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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Spiropentanes, from carbene additions      1086
Squalene      1019
Squalene 2,3-oxide      1019
Squaric acid and aromaticity      70
Squaric acid, $pK_a$      70
Stability criteria for, carbanions      229—232
Stability of arenium ions, table      679
Stability of carbanions, by S, Si and P      231
Stability of carbocations      219—225 1384
Stability of diazonium salts      816
Stability of radicals      241
Stability order for carbanions      228 229
Stability order for carbocations      219
Stability thermodynamic and double bond migration      773
Stabilization of Grignard reagents by ethers      235
Stabilomer      1396
Starands      107
Statistical effects and acid strength      345—346
Staudinger reaction      1555
Steady state approximation      292
Stephen reduction      1204
Stephens — Castro coupling      868
Stereochemistry      125—191
Stereochemistry and 1,2 shifts      1380
Stereochemistry and 1,2-alkyl shifts      1383
Stereochemistry and carbanions      233
Stereochemistry and ester hydrolysis      472
Stereochemistry and ion pairs      398—400
Stereochemistry and mechanism      290
Stereochemistry and nonclassical ions      409
Stereochemistry and ozonolysis      1524
Stereochemistry and the $S_Ni$ mechanism      420
Stereochemistry in the Diels — Alder reaction      1064
Stereochemistry in [1,3]- and [l,5]-alkyl sigmatropic rearrangements      1441
Stereochemistry of $S_N1$ reactions      397
Stereochemistry of $S_N2$ reactions      142
Stereochemistry of $S_N2$ with Walden inversion      391
Stereochemistry of $S_N2’$ reactions      422
Stereochemistry of autoxidation of alkenes with singlet oxygen      922
Stereochemistry of carbene insertion with alkenes      1087
Stereochemistry of the SET mechanism and substitution      403
Stereoelectronic control and the tetrahedral mechanism      427
Stereoelectronic effects and radicals      903
Stereoelectronic effects and the tetrahedral mechanism      427
Stereogenic carbon, definition      128
Stereogenic centers      136
Stereogenic centers and Fischer projections      137
Stereogenic centers more than one      144—147
Stereoisomers      also see “Diastereomers” “Enantiomers”
Stereoisomers and chirality      125—139
Stereoisomers and cis/trans isomers      157—160
Stereoisomers and E2 elimination      1301
Stereoisomers and enantiomer definition      125
Stereoisomers and substituted cyclohexanes      175
Stereoisomers diastereomers      144—147
Stereoisomers topological, catenanes      114
Stereoisomers torsional diastereomers      133
Stereoselective synthesis      147—150 166—167
Stereoselective, definition      166
Stereoselectivity and chiral auxiliaries      149
Stereoselectivity and Cram’s rule      147—148
Stereoselectivity and the Felkin — Ahn model      148
Stereoselectivity and the Wittig reaction      1235
Stereoselectivity in the aldol reaction      1221
Stereoselectivity Lindlar reduction of alkynes      1004
Stereoselectivity of epoxide hydrolysis and Co-salen catalysts      468
Stereoselectivity of hydride reduction of aldehydes and ketones      1198
Stereoselectivity of Michael additions      977
Stereoselectivity of radical addition to alkenes      978
Stereoselectivity of radical hydrogen abstraction      903
Stereospecific synthesis      166—167
Stereospecific, definition      166
Stereospecificity bromine addition to alkenes      973
Stereospecificity electrocyclic rearrangements      1427
Steric effects and acid strength      346
Steric effects and base strength      347
Steric effects and elimination reactions      1319
Steric effects and radicals      900
Steric effects and structure      365—368
Steric effects B strain      366
Steric effects hindrance      see “Steric hindrance”
Steric effects I strain      366
Steric effects masochistic      1080
Steric effects quantitative treatment      374
Steric effects radical addition to alkenes      985
Steric hindrance and ester formation      485
Steric hindrance and ester hydrolysis      470
Steric hindrance and high pressure reactions      458
Steric hindrance and hydrogenation of alkynes      1005
Steric hindrance and nucleophilic addition      1174
Steric hindrance and nucleophilic strength      444
Steric hindrance definition      365
Steric inhibition, of resonance      699
Steric strain      see “Strain”
Steroids, $\alpha/\beta$ nomenclature      146
Stevens rearrangement      878 1419—1421 1454
Stevens rearrangement and sulfur ylids      1420
Stevens rearrangement and the Sommelet — Hauser rearrangement      1420
Stevens rearrangement labeling      1419
