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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Neighboring group effects norbornylmethyl      418
Neighboring group effects of cyclopropylmethyl      416
Neighboring group effects phenonium ion      411 4113
Neighboring group effects silylalkyl      419
Neighboring group effects with aromatic rings      411
Neighboring group participation      407—420
Neighboring^group mechanisms      404—407
Neomenthyl chloride, E2 elimination      1302
Neopentane bond energy      23
Neopentane reaction with super acids      815
Neopentyl bromide, solvolysis      1379
Neopentyl carbocations      1379
Neopentyl tosylate, solvolysis      418
Neopentyllithium      234
Neophyl carbocations      1379
Newman projection, definition      168
Nickel      also see “Raney nickel”
Nickel bis-cyclooctadiene      1091
Nickel carbonyl      see “Nickel tetracarbonyl”
Nickel peroxide, oxidation of ortho-diamine      1527
Nickel tetracarbonyl coupling allylic halides      541
Nickel tetracarbonyl coupling allylic tosylates      543
Nickel tetracarbonyl reaction with alcohols and alkyl halides      564
Nickel tetracarbonyl reaction with organomercury halides      800
Nickel tetracarbonyl reaction with RLi and conjugated compounds      1033
Nickel, catalyst for hydrogenation      1003
Nitramine nitrates, from aziridines and azetidines      494
Nitrate, silver      see “Silver nitrate”
Nitration and ipso attack      686
Nitration of aromatic compounds      697
Nitration of aromatic compounds, and the nitronium ion      697
Nitration of aromatic compounds, reagents for      697
Nitration of aromatic rings, and arenium ions      679
Nitration of heterocycles      697
Nitration of hydrocarbons      924
Nitrenes      253—254
Nitrenes abstraction reactions      254
Nitrenes addition reactions      254
Nitrenes amino-, addition to alkynes      1057
Nitrenes and ab initio studies      253
Nitrenes and azobenzene      254
Nitrenes and formation of aziridines      1057
Nitrenes and nitrenium ions      254
Nitrenes and nucleophilic rearrangements      1378
Nitrenes carbonyl, insertion reactions      782
Nitrenes definition of      253
Nitrenes dimerization reactions      254
Nitrenes formation during elimination      253
Nitrenes from azides      253 783
Nitrenes insertion reactions      253—254 782
Nitrenes intermediates in the Curtius rearrangement      1412
Nitrenes intermediates in the Hofmann rearrangement      1411
Nitrenes intermediates in the Lossen rearrangement      1413
Nitrenes rearrangement reactions      254
Nitrenes single and triplet states      253
Nitrenium ions      254
Nitric acid esters, hydrolysis      465
Nitric acid ionization to nitronium ion      698
Nitric acid oxidation of amines      697
Nitric acid oxidation of thiols      1540
Nitric acid reaction with aromatic compounds      696
Nitric acid reaction with hydrocarbons      924
Nitrile esters, from substitution with nitrite      459
Nitrile imines, as 1,3-dipoles      1060
Nitrile oxides as 1,3-dipoles      1060
Nitrile oxides rearrangement to isocyanates      1465
Nitrile oxides reduction of      1557
Nitrile ylids, as 1,3-dipoles      1060
Nitriles and Stephen reduction      1204
Nitriles and the Blaise reaction      1213
Nitriles and the Pinner synthesis      1183
Nitriles and the Sonn — Mffller method      1204
Nitriles aryl, by the Rosenmund — von Braun reaction      867
Nitriles aryl, by the Sandmeyer reaction      936
Nitriles aryl, from aromatic compounds      722—723
Nitriles aryl, from aryl halides      867
Nitriles aryl, from arylthallium compounds      802
Nitriles aryl, hydrolysis of      876
Nitriles aryl, oxidative cleavage      1530
Nitriles aryl, reagents for formation of      867
Nitriles by Michael addition      1681
Nitriles by pyrolysis of dichloroamines      1348
Nitriles by the Rosenmund — von Braun reaction      1681
Nitriles by the Sandmeyer reaction      1681
Nitriles by the von Braun reaction      1350
Nitriles decyanation      815
Nitriles dialkylamino, oxidation of      1531
Nitriles dissolving metal reduction      815
Nitriles enolate anions, reaction with esters      572
Nitriles from $\alpha$-cyano acids      1681
Nitriles from acid salts and BrCN      1682
Nitriles from acrylonitrile      1681
Nitriles from acyl peroxides      1681
Nitriles from aldehydes      1195 1681
Nitriles from alkyl halides      561—562 1681
Nitriles from alkylation of nitriles      1681
Nitriles from amides      1350 1682
Nitriles from amines      1518 1682
