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| Авторизация |
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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Boradioxolanes, from boranes and CO 1422
Borane complex with THF 1014
Borane ease of reduction of functional groups 1546
Borane reaction with acrolein 1031
Borane reaction with alkenes, isomerization 773
Borane reaction with alkynes 798
Borane reaction with amines and CO 801
Borane reaction with conjugated compounds 1031
Borane reaction with methyl vinyl ketone 1031
Borane reduction of nitro compounds 1554
Borane — dimethyl sulfide and reduction of nitriles 1204
Borane — dimethyl sulfide reaction of conjugated carbonyls 1200
Borane — dimethyl sulfide reduction of enamines 530
Boranes and formation of alkenes 1338
Boranes and inversion of configuration 798
Boranes and reduction of aldehydes or ketones 1200
Boranes and reduction of carboxylic acids 1549
Boranes and reduction of iodo azides 1046
Boranes and Wilkinson’s catalyst 1016
Boranes BINAP and reaction with conjugated ketones 1032
Boranes coupling of 939
Boranes cyclic, from dienes 1015
Boranes disiamylborane 1012
Boranes formation from alkenes 1014
Boranes from bormates with organometallic compounds 1660
Boranes from boron halides and Grignard reagents 1660
Boranes from exchange boranes and alkenes 1660
Boranes from hydroboration of alkenes or alkynes 1660
Boranes from migration of boron 1660
Boranes hydrolysis of 796
Boranes migration of boron 1409
Boranes optically active 1014 1210—1211
Boranes optically active, borolanes 1015
Boranes oxidation with  1016
Boranes oxidation with peroxyacids 1016
Boranes reaction with alkenes 1012 1014 1338
Boranes reaction with alkenes, regioselectivity 1013
Boranes reaction with alkyne anions 1425
Boranes reaction with alkynes 1015 1339
Boranes reaction with ammonia-NaOCl 799
Boranes reaction with basic hydrogen peroxide 796
Boranes reaction with boranes 939
Boranes reaction with bromoketones 559—560
Boranes reaction with carboxylic acids 1005
Boranes reaction with chloramine 800
Boranes reaction with CO 1422—1423
Boranes reaction with diazo compounds 561
Boranes reaction with enolate dianions 1424
Boranes reaction with halo carbonyl compounds 560
Boranes reaction with haloalkynes 1425
Boranes reaction with halogen 798
Boranes reaction with hydroperoxide anion 797
Boranes reaction with NaCN 1423
Boranes thexylborane 1012
Boranes vinyl 798 939 1015
Boranes vinyl, coupling 939
Boranes vinyl, reaction with carboxylic acids 1005
Boranes vinyl, reaction with iodine and NaOH 1424
Borinates, enol see “Enol borinates”
Borohydride, sodium, conjugate reduction 1008
Borolanes, chiral boranes 1015
Boron trifluoride 7 339
Boron trifluoride reaction with mesitylene and ethyl fluoride 678
Boronic acids aryl, coupling with aryl diazonium salts 938
Boronic acids reaction with aryl triflates 868
Boronic esters reaction with halogen 798
Boronic esters reaction with organolithium reagents 1424
Bouveault reaction 1214
Bouveault — Blanc reaction 1199 1551
Boyland — Sims oxidation 724
Bradsher reaction 720
Bredt’s rule 188
Bredt’s rule and decarboxylation 810
Bredt’s rule and elimination reactions 1314
Bredt’s rule and pyrolytic elimination 1325
Bridged carbocations see “Nonclassical ions”
Bridged compounds, cis/trans isomers 161—163
Bridged free radicals 899
Bridgehead atoms and Bredt’s rule 188
Bridgehead atoms effect on nucleophilic substitution 437
Bridgehead carbons and  reactions 761
Bridgehead carbons and radical reactions 894
Bridgehead carbons and the  reaction 764
Bridging compounds, out — in isomers 163
Bromides also see “Halides”
Bromides, aryl, by the Sandmeyer reaction 936
Bromination allylic, by reaction with NBS 911
Bromination of alkenes 971 981—982 1041 1509
Bromination of alkynes 1042
Bromination of hydrocarbons 907—911
Bromination of ketones and aldehydes 776
Bromination Wohl — Ziegler 911
