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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Aldehydes oxidation of, mechanism 917
Aldehydes oxidation with permanganate 918
Aldehydes oxidation, reagents for 917
Aldehydes oxidative cleavage 1521
Aldehydes photochemical cleavage 318
Aldehydes reaction with  533
Aldehydes reaction with  or  1210
Aldehydes reaction with  1240
Aldehydes reaction with  1195
Aldehydes reaction with  1561
Aldehydes reaction with  -methoxyvinyllithium 1227
Aldehydes reaction with active methylene compounds 1225—1228
Aldehydes reaction with acyl halides 1182
Aldehydes reaction with alcohols 1180 1182
Aldehydes reaction with aldehydes 1218—1223
Aldehydes reaction with alkenes 1038 1249—1250
Aldehydes reaction with allylsilanes 1211
Aldehydes reaction with amides 1187
Aldehydes reaction with amines 552 1185—1189
Aldehydes reaction with ammonia 925 1186 1188
Aldehydes reaction with anhydrides 1229 1245
Aldehydes reaction with base and then imines 1222
Aldehydes reaction with bisulfites 1185
Aldehydes reaction with boron carbanions 785
Aldehydes reaction with bromine 914 1196
Aldehydes reaction with bromoesters and Zn 1212
Aldehydes reaction with carboxylic acids, and isonitriles 1251
Aldehydes reaction with chlorine 914
Aldehydes reaction with chloro esters 1230
Aldehydes reaction with conjugated compounds 1212
Aldehydes reaction with cyanide and conjugated compounds 1033
Aldehydes reaction with diazo esters 785
Aldehydes reaction with diazoalkanes 1248
Aldehydes reaction with diazomethane 1248
Aldehydes reaction with dichromate 918
Aldehydes reaction with diethyl diazoacetate 785
Aldehydes reaction with diethylzinc 1211
Aldehydes reaction with dithiols 556
Aldehydes reaction with esters 1223
Aldehydes reaction with formaldehyde 1230
Aldehydes reaction with Girard’s reagents T and P 1193
Aldehydes reaction with Grignard reagents 1205—1209
Aldehydes reaction with halogens 775
Aldehydes reaction with HCN 1239
Aldehydes reaction with hydrazines 1192—1193
Aldehydes reaction with hydrazones 1193
Aldehydes reaction with hydrogen sulfide 1184
Aldehydes reaction with hydroxylamine 1194
Aldehydes reaction with hydroxylamme and formic acid 1195
Aldehydes reaction with KCN 1243
Aldehydes reaction with ketene acetals 1249
Aldehydes reaction with ketenes 1249
Aldehydes reaction with ketones 1218—1223
Aldehydes reaction with Lawesson’s reagent 1184
Aldehydes reaction with Mannich bases 1189
Aldehydes reaction with NBS 914
Aldehydes reaction with organocerium reagents 1205
Aldehydes reaction with organocuprates 1205
Aldehydes reaction with organolithium reagents 1205—1209
Aldehydes reaction with organometallics 1209—1211
Aldehydes reaction with oxidizing agents 917
Aldehydes reaction with Petasis reagent 1238
Aldehydes reaction with phenylhydrazine 1453
Aldehydes reaction with phosphorus ylids 1231—1237
Aldehydes reaction with semicarbazide 1193
Aldehydes reaction with silane carbanions 1228
Aldehydes reaction with silanes 1239
Aldehydes reaction with silyl enol ethers 552
Aldehydes reaction with silyl ketene acetals 1223
Aldehydes reaction with sodium  516
Aldehydes reaction with sulfur ylids 1247
Aldehydes reaction with Tebbe’s reagent 1238
Aldehydes reaction with thiols 1181 1185
Aldehydes reaction with triphenyl phosphite 1196
Aldehydes reaction with water 1175
Aldehydes reduction of 1197—1203
Aldehydes reduction with boranes 1200
Aldehydes reduction with hydrazine-KOH 1547
Aldehydes reduction with hydrides 1197—1198
Aldehydes reduction with metals in water 1200
Aldehydes reduction with silanes and base 1200
Aldehydes reduction with sodium in ethanol 1199
Aldehydes reduction with Zn-Hg/HCl 1547
Aldehydes reduction, chemoselective 1198
Aldehydes reductive amination 1188
Aldehydes reductive coupling 1559—1561
Aldehydes reductive dimerization 1182
Aldehydes reductive removal of O 1547
Aldehydes trimerization of 1245
Aldehydes, aromatic and the Duff reaction 717
Aldehydes, aromatic and the Tishchenko reaction 1565
Aldehydes, aromatic by bromination of methyl aryls 1534
Aldehydes, aromatic by the Etard reaction 1534
Aldehydes, aromatic by the Gatterman reaction 715
Aldehydes, aromatic by the Gatterman — Koch reaction 715
Aldehydes, aromatic by the Reimer — Tiemann reaction 716
Aldehydes, aromatic by the Vilsmeier reaction 715
