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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Enol ethers propargyl      see “Ethers propargyl
Enol ethers pyrolysis of      1329
Enol ethers reaction with alcohols      487
Enol ethers, allyl      see “Ethers allyl
Enol ethers, silyl addition to conjugated ketones      1024
Enol ethers, silyl and the Sakurai reaction      1024
Enol ethers, silyl coupling with $Ag_2O/DMSO$      1543
Enol ethers, silyl from enolate anions      794
Enol ethers, silyl from ketones and aldehydes      793
Enol ethers, silyl from vinyllithium reagents      796
Enol ethers, silyl kinetic and thermodynamic      794
Enol ethers, silyl nucleophilic strength      1221
Enol ethers, silyl reaction with DDQ      1512
Enol ethers, silyl reaction with Grignard reagents      546
Enol ethers, silyl reaction with ketones and aldehydes      552
Enol ethers, silyl reaction with methyllithium      554
Enol ethers, silyl reagents for preparation      794
Enol thioethers from aldehydes      1668
Enol thioethers from alkynes      1668
Enol thioethers from ketones      1185 1668
Enol thioethers from sulfoxides      1668
Enol thioethers fromthiols      1185 1668
Enolate anions      also see “Carbanions”
Enolate anions ab initio studies      237
Enolate anions acetoacetic ester synthesis      549
Enolate anions ambident nucleophiles      458
Enolate anions and aggregates      237
Enolate anions and Baldwin’s rules      283—284
Enolate anions and Claisen rearrangement      1452
Enolate anions and cyanoacetic ester synthesis      549
Enolate anions and Grignard reagents      1207
Enolate anions and Katritzky pyrylium-pyridinium reagents      551
Enolate anions and keto-enol tautomerism      775
Enolate anions and Michael addition      1023
Enolate anions and solvents      548
Enolate anions and the Robinson annulation      1222
Enolate anions and xray crystal structure      236
Enolate anions as ambident nucleophiles      458
Enolate anions bases for their formation      548
Enolate anions E/Z isomers      237
Enolate anions enantioselective protonation      794
Enolate anions formation of      793
Enolate anions from active hydrogen compounds      1668
Enolate anions from aldehydes      1668
Enolate anions from enol acetates      1668
Enolate anions from enols      75
Enolate anions from organocuprate conjugate addition      1027
Enolate anions from organolithium reagents      1209
Enolate anions halogenation of      776
Enolate anions in coupling reactions      1543
Enolate anions in the aldol reaction      1218
Enolate anions in the malonic ester synthesis      549
Enolate anions metal variation in the aldol reaction      1221
Enolate anions phase transfer and alkylation      548
Enolate anions protonation of      976
Enolate anions reaction with acyl halides      569
Enolate anions reaction with alkyl halides      548
Enolate anions reaction with anhydrides      569
Enolate anions reaction with aryl halides      869
Enolate anions reaction with aziridines      548
Enolate anions reaction with diazonium salts      778
Enolate anions reaction with disulfides      783
Enolate anions reaction with palladium compounds      551
Enolate anions reaction with PhSeCl or PhSeBr      783
Enolate anions reaction with silyl halides      793
Enolate anions reaction with tosyl azide      780
Enolate anions reaction with tosyl cyanide      786
Enolate anions reaction with zinc chloride      1221
Enolate anions structure of      236—237
Enolate anions, ester and the Claisen condensation      552
Enolate anions, ester reaction with esters      569—570
Enolate anions, ketone      1668
Enolate anions, ketone and solvents      552
Enolate anions, ketone and the aldol condensation      552
Enolate anions, ketone and vinylogy      553
Enolate anions, ketone bases for      551
Enolate anions, ketone reaction with alkyl halides      551
Enolate anions, ketone reaction with esters      571
Enolate anions, ketone regioselectivity of alkylation      554
Enolate anions, ketone thermodynamic stability      554
Enolate anions, nitrile      552—553
Enolate anions, nitrile reaction with esters      572
Enolate dianions, reaction with boranes      1424
Enolate radicals      242
Enolendo and Baldwin’s rules      284
Enolene rearrangement      1450
Enolexo and Baldwin’s rules      284
Enolization and Grignard reagents      1207
Enolization and organolithium reagents      1209
Enols and keto-enol tautomerism      73—75
Enols and NMR      75
Enols and the aldol reaction      1222
Enols and the Bucherer reaction      865
Enols borinate, halogenation of      777
Enols chiral in the aldol reaction      1221
Enols enol content of carbonyl compounds      74
Enols fluorinated, enol content      74—75
Enols from enolate anions      976
Enols Fuson-type      74
Enols of acetoacetic ester      74—75
Enols stable      189
Enols tautomerization with keto form      773—775
Entgegen nomenclature      157
Enthalpy      see “Energy”
Enthalpy formal steric      190
entropy      277—278
Entropy and temperature      278
Entropy and the aldol reaction      1222
Entropy cleavage in ethane      278
