Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure :: Электронная библиотека попечительского совета мехмата МГУ

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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

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Carbenes rearrangement of      252 1084
Carbenes rearrangements      1392
Carbenes ring enlargement      250—251
Carbenes singlet      248 791 1086
Carbenes stability of      247—249
Carbenes stable      251
Carbenes stereospecific reactions      248—249
Carbenes structure of      247—249
Carbenes triplet      248 252 791
Carbenes triplet vs. singlet energy      248
Carbenium ions      219; see “Carbocations”
Carbenoids and insertion      251
Carbenoids and the Simmons — Smith procedure      1088
Carbenoids chiral      249
Carbenoids definition      250
Carbenoids diazo compounds and alcohols      479
Carbenoids insertion reactions      791
Carbobenzoxy chloride, from benzyl alcohol      483
Carbocations      218—227
Carbocations $pK_{R+}$       224
Carbocations 2,3,3-trimethyl-2-butyl      419
Carbocations acyl      223 712—714
Carbocations alkynyl      430
Carbocations allylic      221
Carbocations and       220
Carbocations and $\sigma$ -bond rearrangements      1460
Carbocations and acylation of alkenes      784
Carbocations and addition of alcohols to alkenes      996
Carbocations and addition of alkanes to alkenes      1017
Carbocations and cleavage of aromatic compounds      730
Carbocations and conjugate addition      979
Carbocations and dehydration of alcohols      1328
Carbocations and Demyanov reactions      1398—1400
Carbocations and electrophilic addition to alkenes      971—972
Carbocations and equilibria      220
Carbocations and Friedel — Crafts alkylation      710
Carbocations and hydration of alkenes      994
Carbocations and hydrogen bonding      101—102
Carbocations and hyperconjugation      220
Carbocations and isotope effects      220
Carbocations and Markovnikov’s rule      984
Carbocations and NMR      219 225 710
Carbocations and nucleophilic rearrangements      1378
Carbocations and pinacol rearrangement      1397
Carbocations and reaction of alkenes with acids      974
Carbocations and spectroscopy      219 224 710
Carbocations and super acids      219
Carbocations and the reaction      393
Carbocations and the field effect      220
Carbocations and the Koch — reaction      564
Carbocations and the Ritter reaction      1244
Carbocations and transetherification      481
Carbocations and Wagner — Meerwein rearrangements      1393
Carbocations and Wheland intermediates      676
Carbocations arenium ions      222
Carbocations aryl      929
Carbocations benzylic      222
Carbocations bridged      407—420 (also see “Nonclassical ions”)
Carbocations bridgehead      224—225
Carbocations by addition      227
Carbocations by alkyl halide hydrolysis      366
Carbocations cyclobutylmethyl, rearrangement of      418
Carbocations cyclopropyl      438
Carbocations cyclopropyl — allyl      1399
Carbocations cyclopropyl, ring opening      1434
Carbocations cyclopropylmethyl      417
Carbocations cyclopropylmethyl, rearrangement of      417
Carbocations definition      218
Carbocations degenerate      1380
Carbocations delocalization and stability      221
Carbocations delocalization, table      221
Carbocations dications      222
Carbocations dissociation energies, table      224
Carbocations double bond migrations      772
Carbocations from alkyl halides      564
Carbocations from alkyl halides and Lewis acids      710
Carbocations from cleavage of hydrocarbons      814
Carbocations from diazonium salts      787 1394
Carbocations from diazotized amines      1382
Carbocations from diazotized isobutylamine      1383
Carbocations homoallylic      408
Carbocations hydride shifts and NMR      1379
Carbocations in SN1reactions, detection of      396
