Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure :: Электронная библиотека попечительского совета мехмата МГУ

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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

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Amino acids from acyl halides      1656
Amino acids from aldehydes      1656
Amino acids from carboxylic acids      1656
Amino acids from dialkyl azodicarboxylate      1656
Amino acids from esters      1656
Amino acids from halo acids      1656
Amino acids from hydrolysis of cyanohydrins      1656
Amino acids from hydrolysis of lactams      1656
Amino acids from imides      1656
Amino acids from ketones      1656
Amino acids from lactones      511
Amino acids from N-acetylaminomalonic esters      1656
Amino acids from nitroso compounds      1656
Amino acids from oximes      1656
Amino acids reaction with anhydrides      812
Amino alcohols and scmipinacol rearrangement      1397
Amino alcohols catalysts for formation from epoxides      504
Amino alcohols from cnamincs      1014
Amino alcohols from epoxides      504
Amino alcohols from oxetanes      505
Amino alcohols reaction with nitrous acid      1397
Amino alcohols reaction with triphenylphosphine dibromide      502
Amino esters by the Hofmann reaction      1656
Amino esters by the Sorensen reaction      1656
Amino esters by the Strecker synthesis      1656
Amino esters from $\beta$ -lactones      1656
Amino esters from acyl halides      1656
Amino esters from aldehydes      1656
Amino esters from azodicarboxylates      1656
Amino esters from carboxylic acids      1656
Amino esters from esters      1656
Amino esters from halo acids      1656
Amino esters from hydrolysis of cyanohydrins      1656
Amino esters from hydrolysis of lactams      1656
Amino esters from imides      1656
Amino esters from ketones      1656
Amino esters from N-acetylaminomalonic esters      1656
Amino esters from nitroso compounds      1656
Amino esters from oximes      1656
Amino ethers from alcohols      1656
Amino ethers from aldehydes      1656
Amino ethers from alkenes      481 1656
Amino ethers from aziridines      1656
Amino ethers from phenols      1656
Amino ethers reaction with Grignard reagents      546
Amino groups, migration      1408
Amino heterocycles by the Chichibabin reaction      873
Amino heterocycles preparation of      873
Amino nitriles, by the Strecker synthesis      1240
Amino phenols by the Bamberger rearrangement      878
Amino phenols from hydroxyl amines      878
Amino thioethers, from alkenes      1058
Amino thiols by the Herz reaction      1656
Amino thiols from aldehydes      1656
Amino thiols from aromatic amines      1656
Amino thiols from episulfides      504 1656
Aminoalkylation, of phenols      722
Aminomalonates, from nitriles      1241
Aminomethyl aromatic compounds      877
Aminomethylation, of phenols      722
Aminonaphthalene      see “Naphthylamines”
Aminonitrenes, reaction with alkenes      1057
Aminosulfenylation, of alkenes      1058
Aminotetrahydropyrans and the anomeric effect      177
Ammonia and reduction of aromatic compounds      1009
Ammonia reaction with acyl halides      506
Ammonia reaction with aldehydes or ketones      1186
Ammonia reaction with alkenes      999
Ammonia reaction with anhydrides      507
Ammonia reaction with aryl halides      864
Ammonia reaction with boranes and NaOCl      799
Ammonia reaction with carboxyhc acids      508
Ammonia reaction with cyanamide      1192
Ammonia reaction with cyanohydrins      502
Ammonia reaction with cyclic anhydrides      508
Ammonia reaction with dinitriles      1192
Ammonia reaction with epoxides      504
Ammonia reaction with esters      510
Ammonia reaction with isocyanates      1191
Ammonia reaction with naphthols      865
Ammonia reaction with nitriles      1191
Ammonia reaction with pyrylium ions      1186
Ammonia reaction with sulfonyl chlorides      576
Ammonium chloride, and the Mannich reaction      1189
Ammonium hydroxides, thermolysis of      1331
Ammonium salts and the E2 elimination      1306
Ammonium salts and the Emde reduction      530
Ammonium salts and the Stevens rearrangement      1419
Ammonium salts aryl and the Hofmann — Martius reaction      729
Ammonium salts as phase transfer catalysts      454—455
Ammonium salts benzylic and the Sommelet — Hauser rearrangement      877
Ammonium salts benzylic, reaction with amide bases      877
Ammonium salts by the Menshutkin reaction      499
Ammonium salts elimination reactions      1332
Ammonium salts elimination, and cis/trans isomers      1333
Ammonium salts from amine addition to alkenes      1000
Ammonium salts from amines and alkyl halides      499
Ammonium salts reaction with       530
Ammonium salts reaction with amide bases      1419
Ammonium salts reaction with amides      512
