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| Авторизация |
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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Carbenes rearrangement of 252 1084
Carbenes rearrangements 1392
Carbenes ring enlargement 250—251
Carbenes singlet 248 791 1086
Carbenes stability of 247—249
Carbenes stable 251
Carbenes stereospecific reactions 248—249
Carbenes structure of 247—249
Carbenes triplet 248 252 791
Carbenes triplet vs. singlet energy 248
Carbenium ions 219; see “Carbocations”
Carbenoids and insertion 251
Carbenoids and the Simmons — Smith procedure 1088
Carbenoids chiral 249
Carbenoids definition 250
Carbenoids diazo compounds and alcohols 479
Carbenoids insertion reactions 791
Carbobenzoxy chloride, from benzyl alcohol 483
Carbocations 218—227
Carbocations  224
Carbocations 2,3,3-trimethyl-2-butyl 419
Carbocations acyl 223 712—714
Carbocations alkynyl 430
Carbocations allylic 221
Carbocations and  220
Carbocations and  -bond rearrangements 1460
Carbocations and acylation of alkenes 784
Carbocations and addition of alcohols to alkenes 996
Carbocations and addition of alkanes to alkenes 1017
Carbocations and cleavage of aromatic compounds 730
Carbocations and conjugate addition 979
Carbocations and dehydration of alcohols 1328
Carbocations and Demyanov reactions 1398—1400
Carbocations and electrophilic addition to alkenes 971—972
Carbocations and equilibria 220
Carbocations and Friedel — Crafts alkylation 710
Carbocations and hydration of alkenes 994
Carbocations and hydrogen bonding 101—102
Carbocations and hyperconjugation 220
Carbocations and isotope effects 220
Carbocations and Markovnikov’s rule 984
Carbocations and NMR 219 225 710
Carbocations and nucleophilic rearrangements 1378
Carbocations and pinacol rearrangement 1397
Carbocations and reaction of alkenes with acids 974
Carbocations and spectroscopy 219 224 710
Carbocations and super acids 219
Carbocations and the  reaction 393
Carbocations and the field effect 220
Carbocations and the Koch — reaction 564
Carbocations and the Ritter reaction 1244
Carbocations and transetherification 481
Carbocations and Wagner — Meerwein rearrangements 1393
Carbocations and Wheland intermediates 676
Carbocations arenium ions 222
Carbocations aryl 929
Carbocations benzylic 222
Carbocations bridged 407—420 (also see “Nonclassical ions”)
Carbocations bridgehead 224—225
Carbocations by addition 227
Carbocations by alkyl halide hydrolysis 366
Carbocations cyclobutylmethyl, rearrangement of 418
Carbocations cyclopropyl 438
Carbocations cyclopropyl — allyl 1399
Carbocations cyclopropyl, ring opening 1434
Carbocations cyclopropylmethyl 417
Carbocations cyclopropylmethyl, rearrangement of 417
Carbocations definition 218
Carbocations degenerate 1380
Carbocations delocalization and stability 221
Carbocations delocalization, table 221
Carbocations dications 222
Carbocations dissociation energies, table 224
Carbocations double bond migrations 772
Carbocations from alkyl halides 564
Carbocations from alkyl halides and Lewis acids 710
Carbocations from cleavage of hydrocarbons 814
Carbocations from diazonium salts 787 1394
Carbocations from diazotized amines 1382
Carbocations from diazotized isobutylamine 1383
Carbocations homoallylic 408
Carbocations hydride shifts and NMR 1379
Carbocations in SN1reactions, detection of 396
Carbocations intramolecular insertion 787
Carbocations Markovnikov’s rule and Friedel Crafts alkylation 710
Carbocations memory effects 1386
Carbocations migratory aptitude and anchimeric assistance 1385
Carbocations migratory aptitude of aryl groups 1386
Carbocations nonclassical 407—420 1387
Carbocations norbornyl 1394
Carbocations order of stability 219
Carbocations phenyl and vinyl 223
Carbocations propargyl cations 222
Carbocations propeller shaped 225
Carbocations reaction with hydrocarbons 786
Carbocations rearrangement and Friedel — Crafts alkylation 709
Carbocations rearrangement of 227 407—420 786 1379 1382 1386
Carbocations resonance stabilized, and conjugate addition 980
Carbocations stability 1384 1395
Carbocations stability and structure 219—225
Carbocations stability with cyclopropyl groups 222—223
Carbocations stability, and alkene addition reactions 984
Carbocations stability, and Markovnikov’s rule 984
Carbocations stability, and the reaction 395
Carbocations stability, quantitative treatment 223—224
Carbocations stabilization by  -substituents 435
Carbocations stabilization by heteroatoms 223
Carbocations symmetrically stabilized 417
Carbocations table of chemical shifts 225
Carbocations tight ion pairs, and Friedel — Crafts alkylation 711