Carbocations intramolecular insertion      787
Carbocations Markovnikov’s rule and Friedel Crafts alkylation      710
Carbocations memory effects      1386
Carbocations migratory aptitude and anchimeric assistance      1385
Carbocations migratory aptitude of aryl groups      1386
Carbocations nonclassical      407—420 1387
Carbocations norbornyl      1394
Carbocations order of stability      219
Carbocations phenyl and vinyl      223
Carbocations propargyl cations      222
Carbocations propeller shaped      225
Carbocations reaction with hydrocarbons      786
Carbocations rearrangement and Friedel — Crafts alkylation      709
Carbocations rearrangement of      227 407—420 786 1379 1382 1386
Carbocations resonance stabilized, and conjugate addition      980
Carbocations stability      1384 1395
Carbocations stability and structure      219—225
Carbocations stability with cyclopropyl groups      222—223
Carbocations stability, and alkene addition reactions      984
Carbocations stability, and Markovnikov’s rule      984
Carbocations stability, and the reaction      395
Carbocations stability, quantitative treatment      223—224
Carbocations stabilization by $\alpha$ -substituents      435
Carbocations stabilization by heteroatoms      223
Carbocations symmetrically stabilized      417
Carbocations table of chemical shifts      225
Carbocations tight ion pairs, and Friedel — Crafts alkylation      711
Carbocations triarylmethyl      225
Carbocations trications      222
Carbocations twisted      1387
Carbocations vinyl      430
Carbocations vinyl, and Friedel — Crafts alkylation      711
Carbocations vinyl, from alkynes      975
Carbodiimides from addition of iscyanates to isocyanates      1660
Carbodiimides from isocyanates      1246
Carbohydrates and the anomeric effect      176—177
Carbohydrates and the Kiliani — Fischer synthesis      1240
Carbon $\sideset{^{14}}{}C$ , and isotopic labeling      289
Carbon acids      328 (also see “Acids”)
Carbon dioxide extrusion from peroxides      1354
Carbon dioxide extrusion in the Story synthesis      1355
Carbon dioxide reaction with alkoxides      1184
Carbon dioxide reaction with amines and iodoethane      820
Carbon dioxide reaction with Grignard reagents      1215
Carbon dioxide reaction with organolithium reagents      801
Carbon dioxide reaction with phenoxides      718
Carbon dioxide reaction with phosphorus ylids      1237
Carbon dioxide supercritical, and Diels — Alder reactions      1066
Carbon dioxide supercritical, as a solvent      454
Carbon disulflde and reduction of hydroxylamines      1554
Carbon disulflde reaction with alcohols      1184
Carbon disulflde reaction with amines      1192
Carbon disulflde reaction with Grignard reagents      1215
Carbon disulflde reaction with ketones      1229
Carbon monoxide and double carbonylation      565
Carbon monoxide and retro Diels — Alder reactions      1347
Carbon monoxide and the Koch or Koch — Haaf reactions      1035
Carbon monoxide extrusion from ketones      1347
Carbon monoxide reaction with alkenes and       1037
Carbon monoxide reaction with alkenes and amines      1035
Carbon monoxide reaction with alkenes and formic acid      1035
Carbon monoxide reaction with alkenes and water      1035
Carbon monoxide reaction with alkyl halides and alcohols      564
Carbon monoxide reaction with amines      820
Carbon monoxide reaction with aryl halides and alcohols      870
Carbon monoxide reaction with boranes      1422—1423
Carbon monoxide reaction with organolithium reagents      801

Carbon monoxide reaction with RLi and ketones      1207
Carbon monoxide reaction with tetracarbonylferrate      563
Carbon monoxide reaction with vinylmercury halides      801
Carbon nucleophiles      see “Carbanions” “Nucleophiles”
Carbon tetrabromide and , alkenylation      1233
Carbon tetrabromide dipole moment      16