Nitriles from aromatic acyl cyanides      1681
Nitriles from aromatic rings      1681
Nitriles from aryl halides      1681
Nitriles from aryl nitro compounds      1681
Nitriles from benzylic compounds      1681
Nitriles from boranes      1681
Nitriles from carboxylate salts      1246
Nitriles from carboxylic acids      1682
Nitriles from diazo nitriles      1681
Nitriles from diazonium salts      1681
Nitriles from dimethylhydrazones      1519
Nitriles from esters      1195 1681
Nitriles from formic acid      1195
Nitriles from gem-dinitriles      528
Nitriles from halo nitriles      1681
Nitriles from hydrazones      1241 1682
Nitriles from hydrazonium salts      1348
Nitriles from hydroxylamine      1195
Nitriles from isonirriles      1421
Nitriles from keto oximes      1349
Nitriles from mercury hydrides      1681
Nitriles from nitrile oxides      1557 1682
Nitriles from nitriles      1681
Nitriles from nitro compounds      1681 1682
Nitriles from organometallic compounds      1681
Nitriles from oxime tosylates      1349
Nitriles from oximes      1348 1682
Nitriles from rearrangement of isocyanides      1682
Nitriles from substitution with cyanide      459
Nitriles from sulfonyl hydrazones      1682
Nitriles from tin hydrides      1681
Nitriles from tosylmethylisocyanide      1681
Nitriles from unsaturated nitriles      1681
Nitriles fromalkenes      1038 1681
Nitriles fromketones      1681
Nitriles hydrogenolysis of      528
Nitriles hydrolysis of      1179
Nitriles reaction with alcohols      1183 1244
Nitriles reaction with alkenes      1245
Nitriles reaction with amines      1192
Nitriles reaction with ammonia      1191
Nitriles reaction with aromatic compounds      722
Nitriles reaction with Grignard reagents      1217
Nitriles reaction with nitriles      1238 1241
Nitriles reaction with sodium      815
Nitriles reduction to aldehydes      1204
Nitriles reduction with $LiAlH_4$      1204
Nitriles reduction with limonene and Pd-C      1556
Nitriles reduction, reagents for      1204
Nitriles trimerization of      1246
Nitrilium ions, alkyl, reduction of      1204
Nitrite ion, as an ambident nucleophile      459
Nitrite, sodium reaction with alkenes and acetic acid      1339
Nitrite, sodium reaction with alkyl halides      515
Nitrite, sodium reaction with aryl diazonium salts      936
Nitrites, and electrophilic aromatic substitution      705
Nitro anions alkylation      459
Nitro anions ambident nucleophiles      459
Nitro anions as an ambident nucleophile      459
Nitro compounds aci form      76
Nitro compounds and tautomerism      76
Nitro compounds and the Nef reaction      1178
Nitro compounds aromatic, reaction with $Na_3AsO_3$      1563
Nitro compounds aromatic, reaction with cyanide      876
Nitro compounds aromatic, reaction with sulfur ylids      872
Nitro compounds aromatic, reduction of      1554
Nitro compounds aromatic, reduction with $LiAlH_4$      1563
Nitro compounds aromatic, reduction with $Zn/H_2O$      1554
Nitro compounds aryl, from aryl diazonium salts      936
Nitro compounds azinic acids      76
Nitro compounds by Michael addition      1682
Nitro compounds from $\alpha$-nitro acids      1682
Nitro compounds from aldehydes      1682
Nitro compounds from alkenes      1682
Nitro compounds from alkyl halides      515 1682
Nitro compounds from amides      1682
Nitro compounds from amines      1539 1682
Nitro compounds from aromatic compounds      696 1682
Nitro compounds from aromatic nitro compounds      1682
Nitro compounds from azides      1682
Nitro compounds from diazonium salts      1682
Nitro compounds from hydrocarbons      924
Nitro compounds from isocyanates      1540 1682
Nitro compounds from nitro compounds      1682
Nitro compounds from nitroalkenes      1682
Nitro compounds from nitroso compounds      1682
Nitro compounds from organometallic reagents      1682
Nitro compounds from pyrylium salts      1682
Nitro compounds from rearrangement of N-nitro aromatic amines      1682
Nitro compounds from substitution with nitrite      459
Nitro compounds from unsaturated nitro compounds      1682
Nitro compounds fromalkanes      1682
Nitro compounds fromketones      1682
Nitro compounds fromoximes      1539 1682
Nitro compounds halo, from alkenes      1046
Nitro compounds hydrogenolysis of      531
Nitro compounds hydrolysis of      1178
Nitro compounds nitronic acids      76
Nitro compounds oxidationof      1537
Nitro compounds reaction with cyanide and $K_3Fe(CN)_6$      786
Nitro compounds reaction with enolate anions      550