Ammonium salts reaction with organolithium reagents      792 1332
Ammonium salts reaction with urea      512
Anchimeric assistance      404 (also see “Neighboring group effects”)
Anchimeric assistance and migratory aptitude in carbocation      1385
Anchimeric assistance and nonclassical ions      409
Angelic acid, from vinyl bromides      766
Angle strain cyclobutane      182
Angle strain cyclopropane      181
Angles bond and E2 elimination      1303
Angles dihedral and conformation      168
Angles dihedral, and E2 elimination      1303
Angles torsion      168
Angular momentum, and photochemistry      315
Anhydrides acetic, with DMSO for oxidation of alcohols      1516
Anhydrides alcoholysis of      483
Anhydrides and acylation of alkenes      784
Anhydrides and leaving groups      449
Anhydrides and the Perkin reaction      1229
Anhydrides by-products of the Baeyer — Villiger reaction      1657
Anhydrides cyclic, from diacids      491
Anhydrides cyclic, reaction with alcohols      483
Anhydrides from $\alpha$ -diketones and peroxy compounds      1657
Anhydrides from acid derivatives      1656
Anhydrides from acids and enol esters      491
Anhydrides from acids and esters      491
Anhydrides from acyl halides      490 1656
Anhydrides from acyloxylation of aldehydes      1657
Anhydrides from alkenes      1657
Anhydrides from ammonium carboxylates      491
Anhydrides from aryl halides and CO      1657
Anhydrides from carboxylic acid salts      490 509 1656 1657
Anhydrides from carboxylic acids      1657
Anhydrides from dehydration of carboxylic acids      491 1656
Anhydrides from diazonium fluoroborates      1657
Anhydrides from ketenes      1657
Anhydrides from oxidation of aromatic rings      1657
Anhydrides hydrolysis of      469
Anhydrides intermediate in preparing acyl halides      523
Anhydrides maleic      see “Maleic anhydride”
Anhydrides mixed      508
Anhydrides organic-inorganic      494
Anhydrides reaction with alcohols      483
Anhydrides reaction with aldehydes      1229 1245
Anhydrides reaction with amides      508
Anhydrides reaction with amino acids      812
Anhydrides reaction with ammonia      507
Anhydrides reaction with aromatic compounds      713
Anhydrides reaction with enamines      788
Anhydrides reaction with enolate anions      569
Anhydrides reaction with Grignard reagents      567

Anhydrides reaction with HF      524
Anhydrides reaction with hydrogen peroxide      492
Anhydrides reaction with oximes      1348
Anhydrides reaction with phosphorus ylids      1237
Anhydrides reaction with Zn, AcOH      1550
Anhydrides reagents for formation of      509
Anhydrides reduction to aldehydes      533
Anhydrides reduction to lactones      1550
Anhydrides triffic, and the Ritter reaction      1245
Anhydrides trifluoroacetic, with DMSO for oxidation of alcohols      1516
Aniline addition to alkenes      1001
Aniline derivatives      also see “Amines aromatic”
Aniline derivatives and cine substitution      864
Aniline derivatives and the Friedlander quinoline synthesis      1186
Aniline derivatives and the Gabriel synthesis      864
Aniline derivatives by the Bamberger rearrangement      878
Aniline derivatives by the Goldberg reaction      864
Aniline derivatives by the Hofmann — Martius reaction      729
Aniline derivatives by the Reilly — Hickinbottom rearrangement      729
Aniline derivatives from aryl acyl halides      1413
Aniline derivatives from aryl halides      854 864
Aniline derivatives from aryl nitrogen compounds      1559
Aniline derivatives from azo compound      1559
Aniline derivatives from azoxy compound      1559
Aniline derivatives from benzynes      854
Aniline derivatives from hydrazo compound      1559
Aniline derivatives from hydroxylamines      878
Aniline derivatives from nitro compounds      1552
Aniline derivatives oxidation of      1539
Aniline derivatives reaction with aryl halides, catalysts for      864
Aniline resonance forms      42
Anilines deuterated, rearrangement of      727
Anilines trifluoroacetyl, hydrolysis      475
Anionic cleavage      759 808
Anionotropic rearrangements      1377
Anions acyl and Umpolung      553
Anions allylic and rate acceleration in Diels — Alder reactions      1066
Anions allylic and [3+2]-cycloadditions      1076
Anions allylic carboxylate, and resonance      344
Anions allylic size and reaction rate      451
Anions allylic sulfonyl      574—575
Anisole chlorination in cyclodextrin, ortho/para ratio      686
Anisole nitrosation of      699
Annellation, and aromaticity      50
Annulation, Robinson      1222
Annulenes and aromaticity      62—69
Annulenes and NMR      63—69
Annulenes annulenoannulenes      90
Annulenes definition      57
Annulenoannulenes      90
Anomeric effect      176—177
Antarafacial addition, in Diels — Alder reactions      1073
