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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Substitution, $S_N2$ and branching effects      432
Substitution, $S_N2$ and electrophilic addition to alkenes      972
Substitution, $S_N2$ and enolate anion alkylations      550
Substitution, $S_N2$ and epoxides      461
Substitution, $S_N2$ and Marcus theory      287
Substitution, $S_N2$ and mass spectrometry      392
Substitution, $S_N2$ and organocuprate reactions      539—540
Substitution, $S_N2$ and stereochemistry      142
Substitution, $S_N2$ and the Finkelstein reaction      517
Substitution, $S_N2$ and the Hammond postulate      285
Substitution, $S_N2$ and the Menshutkin reaction      393
Substitution, $S_N2$ and the nucleophile      438—443
Substitution, $S_N2$ and Walden inversion      391
Substitution, $S_N2$ crossover experiments      393
Substitution, $S_N2$ effect of $\alpha$- or $\beta$-substituents      436
Substitution, $S_N2$ intermediate mechanism      401
Substitution, $S_N2$ internal      406
Substitution, $S_N2$ internal, epoxides from      478
Substitution, $S_N2$ kinetics      390
Substitution, $S_N2$ mechanism      390—393
Substitution, $S_N2$ neighboring group mechanism      404
Substitution, $S_N2$ participation by dioxane solvent      402
Substitution, $S_N2$ pseudo-first order kinetics      390
Substitution, $S_N2$ rate expression      390
Substitution, $S_N2$ rate of reaction for alkyl substrates      432
Substitution, $S_N2$ transition state      390
Substitution, $S_N2$ vs. $S_N2’$      422
Substitution, $S_N2’$      422—424
Substitution, $S_N2’$ and $S_Ni$      422
Substitution, $S_N2’$ and conjugate addition to alkenes      980
Substitution, $S_N2’$ stereochemistry      422
Substitution, $S_N2’$ with cuprates      423
Substitution, $S_N2’$ with cyclopropylmethyl halides      423
Substitution, $S_N2’$ with organocuprates      540
Substitution, $S_N2’$ with vinyl epoxides and organocuprates      547
Substitution, $S_Ni$ and formation of gem-dichlorides      1196
Substitution, $S_Ni$ mechanism      420
Substitution, $S_Ni$ stereochemistry      420
Substitution, $S_Ni$ UIPAC nomenclature      420
Substitution, $S_Ni’$      422—423
Substitution, $S_{RN}1$ and vinylic halides      431
Substitution, electrophilic $\pi$-complexes      679
Substitution, electrophilic $\sigma$-substitution, mechanism      702
Substitution, electrophilic alternant hydrocarbons      690
Substitution, electrophilic and activation hardness      692
Substitution, electrophilic and double bond shifts      766
Substitution, electrophilic and hardness      692
Substitution, electrophilic and HSAB      692
Substitution, electrophilic and nitronium ion      680
Substitution, electrophilic and SET mechanism      694
Substitution, electrophilic and strain      690
Substitution, electrophilic and the Baker — Nathan order      685
Substitution, electrophilic and the Hammett equation      692
Substitution, electrophilic and the Hammond postulate      681
Substitution, electrophilic and the ortho/para ratio      685
Substitution, electrophilic arenium ion mechanism      675—680
Substitution, electrophilic arenium ions      676
Substitution, electrophilic arenium ions, isolation of      678
Substitution, electrophilic aromatic, activating groups      681—684
Substitution, electrophilic benzenonium ions      678
Substitution, electrophilic bromination, reagents for      705
Substitution, electrophilic chlorination      679
Substitution, electrophilic deactivating groups      681—684
Substitution, electrophilic deuteration, reagents for      696
Substitution, electrophilic deuterium exchange      695
Substitution, electrophilic electrophiles      692
Substitution, electrophilic encounter complexes      680
Substitution, electrophilic encounter-complex      694
Substitution, electrophilic estimating isomer distribution      691
Substitution, electrophilic field effects      681