Carbon, trigonal, and the tetrahedral mechanism      424
Carbonate esters      see “Esters carbonate”
Carbonates Carbonium ions      218
Carbonates from alcohols      483
Carbonates from alcoholysis of phosgene      1660
Carbonates from alkyl halides and carbonate salts      1660
Carbonium ions      see “Carbocations”
Carbonyl nitrenes, insertion reactions      782
Carbonyl oxides, as 1,3-dipoles      1060
Carbonylation of alkenes      1035
Carbonylation of alkyl halides      565
Carbonylations, double      565
Carbonyls, stabilization of carbanions      230
Carboxylate anions and leaving gronps      449
Carboxylate anions and resonance      344
Carboxylate anions decarboxylation of      810
Carboxylate salts      see “Carboxylic acid salts”
Carboxylate salts, and decarboxylation      732
Carboxylates, ammonium, conversion to anhydrides      491
Carboxylation, of aromatic rings      718
Carboxylation, of phenoxides      718
Carboxylations, by the Kolbe — Schmitt reaction      718
Carboxylic acid esters      see “Esters”
Carboxylic acid salts acylation of      572
Carboxylic acid salts alkylation with      488
Carboxylic acid salts and phase transfer catalysts      488
Carboxylic acid salts by the Cannizzaro reaction      1564
Carboxylic acid salts coupling      941—942
Carboxylic acid salts electrolysis of      941—942
Carboxylic acid salts from aldehydes      1564
Carboxylic acid salts from esters      521
Carboxylic acid salts from Grignard reagents      796
Carboxylic acid salts pyrolysis of      508
Carboxylic acid salts reaction with acyl halides      490
Carboxylic acid salts reaction with alkyl chlorosulfites      489
Carboxylic acid salts reaction with alkyl halides      488 555
Carboxylic acid salts reaction with BrCN or C1CN      1246
Carboxylic acid salts reaction with LDA      572
Carboxylic acid salts reaction with mesylates      489
Carboxylic acid salts reaction with onium salts      489
Carboxylic acid salts silver, and dihydroxylation of alkenes      1049
Carboxylic acid salts silver, and the Hunsdiecker reaction      942—943
Carboxylic acid salts silver, and the Simonini reaction      943
Carboxylic acid salts silver, reaction with bromine      942—943
Carboxylic acid salts silver, reaction with iodine      943
Carboxylic acids and acylation of alkenes      784
Carboxylic acids and dissolving metal reduction      532
Carboxylic acids and the Passerini reaction      1252
Carboxylic acids and transesterification      487
Carboxylic acids aryl, by hydrolysis of aryl nitrites      876
Carboxylic acids aryl, by the von Richter rearrangement      876
Carboxylic acids aryl, decarboxylation of      732
Carboxylic acids aryl, decarboxylation, and rearrangements      733
Carboxylic acids aryl, from aromatic compounds      718
Carboxylic acids aryl, from aromatic nitro compounds      876
Carboxylic acids aryl, reaction with Li/THF      1563
Carboxylic acids by cleavage of ethers      1537
Carboxylic acids by Favorskii rearrangement      1403
Carboxylic acids by oxidative cleavage of ketones or aldehydes      1521
Carboxylic acids by tetracarbonylferrate      565
Carboxylic acids by the Arndt — Eistert rearrangement      1661
Carboxylic acids by the Barbier — Wieland procedure      1526
Carboxylic acids by the Cannizzaro reaction      1662
Carboxylic acids by the haloform reaction      813
Carboxylic acids by the Koch reaction      564 1035
Carboxylic acids by the Koch — Haaf reaction      1035
Carboxylic acids by the Kolbe — Schmitt reaction      1661
Carboxylic acids by the malonic ester synthesis      1661
Carboxylic acids by the Perkin reaction      1229
Carboxylic acids by the von Richter reaction      1661
Carboxylic acids by the Willgerodt reaction      1662
Carboxylic acids by the Wittig reaction      1237
Carboxylic acids coupling with allylic acetates      944
Carboxylic acids decarboxylation of      808
Carboxylic acids dehydration of      491
