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| Авторизация |
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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
HOMO and Diels — Alder reactions 1070
Homo Diels — Alder reaction 1063
HOMO of cyclobutenes 1428
Homoaldol reaction 1227
Homoallylic carbocations 408
Homoanomeric interaction 176
Homoaromatic compounds 70
Homoconjugation 40
Homocubyl radical 1390
Homoenolate ions 232; see “Carbanions”
Homologation, of aldehydes and ketones 1407
Homologation, of esters 568
Homolytic bond cleavage and mechanism 275
Horner — Emmons reaction 1233
Horner — Emmons reaction, intramolecular 1234
Hosts and crown ethers 105
Hosts and resolution 152
Houben — Weyl 1623
Houben-Hoesch reaction 722
HSAB see “Hard-soft acid-base theory”
Huang-Minion modification 1547
Hueckel method 34
Hueckel systems 1071
Hueckel’s rule 1070
Hueckel’s rule and antiaromaticity 61
Hueckel’s rule and aromaticity 57—58
Hund’s rule and aromaticity 57
Hund’s rule and carbenes 248
Hund’s rule and photochemistry 308
Hunsdiecker reaction 899 942—943
Hurtley reaction 869
hybridization 6—8
Hybridization  , and radicals 244
Hybridization and acid-base strength 348—349
Hybridization and bond angles 21
Hybridization and C-H acid strength 433
Hybridization and carbanions 233
Hybridization and electronegativity 15
Hybridization and field effects 18
Hybridization and the  reaction 390
Hybridization digonal 7
Hybridization sp 9
Hybridization trigonal 7
Hydrates and I strain 1176
Hydrates from aldehydes 1175
Hydrates from ketones 1175
Hydration of alkenes, reagents for 993—994
Hydration of alkynes 995
Hydration of allenes 996
Hydrazide ions, reaction with heterocycles 873
Hydrazides acyl, reaction with nitrous acid 1412
Hydrazides from acyl halides 507 1672
Hydrazides from carboxylic esters 1672
Hydrazides from esters 510
Hydrazides from hydrazines 1672
Hydrazine and inclusion compounds 111
Hydrazine reaction with acyl halides 507
Hydrazine reaction with esters 510
Hydrazine reaction with phthalimides 513
Hydrazines by the Hofmann rearrangement 1673
Hydrazines from alkenes 1673
Hydrazines from azo compounds 1556 1673
Hydrazines from diazonium salts 1556 1673
Hydrazines from heterocycles 1673
Hydrazines from hydrazines 1673
Hydrazines from N-nitro compounds 1673
Hydrazines from N-nitroso compounds 1554 1673
Hydrazines from ureas 1411 1673
Hydrazines reaction with aldehydes or ketones 1192—1193
Hydrazines reaction with diketones 1193
Hydrazines reaction with hydroxy aldehydes or ketones 1193
Hydrazines reaction with keto esters 1193
Hydrazines reaction with nitrous acid 817
Hydrazo compounds from nitro compounds 1564
Hydrazo compounds, oxidation with NaOBr 1519
Hydrazo compounds, reduction with Zn-HCl 1559
Hydrazobenzenes from aromatic nitro compounds 1553
Hydrazobenzenes rearrangement with acid 1455
Hydrazoic acid, reaction with alcohols 502
Hydrazoic acid, reaction with alkenes 1002
Hydrazoic acid, reaction with aromatic compounds 701
Hydrazoic acid, reaction with carboxylic acids 1413
Hydrazoic acid, reaction with cyclic ketones 1414
Hydrazoic acid, reaction with ketones 1414
Hydrazone, anions, reaction with alkyl halides 555
Hydrazones alkylation of 552
Hydrazones and the Eschenmoser — Tanabe reaction 1347
Hydrazones aryl, and the Fisher indole synthesis 1452
Hydrazones aryl, cyclization with Lewis aids 1452
Hydrazones by the Japp — Klingemann reaction 779
Hydrazones dimethyl, elimination reactions 1348
Hydrazones dimethyl, oxidation of 1519
Hydrazones from active methylene compounds 778
Hydrazones from aldehydes and ketones 1192—1193 1673
Hydrazones from azines 1193
Hydrazones from diazonium salts 778
Hydrazones from tautomerism of azo compounds 778
Hydrazones hydrolysis of 1177
Hydrazones in the Wolff-Kishner reduction 1548
Hydrazones reaction with  1196
Hydrazones reaction with aldehydes 1193
Hydrazones reaction with HCN 1240
Hydrazones reaction with KCN 1241
Hydrazones reaction with ketenes 1250
