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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Ketones from ketones      559—560 1401 1678 1679
Ketones from ketonic decarboxylation      1678
Ketones from lithium alkynyltrialkylborates      1679
Ketones from lithium carboxylates      1679
Ketones from malonic acid derivatives      1530
Ketones from malonic acids      1680
Ketones from mercury hydrides      1679
Ketones from nitriles      1217 1678 1679 1680
Ketones from nitro compounds      1178 1537 1680
Ketones from organocuprates      1027 1678
Ketones from organolithium reagents      1213 1679
Ketones from organomercury halides      800
Ketones from organometallic compounds      1678 1679
Ketones from oxazines      559 1678
Ketones from oximes      938 1679
Ketones from phenyllithium      1215
Ketones from photolysis of acylated arylamines      1678
Ketones from pyrolysis of $\beta$-hydroxy alkenes      1679
Ketones from rearrangement of glycols      1679
Ketones from rearrangement of hydroxy alkenes      1678
Ketones from rearrangement of phenolic ethers      1678
Ketones from reduction of $\beta$-keto sulfoxides      1678
Ketones from reduction of diazo ketones or nitro ketones      1678
Ketones from reduction of diketones or quinones      1680
Ketones from reduction of halo ketones      1678
Ketones from reduction of hydroxy ketones      1678
Ketones from reduction of phenols      1679
Ketones from ring expansion of certain hydroxyamines      1679
Ketones from secondary alcohols      1679
Ketones from silyl enol ethers      1679
Ketones from thioketones      1185
Ketones from tin hydrides      1679
Ketones from tosylates      1680
Ketones from unsaturated ketones      1679
Ketones from vinyl sulfides      783
Ketones fromalkenes      1033 1035 1038 1522 1525—1526 1537—1538 1679 1680
Ketones fromatkynes      1679
Ketones fromdiols      1396—1398 1519—1521
Ketones halo, from ketones      775
Ketones halogenation, mechanism      776
Ketones homologation with $Me_3SiI$      1407
Ketones homologation with diazomethane      1407
Ketones hydroxy      see “Hydroxy ketones”
Ketones hydroxylation of, reagents for      916
Ketones in the Mannich reaction      1189
Ketones in the Mukaiyama aldol reaction      1223
Ketones indirectly, from carboxylic esters      1679
Ketones methyl, and the haloform reaction      813
Ketones methyl, and the Willgerodt reaction      1567
Ketones methyl, cleavage with halogens      813
Ketones methyl, from diazomethane homologation of aldehydes      1408
Ketones methylation by the Simmons — Smith reaction      1089
Ketones methylation with $Me_3Al$      1214
Ketones non-enolizable, cleavage by base      813
Ketones oxidation with $MeReO_3$/$H_2O_2$      1533
Ketones oxidation with $SeO_2$      1509
Ketones oxidation with dimethyldioxirane      916
Ketones oxidation with Ptsum sativum      1533
Ketones photochemical cleavage      245 318
Ketones photochemical dimerization      1560
Ketones protection as dithioketals      1182
Ketones reaction with $CS_2$      1229
Ketones reaction with $Me_3Al$ or $Me_3TiCl_2$      1210
Ketones reaction with $Me_3SiCN$      1240
Ketones reaction with $PCl_5$      1195
Ketones reaction with $TiCl_3/Zn-Cu$      1561
Ketones reaction with $\alpha$-methoxyvinyllithium      1227
Ketones reaction with active methylene compounds      1225—228
Ketones reaction with acyl halides      1182
Ketones reaction with alcohols      1180 1182
Ketones reaction with aldehydes      1218—1223 1248
Ketones reaction with alkenes      1249
Ketones reaction with alkyl halides      492
Ketones reaction with allenes      1250
Ketones reaction with amines      553 1185—1187
Ketones reaction with amines and hydrogen      1187—1189
Ketones reaction with ammonia      1186
Ketones reaction with ammonia and hydrogen      1188
Ketones reaction with bisulfite      1185
Ketones reaction with bromoesters and Zn      1212
Ketones reaction with carboxylic acids and isonitriles      1251
Ketones reaction with chloro esters      1230
Ketones reaction with diazoalkanes      1248
Ketones reaction with enol esters      487
Ketones reaction with esters      1223
Ketones reaction with formaldehyde      1230
Ketones reaction with Girard’s reagents T and P      1193
Ketones reaction with Grignard reagents      1205—1209
Ketones reaction with halogens      775
Ketones reaction with HCN      1239
Ketones reaction with hydrazines      1192—1193
Ketones reaction with hydrazoic acid      1414
Ketones reaction with hydrogen sulfide      1184
Ketones reaction with hydroxylamine      1194
