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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Esters dissolving metal reduction of      529
Esters dithiocarboxylic, from carboxylic acids      1184
Esters enolate anion, reaction with esters      569—570
Esters enolates      also see “Enolate anions”
Esters formate, reaction with alkenes      1034
Esters formation from carboxylic acids and microwaves      484
Esters formation of and steric hindrance      485
Esters formation, mechanism of      485
Esters from $\beta$-keto esters      1662
Esters from 1,1,1-trihalides      463
Esters from acetophenones      1663
Esters from acyl halides      483 1662
Esters from acyl hydrazides      488
Esters from acyl peroxides      1662
Esters from alcohols      483 486 488 801 1183 1662 1663
Esters from alcoholysis of acyl halides      482
Esters from aldehydes      1565 1663
Esters from alkenes      997 1662 1663
Esters from alkyl halides      564 1662
Esters from alkyne ethers      1662
Esters from amides      488 1662
Esters from anhydrides      483 1662
Esters from aryl esters      1662
Esters from aryl halides      1662
Esters from aryl nitro compounds      1662
Esters from boranes      1662
Esters from carboxylic acid salts      1662
Esters from carboxylic acids      484—486 489 490 997 1528 1662 1663
Esters from chloro ketones      1403
Esters from chloroformates      1662
Esters from conjugated esters      1662
Esters from cyclic ketones      1663
Esters from diazo compounds      490 1662
Esters from diazo esters      1662
Esters from diazo ketones      1406
Esters from dimethylfonnamide acetals      489
Esters from enol ethers      1539 1663
Esters from esters      486 1662
Esters from ethers      483 1534 1662 1663
Esters from Grignard reagents      1662
Esters from halo esters      1662
Esters from hydrazides      1662
Esters from hydrocarbons      922—923
Esters from hydrolysis of ortho esters      1662
Esters from iminium salts      1183
Esters from ketenes      1662
Esters from keto esters      812
Esters from ketones      1417 1663
Esters from mercury hydrides      1662
Esters from methyl ketones      1662
Esters from nitriles      1183 1663
Esters from nitrogen heterocycles      1662
Esters from organometallic compounds      1662
Esters from oxazines      559 1662
Esters from oxidative cleavage of silyl ketones      1521
Esters from ozonides      1663
Esters from phenols      1662
Esters from rearrangement of $\alpha$-halo ketones      1663
Esters from rearrangement of diazo ketones      1663
Esters from tin hydrides      1662
Esters from transesterification      1662
Esters from trihalides      1662
Esters from unsaturated esters      1662
Esters from unsaturated ketones      1662
Esters gas phase reactions      473
Esters glycidic      1230
Esters homologation of      568
Esters hydrogenolysis of      527 529
Esters methyl, cleavage with NaCN-HMPA      562
Esters methyl, from diazomethane and carboxylic acids      490
Esters Mosher’s derivative      142—143
Esters of glutaric acid and the Stobbe condensation      1224
Esters of inorganic acids, hydrolysis of      464
Esters oxime and the Beckmann rearrangement      1415
Esters phenolic, from arylmethyl ketones      1528
Esters phenylthio, radical cyclization      1244
Esters phosphonate and Lawesson’s reagent      1331
Esters phosphonate, cleavage      1331
Esters propargyl, reaction with organocuprates      545
Esters pyrolysis of      1327 1329
Esters reaction with $Cp_2TiCl_2$      1552
Esters reaction with $LiAlH_4$      1551
Esters reaction with $LiAlH_4-BF_3$      1550
Esters reaction with $Me_2AlNH_2$      1195
Esters reaction with $Me_3Al$      567
Esters reaction with alcohols      486
Esters reaction with aldehydes or ketones      1223
Esters reaction with amide bases      1224
Esters reaction with amines      510
Esters reaction with ammonia      510
Esters reaction with carboxylic acid dianions      572
Esters reaction with carboxylic acids      491
Esters reaction with dimagnesium compounds      1214
Esters reaction with Grignard reagents      567 1214
Esters reaction with ketone enolate anions      571
Esters reaction with Lawesson’s reagent      1184
Esters reaction with Li and amines      529
Esters reaction with lithium amides      510
Esters reaction with lithium iodide      521
Esters reaction with nitrile enolate anions      572
Esters reaction with nitrous acid      465
Esters reaction with organolithium reagents      567