Nitro compounds reduction of      1552 1558
Nitro compounds reduction with Al(Hg)      1552
Nitro compounds reduction with Bakers yeast      1553
Nitro compounds reduction with borane      1554
Nitro compounds reduction with Sm      1552
Nitro compounds reduction with Zn/HCl      1552
Nitro compounds reduction with Zn/NaOH      1564
Nitro compounds reduction, reagents for      531
Nitro, as a leaving group      550
Nitroacetic acid      342
Nitroanilines, $pK_a$      344
Nitroanilines, base strength      344
Nitrobenzamides, hydrolysis of      428
Nitrobenzene dipole moment      16
Nitrobenzene from bromobenzene      699
Nitrogen bonding      11
Nitrogen dioxide, and amide hydrolysis      475
Nitrogen pentoxide, dissociation to nitronium ion      698
Nitrogen PES spectrum      10—11
Nitrogen reaction with organolithium reagents      800
Nitrogen ylids      see “Ylids”
Nitromethane, $pK_a$      230
Nitronaphthalenes      873
Nitrones as 1,3-dipoles      1060
Nitrones from alkylation of oximes      1682
Nitronic acids      see “Nitro compounds”
Nitronic esters, by substitution with nitro anions      460
Nitronium ion and electrophilic aromatic substitution      680
Nitronium ion and nitration of aromatic compounds      697
Nitronium ion from $N_2O_5$      698
Nitronium ion from nitric acid      698
Nitronium ion kinetics      698
Nitronium ion spectroscopy of      698
Nitrosation of alcohols, and the Barton reaction      1463
Nitrosation of enolate anions      780
Nitrosation of enols      779
Nitrosation of rings      699
Nitroso amines, from Fischer — Hepp rearrangement      728
Nitroso compounds and the Barton reaction      1463
Nitroso compounds as spin traps      239
Nitroso compounds by Fischer — Hepp rearrangement      1683
Nitroso compounds by the Barton reaction      1683
Nitroso compounds elimination reactions      1352
Nitroso compounds from alkenes      1683
Nitroso compounds from amides      1683
Nitroso compounds from amines      817 1683
Nitroso compounds from aromatic acids      1683
Nitroso compounds from aromatic amines      699
Nitroso compounds from aromatic compounds      1683
Nitroso compounds from arylamines      1539
Nitroso compounds from hydroxylamines      1683
Nitroso compounds from nitrites      1683
Nitroso compounds from rearrangement of N-nitroso aromatic amines      1683
Nitroso compounds halo, from alkenes      1045
Nitroso compounds reaction with aryl amines      818
Nitroso compounds reaction with hydroxylamines      819
Nitroso compounds reaction with phosphorus ylids      1237
Nitroso compounds reduction with Zn/HCl      1554
Nitroso-oxime tautomerism      76 (also see “Tautomerism”)
Nitrosodisulfonate, dipotassium      see “Freny’s salt”
Nitrosyl chloride and amide hydrolysis      475
Nitrosyl chloride reaction with alkenes      1045
Nitrosyl chloride reaction with amines      818
Nitrous acid and amide hydrolysis      475
Nitrous acid and elimination of aziridines      1343
Nitrous acid and semipinacol rearrangement      1397
Nitrous acid formation of aryl nitroso compounds      699
Nitrous acid reaction with acylhydrazides      1412
Nitrous acid reaction with amines      816 1398
Nitrous acid reaction with amino alcohols      1397
Nitrous acid reaction with aromatic amines      699
Nitrous acid reaction with hydrazines      817
Nitrous acid reaction with hydroxy amines      1399
Nitrous acid reaction with secondary amines      817
Nitrous oxide, as a 1,3-dipole      1060
Nitroxyl radicals, and oxidation of alcohols      1515
Nitryl chloride, reaction with alkenes      1046
NMR and $S_NAr$ intermediates      851
NMR and antiaromaticity      67—68
NMR and arenium ions      413
NMR and aromaticity      46—47
NMR and Birch reduction intermediates      1011
NMR and bond rotation      295
NMR and carbocations      219 225 710
NMR and cation rearrangement      419
NMR and chiral shift reagents      156
NMR and chiral solvents      156
NMR and CIDNP      240—241
NMR and cyclobutadiene derivatives      60
NMR and cyclooctatetraene      62
NMR and cyclopropylmethyl cations      418
NMR and degenerate Cope rearrangement      1447
NMR and electrocyclic rearrangements      1435
NMR and electronegativity      15
NMR and emission      240
NMR and enol content      75
NMR and Grignard reagents      235—236
NMR and hydride shifts in carbocations      1379
NMR and hydrogen bonding      100
NMR and intermediates in the Chichibabin reaction      873
NMR and isochronous atoms      165
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