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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Acetals from ortho esters      1642
Acetals from phenols      1642
Acetals hydrogenolysis, reagents for      528
Acetals hydrolysis      465
Acetals hydrolysis and the $S_N1$ mechanism      466
Acetals hydrolysis and the Bronsted coefficient      466
Acetals hydrolysis, and microwaves      467
Acetals hydrolysis, reagents for      467
Acetals ketene, reaction with aldehydes or ketones      1249
Acetals ketene, silyl, and the Mukaiyama aldol reaction      1223
Acetals rate of hydrolysis and structure      466
Acetals reaction with carboxylic acids      489
Acetals reaction with Lewis acids      467
Acetamides, N-chloro, rearrangement of      728
Acetates allylic, coupling with carboxylic acids      944
Acetates coupling with nickel tetracarbonyl      545
Acetates elimination with Pd      1330
Acetates reaction with organocuprates      545
Acetic acid and acid strength      327
Acetic acid pKa      342
Acetic acid reaction with alkenes and $NaNO_2$      1339
Acetic acid thermodynamic ionization values      350
Acetic anhydride and DMSO, for oxidation of alcohols      1516
Acetic anhydride cleavage of ethers      489
Acetic anhydride dehydrating agent      491
Acetic anhydride reaction with alkenes      1058
Acetic anhydride reaction with oximes      1348
Acetic-phosphoric anhydride, acylation of alcohols      483
Acetoacetic ester enol of      74—75
Acetoacetic ester synthesis      549
Acetoacetic esters alkylation      549
Acetoacetic esters dianion      550
Acetolysis, substituent effects      412
Acetone, as a solvent      450
Acetonitrile as a solvent      450
Acetonitrile reaction with hydrocarbons      925
Acetyl hypofluorite, and aromatic fluorination      707
Acetyl tosylate, cleavage of ethers      490
acetylene      see “Ethyne”
Acetylene dicarboxy, reaction with bromine      973
Acetylene reaction with aromatic compounds      708
Acetylides      see “Alkyne anions”
Achirality, definition      125
Aci form nitronic acids      76
Aci form of nitro compounds      76
Acid derivatives, reaction with amines      512
Acid derivatives, reaction with Grignard reagents      567
Acid derivatives, reactivity and leaving groups      449
Acid form, azinic acids      76
Acid strength ab initio calculation      328
Acid strength acetic acid      342
Acid strength alcohols vs. carboxylic acids      344
Acid strength alcohols, order of      350
Acid strength amides      344
Acid strength amines      344
Acid strength and conformation      347
Acid strength and diazonium salts coupling      700
Acid strength and entropy effect      347
Acid strength and equilibrium constants      336
Acid strength and free energy      336
Acid strength and Ho      334—335
Acid strength and hybridization      348—349
Acid strength and hydrogen bonding      99 101—102 346
Acid strength and hydron donors      352
Acid strength and inductive effects      17
Acid strength and internal hydrogen bonding      333
Acid strength and lyonium ions      335
Acid strength and principle of imperfect synchronization      334
Acid strength and reaction medium      349—351
Acid strength and reaction with metals      793
Acid strength and solvation      349
Acid strength and steric effects      346
Acid strength and structure      342—349
Acid strength and the Hammett reaction constant      350
Acid strength and the Periodic table      345
Acid strength C-H, and hybridization      433
Acid strength crystallographic scale      328
Acid strength definition      327
Acid strength esters      344
Acid strength ethers      344
Acid strength field effects      342—343
Acid strength gas phase      350
Acid strength Hammet acidity function      334
Acid strength hydroxybenzoic acids      346
Acid strength kinetic      228—229
Acid strength Lewis acids      340
Acid strength nitroacetic acid      342
Acid strength of $\beta$-hydrogen in E2 elimination      1316
Acid strength of 1,3-pentanedione      347
Acid strength of dimethyl malonate      347
Acid strength of dinitromethane      230
Acid strength of fluorene      52
Acid strength of indene      52
Acid strength of Meldrum’s acid      347
Acid strength of nitromethane      230
Acid strength of pentakis (trifluoromethy) clopentadiene      52
Acid strength of quinoline conjugate acid      347
Acid strength of solvents      334—336
Acid strength of squaric acid      70
Acid strength phenols      345
Acid strength resonance effects      343—345
Acid strength scales of acidity      335