Substitution, electrophilic fluorination, reagents for      707
Substitution, electrophilic Friedel — Crafts      see “Friedel — Crafts”
Substitution, electrophilic Friedel — Crafts acylation      712—714
Substitution, electrophilic Friedel — Crafts alkylation      707—711
Substitution, electrophilic fused ring aromatics      689—690
Substitution, electrophilic halogenation, reagents for      705—706
Substitution, electrophilic heterocycles      688
Substitution, electrophilic hydrogen exchange      696
Substitution, electrophilic iodination, reagents for      706
Substitution, electrophilic ipso attack      686
Substitution, electrophilic ipso attack, migration      687
Substitution, electrophilic ipso position      686
Substitution, electrophilic isotope effects      676
Substitution, electrophilic leaving group effects      695
Substitution, electrophilic meta-      681
Substitution, electrophilic migration      687
Substitution, electrophilic Mills — Nixon effect      690
Substitution, electrophilic monosubstituted benzenes      681—687
Substitution, electrophilic multiple substituents      687
Substitution, electrophilic nitration      679
Substitution, electrophilic nitration, reagents for      697
Substitution, electrophilic nitronium ion      697
Substitution, electrophilic on zeolites      705
Substitution, electrophilic ortho effect      688
Substitution, electrophilic ortho-      681
Substitution, electrophilic other ring systems      688—690
Substitution, electrophilic para-      681
Substitution, electrophilic partial rate factor      685 690
Substitution, electrophilic partition factor      677
Substitution, electrophilic partitioning effect      677
Substitution, electrophilic pentamethylbenzenonium ion      678
Substitution, electrophilic polycyclic aromatics      688—690
Substitution, electrophilic predicting product distributions      691
Substitution, electrophilic rate determining step      694
Substitution, electrophilic rate of reaction      688 690
Substitution, electrophilic regioselectiviry      681—687
Substitution, electrophilic relative rates of substitution      694
Substitution, electrophilic resonance effects      681
Substitution, electrophilic resonance interaction      682
Substitution, electrophilic steric inhibition of resonance      699
Substitution, electrophilic substituent effects      683—684 691
Substitution, electrophilic substrate reactivity      690
Substitution, electrophilic sulfonation, and $SO_3$      702
Substitution, electrophilic sulfonation, and sulfone side products      702
Substitution, electrophilic sulfonation, mechanism      702
Substitution, electrophilic the $S_E1$ mechanism      681
Substitution, electrophilic the Hammett — Brown relationship      693
Substitution, electrophilic the Herz reaction      704
Substitution, electrophilic the selectivity relationship      692
Substitution, electrophilic tritiation, reagents for      696
Substitution, electrophilic tritium exchange      696
Substitution, electrophilic Vilsmeier reaction      715
Substitution, electrophilic Wheland intermediates      676
Substitution, electrophilic with iodine      706
Substitution, electrophilic with nitrites      705
Substitution, electrophilic, aromatic      also see “Friedel — Crafts acylation”
Substitution, nucleophilic ambident substrates      461
Substitution, nucleophilic and ambident nucleophiles      458—461
Substitution, nucleophilic and aprotic solvents      441
Substitution, nucleophilic and bridgehead atoms      437
Substitution, nucleophilic and cryptands      443
Substitution, nucleophilic and high pressure      457
Substitution, nucleophilic and I strain      437
Substitution, nucleophilic and ionic strength of the medium      451
Substitution, nucleophilic and microwave irradiation      457
Substitution, nucleophilic and phase transfer catalysis      454—456
Substitution, nucleophilic and reaction medium      450—454
Substitution, nucleophilic and solvent mixtures      452
