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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Neighboring group effects norbornylmethyl 418
Neighboring group effects of cyclopropylmethyl 416
Neighboring group effects phenonium ion 411 4113
Neighboring group effects silylalkyl 419
Neighboring group effects with aromatic rings 411
Neighboring group participation 407—420
Neighboring^group mechanisms 404—407
Neomenthyl chloride, E2 elimination 1302
Neopentane bond energy 23
Neopentane reaction with super acids 815
Neopentyl bromide, solvolysis 1379
Neopentyl carbocations 1379
Neopentyl tosylate, solvolysis 418
Neopentyllithium 234
Neophyl carbocations 1379
Newman projection, definition 168
Nickel also see “Raney nickel”
Nickel bis-cyclooctadiene 1091
Nickel carbonyl see “Nickel tetracarbonyl”
Nickel peroxide, oxidation of ortho-diamine 1527
Nickel tetracarbonyl coupling allylic halides 541
Nickel tetracarbonyl coupling allylic tosylates 543
Nickel tetracarbonyl reaction with alcohols and alkyl halides 564
Nickel tetracarbonyl reaction with organomercury halides 800
Nickel tetracarbonyl reaction with RLi and conjugated compounds 1033
Nickel, catalyst for hydrogenation 1003
Nitramine nitrates, from aziridines and azetidines 494
Nitrate, silver see “Silver nitrate”
Nitration and ipso attack 686
Nitration of aromatic compounds 697
Nitration of aromatic compounds, and the nitronium ion 697
Nitration of aromatic compounds, reagents for 697
Nitration of aromatic rings, and arenium ions 679
Nitration of heterocycles 697
Nitration of hydrocarbons 924
Nitrenes 253—254
Nitrenes abstraction reactions 254
Nitrenes addition reactions 254
Nitrenes amino-, addition to alkynes 1057
Nitrenes and ab initio studies 253
Nitrenes and azobenzene 254
Nitrenes and formation of aziridines 1057
Nitrenes and nitrenium ions 254
Nitrenes and nucleophilic rearrangements 1378
Nitrenes carbonyl, insertion reactions 782
Nitrenes definition of 253
Nitrenes dimerization reactions 254
Nitrenes formation during elimination 253
Nitrenes from azides 253 783
Nitrenes insertion reactions 253—254 782
Nitrenes intermediates in the Curtius rearrangement 1412
Nitrenes intermediates in the Hofmann rearrangement 1411
Nitrenes intermediates in the Lossen rearrangement 1413
Nitrenes rearrangement reactions 254
Nitrenes single and triplet states 253
Nitrenium ions 254
Nitric acid esters, hydrolysis 465
Nitric acid ionization to nitronium ion 698
Nitric acid oxidation of amines 697
Nitric acid oxidation of thiols 1540
Nitric acid reaction with aromatic compounds 696
Nitric acid reaction with hydrocarbons 924
Nitrile esters, from substitution with nitrite 459
Nitrile imines, as 1,3-dipoles 1060
Nitrile oxides as 1,3-dipoles 1060
Nitrile oxides rearrangement to isocyanates 1465
Nitrile oxides reduction of 1557
Nitrile ylids, as 1,3-dipoles 1060
Nitriles and Stephen reduction 1204
Nitriles and the Blaise reaction 1213
Nitriles and the Pinner synthesis 1183
Nitriles and the Sonn — Mffller method 1204
Nitriles aryl, by the Rosenmund — von Braun reaction 867
Nitriles aryl, by the Sandmeyer reaction 936
Nitriles aryl, from aromatic compounds 722—723
Nitriles aryl, from aryl halides 867
Nitriles aryl, from arylthallium compounds 802
Nitriles aryl, hydrolysis of 876
Nitriles aryl, oxidative cleavage 1530
Nitriles aryl, reagents for formation of 867
Nitriles by Michael addition 1681
Nitriles by pyrolysis of dichloroamines 1348
Nitriles by the Rosenmund — von Braun reaction 1681
Nitriles by the Sandmeyer reaction 1681
Nitriles by the von Braun reaction 1350
Nitriles decyanation 815
Nitriles dialkylamino, oxidation of 1531
Nitriles dissolving metal reduction 815
Nitriles enolate anions, reaction with esters 572
Nitriles from  -cyano acids 1681
Nitriles from acid salts and BrCN 1682
Nitriles from acrylonitrile 1681
Nitriles from acyl peroxides 1681
Nitriles from aldehydes 1195 1681
Nitriles from alkyl halides 561—562 1681
Nitriles from alkylation of nitriles 1681
Nitriles from amides 1350 1682
