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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
HOMO and Diels — Alder reactions      1070
Homo Diels — Alder reaction      1063
HOMO of cyclobutenes      1428
Homoaldol reaction      1227
Homoallylic carbocations      408
Homoanomeric interaction      176
Homoaromatic compounds      70
Homoconjugation      40
Homocubyl radical      1390
Homoenolate ions      232; see “Carbanions”
Homologation, of aldehydes and ketones      1407
Homologation, of esters      568
Homolytic bond cleavage and mechanism      275
Horner — Emmons reaction      1233
Horner — Emmons reaction, intramolecular      1234
Hosts and crown ethers      105
Hosts and resolution      152
Houben — Weyl      1623
Houben-Hoesch reaction      722
HSAB      see “Hard-soft acid-base theory”
Huang-Minion modification      1547
Hueckel method      34
Hueckel systems      1071
Hueckel’s rule      1070
Hueckel’s rule and antiaromaticity      61
Hueckel’s rule and aromaticity      57—58
Hund’s rule and aromaticity      57
Hund’s rule and carbenes      248
Hund’s rule and photochemistry      308
Hunsdiecker reaction      899 942—943
Hurtley reaction      869
hybridization      6—8
Hybridization $sp^2$, and radicals      244
Hybridization and acid-base strength      348—349
Hybridization and bond angles      21
Hybridization and C-H acid strength      433
Hybridization and carbanions      233
Hybridization and electronegativity      15
Hybridization and field effects      18
Hybridization and the $S_N2$ reaction      390
Hybridization digonal      7
Hybridization sp      9
Hybridization trigonal      7
Hydrates and I strain      1176
Hydrates from aldehydes      1175
Hydrates from ketones      1175
Hydration of alkenes, reagents for      993—994
Hydration of alkynes      995
Hydration of allenes      996
Hydrazide ions, reaction with heterocycles      873
Hydrazides acyl, reaction with nitrous acid      1412
Hydrazides from acyl halides      507 1672
Hydrazides from carboxylic esters      1672
Hydrazides from esters      510
Hydrazides from hydrazines      1672
Hydrazine and inclusion compounds      111
Hydrazine reaction with acyl halides      507
Hydrazine reaction with esters      510
Hydrazine reaction with phthalimides      513
Hydrazines by the Hofmann rearrangement      1673
Hydrazines from alkenes      1673
Hydrazines from azo compounds      1556 1673
Hydrazines from diazonium salts      1556 1673
Hydrazines from heterocycles      1673
Hydrazines from hydrazines      1673
Hydrazines from N-nitro compounds      1673
Hydrazines from N-nitroso compounds      1554 1673
Hydrazines from ureas      1411 1673
Hydrazines reaction with aldehydes or ketones      1192—1193
Hydrazines reaction with diketones      1193
Hydrazines reaction with hydroxy aldehydes or ketones      1193
Hydrazines reaction with keto esters      1193
Hydrazines reaction with nitrous acid      817
Hydrazo compounds from nitro compounds      1564
Hydrazo compounds, oxidation with NaOBr      1519
Hydrazo compounds, reduction with Zn-HCl      1559
Hydrazobenzenes from aromatic nitro compounds      1553
Hydrazobenzenes rearrangement with acid      1455
Hydrazoic acid, reaction with alcohols      502
Hydrazoic acid, reaction with alkenes      1002
Hydrazoic acid, reaction with aromatic compounds      701
Hydrazoic acid, reaction with carboxylic acids      1413
Hydrazoic acid, reaction with cyclic ketones      1414
Hydrazoic acid, reaction with ketones      1414
Hydrazone, anions, reaction with alkyl halides      555
Hydrazones alkylation of      552
Hydrazones and the Eschenmoser — Tanabe reaction      1347
Hydrazones aryl, and the Fisher indole synthesis      1452
Hydrazones aryl, cyclization with Lewis aids      1452
Hydrazones by the Japp — Klingemann reaction      779
Hydrazones dimethyl, elimination reactions      1348
Hydrazones dimethyl, oxidation of      1519
Hydrazones from active methylene compounds      778
Hydrazones from aldehydes and ketones      1192—1193 1673
Hydrazones from azines      1193
Hydrazones from diazonium salts      778
Hydrazones from tautomerism of azo compounds      778
Hydrazones hydrolysis of      1177
Hydrazones in the Wolff-Kishner reduction      1548
Hydrazones reaction with $CuBr_2/t-BuOLi$      1196
Hydrazones reaction with aldehydes      1193
Hydrazones reaction with HCN      1240
Hydrazones reaction with KCN      1241
Hydrazones reaction with ketenes      1250