Aldehydes, aromatic decarbonylation 732
Aldehydes, aromatic from aromatic compounds 715
Aldehydes, aromatic from methyl aryls 1533
Aldehydes, aromatic oxidation of 1528
Aldehydes, aromatic reaction with  1565
Aldehydes, aromatic reaction with sulfuric acid 732
Aldehydes, chiral, in the aldol reaction 1222
Aldehydes, conjugated and Michael reactions 1022—1024
Aldehydes, conjugated and the Grignard reaction 1205
Aldehydes, conjugated by [2,3] sigmatropic rearrangement 1454
Aldehydes, conjugated reaction with borane 1031
Aldehydes, conjugated reaction with organocuprates 1027
Aldehydes, rearrangement of 1401
Aldimines see “Imines”
Aldol condensation 236 552 1218—1223
Aldol reaction 236 552 1218—1223
Aldol reaction crossed 1221
Aldol reaction crossed, and the TollenV reaction 1231
Aldol reaction homoaldol 1227
Aldol reaction intramolecular 1222
Aldol reaction intramolecular, and the Robinson annulation 1222
Aldol reaction Mukaiyama 1223
Aldol reaction retro 808
Aldols 150 1220
Aldrich Library of Spectra 1619
Algorithm, for solvent dielectric effects 450
Alkaloids, Cinchona, and dihydroxylation of alkenes 1050
Alkanes also see “Hydrocarbons”
Alkanes addition to alkenes 1017
Alkanes by Clemmensen reduction 1648
Alkanes by the Barton — McCombie reaction 1647
Alkanes by the Haller — Bauer reaction 1648
Alkanes by the Kolbe reaction 1648
Alkanes by the Wurtz reaction 1647
Alkanes by Wolff — Kishner reduction 1648
Alkanes catalytic exchange with deuterium 1005
Alkanes conformations 168
Alkanes cyclic, aromatization 1510
Alkanes from addition of alkanes to alkenes 1648
Alkanes from addition of organometallics to alkenes 1648
Alkanes from addition of organometallics to alkynes 1648
Alkanes from addition to alkenes 1648
Alkanes from alkyl halides with organocuprates 1647
Alkanes from alkyl halides with organometallics 1647
Alkanes from alkylation of alkanes 1648
Alkanes from carboxylic acids with trimethylaluminum 1648
Alkanes from cleavage of alkanes 1648
Alkanes from cleavage of ketones with amide ion 1648
Alkanes from cleavage of nonenolizable ketones 1648
Alkanes from cleavage of tertiary alkoxides 1648
Alkanes from coupling of alcohols 1647
Alkanes from coupling of alkanes 1648
Alkanes from coupling of alkyl halides 1647
| Alkanes from coupling of boranes 1648
Alkanes from coupling of Grignard reagents 1648
Alkanes from coupling of organometallic compounds 1648
Alkanes from decarbonylation of acyl halides 1648
Alkanes from decarbonylation of aldehydes 1648
Alkanes from decarboxylation of carboxylic acids 1648
Alkanes from decarboxylative dimerization 1648
Alkanes from decyanation of nitrites 1648
Alkanes from deoxygenation of aryl ethers 1648
Alkanes from desulfurization of sulfur compounds 1648
Alkanes from dimerization of alkenes 1648
Alkanes from extrusion of  from diacyl peroxides 1648
Alkanes from Grignard reagents and ethers 1647
Alkanes from hydrogenation of alkenes 1648
Alkanes from hydrogenation of alkynes 1648
Alkanes from hydrogenolysis of alcohols 1647
Alkanes from hydrogenolysis of esters 1647
Alkanes from hydrogenolysis of nitriles 1647
Alkanes from insertion of carbenes 1648
Alkanes from ketones with trimethylaluminum 1648
Alkanes from organometallic compounds and acids 1648
Alkanes from organometallic reagents and alkyl sulfates 1647
Alkanes from organometallic reagents and alkyl sulfonates 1647
Alkanes from oxidation of hydrazines 1648
Alkanes from oxidative decarboxylation of carboxylic acids 1648
Alkanes from reduction of aldehydes or ketones 1648
Alkanes from reduction of alkenes 1648
Alkanes from reduction of alkyl halides 1647
Alkanes from reduction of alkynes 1648
Alkanes from reduction of aromatic rings 1648
Alkanes from reduction of carboxylic acids 1648
Alkanes from reduction of cyano to methyl groups 1648
Alkanes from reduction of dithianes 1647
Alkanes from reduction of epoxides 1648
Alkanes from reduction of esters 1648
Alkanes from reduction of the С — N bond 1647
Alkanes from reduction of tosylates 1647
Alkanes from reductive cleavage of carboxylic esters 1647
Alkanes from reductive cleavage of cyclopropanes 1648
Alkanes from reductive cleavage of sulfides 1647
Alkanes from reductive cleavage of sulfoxides 1647
Alkanes from reductive cleavage of thiols 1647
Alkanes radical halogenation, mechanism of 909