Carbocations triarylmethyl 225
Carbocations trications 222
Carbocations twisted 1387
Carbocations vinyl 430
Carbocations vinyl, and Friedel — Crafts alkylation 711
Carbocations vinyl, from alkynes 975
Carbodiimides from addition of iscyanates to isocyanates 1660
Carbodiimides from isocyanates 1246
Carbohydrates and the anomeric effect 176—177
Carbohydrates and the Kiliani — Fischer synthesis 1240
Carbon  , and isotopic labeling 289
Carbon acids 328 (also see “Acids”)
Carbon dioxide extrusion from peroxides 1354
Carbon dioxide extrusion in the Story synthesis 1355
Carbon dioxide reaction with alkoxides 1184
Carbon dioxide reaction with amines and iodoethane 820
Carbon dioxide reaction with Grignard reagents 1215
Carbon dioxide reaction with organolithium reagents 801
Carbon dioxide reaction with phenoxides 718
Carbon dioxide reaction with phosphorus ylids 1237
Carbon dioxide supercritical, and Diels — Alder reactions 1066
Carbon dioxide supercritical, as a solvent 454
Carbon disulflde and reduction of hydroxylamines 1554
Carbon disulflde reaction with alcohols 1184
Carbon disulflde reaction with amines 1192
Carbon disulflde reaction with Grignard reagents 1215
Carbon disulflde reaction with ketones 1229
Carbon monoxide and double carbonylation 565
Carbon monoxide and retro Diels — Alder reactions 1347
Carbon monoxide and the Koch or Koch — Haaf reactions 1035
Carbon monoxide extrusion from ketones 1347
Carbon monoxide reaction with alkenes and  1037
Carbon monoxide reaction with alkenes and amines 1035
Carbon monoxide reaction with alkenes and formic acid 1035
Carbon monoxide reaction with alkenes and water 1035
Carbon monoxide reaction with alkyl halides and alcohols 564
Carbon monoxide reaction with amines 820
Carbon monoxide reaction with aryl halides and alcohols 870
Carbon monoxide reaction with boranes 1422—1423
Carbon monoxide reaction with organolithium reagents 801
| Carbon monoxide reaction with RLi and ketones 1207
Carbon monoxide reaction with tetracarbonylferrate 563
Carbon monoxide reaction with vinylmercury halides 801
Carbon nucleophiles see “Carbanions” “Nucleophiles”
Carbon tetrabromide and  , alkenylation 1233
Carbon tetrabromide dipole moment 16
Carbon, trigonal, and the tetrahedral mechanism 424
Carbonate esters see “Esters carbonate”
Carbonates Carbonium ions 218
Carbonates from alcohols 483
Carbonates from alcoholysis of phosgene 1660
Carbonates from alkyl halides and carbonate salts 1660
Carbonium ions see “Carbocations”
Carbonyl nitrenes, insertion reactions 782
Carbonyl oxides, as 1,3-dipoles 1060
Carbonylation of alkenes 1035
Carbonylation of alkyl halides 565
Carbonylations, double 565
Carbonyls, stabilization of carbanions 230
Carboxylate anions and leaving gronps 449
Carboxylate anions and resonance 344
Carboxylate anions decarboxylation of 810
Carboxylate salts see “Carboxylic acid salts”
Carboxylate salts, and decarboxylation 732
Carboxylates, ammonium, conversion to anhydrides 491
Carboxylation, of aromatic rings 718
Carboxylation, of phenoxides 718
Carboxylations, by the Kolbe — Schmitt reaction 718
Carboxylic acid esters see “Esters”
Carboxylic acid salts acylation of 572
Carboxylic acid salts alkylation with 488
Carboxylic acid salts and phase transfer catalysts 488
Carboxylic acid salts by the Cannizzaro reaction 1564
Carboxylic acid salts coupling 941—942
Carboxylic acid salts electrolysis of 941—942
Carboxylic acid salts from aldehydes 1564
Carboxylic acid salts from esters 521
Carboxylic acid salts from Grignard reagents 796
Carboxylic acid salts pyrolysis of 508
Carboxylic acid salts reaction with acyl halides 490
Carboxylic acid salts reaction with alkyl chlorosulfites 489
Carboxylic acid salts reaction with alkyl halides 488 555
Carboxylic acid salts reaction with BrCN or C1CN 1246
Carboxylic acid salts reaction with LDA 572
Carboxylic acid salts reaction with mesylates 489
Carboxylic acid salts reaction with onium salts 489
Carboxylic acid salts silver, and dihydroxylation of alkenes 1049
Carboxylic acid salts silver, and the Hunsdiecker reaction 942—943
Carboxylic acid salts silver, and the Simonini reaction 943
Carboxylic acid salts silver, reaction with bromine 942—943
Carboxylic acid salts silver, reaction with iodine 943
Carboxylic acids and acylation of alkenes 784
Carboxylic acids and dissolving metal reduction 532
Carboxylic acids and the Passerini reaction 1252
Carboxylic acids and transesterification 487
Carboxylic acids aryl, by hydrolysis of aryl nitrites 876
Carboxylic acids aryl, by the von Richter rearrangement 876
Carboxylic acids aryl, decarboxylation of 732
Carboxylic acids aryl, decarboxylation, and rearrangements 733