Esters reduction by the Bouveault — Blanc procedure      1551
Esters reduction to alcohols      1551
Esters reduction to ethers      1550
Esters sterically hindered, and hydrolysis      470
Esters substitution with bromo esters and Zn      1213
Esters sulfenylation of      783
Esters tethered, acyloin condensation      1602 (ref. 748)
Esters thio      see “Thioesters”
Esters xanthate and the Chugaev reaction      1330
Esters xanthate, pyrolysis of      1330
Esters, acetoacetic      see “Acetoacetic esters”
Esters, conjugated and Michael reactions      1022—1024
Esters, conjugated from esters and aldehydes or ketones      1223
Esters, conjugated reaction with aldehydes      1212
Esters, conjugated reaction with organocuprates      1027
Esters, hydrolysis      371 469—474 1050
Esters, hydrolysis and freezing point depression      472
Esters, hydrolysis and labeling      290 425 472
Esters, hydrolysis and microwaves      470
Esters, hydrolysis and phase transfer catalysis      470
Esters, hydrolysis and ring strain      473
Esters, hydrolysis and stereochemistry      472
Esters, hydrolysis and the tetrahedral mechanism      425
Esters, hydrolysis enzymatic      470
Esters, hydrolysis isotope effects      472
Esters, hydrolysis mechanism      470—473
Esters, hydrolysis reagents for      470
Esters, imino and the Chapman rearrangement      1464
Esters, imino thermolysis      1464
Esters, inorganic alkylation with      478
Esters, inorganic from alcohols      1676
Esters, inorganic from alkenes      1677
Esters, inorganic from alkyl halides      1676
Esters, inorganic from aryl halides      1676
Esters, inorganic from diazonium salts      1677
Esters, inorganic from inorganic halides      1676
Esters, inorganic from trialkylboranes      1676
Esters, inorganic preparation of      493
Esters, malonic      see “Malonic esters”
Esters, sulfonate alkylation with alkoxides      478
Esters, sulfonate allylic coupling with nickel tetracarbonyl      543
Esters, sulfonate as leaving groups      446
Esters, sulfonate by the Knoevenagel condensation      1687
Esters, sulfonate coupling with Grignard reagents      543
Esters, sulfonate coupling with organocuprates      543
Esters, sulfonate elimination reactions      1340
Esters, sulfonate elimination with base      1330
Esters, sulfonate from alcohols      1687
Esters, sulfonate from aldehydes      1687
Esters, sulfonate from aryl nitro compounds      1687
Esters, sulfonate from boranes      1687
Esters, sulfonate from ethers      494 1687
Esters, sulfonate from halo sulfonic acid esters      1687
Esters, sulfonate from ketones      1687
Esters, sulfonate from sulfonamides      576
Esters, sulfonate from sulfonic acid derivatives      494 576 1687
Esters, sulfonate hydrolysis      465
Esters, sulfonate hydrolysis and labeling      574
Esters, sulfonate hydrolysis of      465 575
Esters, sulfonate of phenols, reduction of      867
Esters, sulfonate reaction with $LiAlH_4$      526
Esters, sulfonate reaction with Grignard reagents      574
Esters, sulfonate reaction with halide ions      518
Esters, sulfonate reagents for hydrogenolysis      526
Etard reaction      1534
Ethane cleavage and entropy      278
Ethane conformational energy diagram      168
Ethane heat of combustion      22
Ethanoic acid      see “Acetic acid”
Ethanol, with sodium, for reduction of aldehydes or ketones      1199
Ethanolamine and dealkylation of ammonium salts      503
Ethanonium ion      770
Ethene and resonance      41
Ethene bond angles      9
Ethene bonding      8—9 12
Ethene reaction with bromine      973
Ethene valence electrons      12
Etherification, transannular      920
Ethers $\alpha$-halo, and the Boord reaction      1344
Ethers allyl aryl, and Claisen rearrangement      1449
Ethers allyl vinyl, and Claisen rearrangement      1452
Ethers allyl vinyl, and [l,3]-alkyl sigmatropic rearrangements      1442
Ethers allylic, anion, and the Wittig rearrangement      558
Ethers allylic, carbanions and [2,3] Wittig rearrangement      1454
Ethers allylic, reaction with Grignard reagents      546
Ethers allylic, reaction with organolithium reagents      558
Ethers and acidity      344
Ethers and dialkylamides basses      349
Ethers and esterification reactions      486
Ethers aryl and the $S_{ON}2$ mechanism      862
Ethers aryl, by the Ullmann ether synthesis      863
Ethers aryl, deoxygenation      734
Ethers aryl, from aryl halides      862
Ethers as solvents for Grignard reactions      546
Ethers benzylic, selective cleavage      520