Acid strength statistical effects      345—346
Acid strength t-butylbenzoic acids      346
Acid strength table      329—331
Acid strength table of acidity constants      343
Acid strength the Bunnett-Olsen equation      335
Acid strength thermodynamic      228
Acid strength tri(pentafluorophenyl)methane      343
Acid strength tricyanomethane      344
Acid strength triphenylacetic acid      343
Acid, definition      333
Acid, formic      see “Formic acid”
Acid, salts      see “Carboxylic acid salts”
Acidity constants      327—328 333 343
Acidity scales      335
acids      also see “Carboxylic acids”
Acids addition to ketenes      992
Acids, and Bronsted theory      327—328
Acids, and catalysis      336—338
Acids, as proton donors      327
Acids, carboxylic      see “Carboxylic acids
Acids, hard and soft, definition      340
Acids, hardness, table      340
Acids, Lewis      see “Lewis acids”
Acids, mineral, reaction with alcohols      518
Acids, peroxy      see “Peroxyacids”
Acids, reaction with alkenes      991
Acids, reaction with alkynes      975
Acids, reaction with cyclopropanes      989
Acids, reaction with organometalhc compounds      794
Acids, super acids      328
Acids, thio      see “Thioacids”
Acrolein, reaction with borane      1031
Acrylonitrile, conjugate addition to      976
Actinometer, definition      322
Activated complex, and transition states      279
Activating groups and electrophilic aromatic substitution      681—684
Activating groups and Friedel-Crafts alkylation      709
Activating groups and the Ullmann reaction      871
Activating groups, chair-to-chair interconversions      173
Activating groups, electrophilic aromatic substitution, multiple substituents      687
Activating groups, for $S_NAr$ reactions      858
Activation free energy and reaction coordinate      279
Activation free energy of      278—279
Activation hardness, and electrophilic aromatic substitution      692
Activation volume, and high pressure reactions      457—458
Active hydrogen compounds and the Knoevenagel reaction      1225—1228
Active hydrogen compounds base catalyst condensation      1219
Active hydrogen compounds Michael addition to alkenes      1022—1024
Active hydrogen compounds reaction with aldehydes or ketones      1225—1228
Active hydrogen compounds reaction with aryl halides      869
Acyl anions, and Umpolung      553
Acyl azides      see “Azides”
Acyl azides from acyl halides      515
Acyl bromides, from aldehydes      914
Acyl carbon, and leaving groups      448
Acyl cations      223; see “Acylium ion”
Acyl chlorides      see “Chlorides acyl”
Acyl cyanides, from acyl halides      573
Acyl fluorides from acyl chlorides and HF      524
Acyl fluorides from anhydrides and HF      524
Acyl fluorides from DAST      524
Acyl fluoroborates, reaction with alkenes      1058
Acyl halides      see “Halides acyl”
Acyl hydrazides, conversion to esters      488
Acylals from acylation of ketones      1642
Acylals from addition of carboxylic acids to alkynes      1642
Acylals from aldehydes and anhydrides      1245
Acylals from bisdecarboxylation of malonic acids      1642
Acylals from oxidation of arylmethanes with $CrO_3$ and $Ac_2O$      1642
Acylals, from acylation of aldehydes      1642
Acylation      569
Acylation Friedel-Crafts      712—714
Acylation of alkenes      784
Acylation of amines      511
Acylation of amino acids      812
Acylation of aromatic rings      710
Acylation of conjugated dienes      784
Acylation of enamines      788
Acylation of esters      569—570
Acylation of ketones      569
Acylation reductive, of ketones      1182
Acylation with aldehydes, of heterocycles      934
Acylhydrazides, reaction with nitrous acid      1412
Acylium ion, reaction with alkenes      784
Acyloin condensation      1562
Acyloin condensation with tethered diesters      1602 (ref. 748)
Acyloins      also see “Hydroxy $(\alpha-)$ ketones”
Acyloins, and the benzoin condensation      1243
Acyloxy amides by the Passerini reaction      1252
Acyloxylation of alkenes      997 1033 1048 1058
Acyloxylation of hydrocarbons      923
Acyloxylation of ketones, reagents for      923
Acylureas, for Hofmann rearrangement      1411
Adamantanes      1396
Adamantanes and optical activity      131
Adamantanes, cleavage during hydrogenation      815
Adamantanones      1173
Adamantyl cation      224—225 1383
Adamantyl compounds, and solvent ionizing power      452
Addition 1,2vs. 1,4      980
Addition 1,4      see “Addition conjugate”
Addition compounds      102—114