Stieglitz rearrangement      1416
Stilbenes      288
Stilbenes photochemical isomerization      391—320
Stilbenes photocyclization      1436
Stille reaction      931—932
Stille reaction and cine substitution      932
Stobbe condensation      1224
Stork enamine reaction      787
Stork enamine reaction and Michael reactions      787
Stork enamine reaction enantioselectivity      788
Stork enamine reaction regioselectivity      787
Stork enamine reaction synthesis      555
Stork — Eschenmoser hypothesis      1019
Story synthesis      1355
Strain and $\sigma$-bond rearrangements      1459
Strain and bent bonds      181
Strain and betweenanenes      186
Strain and bond length      184
Strain and Bredt’s rule      188
Strain and cleavage of non-enolizable ketones      814
Strain and conformational transmission      368
Strain and electrophilic aromatic substitution      690
Strain and geared molecules      189
Strain and heat of atomization      180
Strain and NMR      181
Strain and p and s character      181
Strain and substitution      432—433
Strain and twisted molecules      19
Strain angle, cyclobutane      182
Strain angle, cyclopropane      181
Strain B      366
Strain back      366
Strain conformations and reactivity      366
Strain eclipsing and reactivity      366
Strain energy      180
Strain energy calculation      180
Strain energy cyclotetradecane      214
Strain energy, cycloalkanes      185—186
Strain for ring categories      1851 366
Strain in fused ring benzene derivatives      45
Strain in organic molecules      180—191
Strain large-angle      184
Strain Pitzer      184
Strain polycyclic small-ring systems      182—183
Strain ring and ester hydrolysis      473
Strain ring and leaving groups      446
Strain ring size and reactivity      366
Strain rings other than 3 or 4      184—186
Strain small rings      180—184
Strain small-angle      180
Strain steric      180
Strain transannular      184
Strain twisted amides      185
Strain unavoidable crowding      189
Strained molecules, by the Wurtz reaction      536
Strecker synthesis      1240
Strength, of nucleophiles      439
Structure and acid-base strength      342—349
Structure and field effects      363
Structure and reactivity      368—375
Structure and steric effects      365—368
Structure and the Hammett equation      368
Structure of enolate anions      236—237
Structure of organolithium reagents      236
Structure resonance effect      363
Structures, Lewis      12
Strychnine, and resolution      151
Substituent effects $\alpha$-substitution      435
Substituent effects $\beta$-substitution      436
Substituent effects $\beta$-unsaturation      434
Substituent effects and aryl radicals      904
Substituent effects and electrophilic aromatic substitution      683—684 691
Substituent effects elimination reactions      1319
Substituent effects hybridization      433
Substituent effects in alkene metathesis      1457
Substituent effects in the Claisen rearrangement      1451
Substituent effects in the Diels — Alder reaction      1067
Substituent effects inductive effects      436
Substituent effects on $S_N1$ reactions      433—435
Substituent effects on $S_N2$ reactions      436
Substituent effects rate and the Diels — Alder reaction      1065
Substitution $S_E1$      676
Substitution $S_E1$ and electrophilic aromatic substitution      681
Substitution $S_N1$ and aromatic compounds      853
Substitution $S_NAr$      850—853
Substitution $S_NAr$, activating groups      858
Substitution $S_NAr$, and Meisenheimer salts      851
Substitution $S_NAr$, and the Hammett relationship      859
Substitution $S_NAr$, base catalysis      852
Substitution $S_NAr$, dimer mechanism      852
Substitution $S_NAr$, isolation of intermediates      851
Substitution $S_NAr$, isotope effects      852
Substitution $S_NAr$, leaving group effects      860
Substitution $S_NAr$, partitioning effect      852
Substitution $S_NAr$, substrate effects      857
Substitution $S_{ON}2$      862
Substitution $S_{RN}1$      855—856
Substitution $S_{RN}1$ and radicals      856
Substitution $S_{RN}1$ and ultrasound      856
Substitution and anchimeric assistance      404
Substitution and neighboring group mechanism      404—407
Substitution at ally lie carbon      421—424
Substitution benzyne      854
Substitution bimolecular      see “$S_N2$”
Substitution cine and the benzyne mechanism      854
Substitution cine and the Stille reaction      932
Substitution electrophilic, mechanism      275
Substitution free radical, mechanism of      896
Substitution Grignard reagents and aryl oxazolines      868
Substitution mixed $S_N1$-$S_N2$      400—402