Ethers by reductive dimerization of aldehydes or ketones      1182
Ethers by the heteroatom Diels-alder reaction      1669
Ethers by the Williamson ether synthesis      1669
Ethers by transetherification      480 1669
Ethers cleavage of      1537
Ethers cleavage with acetic anhydride      489
Ethers cleavage with acetyl tosylate      490
Ethers cleavage with aniline salts      503
Ethers cleavage with HBr      465 520
Ethers cleavage with HI      465 519
Ethers cleavage with suifinic acids      494
Ethers cleavage with sulfuric acid      465
Ethers demethylation, with thiolate ions      496
Ethers dichloromethyl methyl, reaction with aromatic compounds      717
Ethers from acetals      528 545 1669
Ethers from alcohols      479 482 996 1669
Ethers from aldehydes      1182 1669
Ethers from alkenes      996 1669
Ethers from alkoxides      1669
Ethers from alkyl halides      477 1669
Ethers from aroxides      1669
Ethers from aryl halides      1669
Ethers from diazo compounds      479 1669
Ethers from esters      1550 1669
Ethers from ethers      480 1669
Ethers from Grignard reagents      796 1669
Ethers from inorganic esters      1669
Ethers from ketals      528 545 1669
Ethers from ketones      1182 1669
Ethers from onium ions      1669
Ethers from onium salts      482 1669
Ethers from peroxides      796
Ethers from peroxyesters      1669
Ethers from phenols      1669
Ethers from thiono esters      1550 1669
Ethers halo, elimination reactions      1344
Ethers hydrogenolysis of      528
Ethers methyl, from alcohols and diazomethane      479
Ethers oxidation with dioxirane      1525
Ethers oxidation with ruthenium tetroxide      1534
Ethers propargyl vinyl, Claisen rearrangement      1452
Ethers propargylic, reaction with Grignard reagents      546
Ethers reaction with acyl halides      483
Ethers reaction with alcohols      480
Ethers reaction with alkyl halides      492
Ethers reaction with amide bases      1328
Ethers reaction with carboxylic acids      486
Ethers reaction with Lewis acids      520
Ethers reaction with organolithium reagents      1328 1421
Ethers reaction with oxonium salts      492
Ethers symmetrical, preparation of      480
Ethers thio      see “Thioethers”
Ethers, cyclic and elimination reactions      1329
Ethers, cyclic cleavage with HI      520
Ethers, cyclic from alcohols      919
Ethers, cyclic from diols      480
Ethers, cyclic from lactones      1548 1550
Ethers, cyclic from thionolactones      1215
Ethers, cyclic oxidation of      1534
Etheylenediammetetraacetic acid      see “EDTA”
Ethoxide reaction with 1,1-dichloroethene      428
Ethyl acetoacetate, alkylation of      459
Ethyl chloroformate, reaction with enamines      788
Ethyl diazoacetate, and homologation of ketones      1408
Ethyl ethylthiomethyl sulfoxide, alkylation of      556
Ethyl fluoride, reaction with mesitylene and $BF_3$      678
Ethyl pyroglutamate      see “Pyroglutamate ethyl
Ethylaluminum dichloride, and the Prins reaction      1242
ethylene      see “Ethene”
Ethylene glycol, and the Bamford — Stevens reaction      1335
Ethylene oxide and strain      180
Ethylene oxide reaction with acetyl chloride      521
Ethyllithium      240
Ethylmercuric chloride      237
Ethyne bonding      9—10
Ethyne excited state      311
Exchange H-D and electrophilic aromatic substitution      695
Exchange H-D and super acids      770
Exchange H-D in hydrocarbons      769
Exciplex, in [2+2]-cycloadditions      1082
Excitation, photochemical, types      309
Excited molecules chemical processes      317—321
Excited molecules physical processes      315
Excited states and fluorescence      313—314
Excited states and internal conversion      313
Excited states and phosphorescence      315
Excited states and photochemistry      306
Excited states fate of molecules      313—317
Excited states nomenclature      310—311
Exhaustive alkylation      500
Exo addition, in the Diels — Alder reaction      1064
exo-Deuterio-exo-norbornyl acetate      1442
Exo/endo and Baldwin’s rules      283—284
Extinction coefficient      307
Extrusion of $CO_2$ and the Story synthesis      1355
Extrusion of $CO_2$ from cyclic sulfones      1354—1355
Extrusion reactions      1352
Extrusion reactions decarbonylation of ketones      1347
Extrusion reactions pyrazolines      1353
Extrusion reactions the Ramberg — Backlund reaction      1343
F strain and basicity      3436
Face strain and basicity      346
Favored reactions, and Baldwin’s rules      283—284
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