Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure :: Электронная библиотека попечительского совета мехмата МГУ

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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Aromatic compounds from aryl iodides      1657
Aromatic compounds from aryl nitriles      1657
Aromatic compounds from aryl organometallics      736
Aromatic compounds from aryl sulfonic acids      734—735
Aromatic compounds from arylboranes      1658
Aromatic compounds from benzylic alcohols      1657
Aromatic compounds from benzylic ethers      1657
Aromatic compounds from benzylic halides      1657
Aromatic compounds from cleavage of alkyl arenes      1657
Aromatic compounds from cleavage of aryl ketones      1657
Aromatic compounds from cleavage of tertiary alkoxides      1657
Aromatic compounds from cyclic hydrocarbons      1510
Aromatic compounds from diazonium salts      1657
Aromatic compounds from dimerization of arenes      1658
Aromatic compounds from dimerization of diazonium salts      1657
Aromatic compounds from ene-diynes      1432
Aromatic compounds from Grignard reagents      1658
Aromatic compounds from hydrogenolysis of benzyl alcohols      1657
Aromatic compounds from hydrolysis of organometallic compounds      1657
Aromatic compounds from ketones      1657
Aromatic compounds from methylation of diazonium salts      1658
Aromatic compounds from organocuprates      868
Aromatic compounds from organometallic compounds      1657 1658
Aromatic compounds from oxidation of hydrazines      1658
Aromatic compounds from peroxides      1657
Aromatic compounds from phenolic esters      1657
Aromatic compounds from phenols      866 1657
Aromatic compounds from photochemical arylation      1657
Aromatic compounds from rearrangement of alkyl arenes      1657
Aromatic compounds from stilbenes      1658
Aromatic compounds from substituted aromatic compounds      730—731
Aromatic compounds from sulfur compounds      1658
Aromatic compounds from trimerization of alkynes      1089 1658
Aromatic compounds haloalkylation      721
Aromatic compounds halogenation of      704
Aromatic compounds hydrogenation of      1009
Aromatic compounds in the Diels — Alder reaction      1063
Aromatic compounds methyl, oxidation of      1533
Aromatic compounds monosubstituted, electrophilic aromatic substitution      681—687
Aromatic compounds oxidation to phenols, reagents for      916
Aromatic compounds oxidative cleavage      1526
Aromatic compounds polycyclic, oxidation of      1535
Aromatic compounds radical substitution on side chains      902
Aromatic compounds reaction with       703
Aromatic compounds reaction with acid      730
Aromatic compounds reaction with acyl halides      712
Aromatic compounds reaction with acyl peroxides      932
Aromatic compounds reaction with alkenes      708
Aromatic compounds reaction with alkyl halides      707
Aromatic compounds reaction with anhydrides      713
Aromatic compounds reaction with aryl diazonium salts      700 928
Aromatic compounds reaction with bromine      704
Aromatic compounds reaction with carbenes      1087
Aromatic compounds reaction with chlorine      704
Aromatic compounds reaction with chlorosulfuric acid      703
Aromatic compounds reaction with dichloromethyl methyl ether      717
Aromatic compounds reaction with formaldehyde and HCl      721
Aromatic compounds reaction with formamides      715
Aromatic compounds reaction with Grignard reagents      1030
Aromatic compounds reaction with hexamethylenetetramine      717
Aromatic compounds reaction with hydrazoic acid      701
Aromatic compounds reaction with hydroxamic acid      702
Aromatic compounds reaction with isocyanates      719
Aromatic compounds reaction with isothiocyanates      719
Aromatic compounds reaction with ketones      719
Aromatic compounds reaction with mercury fulminate      723
Aromatic compounds reaction with metals      793
Aromatic compounds reaction with nitric acid      696
Aromatic compounds reaction with nitriles      722
Aromatic compounds reaction with organolithium reagents      791 872
Aromatic compounds reaction with peroxy acids      724
Aromatic compounds reaction with phosgene      718
Aromatic compounds reaction with sulfonyl chlorides      704
Aromatic compounds reaction with sulfuric acid      702 734
Aromatic compounds reaction with thiocyanates      722
Aromatic compounds reaction with trichloroacetonitrile      722—723
Aromatic compounds reaction with zinc cyanide      715
Aromatic compounds reactivity with radicals      904
Aromatic compounds reduction of      1009—1012
Aromatic compounds UV spectra      311
Aromatic electrophilic substitution      see “Substitution”
Aromatic hydrocarbons distorted      44
Aromatic hydrocarbons fused strained rings      45