Substitution, nucleophilic and solvent polarity      450
Substitution, nucleophilic and steric hindrance of nucleophiles      444
Substitution, nucleophilic and the Baker — Nathan order      437
Substitution, nucleophilic and the common-ion effect      451
Substitution, nucleophilic and the salt effect      451
Substitution, nucleophilic and the Swain — Scott equation      444
Substitution, nucleophilic and ultrasound      456—458
Substitution, nucleophilic at vinylic carbon      428—431
Substitution, nucleophilic basicity and leaving group ability      445
Substitution, nucleophilic cyclic substrates      437
Substitution, nucleophilic effect of bridgeheads      437
Substitution, nucleophilic effect of deuterium      438
Substitution, nucleophilic influence of the nucleophile      438—445
Substitution, nucleophilic leaving group effects      445—449
Substitution, nucleophilic leaving groups      434
Substitution, nucleophilic leaving groups, order of leaving      449
Substitution, nucleophilic mechanism      275 424—428
Substitution, nucleophilic nucleophilic strength      439
Substitution, nucleophilic nucleophilicity      444
Substitution, nucleophilic order of nucleophilic strength      443
Substitution, nucleophilic product spread      421
Substitution, nucleophilic reaction rate and anion size      451
Substitution, nucleophilic solvation rule      450
Substitution, nucleophilic solvent effects and nucleophilic strength      443
Substitution, nucleophilic substrate reactivity      439
Substitution, nucleophilic synthetic reactions      440—441
Substitution, nucleophilic tetrahedral mechanism and synthetic reactions      442
Substitution, nucleophilic the alpha effect      445
Substitution, nucleophilic types of transition states      450
Substitution, nucleophilic vicarious      872
Substitution, nucleophilic with ally lie rearrangement      421—424
Substitution, radical ally lie chlorination      914
Substitution, radical allylic brommation      911—913
Substitution, radical and iodine      908
Substitution, radical and racemization      897
Substitution, radical IUPAC nomenclature      897
Substitution, radical mechanism      275
Substitution, radical neighboring group effects      899
Substitution, radical on side chains of aromatic rings      902
Substitution, radical transition state      897
Substitution, radical with alkanes, rate of abstraction      901
Substitution, radical with hydrocarbons, reagents for      908
Substitution, reaction type      275—276
Substitution, SET mechanism      402—404
Substitution, vinyl      428—431
Substitution, vinyl element effect      429
Substitution, vinyl elimination-addition      430
Substitution-elimination of benzylic halides      1543
Substrate effects branching      431
Substrate effects on substitution      431—438
Substrate factor in the Swain — Scott equation      444
Substrates ambident      461
Substrates and mechanism      274
Substrates effect on $S_E1$ reactions      768
Substrates reactivity toward nucleophilic substitution      439
Succinimidyl radical      913
Sugars      see “Carbohydrates”
Sugars and ring-chain tautomerism      77
Sulfates from 1,2-diols      462
Sulfates ring opening      462
Sulfenamiides, reaction with alkenes      1058
Sulfene, and elimination of sulfonyl halides      1338
Sulfenyl chloride, aryl, reaction with aromatic compounds      704
Sulfenylation of amides      783
Sulfenylation of esters      783
Sulfenylation of ketones      783
Sulfides      see “Thioethers”
Sulfides, epi, reaction with acyl halides      521
Sulfinates, alkyl, as side products      498
Sulfinic acid salts, reaction with alkyl halides      498
Sulfinic acids from sulfonyl chloride      577
Sulfinic acids reaction with ethers      494
Sulfite, sodium reduction of diazonium salts      1556
Sulfolene and Diels — Alder reactions      1066
Sulfolene thermolysis of      1066
Sulfonamides acyl, reduction of      1550