Hydrazones reaction with lead tetraacetate      870
Hydrazones reaction with organocerium reagents      1216
Hydrazones reduction of      1203
Hydrazonium salts, elimination reactions      1348
Hydride ion migration, in Wagner — Meerwein shifts      1394
Hydride reagents chemoselectivity      1198
Hydride reagents reaction with alkyl halides      525—526
Hydride reagents reaction with tosylates      526
Hydride reagents reduction of aldehydes and ketones, mechanism of      1202
Hydride reagents reduction of aldehydes or ketones      1197—1198
Hydride shifts, seven      1395
Hydride transfer and oxidation-reduction      1508
Hydride transfer in the Cannizzaro reaction      1565
Hydride transfer in the Tishchenko reaction      1566
Hydro boration and amination of alkenes      1001
Hydro boration and anti-Markovnikov addition      798
Hydro boration asymmetric      1014
Hydro boration double-asyminetric synthesis      1015
Hydro boration of alkenes      1012—1016
Hydro boration of dienes      1015
Hydrobromic acid      see “HBr”
Hydrocarbon, salts      230
Hydrocarbons acyloxylation, reagents for      923
Hydrocarbons and radical substitution with iodine      908
Hydrocarbons aromatic, distorted      44
Hydrocarbons aromatic, fullerenes      70—71
Hydrocarbons aromatization with S or Se      1511
Hydrocarbons autoxidation      920
Hydrocarbons benzenoid polyaromatic      48
Hydrocarbons by Clemmenson reduction      1547
Hydrocarbons by Huang — Minion modification      1547
Hydrocarbons by reduction of alkoxides      1209
Hydrocarbons by Wolff — Kishner reduction      1547
Hydrocarbons chlorosulfonation of      924
Hydrocarbons cleavage with super acids      814
Hydrocarbons conversion to carboxylic acids      564
Hydrocarbons coupling      786
Hydrocarbons cyclic; aromatization      1510
Hydrocarbons fluorination of      908
Hydrocarbons from alcohols      527 544
Hydrocarbons from aldehydes      944 1547
Hydrocarbons from alkenes      1002
Hydrocarbons from amines      530
Hydrocarbons from boranes and carboxylic aids      1005
Hydrocarbons from carboxylate salts      941—942
Hydrocarbons from carboxylic acids      1214
Hydrocarbons from diimide reduction of alkenes      1007
Hydrocarbons from esters      529
Hydrocarbons from hydrocarbons      770 926
Hydrocarbons from hydrogenation of cyclopropanes      1012
Hydrocarbons from ketones      1214 1547
Hydrocarbons from nitriles      528 815
Hydrocarbons from nitro compounds      531
Hydrocarbons from organometallic compounds      536 794
Hydrocarbons from organometalllcs and alkyl halides      540—541
Hydrocarbons from reduction of epoxides      1552
Hydrocarbons from reduction of tosylates      526
Hydrocarbons from sulfonate esters and organocuprates      543
Hydrocarbons from sulfones      531
Hydrocarbons from sulfoxides      531
Hydrocarbons from thiocarbonates      527
Hydrocarbons from thioethers      531 940
Hydrocarbons from thiols      531
Hydrocarbons H-D exchange      769
Hydrocarbons halogenation of      907—911
Hydrocarbons nitration of      924
Hydrocarbons nonalternant      55—57
Hydrocarbons oxidation with chromic acid      915
Hydrocarbons radical bromination      899
Hydrocarbons radical halogenation, mechanism of      909
Hydrocarbons reaction with $SO_2$ and chlorine      924
Hydrocarbons reaction with acetonitrile      925
Hydrocarbons reaction with bromine      907—911
Hydrocarbons reaction with carbocations      786
Hydrocarbons reaction with chlorine      907—911
Hydrocarbons reaction with halogens      907—911
Hydrocarbons reaction with hydroperoxides      922
Hydrocarbons reaction with metals      793
Hydrocarbons reaction with nitric acids      924
Hydrocarbons reaction with oxygen      920
Hydrocarbons reaction with peroxy esters      922—923
Hydrocarbons reaction with radicals      901
Hydrocarbons reaction with super acids      787
Hydrocarbons reaction with trichloroamine      505
Hydrocarbons, alternant and nonalternant      55—57
Hydrocarbons, alternant, energy levels      56
Hydrochloric aid      see “HCl”
Hydrocyanic acid      see “HCN”
Hydrogen atom transfer, and oxidation-reduction      1508
Hydrogen bond, definition      98
Hydrogen bonding      98—102
Hydrogen bonding and $pK_a$      99
Hydrogen bonding and 1,8-biphenylenediol      100
Hydrogen bonding and acid strength      346
Hydrogen bonding and base strength      332
Hydrogen bonding and C-H bonds      101—102
Hydrogen bonding and cyclodextrins      111—112