Carboxylic acids dianions      555
Carboxylic acids dianions, reaction with esters      572
Carboxylic acids esterification of      484—486
Carboxylic acids from 1,1-dichloroethene      1661
Carboxylic acids from acyl halides      1405
Carboxylic acids from alcohols      1537
Carboxylic acids from aldehydes      917 1229
Carboxylic acids from aldehydes and base      1662
Carboxylic acids from alky I halides      564 1661
Carboxylic acids from alkynes      1523 1539 1540
Carboxylic acids from anhydrides      1229
Carboxylic acids from aromatic compounds      1527 1661
Carboxylic acids from ary I halides      1661
Carboxylic acids from carbon dioxide      1215 1661
Carboxylic acids from carboxylate ions      1661
Carboxylic acids from cleavage of carboxylic esters      1661
Carboxylic acids from cleavage of ketones      1661
Carboxylic acids from cleavage of nonenolizable ketones      1661
Carboxylic acids from cleavage of p — diketones      1661
Carboxylic acids from cleavage of p — keto esters      1661
Carboxylic acids from cleavage of secondary alcohols      1661
Carboxylic acids from CO      1661
Carboxylic acids from decarboxylation of dicarboxylic acids      1661
Carboxylic acids from diazoketones      1405
Carboxylic acids from diazonium fluoroborates      1661
Carboxylic acids from enolate dianions      1424
Carboxylic acids from esters      549
Carboxylic acids from fragmentation of certain oximes      1661
Carboxylic acids from Grignard reagents      1215 1661
Carboxylic acids from halo ketones      1403
Carboxylic acids from hydrocarbons      564
Carboxylic acids from hydrolysis of 1,1,1-trihalides      1660
Carboxylic acids from hydrolysis of acyl halides      1660
Carboxylic acids from hydrolysis of amides      1661
Carboxylic acids from hydrolysis of anhydrides      1661
Carboxylic acids from hydrolysis of carboxylic esters      1661
Carboxylic acids from hydrolysis of nitriles      1661
Carboxylic acids from hydrolysis of ortho esters      1660
Carboxylic acids from hydrolysis of oxazines      1661
Carboxylic acids from hydrolysis of primary nitro compound      1661
Carboxylic acids from ketenes      1661
Carboxylic acids from methyl ketones      813
Carboxylic acids from nitriles      1179
Carboxylic acids from oxazolines      559
Carboxylic acids from oxidation of 1,1-diboranes      1661
Carboxylic acids from oxidation of aldehydes      1661
Carboxylic acids from oxidation of amines      1662
Carboxylic acids from oxidation of aromatic side chains      1662
Carboxylic acids from oxidation of aryl ketones      1662
Carboxylic acids from oxidation of arylthioalkynes      1662
Carboxylic acids from oxidation of ethers      1662
Carboxylic acids from oxidation of ozonides      1661
Carboxylic acids from oxidation of primary alcohols      1662
Carboxylic acids from oxidative cleavage of $\alpha$ -diketones      1661
Carboxylic acids from oxidative cleavage of $\alpha$ -keto acids      1661
Carboxylic acids from oxidative cleavage of alkenes      1525—1526 1661
Carboxylic acids from oxidative cleavage of aromatic rings      1661
Carboxylic acids from oxidative cleavage of terminal alkynes      1661
Carboxylic acids from ozonolysis of alkenes      1522
Carboxylic acids from ozonolysis of alkynes      1661
Carboxylic acids from Petasis alkenylation      1661
Carboxylic acids from phosphoranes      1661
Carboxylic acids from pyrolysis of carboxylic esters      1661
Carboxylic acids from pyrolysis of esters      1329
Carboxylic acids from rearrangement of $\alpha$ -halo ketones      1661
Carboxylic acids from rearrangement of aromatic carboxylate ions      1661
Carboxylic acids from rearrangement of aromatic nitro compounds      1661
Carboxylic acids from rearrangement of diazo ketones      1661
Carboxylic acids from reductive cleavage of carboxylic esters      1661

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