Sulfonamides and protection of amines      577
Sulfonamides from acyl sulfonamides      1687
Sulfonamides from alkenes      1687
Sulfonamides from alkyl halides      514
Sulfonamides from amines      1687
Sulfonamides from ammonia      1687
Sulfonamides from aryl nitro compounds      1687
Sulfonamides from boranes      1687
Sulfonamides from halo sulfonamides      1687
Sulfonamides from sulfonamides      1687
Sulfonamides from sulfonyl azides      1555 1687
Sulfonamides from sulfonyl chlorides      576
Sulfonamides from sulfonyl halides      1687
Sulfonamides hydrolysis      576
Sulfonamides reaction with alcohols      576
Sulfonate esters      see “Esters sulfonate”
Sulfonation of aromatic rings      702
Sulfonation of naphthalene      682
Sulfones allyl vinyl and thio-Claisen rearrangement      1452
Sulfones anions, reaction with alkyl halides      555
Sulfones aryl, and the Smiles rearrangement      879
Sulfones aryl, reaction with hydroxide      879
Sulfones as side products or aromatic sulfonation      702
Sulfones bonding      45
Sulfones by Michael addition      1687
Sulfones by the Knoevenagel condensation      1687
Sulfones conjugated, reaction with organocuprates      1028
Sulfones conjugated, reduction with aluminum amalgam      1206
Sulfones coupling with organolithium reagents      544
Sulfones cyclic, extrusion of $SO_2$      1354—1355
Sulfones cyclic, pyrolysis      1354—1355
Sulfones diaryl from aromatic compounds      704
Sulfones elimination with base      1336
Sulfones from aldehydes      1687
Sulfones from alkenes      1687
Sulfones from alkyl halides      498 499 1687
Sulfones from aromatic compounds      1687
Sulfones from aryl halides      1687
Sulfones from aryl nitro compounds      1687
Sulfones from esters      1687
Sulfones from halo sulfones      1687
Sulfones from ketones      1687
Sulfones from organometallic compounds      1687
Sulfones from sulfinate ions      1687
Sulfones from sulfinates      1687
Sulfones from sulfones      1687
Sulfones from sulfonic acid derivatives      1687
Sulfones from sulfonyl chlorides      577—578
Sulfones from sulfonyl halides      1687
Sulfones from sulfoxides      1541 1687
Sulfones from thioethers      1687
Sulfones fromboranes      1687
Sulfones halogenation of      778
Sulfones phenyl vinyl, in the Diels — Alder reaction      1062
Sulfones reaction with NBS or NCS      778
Sulfones reaction with RLi and Pd, for elimination      1336
Sulfones, halo and the Ramberg — Backlund reaction      1341
Sulfones, halo elimination with base      1341
Sulfones, halo from alkenes      1045
Sulfones, halo from sulfonyl halides      1045
Sulfonic acid esters, hydrolysis      465
Sulfonic acids and sulfonyl chlorides      575
Sulfonic acids aryl, by the Jacobsen reaction      734
Sulfonic acids aryl, from aromatic compounds      702 734
Sulfonic acids aryl, heating with sulfuric acid      734—735
Sulfonic acids aryl, reaction with hydroxide      862
Sulfonic acids by the Jacobsen rearrangement      1687
Sulfonic acids from aromatic compounds      1687
Sulfonic acids from aryl halides      1688
Sulfonic acids from disulfides      1540
Sulfonic acids from sulfonamides      576
Sulfonic acids from sulfonate esters      575
Sulfonic acids from sulfonation with rearrangement      1687
Sulfonic acids from sulfones      1540
Sulfonic acids from sulfonic acid derivatives      1687
Sulfonic acids from sulfonic anhydrides      575
Sulfonic acids from sulfoxides      1540
Sulfonic acids from sulfur compounds      1688
Sulfonic acids fromthiols      1540 1688
Sulfonic acids reaction with $PCl_5$      577
Sulfonic acids reaction with orthoformates      576
Sulfonic acids reaction with thionyl chloride      577
Sulfonic acids salts, reaction with thionyl chloride      944
Sulfonic anhydrides, hydrolysis of      575
Sulfonium compounds, elimination reactions      1336
Sulfonium salts from alkyl halides      497
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