Nitriles from amines 1518 1682
Nitriles from aromatic acyl cyanides 1681
Nitriles from aromatic rings 1681
Nitriles from aryl halides 1681
Nitriles from aryl nitro compounds 1681
Nitriles from benzylic compounds 1681
Nitriles from boranes 1681
Nitriles from carboxylate salts 1246
Nitriles from carboxylic acids 1682
Nitriles from diazo nitriles 1681
Nitriles from diazonium salts 1681
Nitriles from dimethylhydrazones 1519
Nitriles from esters 1195 1681
Nitriles from formic acid 1195
Nitriles from gem-dinitriles 528
Nitriles from halo nitriles 1681
Nitriles from hydrazones 1241 1682
Nitriles from hydrazonium salts 1348
Nitriles from hydroxylamine 1195
Nitriles from isonirriles 1421
Nitriles from keto oximes 1349
Nitriles from mercury hydrides 1681
Nitriles from nitrile oxides 1557 1682
Nitriles from nitriles 1681
Nitriles from nitro compounds 1681 1682
Nitriles from organometallic compounds 1681
Nitriles from oxime tosylates 1349
Nitriles from oximes 1348 1682
Nitriles from rearrangement of isocyanides 1682
Nitriles from substitution with cyanide 459
Nitriles from sulfonyl hydrazones 1682
Nitriles from tin hydrides 1681
Nitriles from tosylmethylisocyanide 1681
Nitriles from unsaturated nitriles 1681
Nitriles fromalkenes 1038 1681
Nitriles fromketones 1681
Nitriles hydrogenolysis of 528
Nitriles hydrolysis of 1179
Nitriles reaction with alcohols 1183 1244
Nitriles reaction with alkenes 1245
Nitriles reaction with amines 1192
Nitriles reaction with ammonia 1191
Nitriles reaction with aromatic compounds 722
Nitriles reaction with Grignard reagents 1217
Nitriles reaction with nitriles 1238 1241
Nitriles reaction with sodium 815
Nitriles reduction to aldehydes 1204
Nitriles reduction with  1204
Nitriles reduction with limonene and Pd-C 1556
Nitriles reduction, reagents for 1204
Nitriles trimerization of 1246
Nitrilium ions, alkyl, reduction of 1204
Nitrite ion, as an ambident nucleophile 459
| Nitrite, sodium reaction with alkenes and acetic acid 1339
Nitrite, sodium reaction with alkyl halides 515
Nitrite, sodium reaction with aryl diazonium salts 936
Nitrites, and electrophilic aromatic substitution 705
Nitro anions alkylation 459
Nitro anions ambident nucleophiles 459
Nitro anions as an ambident nucleophile 459
Nitro compounds aci form 76
Nitro compounds and tautomerism 76
Nitro compounds and the Nef reaction 1178
Nitro compounds aromatic, reaction with  1563
Nitro compounds aromatic, reaction with cyanide 876
Nitro compounds aromatic, reaction with sulfur ylids 872
Nitro compounds aromatic, reduction of 1554
Nitro compounds aromatic, reduction with 1563
Nitro compounds aromatic, reduction with  1554
Nitro compounds aryl, from aryl diazonium salts 936
Nitro compounds azinic acids 76
Nitro compounds by Michael addition 1682
Nitro compounds from -nitro acids 1682
Nitro compounds from aldehydes 1682
Nitro compounds from alkenes 1682
Nitro compounds from alkyl halides 515 1682
Nitro compounds from amides 1682
Nitro compounds from amines 1539 1682
Nitro compounds from aromatic compounds 696 1682
Nitro compounds from aromatic nitro compounds 1682
Nitro compounds from azides 1682
Nitro compounds from diazonium salts 1682
Nitro compounds from hydrocarbons 924
Nitro compounds from isocyanates 1540 1682
Nitro compounds from nitro compounds 1682
Nitro compounds from nitroalkenes 1682
Nitro compounds from nitroso compounds 1682
Nitro compounds from organometallic reagents 1682
Nitro compounds from pyrylium salts 1682
Nitro compounds from rearrangement of N-nitro aromatic amines 1682
Nitro compounds from substitution with nitrite 459
Nitro compounds from unsaturated nitro compounds 1682
Nitro compounds fromalkanes 1682
Nitro compounds fromketones 1682
Nitro compounds fromoximes 1539 1682
Nitro compounds halo, from alkenes 1046
Nitro compounds hydrogenolysis of 531
Nitro compounds hydrolysis of 1178
Nitro compounds nitronic acids 76
Nitro compounds oxidationof 1537
Nitro compounds reaction with cyanide and  786
Nitro compounds reaction with enolate anions 550