Aromatic rings expansion, and the Reimer — Tiemann reaction      717
Aromatic rings neighboring group participation      411
Aromatic rings stabilization of carbanions      231
Aromatic sextet      34 46
Aromatic substitution      see “Substitution”
Aromaticity      46—71 (also see “Antiaromaticity”)
Aromaticity and annellation      50
Aromaticity and annulenes      57 62—69
Aromaticity and fullerenes      70—71
Aromaticity and fused ring aromatics      54—56
Aromaticity and hardness      52
Aromaticity and heterocycles      51
Aromaticity and Huckel’s rule      57—58
Aromaticity and Hund’s rule      57
Aromaticity and medium-ring derivatives      48—54
Aromaticity and mesoionic compounds      69—70
Aromaticity and NMR      46—47
Aromaticity and ring current      46—47
Aromaticity and squaric acid      70
Aromaticity and syndones      70
Aromaticity and [10]annulene      62
Aromaticity conjugated circuit model      48
Aromaticity criteria for      58
Aromaticity definition      46
Aromaticity diatopic compounds      46—47
Aromaticity fused ring aromatics      48—50
Aromaticity hardness model      48
Aromaticity Herndon model      48
Aromaticity Hess — Schaad model      47—48
Aromaticity heterocycles      48
Aromaticity homoaromatic compounds      70
Aromaticity nitrogen heterocycles      48
Aromaticity other than six electrons      57—69
Aromaticity oxygen heterocycles      48
Aromaticity pentalene dianion      55
Aromaticity super aromaticity      66
Aromaticity tetramethylcyclooctatetraene dication      54
Aromaticity two-electron systems      58
Aromaticity unusual criteria      69—71
Aromatization and hydrogenation catalysts      1510
Aromatization of ene-diynes      1433
Aromatization with S and Se      1511
Aroxide ion      1464
Arsenite, sodium, reaction with aryl nitro compounds      1563
Arsines, triaryl, reaction with alkyl halides      1233
Arykhallium compounds, reaction with CuCN      802
Aryl aldehydes      see “Aldehydes”
Aryl cations      929
Aryl diazonium compounds      see “Diazonium”
Aryl diazonium salts      see “Diazonium salts aryl”
Aryl fluorides      see “Fluorides”
Aryl groups, migratory aptitude and carbocations      1386
Aryl halides      see “Halides aryl”
Aryl radicals      see “Radicals aryl”
Aryl sulfides      see “Thioethers aryl”
Aryl sulfonic acids      see “Sulfonic acids”
Aryl thioethers      see “Thioethers aryl”
Arylammonium salts, reaction with HCl      729
Arylation by the Pschorr ring closure      929
Arylation Friedel — Crafts      711
Arylation intramolecular      929
Arylation Meerwein      929—930
Arylation of active methylene compounds      869
Arylation of acyl peroxides      932
Arylation of amines      501
Arylation of aryl diazonium compounds      928
Arylation of aryl iodides      933

Arylation with aryllead tricarboxylates      932
Arylazo(N-) amines, rearrangement of      728
Arylhydrazones, cyclization with Lewis acids      1452
Arylidene bisamides      1187
Aryllead tricarboxylates, arylation reactions      932
Arylsulfonic trifluoromethanesulfonic anhydride, reaction with aromatic compounds      704
Arylthallium reagents, reaction with alcohols and CO      801
Aryltin, reaction with haloalkynes      561
Arynes      855; see “Benzynes”
Ascaridole, from terpinene      1055
Ascorbic acid and oxidation of aromatic compounds      916
Ascorbic acid and Udenfriend’s reagent      916
Aspartic acid, specific rotation      127
Asymmetric boranes      1014
Asymmetric carbon      see “Stereogenic carbon”
Asymmetric induction      150
Asymmetric induction and reduction of ketones      1200
Asymmetric induction in the Baylis-Hillman reaction      1212
Asymmetric induction with sparteine      537
Asymmetric radicals      244
Asymmetric synthesis      see “Synthesis”
Asymmetric synthesis and enantiomeric composition      143
Asymmetric synthesis double      150
Asymmetric synthesis general principles      147—150
Ate complexes and reduction of alkyl halides      525
Ate complexes definition      339
Atomic orbitals      see “Orbitals atomic”
Atropisomers      132
Austin model 1 method      34
Autoxidation and allylic rearrangement      921
Autoxidation and radicals      921
Autoxidation of alkanes      920
Autoxidation of aromatic diols      1518
Autoxidation of hydrocarbons      920
Auxochrome, definition      310
Axes, chiral      see “Chiral axes”
Axial bonds      172
Axis of symmetry, alternating      127—128
Aza-Cope rearrangement      1445
Aza-Wittig rearrangement      1422
Azaadamantanones      185
Azabullvalenes      1493 (ref. 521)
Azadienes, in Diels-Alder reactions      1075
Azeotropic distillation and ester formation      484
Azeotropic distillation and formation of acetals or ketals      1180
Azeotropic distillation and formation of enamines      1187