Hydrazones reaction with lead tetraacetate 870
Hydrazones reaction with organocerium reagents 1216
Hydrazones reduction of 1203
Hydrazonium salts, elimination reactions 1348
Hydride ion migration, in Wagner — Meerwein shifts 1394
Hydride reagents chemoselectivity 1198
Hydride reagents reaction with alkyl halides 525—526
Hydride reagents reaction with tosylates 526
Hydride reagents reduction of aldehydes and ketones, mechanism of 1202
Hydride reagents reduction of aldehydes or ketones 1197—1198
Hydride shifts, seven 1395
Hydride transfer and oxidation-reduction 1508
Hydride transfer in the Cannizzaro reaction 1565
Hydride transfer in the Tishchenko reaction 1566
Hydro boration and amination of alkenes 1001
Hydro boration and anti-Markovnikov addition 798
Hydro boration asymmetric 1014
Hydro boration double-asyminetric synthesis 1015
Hydro boration of alkenes 1012—1016
Hydro boration of dienes 1015
Hydrobromic acid see “HBr”
Hydrocarbon, salts 230
Hydrocarbons acyloxylation, reagents for 923
Hydrocarbons and radical substitution with iodine 908
Hydrocarbons aromatic, distorted 44
Hydrocarbons aromatic, fullerenes 70—71
Hydrocarbons aromatization with S or Se 1511
Hydrocarbons autoxidation 920
Hydrocarbons benzenoid polyaromatic 48
Hydrocarbons by Clemmenson reduction 1547
Hydrocarbons by Huang — Minion modification 1547
Hydrocarbons by reduction of alkoxides 1209
Hydrocarbons by Wolff — Kishner reduction 1547
Hydrocarbons chlorosulfonation of 924
Hydrocarbons cleavage with super acids 814
Hydrocarbons conversion to carboxylic acids 564
Hydrocarbons coupling 786
Hydrocarbons cyclic; aromatization 1510
Hydrocarbons fluorination of 908
Hydrocarbons from alcohols 527 544
Hydrocarbons from aldehydes 944 1547
Hydrocarbons from alkenes 1002
Hydrocarbons from amines 530
Hydrocarbons from boranes and carboxylic aids 1005
Hydrocarbons from carboxylate salts 941—942
Hydrocarbons from carboxylic acids 1214
| Hydrocarbons from diimide reduction of alkenes 1007
Hydrocarbons from esters 529
Hydrocarbons from hydrocarbons 770 926
Hydrocarbons from hydrogenation of cyclopropanes 1012
Hydrocarbons from ketones 1214 1547
Hydrocarbons from nitriles 528 815
Hydrocarbons from nitro compounds 531
Hydrocarbons from organometallic compounds 536 794
Hydrocarbons from organometalllcs and alkyl halides 540—541
Hydrocarbons from reduction of epoxides 1552
Hydrocarbons from reduction of tosylates 526
Hydrocarbons from sulfonate esters and organocuprates 543
Hydrocarbons from sulfones 531
Hydrocarbons from sulfoxides 531
Hydrocarbons from thiocarbonates 527
Hydrocarbons from thioethers 531 940
Hydrocarbons from thiols 531
Hydrocarbons H-D exchange 769
Hydrocarbons halogenation of 907—911
Hydrocarbons nitration of 924
Hydrocarbons nonalternant 55—57
Hydrocarbons oxidation with chromic acid 915
Hydrocarbons radical bromination 899
Hydrocarbons radical halogenation, mechanism of 909
Hydrocarbons reaction with  and chlorine 924
Hydrocarbons reaction with acetonitrile 925
Hydrocarbons reaction with bromine 907—911
Hydrocarbons reaction with carbocations 786
Hydrocarbons reaction with chlorine 907—911
Hydrocarbons reaction with halogens 907—911
Hydrocarbons reaction with hydroperoxides 922
Hydrocarbons reaction with metals 793
Hydrocarbons reaction with nitric acids 924
Hydrocarbons reaction with oxygen 920
Hydrocarbons reaction with peroxy esters 922—923
Hydrocarbons reaction with radicals 901
Hydrocarbons reaction with super acids 787
Hydrocarbons reaction with trichloroamine 505
Hydrocarbons, alternant and nonalternant 55—57
Hydrocarbons, alternant, energy levels 56
Hydrochloric aid see “HCl”
Hydrocyanic acid see “HCN”
Hydrogen atom transfer, and oxidation-reduction 1508
Hydrogen bond, definition 98
Hydrogen bonding 98—102
Hydrogen bonding and  99
Hydrogen bonding and 1,8-biphenylenediol 100
Hydrogen bonding and acid strength 346
Hydrogen bonding and base strength 332
Hydrogen bonding and C-H bonds 101—102
Hydrogen bonding and cyclodextrins 111—112