Ketones reaction with isopropyl acetate      487
Ketones reaction with ketene acetals      1249
Ketones reaction with ketenes      1249
Ketones reaction with ketones      1218—1223 1248
Ketones reaction with Lawesson’s reagent      1184
Ketones reaction with magnesium methyl carbonates      1229
Ketones reaction with organocerium reagents      1205
Ketones reaction with organolithium reagents      1205—1209
Ketones reaction with other organometallics      1209—1211
Ketones reaction with peroxyacids      1417
Ketones reaction with Petasis reagent      1238
Ketones reaction with phenylhydrazine      1453
Ketones reaction with phosphorus ylids      1231—1237
Ketones reaction with semicarbazide      1193
Ketones reaction with silane carbanions      1228
Ketones reaction with silanes and base      1200
Ketones reaction with silyl enol ethers      552
Ketones reaction with silyl ketene acetals      1223
Ketones reaction with sulfur ylids      1247
Ketones reaction with Tebbe’s reagent      1238
Ketones reaction with thiols      1182 1185
Ketones reaction with water      1175
Ketones rearrangement of      1401
Ketones reduction      1197—1203
Ketones reduction with boranes      1200
Ketones reduction with hydrazine-KOH      1547
Ketones reduction with hydrides      1197—1198
Ketones reduction with metals in water      1200
Ketones reduction with sodium in ethanol      1199
Ketones reduction with Zn-Hg/HCl      1547
Ketones reduction, and Cram’s rule      1201
Ketones reductive acylation      1182
Ketones reductive animation      1188
Ketones reductive coupling      1559—1561
Ketones reductive dimerization      1182
Ketones reductive removal of O      1547
Ketones silyl, oxidative cleavage      1521
Ketones sulfenylation of      783
Ketones, conjugated addition to silyl enol ethers      1024
Ketones, conjugated and Michael reactions      1022—1024
Ketones, conjugated and the Grignard reaction      1205
Ketones, conjugated and the Sakurai reaction      1024
Ketones, conjugated and vinylogy      553
Ketones, conjugated by Nazarov cyclization      1021
Ketones, conjugated by selenoxides      1336
Ketones, conjugated by the Pauson — Khand reaction      1091
Ketones, conjugated by the Robinson annulation      1222
Ketones, conjugated reaction with borane      1031
Ketones, conjugated reaction with hydroperoxide anion      1509
Ketones, conjugated reduction of      1007
Ketones, cyclic      see “Cyclic ketones”
Ketones, di-      see “Diketones”
Ketyl intermediates, in Grignard reagents      1208
Kiliani — Fischer synthesis      1240
Kindler modification, to the Willgerodt reaction      1567
Kinetic acidity      228—229
Kinetic and thermodynamic control      284—285
Kinetic resolution      149 153—154
Kinetic resolution and dihydroxylation      154
Kinetic resolution and epoxidation      154
Kinetics and diffusion control      279
Kinetics and E1 elimination      1307
Kinetics and E2 elimination      1300
Kinetics and equilibrium      293
Kinetics and frequency factor      296
Kinetics and half-life      294—295
Kinetics and intermediates      281—282
Kinetics and lactonization      281
Kinetics and mechanism      290—296
Kinetics and molecularlity      291
Kinetics and NMR      295
Kinetics and primary isotope effects      298
Kinetics and rate constants      281 291
Kinetics and rate law      290
Kinetics and reaction coordinates      279
Kinetics and reactions      278—282
Kinetics and reactions of nitromum ion      698
Kinetics and ring closing reactions      281
Kinetics and second order reaction      291
Kinetics and secondary isotope effects      298
Kinetics and solvent isotope effects      299
Kinetics and steady state approximation      292
Kinetics and the $S_N1$reaction      394 396
Kinetics and the $S_N2$ reaction      390
Kinetics and the tetrahedral mechanism      425
Kinetics and third order reactions      291
Kinetics and transition state      279
Kinetics classifications, for $\beta$-eliminations      1309
Kinetics first order reaction      291
Kinetics kinetic vs. thermodynamic control      284—285
Kinetics pseudo-first order      293
Kinetics rate determining step      291—292
Knoevenagel condensation      1219 1225—1228
Knoevenagel condensation and high pressure      457
Knoevenagel condensation and lithiated ally lie carbamates      1227
Knoevenagel condensation and microwaves      1226
Knoevenagel condensation and the Tollens’ reaction      1231
Knoevenagel condensation and zeolites      1226
Knoevenagel condensation Doebner modification      1226
Knoevenagel condensation solid state reactions      1226