Azeotropic distillation and formation of i mines      1186
Azetidines, preparation of      501
Azetidines, reaction with       494
Azide amides, from azidation of amides      1659
Azide ion reaction with acyl halides      515
Azide ion reaction with alkenes      1046
Azide ion reaction with alkyl halides      515
Azides acyl, and the Curtius rearrangement      1412
Azides acyl, from acylhydrazines and HONO      1412
Azides acyl, thermolysis of      1412
Azides alkyl, and the diazonium leaving group      447
Azides alkyl, thermolysis of      1412
Azides aryl, reaction with amines      1413
Azides as 1,3-dipoles      1060
Azides cycloalkyl, ring expansion by Curtius rearrangement      1413
Azides from acyl peroxide      1658
Azides from alcohols      1658
Azides from aldehydes      516
Azides from alkenes      1002 1046 1658
Azides from alkyl halides      515
Azides from amides      1658
Azides from amine N-oxides      1557
Azides from azide ions      1658
Azides from hydrazides      1658
Azides from hydrazines      817 1658
Azides hydrolysis of      799
Azides iodo, conversion to aziridines      1046
Azides iodo, from alkenes      1046
Azides reaction with alkenes      1057 1059
Azides reaction with alkynes      1061
Azides reaction with amides      781
Azides reaction with tin hydride and radicals      1389
Azides reagents for preparation of      515—516
Azides reduction of, reagents      1555
Azides thermal decomposition to nitrenes      253
Azides tosyl, reaction with active methylene compounds      780
Azides tosyl, reaction with organolithium reagents      799
Azides trimethylsilyl, reaction with aromatic compounds      701
Azido amides, from amides      781
Azidochloromethylene dimethylammonium      701
Azine, from hydrazones and aldehydes      1193
Azines from addition of hydrazine to aldehydes      1659
Azines from addition of hydrazine to ketones      1659
Azines reaction with hydrazine and NaOH      1193
Azinic acids      76; see “Nitro compounds”
Azirene intermediate      288
Azirene intermediate in the Neber rearrangement      1410
Aziridines ambident substrates      461
Aziridines and the Darzens glycidic ester synthesis      1230
Aziridines by extrusion reactions      1353
Aziridines from $\beta$ -iodo azides      1659
Aziridines from a-halo carbonyl compounds      1659
Aziridines from amino alcohols      502
Aziridines from azides      1057
Aziridines from azido alcohols      515
Aziridines from bromo-amines      500
Aziridines from carbenes      1659
Aziridines from conjugated amides      501
Aziridines from cyclization of $\beta$ -azido alcohols      1659
Aziridines from cyclization of amino alcohols      1659
Aziridines from cyclization of haloamines      1659
Aziridines from diazoalkanes      1659
Aziridines from epoxides      515 1659
Aziridines from epoxy amines      504
Aziridines from imines      1659
Aziridines from imines and diazoalkanes      1217
Aziridines from imines and halo esters      1230
Aziridines from iodo azides      1046
Aziridines from oximes      1555
Aziridines from reduction of oximes      1659
Aziridines from triazolines      1057 1659
Aziridines fromalkenes      1057 1659
Aziridines reaction with       494
Aziridines reaction with alkoxides      481
Aziridines reaction with alkynes      1062
Aziridines reaction with amines      505
Aziridines reaction with ammonia      504
Aziridines reaction with HONO (elimination)      1343
Aziridines reaction with nucleophiles      446
Aziridines reaction with organometallics      548
Aziridines reduction of      531
Aziridines thermolysis and reaction with alkenes      1061
Aziridines thermolysis to nitrenes      783
Aziridines vinyl, and [1,5]-H sigmatropic rearrangements      1440
Aziridino hydrazones, reaction with lithium diisopropylamide      1335
Azirines, from azide addition to alkynes      1058
Azo compounds by diazonium coupling      700
Azo compounds by the Mills reaction      818 1659
Azo compounds by the Wallach reaction      1659
Azo compounds from aliphatic diazonium coupling      1659
Azo compounds from amines      1659
Azo compounds from aromatic amines      818
Azo compounds from aromatic nitro compounds      1659
Azo compounds from aryl diazonium salts      937 1659
Azo compounds from azoxy compounds      1557
Azo compounds from hydrazo compounds      1519
Azo compounds from N-azo amines      728
Azo compounds from nitro compounds      1563
Azo compounds from oxidation of hydrazines      1659
Azo compounds from rearrangement of aryl triazenes      1659
Azo compounds from rearrangement of azoxy compounds      1659
Azo compounds from reduction of azoxy compounds      1659
Azo compounds from reduction of nitro compounds      1659
Azo compounds fromnitroso compounds      1659

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