Carboxylic acids aryl, from aromatic compounds 718
Carboxylic acids aryl, from aromatic nitro compounds 876
Carboxylic acids aryl, reaction with Li/THF 1563
Carboxylic acids by cleavage of ethers 1537
Carboxylic acids by Favorskii rearrangement 1403
Carboxylic acids by oxidative cleavage of ketones or aldehydes 1521
Carboxylic acids by tetracarbonylferrate 565
Carboxylic acids by the Arndt — Eistert rearrangement 1661
Carboxylic acids by the Barbier — Wieland procedure 1526
Carboxylic acids by the Cannizzaro reaction 1662
Carboxylic acids by the haloform reaction 813
Carboxylic acids by the Koch reaction 564 1035
Carboxylic acids by the Koch — Haaf reaction 1035
Carboxylic acids by the Kolbe — Schmitt reaction 1661
Carboxylic acids by the malonic ester synthesis 1661
Carboxylic acids by the Perkin reaction 1229
Carboxylic acids by the von Richter reaction 1661
Carboxylic acids by the Willgerodt reaction 1662
Carboxylic acids by the Wittig reaction 1237
Carboxylic acids coupling with allylic acetates 944
Carboxylic acids decarboxylation of 808
Carboxylic acids dehydration of 491
Carboxylic acids dianions 555
Carboxylic acids dianions, reaction with esters 572
Carboxylic acids esterification of 484—486
Carboxylic acids from 1,1-dichloroethene 1661
Carboxylic acids from acyl halides 1405
Carboxylic acids from alcohols 1537
Carboxylic acids from aldehydes 917 1229
Carboxylic acids from aldehydes and base 1662
Carboxylic acids from alky I halides 564 1661
Carboxylic acids from alkynes 1523 1539 1540
Carboxylic acids from anhydrides 1229
Carboxylic acids from aromatic compounds 1527 1661
Carboxylic acids from ary I halides 1661
Carboxylic acids from carbon dioxide 1215 1661
Carboxylic acids from carboxylate ions 1661
Carboxylic acids from cleavage of carboxylic esters 1661
Carboxylic acids from cleavage of ketones 1661
Carboxylic acids from cleavage of nonenolizable ketones 1661
Carboxylic acids from cleavage of p — diketones 1661
Carboxylic acids from cleavage of p — keto esters 1661
Carboxylic acids from cleavage of secondary alcohols 1661
Carboxylic acids from CO 1661
Carboxylic acids from decarboxylation of dicarboxylic acids 1661
Carboxylic acids from diazoketones 1405
Carboxylic acids from diazonium fluoroborates 1661
Carboxylic acids from enolate dianions 1424
Carboxylic acids from esters 549
Carboxylic acids from fragmentation of certain oximes 1661
Carboxylic acids from Grignard reagents 1215 1661
Carboxylic acids from halo ketones 1403
Carboxylic acids from hydrocarbons 564
Carboxylic acids from hydrolysis of 1,1,1-trihalides 1660
Carboxylic acids from hydrolysis of acyl halides 1660
Carboxylic acids from hydrolysis of amides 1661
Carboxylic acids from hydrolysis of anhydrides 1661
Carboxylic acids from hydrolysis of carboxylic esters 1661
Carboxylic acids from hydrolysis of nitriles 1661
Carboxylic acids from hydrolysis of ortho esters 1660
Carboxylic acids from hydrolysis of oxazines 1661
Carboxylic acids from hydrolysis of primary nitro compound 1661
Carboxylic acids from ketenes 1661
Carboxylic acids from methyl ketones 813
Carboxylic acids from nitriles 1179
Carboxylic acids from oxazolines 559
Carboxylic acids from oxidation of 1,1-diboranes 1661
Carboxylic acids from oxidation of aldehydes 1661
Carboxylic acids from oxidation of amines 1662
Carboxylic acids from oxidation of aromatic side chains 1662
Carboxylic acids from oxidation of aryl ketones 1662
Carboxylic acids from oxidation of arylthioalkynes 1662
Carboxylic acids from oxidation of ethers 1662
Carboxylic acids from oxidation of ozonides 1661
Carboxylic acids from oxidation of primary alcohols 1662
Carboxylic acids from oxidative cleavage of -diketones 1661
Carboxylic acids from oxidative cleavage of -keto acids 1661
Carboxylic acids from oxidative cleavage of alkenes 1525—1526 1661
Carboxylic acids from oxidative cleavage of aromatic rings 1661
Carboxylic acids from oxidative cleavage of terminal alkynes 1661
Carboxylic acids from ozonolysis of alkenes 1522
Carboxylic acids from ozonolysis of alkynes 1661
Carboxylic acids from Petasis alkenylation 1661
Carboxylic acids from phosphoranes 1661
Carboxylic acids from pyrolysis of carboxylic esters 1661
Carboxylic acids from pyrolysis of esters 1329
Carboxylic acids from rearrangement of -halo ketones 1661
Carboxylic acids from rearrangement of aromatic carboxylate ions 1661
Carboxylic acids from rearrangement of aromatic nitro compounds 1661
Carboxylic acids from rearrangement of diazo ketones 1661
Carboxylic acids from reductive cleavage of carboxylic esters 1661
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