Bromine and NBS 913
Bromine and the Hunsdiecker reaction 942—943
Bromine reaction with 1,2-dimethylcyclohexene 974
Bromine reaction with aldehydes 914
Bromine reaction with aldehydes andtriphenyl phosphate 1196
Bromine reaction with alkenes 971
Bromine reaction with alkynes 1042
Bromine reaction with anthracene 50
Bromine reaction with aromatic compounds 704
Bromine reaction with boranes 798
Bromine reaction with carboxylic acids 777
Bromine reaction with dicarboxyacetylene 973
Bromine reaction with ethene 973
Bromine reaction with hydrocarbons 907—911
Bromine reaction with ketones and aldehydes 775
Bromine reaction with malcic acid 972
Bromine reaction with metal ketones 813
Bromine reaction with silver carboxylates 942—943
Bromo acids by the Hell — Volhard — Zelenskii reaction 777
Bromo acids from carboxylic acids 777
Bromo esters and the Blaise reaction 1213
Bromo esters in the Refonnatsky reaction 1212
Bromo esters substitution with esters and Zn 1213
Bromo ketones, reaction with boranes 559—560
Bromoamines, from amines 819
Bromobenzene, reaction with organolithium reagents 699
Bromoform by the haloform reaction 813
Bromoform flash photolysis of 249
Bromolactamization 1043
Bromonium ion, ab initio MO studies 973
Bromonium ions 405 407 971
Bronsted catalysis equation 337
Bronsted coefficient, and acetal hydrolysis 466
Bronsted equation, and E2C elimination 1313
Bronsted law, and the Marcus equation 338
Bronsted relation 371
Bronsted theory 327—328
Brosylate, leaving group 446
Brucine, and resolution 151
Bucherer reaction 861 865
Buckminsterfullerene 70—71
Buckyballs see “Fullerenes”
Buffers, and the Baeyer — Villiger rearrangement 1417
Bullvalene 1448
Bullvalenes, aza- 1493 (ref. 521)
Bunneft — Olsen equation 335
Bunte salts 1,3-butadiene, and photochemistry 310
Bunte salts bond electron density 37
Bunte salts conjugated bonds 36
Bunte salts dimcrization 1091
Bunte salts from alkyl halides and thiosulfate ion 1660
Bunte salts hydrolysis of 495 498
Bunte salts invalid resonance form 41
Bunte salts photochemical reactions 1081
Bunte salts preparation of 498
Bunte salts reaction with nucleophiles 498
Bunte salts resonance contributors 37
Bunte salts resonance energy 37
| Bunte salts trimerization of 1091
Butane and gauche conformation 169—170
Butane conformational energy diagram 170
Butanediol 290
Butylamine, diazotization reactions 448
Butyllithium 236
Butyllithium reaction with bromobenzene 699
Butyllithium reaction with thionolactones 1215
c and r nomenclature 161
C=N compounds hydrolysis of, reagents 1177
C=N compounds reaction with HCN 1240
Cadi -Chodkiewicz reaction 927
Cadmium, and aryl carboxylic acid decaiboxylation 733
Cage compounds 109 (also see “Inclusion componnds”)
Cahn — Ingold-Prelog system see “CIP system”
Calcium hydroxide, in the Tollens’ reaction 1231
Calixaromatic compounds 106 935
Calixaromatic compounds and chirality 136
Cambridge structural database 99
Camphene 1394
Camphenilone 232
Camphor 162
Cannizzaro reaction 463 1200 1508 1564—1565
Cannizzaro reaction crossed 1219 1564
Cannizzaro reaction crossed, and the Tollens’ reaction 1231
Cannizzaro reaction internal 1565
Cannizzaro reaction with -keto aldehydes 1565
Canonical forms 32
Caprolactam see “Hexaydroazepin-2-one”
Captodative compounds, and cis/trans isomers 159
Captodative effects and ESR 242
Captodative effects and resonance 60
Captodative effects in radicals 242
Carbamates by radical coupling 934
Carbamates by the Curtius rearrangement 1660
Carbamates by the Hofmann rearrangement 1660
Carbamates from alcohols 1182—1183 1660
Carbamates from alkoxides 1660
Carbamates from alkyl halides 489 1660
Carbamates from amides 1660
Carbamates from amines 507 820 1660
Carbamates from chloroformates 1660
Carbamates from cleavage of tertiary amines 1660
Carbamates from cyanogen chloride 1183
Carbamates from insertion by nitrenes 1660