Hydrogen bonding and infrared      100
Hydrogen bonding and isocyanides      101
Hydrogen bonding and NMR      100
Hydrogen bonding and pentane-2,4-dione      99—100
Hydrogen bonding and the Cambridge structural database      99
Hydrogen bonding effect on physical properties      101
Hydrogen bonding in few-amides      102
Hydrogen bonding internal, and acid strength      333
Hydrogen bonding relationship to acidity and basicity      99
Hydrogen bonds bifurcated      99
Hydrogen bonds three-center      99—100
Hydrogen exchange and electrophilic aromatic substitution      696
Hydrogen exchange in carbocation reactions      786
Hydrogen neighboring group effects      419
Hydrogen peroxide and coupling of thiols      1543
Hydrogen peroxide and oxidation of aromatic compounds      916
Hydrogen peroxide and oxidation of boranes      797
Hydrogen peroxide and oxidation of thioethers      1541
Hydrogen peroxide NaOH and oxidation of boranes      1016
Hydrogen peroxide oxidation of carboxylic acids      1542
Hydrogen peroxide reaction with amines      1541
Hydrogen sulfide addition to alkenes      999
Hydrogen sulfide anion, reaction with aryl halides      863
Hydrogen sulfide reaction with aldehydes or ketones      1184
Hydrogen sulfide reaction with alkyl halides      495
Hydrogen with amines with aldehydes or ketones      1188
Hydrogen with ammonia and aldehydes or ketones      1188
Hydrogen-deuterium exchange, with hydrocarbons      769
Hydrogen-metal exchange, formation of Grignard reagents      807
Hydrogenation and cleavage in adamantanes      815
Hydrogenation and desulfurization      940
Hydrogenation and reduction of azo compounds      1556
Hydrogenation and Wilkinson’s catalyst      1003
Hydrogenation asymmetric      1003
Hydrogenation asymmetric, of aldehydes and ketones      1201
Hydrogenation catalysts for      1003—1004
Hydrogenation catalysts, and aromatization      1510
Hydrogenation catalytic      1002—1007
Hydrogenation ease of reduction of functional groups      1545
Hydrogenation of acyl halides      532
Hydrogenation of alcohols      527
Hydrogenation of aldehydes      1198
Hydrogenation of alkenes      1002—1007
Hydrogenation of alkenes with CO      1037
Hydrogenation of alkenes, prochiral substrates      1003
Hydrogenation of alkyl halides      525
Hydrogenation of alkynes      1004
Hydrogenation of alkynes, and steric hindrance      1005
Hydrogenation of aromatic compounds      1009
Hydrogenation of cyclopropane s      1012
Hydrogenation of esters      1550
Hydrogenation of hydroperoxides      1558
Hydrogenation of isocyanates      1203
Hydrogenation of ketones      1198
Hydrogenation of oximes      1554
Hydrogenation of thiols and thioethers      940
Hydrogenation of thiophene      941
Hydrogenation ofdienes      1005
Hydrogenation reactivity of alkenes      1004
Hydrogenation transfer hydrogenation      1008
Hydrogenolysis      524
Hydrogenolysis and Raney nickel      532
Hydrogenolysis of acetals      528
Hydrogenolysis of acyl halides      532
Hydrogenolysis of alcohols      527
Hydrogenolysis of diols      527
Hydrogenolysis of esters      527 529 1552
Hydrogenolysis of ethers      528
Hydrogenolysis of ketals      528
Hydrogenolysis of nitriles      528
Hydrogenolysis of nitro compound      531
Hydrogenolysis of selenides      532
Hydrogenolysis of sulfonate esters      526
Hydrogenolysis of sulfones      549
Hydrogenolysis of thioethers      531
Hydrogenolysis of thiols      531
Hydroiodic acid      see “HI”
Hydrolysis and nucleophilic catalysis      469
Hydrolysis basic, of keto esters      812
Hydrolysis of 1,1,1-trihalides      463
Hydrolysis of 1,1-diethoxyethane      466
Hydrolysis of 1,4-diketones      1181
Hydrolysis of acetals      465
Hydrolysis of acetals by $S_N1$ mechanism      466
Hydrolysis of acetals, and microwaves      467
Hydrolysis of acetals, and the Bronsted coefficient      466
Hydrolysis of acetals, rate and structure      466
Hydrolysis of acetals, reagents for      467
Hydrolysis of acyl halides      469
Hydrolysis of alkyl halides      462
Hydrolysis of amides      474—476
Hydrolysis of amides, and diazonium ions      475
Hydrolysis of amides, and radiolabeling      476
Hydrolysis of amides, mechanism      475
Hydrolysis of amides, rate of reaction      475
Hydrolysis of anhydrides      469
Hydrolysis of aryl mtriles      876
Hydrolysis of azides      799
Hydrolysis of benzamide      427
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