Nitro compounds reduction of 1552 1558
Nitro compounds reduction with Al(Hg) 1552
Nitro compounds reduction with Bakers yeast 1553
Nitro compounds reduction with borane 1554
Nitro compounds reduction with Sm 1552
Nitro compounds reduction with Zn/HCl 1552
Nitro compounds reduction with Zn/NaOH 1564
Nitro compounds reduction, reagents for 531
Nitro, as a leaving group 550
Nitroacetic acid 342
Nitroanilines,  344
Nitroanilines, base strength 344
Nitrobenzamides, hydrolysis of 428
Nitrobenzene dipole moment 16
Nitrobenzene from bromobenzene 699
Nitrogen bonding 11
Nitrogen dioxide, and amide hydrolysis 475
Nitrogen pentoxide, dissociation to nitronium ion 698
Nitrogen PES spectrum 10—11
Nitrogen reaction with organolithium reagents 800
Nitrogen ylids see “Ylids”
Nitromethane, 230
Nitronaphthalenes 873
Nitrones as 1,3-dipoles 1060
Nitrones from alkylation of oximes 1682
Nitronic acids see “Nitro compounds”
Nitronic esters, by substitution with nitro anions 460
Nitronium ion and electrophilic aromatic substitution 680
Nitronium ion and nitration of aromatic compounds 697
Nitronium ion from  698
Nitronium ion from nitric acid 698
Nitronium ion kinetics 698
Nitronium ion spectroscopy of 698
Nitrosation of alcohols, and the Barton reaction 1463
Nitrosation of enolate anions 780
Nitrosation of enols 779
Nitrosation of rings 699
Nitroso amines, from Fischer — Hepp rearrangement 728
Nitroso compounds and the Barton reaction 1463
Nitroso compounds as spin traps 239
Nitroso compounds by Fischer — Hepp rearrangement 1683
Nitroso compounds by the Barton reaction 1683
Nitroso compounds elimination reactions 1352
Nitroso compounds from alkenes 1683
Nitroso compounds from amides 1683
Nitroso compounds from amines 817 1683
Nitroso compounds from aromatic acids 1683
Nitroso compounds from aromatic amines 699
Nitroso compounds from aromatic compounds 1683
Nitroso compounds from arylamines 1539
Nitroso compounds from hydroxylamines 1683
Nitroso compounds from nitrites 1683
Nitroso compounds from rearrangement of N-nitroso aromatic amines 1683
Nitroso compounds halo, from alkenes 1045
Nitroso compounds reaction with aryl amines 818
Nitroso compounds reaction with hydroxylamines 819
Nitroso compounds reaction with phosphorus ylids 1237
Nitroso compounds reduction with Zn/HCl 1554
Nitroso-oxime tautomerism 76 (also see “Tautomerism”)
Nitrosodisulfonate, dipotassium see “Freny’s salt”
Nitrosyl chloride and amide hydrolysis 475
Nitrosyl chloride reaction with alkenes 1045
Nitrosyl chloride reaction with amines 818
Nitrous acid and amide hydrolysis 475
Nitrous acid and elimination of aziridines 1343
Nitrous acid and semipinacol rearrangement 1397
Nitrous acid formation of aryl nitroso compounds 699
Nitrous acid reaction with acylhydrazides 1412
Nitrous acid reaction with amines 816 1398
Nitrous acid reaction with amino alcohols 1397
Nitrous acid reaction with aromatic amines 699
Nitrous acid reaction with hydrazines 817
Nitrous acid reaction with hydroxy amines 1399
Nitrous acid reaction with secondary amines 817
Nitrous oxide, as a 1,3-dipole 1060
Nitroxyl radicals, and oxidation of alcohols 1515
Nitryl chloride, reaction with alkenes 1046
NMR and  intermediates 851
NMR and antiaromaticity 67—68
NMR and arenium ions 413
NMR and aromaticity 46—47
NMR and Birch reduction intermediates 1011
NMR and bond rotation 295
NMR and carbocations 219 225 710
NMR and cation rearrangement 419
NMR and chiral shift reagents 156
NMR and chiral solvents 156
NMR and CIDNP 240—241
NMR and cyclobutadiene derivatives 60
NMR and cyclooctatetraene 62
NMR and cyclopropylmethyl cations 418
NMR and degenerate Cope rearrangement 1447
NMR and electrocyclic rearrangements 1435
NMR and electronegativity 15
NMR and emission 240
NMR and enol content 75
NMR and Grignard reagents 235—236
NMR and hydride shifts in carbocations 1379
NMR and hydrogen bonding 100
NMR and intermediates in the Chichibabin reaction 873
NMR and isochronous atoms 165
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