Antarafacial migration, [1,5]-H sigmatropic rearrangement      1437
Antarafacial process      1342
Anthracene Dewar structure      43
Anthracene hydrogenation of      1010
Anthracene in the Diels-Alder reaction      1063
Anthracene photodimers, bond distances      19
Anthracene reaction with benzyne      1063
Anthracene reaction with bromine      50
Anti conformation      169
Anti nomenclature      147
Anti — Bredt alkenes, and the Wittig reaction      1233
Anti — elimination, and E2elimination      1300
Anti — Markovnikov addition amines from boranes      800
Anti — Markovnikov addition and hydroboration      798
Anti — Markovnikov addition hydration of alkenes      994
Anti — Markovnikov addition of HBr to alkenes      991
Anti — Markovnikov addition radical addition of silanes to alkenes      1039
Anti — Markovnikov addition thiols to alkenes      998
Anti-periplanar conformation, and E2 elimination      1300
Antiaromatic, and oxirenes      1054
Antiaromaticity and addition to alkenes      983
Antiaromaticity and benzocycloheptatrienyl anion      62
Antiaromaticity and cycloheptatrienyl anion      62
Antiaromaticity and cyclooctatetraene      62
Antiaromaticity and cyclopentadienyl cation      60—61
Antiaromaticity and eight-electron systems      62
Antiaromaticity and Hiickel’s rule      61
Antiaromaticity and ten-electron systems      62—64
Antiaromaticity cyclopropenyl anion      60—61
Antiaromaticity definition      58—59
Antiaromaticity four electron systems      58—61
Antibodies, in the Diels — Alder reaction      1065
Anticlinal conformation      169
Antimony pentafluoride, and carbocations      220
Aprotic solvents      450
Aqueous media, and the Diels — Alder reaction      1066
Arbuzov reaction      1234
Arenes, protection of      1066
Arenium ion mechanism      675—680
Arenium ion mechanism, mercuration of aromatic compounds      793
Arenium ions      222 411 1402 “Phenonium
Arenium ions $\pi$ -complexes      679
Arenium ions and ipso attack      686
Arenium ions and NMR      413
Arenium ions are decarboxylation of aryl carboxylic acids      733
Arenium ions as intermediates      676
Arenium ions for naphthalene derivative      689
Arenium ions isolation of      678
Arenium ions stability of, table      679
Arenonium ions, and the mechanism      853
Arenonium ions, from diazonium salts      853
Argon matrix trapping      187
Arndt — Eistert synthesis      573 1405—1407
Arndt — Eistert synthesis, and Wolff rearrangement      1405
Aromatic aldehydes      see “Aldehydes aromatic”
Aromatic amines      see “Amines aromatic”
Aromatic compounds      see “Aromatic compounds”
Aromatic compounds alkyl, oxidation of      1527
Aromatic compounds alkylation of      932
Aromatic compounds amidation of      702
Aromatic compounds and reactions      850—853
Aromatic compounds and aminium radical ions      701
Aromatic compounds and Benkeser reduction      1012
Aromatic compounds and benzylic radical bromination      912
Aromatic compounds and Birch reduction      1010—1012
Aromatic compounds and dissolving metal reductions      1009
Aromatic compounds and electrophilic aromatic substitution      688—690
Aromatic compounds and the reaction      853
Aromatic compounds and the Heck reaction      930
Aromatic compounds and the Scholl reaction      711
Aromatic compounds by Diels — Alder reactions      1658
Aromatic compounds by Friedel — Crafts alkylation      1657
Aromatic compounds by the Etard reaction      15134
Aromatic compounds by the Gomberg — Bachmann reaction      1657
Aromatic compounds by the Haller — Bauer reaction      1657
Aromatic compounds by the Pschorr reaction      1657
Aromatic compounds by the Scholl arylation      1657
Aromatic compounds by the Ullmann reaction      1657
Aromatic compounds chloromethylation of      721
Aromatic compounds cleavage of alkyl groups      730—731
Aromatic compounds coupling      711
Aromatic compounds dihydroxylation of      1050
Aromatic compounds from $\alpha$ -aryl acids      1657
Aromatic compounds from aldehydes      732
Aromatic compounds from alkynes      1658
Aromatic compounds from aromatic acids      1657 1658
Aromatic compounds from aromatic acyl halides      1658
Aromatic compounds from aromatic aldehydes      1657 1658
Aromatic compounds from aromatic compounds      1657
Aromatic compounds from aromatic ketones      1657 1658
Aromatic compounds from aromatic nitro compounds      1657
Aromatic compounds from aromatic sulfonic acids      1657
Aromatic compounds from aromatization of six-membered rings      1658
Aromatic compounds from aryl alkenes      1658
Aromatic compounds from aryl diazonium salts      934
Aromatic compounds from aryl esters      1657
Aromatic compounds from aryl ethers      734 1657
Aromatic compounds from aryl halides      735 868

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