Substitution nucleophilic bimolecular      see “Substitution
Substitution nucleophilic internal      see “Substitution
Substitution nucleophilic unimolecular      see “Substitution
Substitution nucleophilic, effect of nucleophile      861
Substitution nucleophilic, intramolecular      879
Substitution nucleophilic, leaving group effects      860
Substitution nucleophilic, other mechanisms      857
Substitution nucleophilic, substrate effects      857
Substitution radical      897—899
Substitution radical and ipso substitution      905
Substitution radical, mechanism of      898
Substitution reactions and alkyne carbon      433
Substitution reactions and bromonium ions      405
Substitution reactions and chain reactions      403
Substitution reactions and entropy of activation      404
Substitution reactions and isotope effects      299
Substitution reactions and neighboring group participation      407—420
Substitution reactions and radicals      402—404
Substitution reactions and SET mechanism      433
Substitution reactions at vinyl carbon      433
Substitution reactions B strain      432—433
Substitution reactions branching effects      431
Substitution reactions competition with elimination      1320
Substitution reactions IUPAC rules      382—383
Substitution reactions reactivity      431—462
Substitution reactions substrate      431—438
Substitution reactions with aryl substrates      433
Substitution vicarious nucleophilic substitution of H      872
Substitution, $S_E1$      763—767
Substitution, $S_E1$ and carbanions      764
Substitution, $S_E1$ and electrofuges      769
Substitution, $S_E1$ and ion pairs      768
Substitution, $S_E1$ and racemization      763—764
Substitution, $S_E1$ and solvent effects      764
Substitution, $S_E1$ and tautomerization      763
Substitution, $S_E1$ and the leaving group      764
Substitution, $S_E1$ conducted tour mechanism      766
Substitution, $S_E1$ effect of leaving groups      768
Substitution, $S_E1$ effect of substrates      768
Substitution, $S_E1$ isoinversion      765
Substitution, $S_E1$ isoracemization      765
Substitution, $S_E1$ isotopic exchange      765
Substitution, $S_E1$ solvent effects      769
Substitution, $S_E2$      759—763
Substitution, $S_E2$ absolute configuration      761
Substitution, $S_E2$ and bridgehead carbons      761
Substitution, $S_E2$ and EDA complexes      763
Substitution, $S_E2’$      760 767
Substitution, $S_Ei$      759—763
Substitution, $S_Ei$ salt effects      763
Substitution, $S_Ei$ solvent effects      763
Substitution, $S_Ei’$      767
Substitution, $S_N1$ and adamantyl compounds      433
Substitution, $S_N1$ and ambident nucleophiles      460
Substitution, $S_N1$ and bicyclic systems      397
Substitution, $S_N1$ and branching effects      432
Substitution, $S_N1$ and bridgehead carbons      764
Substitution, $S_N1$ and carbocation stability      395
Substitution, $S_N1$ and Markovnikov’s rule      984
Substitution, $S_N1$ and reactions of alcohols with $AlMe_3$      544
Substitution, $S_N1$ and rearrangements      1381
Substitution, $S_N1$ and the Hammett relationship      436
Substitution, $S_N1$ and the Hammond postulate      432
Substitution, $S_N1$ and trifluoroacetic acid as a solvent      451
Substitution, $S_N1$ at vinylic carbon      430
Substitution, $S_N1$ common ion effect      395
Substitution, $S_N1$ cubyl cation and ab initio calculations      397
Substitution, $S_N1$ effect of $\beta$-substitution      436
Substitution, $S_N1$ effect on rate of $\beta$-unsaturation      434
Substitution, $S_N1$ effects of $\alpha$-substitution      435
Substitution, $S_N1$ influence of inductive effects      436
Substitution, $S_N1$ ion pairing      397—400
Substitution, $S_N1$ IUPAC mechanistic description      394
Substitution, $S_N1$ kinetic studies      396
Substitution, $S_N1$ limiting      394
Substitution, $S_N1$ mass law effect      395
Substitution, $S_N1$ mechanism      393—400
Substitution, $S_N1$ planar intermediates      396
Substitution, $S_N1$ rate law      394
Substitution, $S_N1$ reaction rates of alkyl tosylates      434
Substitution, $S_N1$ salt effect      395
Substitution, $S_N1$ solvation      394
Substitution, $S_N1$ solvolysis rates for alkyl halides      432
Substitution, $S_N1$ stereochemistry      397
Substitution, $S_N1cB$      448
Substitution, $S_N1’$      423
Substitution, $S_N2$ ab initio studies      393
Substitution, $S_N2$ anchimeric assistance      404
Substitution, $S_N2$ and $LiAlH_4$ reduction of epoxides      529
Substitution, $S_N2$ and ambident nucleophiles      460
Substitution, $S_N2$ and backside attack      390
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