reaction with HONO (elimination) 1343
Aziridines reaction with nucleophiles 446
Aziridines reaction with organometallics 548
Aziridines reduction of 531
Aziridines thermolysis and reaction with alkenes 1061
Aziridines thermolysis to nitrenes 783
Aziridines vinyl, and [1,5]-H sigmatropic rearrangements 1440
Aziridino hydrazones, reaction with lithium diisopropylamide 1335
Azirines, from azide addition to alkynes 1058
Azo compounds by diazonium coupling 700
Azo compounds by the Mills reaction 818 1659
Azo compounds by the Wallach reaction 1659
Azo compounds from aliphatic diazonium coupling 1659
Azo compounds from amines 1659
Azo compounds from aromatic amines 818
Azo compounds from aromatic nitro compounds 1659
Azo compounds from aryl diazonium salts 937 1659
Azo compounds from azoxy compounds 1557
Azo compounds from hydrazo compounds 1519
Azo compounds from N-azo amines 728
Azo compounds from nitro compounds 1563
Azo compounds from oxidation of hydrazines 1659
Azo compounds from rearrangement of aryl triazenes 1659
Azo compounds from rearrangement of azoxy compounds 1659
Azo compounds from reduction of azoxy compounds 1659
Azo compounds from reduction of nitro compounds 1659
Azo compounds fromnitroso compounds 1659
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