Hydrogen bonding and infrared 100
Hydrogen bonding and isocyanides 101
Hydrogen bonding and NMR 100
Hydrogen bonding and pentane-2,4-dione 99—100
Hydrogen bonding and the Cambridge structural database 99
Hydrogen bonding effect on physical properties 101
Hydrogen bonding in few-amides 102
Hydrogen bonding internal, and acid strength 333
Hydrogen bonding relationship to acidity and basicity 99
Hydrogen bonds bifurcated 99
Hydrogen bonds three-center 99—100
Hydrogen exchange and electrophilic aromatic substitution 696
Hydrogen exchange in carbocation reactions 786
Hydrogen neighboring group effects 419
Hydrogen peroxide and coupling of thiols 1543
Hydrogen peroxide and oxidation of aromatic compounds 916
Hydrogen peroxide and oxidation of boranes 797
Hydrogen peroxide and oxidation of thioethers 1541
Hydrogen peroxide NaOH and oxidation of boranes 1016
Hydrogen peroxide oxidation of carboxylic acids 1542
Hydrogen peroxide reaction with amines 1541
Hydrogen sulfide addition to alkenes 999
Hydrogen sulfide anion, reaction with aryl halides 863
Hydrogen sulfide reaction with aldehydes or ketones 1184
Hydrogen sulfide reaction with alkyl halides 495
Hydrogen with amines with aldehydes or ketones 1188
Hydrogen with ammonia and aldehydes or ketones 1188
Hydrogen-deuterium exchange, with hydrocarbons 769
Hydrogen-metal exchange, formation of Grignard reagents 807
Hydrogenation and cleavage in adamantanes 815
Hydrogenation and desulfurization 940
Hydrogenation and reduction of azo compounds 1556
Hydrogenation and Wilkinson’s catalyst 1003
Hydrogenation asymmetric 1003
Hydrogenation asymmetric, of aldehydes and ketones 1201
Hydrogenation catalysts for 1003—1004
Hydrogenation catalysts, and aromatization 1510
Hydrogenation catalytic 1002—1007
Hydrogenation ease of reduction of functional groups 1545
Hydrogenation of acyl halides 532
Hydrogenation of alcohols 527
Hydrogenation of aldehydes 1198
Hydrogenation of alkenes 1002—1007
Hydrogenation of alkenes with CO 1037
Hydrogenation of alkenes, prochiral substrates 1003
Hydrogenation of alkyl halides 525
Hydrogenation of alkynes 1004
Hydrogenation of alkynes, and steric hindrance 1005
Hydrogenation of aromatic compounds 1009
Hydrogenation of cyclopropane s 1012
Hydrogenation of esters 1550
Hydrogenation of hydroperoxides 1558
Hydrogenation of isocyanates 1203
Hydrogenation of ketones 1198
Hydrogenation of oximes 1554
Hydrogenation of thiols and thioethers 940
Hydrogenation of thiophene 941
Hydrogenation ofdienes 1005
Hydrogenation reactivity of alkenes 1004
Hydrogenation transfer hydrogenation 1008
Hydrogenolysis 524
Hydrogenolysis and Raney nickel 532
Hydrogenolysis of acetals 528
Hydrogenolysis of acyl halides 532
Hydrogenolysis of alcohols 527
Hydrogenolysis of diols 527
Hydrogenolysis of esters 527 529 1552
Hydrogenolysis of ethers 528
Hydrogenolysis of ketals 528
Hydrogenolysis of nitriles 528
Hydrogenolysis of nitro compound 531
Hydrogenolysis of selenides 532
Hydrogenolysis of sulfonate esters 526
Hydrogenolysis of sulfones 549
Hydrogenolysis of thioethers 531
Hydrogenolysis of thiols 531
Hydroiodic acid see “HI”
Hydrolysis and nucleophilic catalysis 469
Hydrolysis basic, of keto esters 812
Hydrolysis of 1,1,1-trihalides 463
Hydrolysis of 1,1-diethoxyethane 466
Hydrolysis of 1,4-diketones 1181
Hydrolysis of acetals 465
Hydrolysis of acetals by  mechanism 466
Hydrolysis of acetals, and microwaves 467
Hydrolysis of acetals, and the Bronsted coefficient 466
Hydrolysis of acetals, rate and structure 466
Hydrolysis of acetals, reagents for 467
Hydrolysis of acyl halides 469
Hydrolysis of alkyl halides 462
Hydrolysis of amides 474—476
Hydrolysis of amides, and diazonium ions 475
Hydrolysis of amides, and radiolabeling 476
Hydrolysis of amides, mechanism 475
Hydrolysis of amides, rate of reaction 475
Hydrolysis of anhydrides 469
Hydrolysis of aryl mtriles 876
Hydrolysis of azides 799
Hydrolysis of benzamide 427
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