Alkanes rate of radical abstraction 901
Alkanes reaction with halogens 907—911
Alkene acids, cyclization of 1043
Alkene alcohols by the Prins reaction 1241
Alkene alcohols conversion to halo ethers 1056
Alkene alcohols fragmentation 1351
Alkene alcohols from aldehydes and silanes 1239
Alkene alcohols from alkenes and formaldehyde 1241
Alkene aldehydes by oxy-Cope rearrangement 1445
Alkene aldehydes from diene alcohols 1445
Alkene amides, cyclization of 1043
Alkene amines, from alkenes 782
Alkene ketones by Claisen rearrangement 1452
Alkene ketones from allyl vinyl ethers 1452
Alkene metathesis 1457—1459; see “Metathesis alkene”
Alkenes acylation and Markovnikov’s rule 784
Alkenes acylation of 784
Alkenes acyloxylation 1033
Alkenes addition and exo/endo diastereoselectivity 987
Alkenes addition and reactivity 981
Alkenes addition of aldehydes 1033
Alkenes addition of alkanes 1017
Alkenes addition of aniline 1001
Alkenes addition of carbanions 1018
Alkenes addition of formamides 1034
Alkenes addition of formates 1034
Alkenes addition of nucleophilic radicals 983
Alkenes addition of organometallics 1024—1026
Alkenes addition of silanes 1018 1039
Alkenes addition of water 974
Alkenes addition to alkenes 1019
Alkenes addition to and antiaromaticity 983
Alkenes addition to and hyperconjugation 987
Alkenes addition to and the Cieplak effect 988
Alkenes addition to, electronic effects 987
Alkenes addition to, field effects 987
Alkenes addition, cyclic mechanisms 979
Alkenes addition, regioselectivity 984
Alkenes alkylation by the Prins reaction 1047
Alkenes alkylation of 1047
Alkenes ally lie oxidation, reagents for 915
Alkenes allylic rearrangement 771
Alkenes aminosulfenylation 1058
Alkenes and alkene formation from boranes 1338
Alkenes and allylic radicals 902
Alkenes and Birch reduction 1008
Alkenes and Bredt's rule 188
Alkenes and cis/trans isomers 157—160
Alkenes and diastereomers 157—160
Alkenes and Friedel — Crafts acylation 784
Alkenes and Friedel — Crafts alkylation 710
Alkenes and LIDAKOR 1329
Alkenes and Markovnikov’s rule 984
Alkenes and organolithium reagents 1649
Alkenes and PES 12
Alkenes and phase transfer conditions 1085
Alkenes and radical bromination 911
Alkenes and Tebbe’s reagent 1649
Alkenes and termolecular addition 972
Alkenes and the Barbier — Wieland procedure 1526
Alkenes and the Bayer test 1049
Alkenes and the CIP method 157
Alkenes and the Heck reaction 930
Alkenes and the Michael reaction 1022—1024
Alkenes and the Paterno — Buechi reaction 1249
Alkenes and the Petasis reagent 1649
Alkenes and thermolysis of aziridines 1061
Alkenes and Wohl — Ziegler bromination 911
Alkenes anti-Bredt and the Wittig reaction 1233
Alkenes anti-Bredt anti-Markovnikov addition 991 994
Alkenes Bakers yeast reduction 1004
Alkenes by Chugaev elimination 1649
Alkenes by Cope elimination 1333 1649
Alkenes by Cope rearrangement 1650
Alkenes by diazonium ions 1335
Alkenes by E2 elimination 1304
Alkenes by extrusion reactions 1650
Alkenes by Hofmann elimination 1331 1649
Alkenes by McMurry reaction 1561
Alkenes by Meerwein arylation 1649
Alkenes by Peterson olefination 1649
Alkenes by protonation of vinylboranes 1425
Alkenes by remote dehydrogenation 1650
Alkenes by the Bamford — Stevens reaction 1335
Alkenes by the Boord reaction 1344 1650
Alkenes by the Chugaev reaction 1330
Alkenes by the Corey — Winter reaction 1340
Alkenes by the Demyanov rearrangement 1650
Alkenes by the di- -methane rearrangement 1650
Alkenes by the Diels — Alder reaction 1649
Alkenes by the ene reaction 1021 1649
Alkenes by the Horner — Emmons reaction 1233
Alkenes by the Peterson alkenylation reaction 1228
Alkenes by the Ramberg — Backlund reaction 1341 1650
Alkenes by the Reformatsky reaction 1649
Alkenes by the Shapiro reaction 1334
Alkenes by the Vilsmeier reaction 785
Alkenes by the Wadsworth — Emmons reaction 1233
Alkenes by the Wittig reaction 1231—1237
Alkenes by the Wittig — Horner reaction 1233
Alkenes by the Wurtz reaction 535
Alkenes by twofold extrusion 1355
Alkenes by Wagner — Meerwein rearrangement 1650
Alkenes by Wittig olefination 1231—1237 1649
Alkenes carbocation intermediates 974
Alkenes carbocations and Friedel — Crafts alkylation 710
Alkenes carbonylation of, with alkenes 1035
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