Knoevenagel condensation solvents effects      1227
Knoevenagel condensation with $\alpha$-methoxyvinyllithium      1227
Knoevenagel condensation with tosylhydrazones      1227
Knots      see “Molecular knots”
Knots, molecular      114
Kobe — Schmitt reaction      718
Koch reaction      1035
Koch — Haaf reaction      564 1035
Kolbe electrosynthesis      942
Kolbe reaction      941—942 1354 1508
Kolbe reaction photochemical      942
Kornblum’s rule      460(ref. 470) 605
Krebs cycle, and enantiotopic atoms      164
Krohnke reaction      1536
l,2,5-tri-t-butyl[2,2.0]hexadiene      1433
l,2-Dibromo-l,2-diphenylethane, and E2 elimination      1301
l,3-Dioxa[8]-2,7-pyrenophane      44
l,4-Dichloro-l,3-butadienes      1434
l,5-Diazabicyclo[3.4.0]non-5-ene      see “DBN”
l,l'-Binaphthyl, resolution      153
l,l,l,3,3,3-Hexafluoro-2-propanol, as a solvent      451
L-proline      642 (ref. 1349)
l-t-butyl-l,2-Cyclooctadiene      187
Labeling and $\sideset{^{14}}{}C$      289
Labeling and alkynes      430
Labeling and amide hydrolysis      476
Labeling and enantiotopic atoms      164
Labeling and enol ether hydrolysis      467
Labeling and ester hydrolysis      290 472
Labeling and keto-enol tautomerism      775
Labeling and labeled COa with Grignard reagents      1215
Labeling and mechanisms      289—290
Labeling and ozonolysis      1525
Labeling and protonated cyclopropanes      1382
Labeling and radical rearrangements      1389
Labeling and reduction of sulfoxides      1557
Labeling and the Baeyer — Villiger rearrangement      1418
Labeling and the benzidine rearrangement      1456
Labeling and the benzyne mechanism      854
Labeling and the Favorskii rearrangement      1404
Labeling and the Stevens rearrangement      1419
Labeling and the tetrahedral mechanism      425
Labeling and the Wallach rearrangement      1465
Labeling in aromatic compound cleavage      731
Labeling in the hydrolysis of aryl sulfonates      574
Labeling in the photochemical Wolff rearrangement      1406
Labeling in the Shapiro reaction      1335
Labeling of adamantane, and rearrangements      1396
Labeling oxygen, and solvolysis      398
Labeling rearrangement of N-nitro amines      727
Lactams alkoxy, reaction wt Grignard reagents      546
Lactams and reductive alkylation      513
Lactams by halolactamization      1680
Lactams by the Beckmann rearrangement      1680
Lactams by the Schmidt rearrangement      1680
Lactams by transamidation      512
Lactams enzymatic formation      508
Lactams from alkene amides      1043
Lactams from alkene-acids      1680
Lactams from alkenes      1059 1680
Lactams from amines      1680
Lactams from aminocyclopropanols      1680
Lactams from ammo acids      508 1680
Lactams from ammonia      1680
Lactams from azido carboxylic acids      508
Lactams from carbamates      1002
Lactams from cyclic amines      1535 1680
Lactams from cyclic ketones      1414 1680
Lactams from enamines      1680
Lactams from halo amides      1680
Lactams from halo esters      1680
Lactams from imines      1680
Lactams from isocyanates      1680
Lactams from ketenes      1680
Lactams from lactams      512 546 1680
Lactams from lactones      510 1680
Lactams from reactions of alkenes, CO, and water      1036
Lactams from rearrangement of qximes      1680
Lactams from ring expansion of lactams      1680
Lactams from unsaturated amines      1680
Lactams fromimides      1680
Lactams in Diels — Alder reactions      1075
Lactams N-chloromethyl, reaction with amines      500
Lactams oxidation of      1535
Lactams reaction with alky I halides      513
Lactams reaction with amide bases      512
Lactim ethers, in Diels — Alder reactions      1075
Lactones and the Mukaiyama reagent      485
Lactones bicyclic, fragmentation reactions      1348
Lactones by extrusion of $CO_2$ from l,2-dioxolane-3,5-diones      1680
Lactones by halolactonizations      1680
Lactones by internal $S_N2$      406
Lactones by intramolecular coupling      1680
Lactones by oxidation of cyclic esters      1534
Lactones by the Baeyer — Villiger rearrangement      1680
Lactones by the Story reaction      1355 1680
Lactones by transesterification      487
Lactones cleavage with thiols      496
Lactones conformations      178
Lactones decarboxylation      1354
Lactones enantioselective formation      1249
Lactones from alcohols      1680
Lactones from aldehydes      1249 1680
Lactones from alkene acids      1043
Lactones from anhydrides      1550 1680
Lactones from cleavage of cyclic $\alpha$-cyano ketones      1680
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