Addition compounds, definition      102
Addition reactions, mechanism      276
Addition reactions, of nitrenes      254
Addition reactions, of radicals      246
Addition reactions, to cyclopropanes      988—990
Addition to alkenes, and antiaromaticity      983
Addition to alkenes, and hyperconjugation      987
Addition to alkenes, and the Cieplak effect      988
Addition to alkenes, by alkanes      1017—1019
Addition to alkenes, by boranes      1012—1016
Addition to alkenes, cyclic mechanism      979
Addition to alkenes, electronic effects      987
Addition to alkenes, exo/endo diastereoselectivity      987
Addition to alkenes, field effects      987
Addition to alkenes, reactivity of alkenes      981
Addition to alkenes, regioselectivity      984
Addition to alkynes      997
Addition, alcohols to alkenes      996
Addition, alkenes to alkenes, and Ziegler catalysts      1020
Addition, conjugate      979—981
Addition, conjugate and $S_N2'$ reactions      980
Addition, conjugate and chiral templates      1029
Addition, conjugate and enolate anions      1023
Addition, conjugate and Grignard reagents      1028
Addition, conjugate and Mannich bases      1023
Addition, conjugate and organolithium reagents      1029
Addition, conjugate chiral additives      1023
Addition, conjugate cyanoethylation      976
Addition, conjugate definition      976
Addition, conjugate enantio selectivity of      1029
Addition, conjugate hydrogenation of dienes      1005
Addition, conjugate Michael addition      976
Addition, conjugate organocuprates      1027
Addition, conjugate reduction      1008—1009
Addition, conjugate with nucleophiles      1022—1024
Addition, conjugate with radicals      1024
Addition, conjugate, alkyl halides to dienes      1047
Addition, conjugate, amines to alkenes      1000
Addition, electrophilic      276
Addition, electrophilic to alkenes      970—975
Addition, electrophilic to alkenes, diastereoselectivity      971
Addition, electrophilic to cyclopropanes      988—990
Addition, Michael      977 1022—1024
Addition, nucleophilic      276
Addition, nucleophilic and conjugation      1174
Addition, nucleophilic and iminium ions      1178
Addition, nucleophilic and steric hindrance      1174
Addition, nucleophilic to alkenes      1000
Addition, nucleophilic to carbonyls      1173
Addition, pericyclic      276
Addition, radical      276
Addition, radical intramolecnlar      985
Addition, radical reversibility      981
Addition, radical to alkenes      977—979
Addition, radical to alkenes, and cis/trans isomerization      979
Addition, radical to alkenes, and ESR      979
Addition, radical to alkenes, and the Felkin-Ahn rule      981
Addition, radical to alkenes, by silane tethers      1032
Addition, radical to alkenes, stereo selectivity      978
Addition, radical to alkenes, steric effects      985
Addition, radical to conjugated compounds      1032
Addition, radical to cyclopropanes      990
Addition, radical to dienes      978
Addition, termolecular      972
Addition-elimination mechanism and oxidation-reduction      1509
Addition-elimination mechanism and substitution at vinyl carbon      428
Addition-elimination mechanism and transmetallation      803
Addition-elimination mechanism metal hydride      772
Additions, IUPAC rules      383
Adsorption, and catalytic hydrogenation      1006
Aggregates and enolate anions      237
Aggregates and organolithium reagents      237
Aggregates in dialkylamide bases      348
Aggregation, effect of HMPA      349
AIBN and formation of aryl esters      870
AIBN and hydrogenolysis of alcohols      527
AIBN and radical addition of silanes to alkenes      1039
AIBN and radical coupling of dialdehydes      1561
AIBN and radical cyclization to C=N and C=O      1244
AIBN and reaction of aldehydes with ammonia/NBS      925
AIBN and the Barton-McCombie reaction      527
AIBN conpling silanes and lactones      536
AIBN radical initiator      911 914
Alanes, vinyl      1210
Alcohols acylation with acetic-phosphoric anhydride      483
Alcohols and acid strength      344
Alcohols and Birch reduction      1010
Alcohols and Oppenauer oxidation      1516
Alcohols and Swern oxidation      1516
Alcohols and the Dess-martin periodinane      1516
Alcohols and the Koch-Haaf reaction      564
Alcohols and the Meerwein-Ponndorf-Verley reduction      1199
Alcohols and the Oppenauer oxidation      1199
Alcohols and the Pinner synthesis      1183
Alcohols by Payne rearrangement      1643
Alcohols by radical oxygenation      914
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