Carbamates from isocyanates 1182—1183 1660
Carbamates from nitro compounds 1660
Carbamates from nitroso compounds 1660
Carbamates from rearrangement of acyl azides 1660
Carbamates hydrolysis of 474
Carbamates lithiated allylic, and the Knoevenagel reaction 1227
Carbamates reaction with Grignard reagents 568
Carbamates reaction with isocyanic acid 1183
Carbamates reaction with phenyllithium 1215
Carbamoyl chloride, reaction with aromatic compounds 718
Carbanion, and inversion 233
Carbanion, sulfone, reduction with  1355
Carbanions 227—238
Carbanions addition to alkenes 1018
Carbanions addition to dienes 1018
Carbanions allylic 229
Carbanions and  hybridization 233
Carbanions and basicity 227—228
Carbanions and conjugation 229—230
Carbanions and field effects 231
Carbanions and kinetic acidity 228—229
Carbanions and organometallics 227
Carbanions and planar shape 233
Carbanions and prochiral centers 233
Carbanions and pyramidal structure 232
Carbanions and racemization 764
Carbanions and s character 228 231
Carbanions and solvation 232
Carbanions and stereochemistry 233
Carbanions and the  reaction 764
Carbanions and the Grovenstein — Zimmerman rearrangement 1396
Carbanions and thermodynamic acidity 228
Carbanions andylids 231
Carbanions benzylic 229
Carbanions boron, reaction with aldehydes 785
Carbanions criteria for stability 229—232
Carbanions cyclopentadienyl 230
Carbanions enolate anions 230
Carbanions enolate anions and structure 236—237
Carbanions fate of 237—238
Carbanions from alkyltrimethylsilanes 229
Carbanions generation of 237—238
Carbanions homoenolate ions 232
Carbanions methyl 229
Carbanions nitro anions 459
Carbanions order of stability 228
Carbanions oxidation to radicals 238
Carbanions rate of isotopic exchange 765
Carbanions reaction with acyl halides 569
Carbanions reaction with alkyl halides 548—551
Carbanions silyl, reaction with aldehydes or ketones 1228
Carbanions stability of 227—234
Carbanions stability, order of 229
Carbanions stabilization by an aromatic ring 231
Carbanions stabilization by carbonyls 230
Carbanions stabilization by functional groups 232
Carbanions stabilization by nonadjacent  -bond 232
Carbanions stabilization by S, Si and P 231
Carbanions structure of 227—234
Carbanions vinyl 233
Carbanions vinyl, and the  mechanism 766
Carbanions vinyl, configuration 766
Carbene 319
Carbenes 247—253
Carbenes and caibynes 249
Carbenes and CIDNP 791
Carbenes and dimcrization 252
Carbenes and formation of allenes 1400
Carbenes and Hund’s rule 248
Carbenes and infrared 1086
Carbenes and phase transfer 1085
Carbenes and the Reimer — Tiemann reaction 716
Carbenes and the Wolff rearrangement 252
Carbenes and ultrasound 789
Carbenes and xray 251
Carbenes by -elimination 249
Carbenes cis/trans isomerization 249
Carbenes disproportionation of 790
Carbenes enantioselectivity 1086
Carbenes fate of 249—252
Carbenes formation of cis/trans isomers 248
Carbenes formation of cyclopropanes 248
Carbenes from diazirines 250
Carbenes from diazo compounds and alcohols 479
Carbenes from ketenes 250
Carbenes from organometallics and alkyl halides 807
Carbenes generation of 249—253
Carbenes halo see “Halocarbene”
Carbenes halo, insertion reactions 789
Carbenes insertion reactions 251 788—791
Carbenes insertion reactions, and radicals 790
Carbenes insertion, and absolute configuration 790
Carbenes intramolecular insertion 789
Carbenes metal and alkene metathesis 1458
Carbenes metal complexes 1086
Carbenes metal, and alkenylation reactions 1238
Carbenes metal, insertion reactions 789
Carbenes reaction with alkenes 789 1086
Carbenes reaction with alkenes, stereochemistry 1087
Carbenes reaction with allenes 1086
Carbenes reaction with aromatic compounds 1087
Carbenes reaction with benzene 1087
Carbenes reaction with dienes 1085
Carbenes reaction with indoles 1087
Carbenes reaction with pyrroles 1087
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