Entropy effect and acid or base strength      347
Entropy of activation and substitution      404
Envelope conformation      178
Enzymes and Bakers yeast reduction      1004 1200 1553—1555
Enzymes and dihydroxylation of aromatic compounds      1050
Enzymes and formation of lactams      508
Enzymes and hydrolysis, of epoxides      468
Enzymes and hydrolysis, of esters      470
Enzymes and Meinwald rearrangement      1398
Enzymes and reduction of ketones      1200
Enzymes and transesterification      487
Enzymes from dimerization of alkynes      1668
Ephedrine, and resolution      151
Epimers, definition      146
Episulfides ambident substrates      461
Episulfides and nucleophiles      446
Episulfides elimination with triphenylphosphine      1341
Episulfides from cyclization of $\beta$-halo disulfides      1669
Episulfides from diazoalkanes      1248 1669
Episulfides from epoxides      1248 1669
Episulfides from thioketones      1248 1669
Episulfides reaction with ammonia      504
Episulfone intermediates, in the Ramberg — Backlund reaction      1342
Episulfones from sulfonyl halides and diazomethane      1249
Episulfones thermolysis of      1248
Epoxidation and kinetic resolution      154
Epoxidation by the Darzen’s reaction      1219
Epoxidation Jacobsen — Katsuki      1053
Epoxidation of alkenes      1051—1054
Epoxidation of alkenes, and the Baeyer — Villiger reaction      1052
Epoxidation of alkenes, Sharpless asymmetric      1053
Epoxidation of conjugated compounds      1053
Epoxides alcoholysis of      481
Epoxides ambident substrates      461
Epoxides and enzyme-induced rearrangements      1398
Epoxides and Meinwald rearrangement      1398
Epoxides and pinacol rearrangement      1398
Epoxides and the Payne rearrangement      481
Epoxides by internal $S_N2$      406 478
Epoxides by Payne rearrangement      1669
Epoxides by photooxygenation of alkenes      1054
Epoxides by the Darzens glycidic ester condensation      1230
Epoxides by the Darzens reaction      1669
Epoxides by the Prilezhaev reaction      1052
Epoxides elimination with triethyl phosphite      1341
Epoxides elimination with triphenylphosphine      1341
Epoxides from $\alpha$-halo esters      1669
Epoxides from 1,2-diols      1669
Epoxides from 2,3-epoxy alcohols      1669
Epoxides from aldehydes      1247 1248 1669
Epoxides from alkenes      1051—1054 1669
Epoxides from alkenes, reagents for      1054
Epoxides from amides      1669
Epoxides from carbonyl compounds      1206
Epoxides from diazoalkanes      1248
Epoxides from diazomethane      1669
Epoxides from dihalides      1206 1669
Epoxides from halohydrins      478 1669
Epoxides from secododecahedrane      1669
Epoxides from sulfur ylids      1247 1669
Epoxides fromketones      1247 1248 1669
Epoxides hydrolysis of      468
Epoxides hydrolysis of and high pressure      468
Epoxides hydrolysis, enzymatic      468
Epoxides hydrolysis, selectivity with Co-salen catalysts      468
Epoxides isomerization of      481
Epoxides oxidative cleavage      1520
Epoxides reaction with $LiAlH_4$      529
Epoxides reaction with $NH_4SCN$ and eerie ammonium nitrate      1248
Epoxides reaction with $Ph_2Pli$      1341
Epoxides reaction with $Ph_3=NPh$      515
Epoxides reaction with alcohols      481
Epoxides reaction with alkoxides      481
Epoxides reaction with allyl silanes      535
Epoxides reaction with ammonia      504
Epoxides reaction with base      1329
Epoxides reaction with dithiane anions      557
Epoxides reaction with Grignard reagents      546
Epoxides reaction with HX      520
Epoxides reaction with nucleophiles      446
Epoxides reaction with organobarium compounds      547
Epoxides reaction with organocuprates      547
Epoxides reaction with organolithium reagents      546 1329
Epoxides reaction with phosphines      1235
Epoxides reaction with Red — Al      529
Epoxides reaction with sulfide ions      497
Epoxides reaction with thiols      481
Epoxides reagents for preparing halohydrins      521
Epoxides rearrangement with acid      1398
Epoxides rearrangement with hydroxide      1463
Epoxides reduction      1552
Epoxides reduction, reagents for      529
Epoxides vinyl, rearrangement in Grignard reactions      547
Epoxides vinylic, reaction with Grignard reagents      547
Epoxy alcohols and the Payne rearrangement      481
Epoxy alcohols from epoxy ketones      1200
Epoxy alcohols rearrangements with $TiCl_4$      1398
Epoxy alcohols ring opening      462
Epoxy amines, conversion to aziridines      504
Epoxy esters, by the Darzens glycidic ester condensation      1230
Epoxy hydrazones, fragmentation with base      1347
Epoxy ketones from conjugated ketones      1509
Epoxy ketones reduction of      1200
EPR      see “ESR”
Equatorial bonds      172
Equilibrium and carbocation rearrangements      1380
Equilibrium and conformations of cyclohexane      172—175
Equilibrium and conformations of substituted cyclohexanes      175
Equilibrium and ester hydrolysis      470
Equilibrium and keto-enol tautomerism      774
Equilibrium and kinetics      293
Equilibrium and leaving reaction at acyl carbon      448
Equilibrium and the adamantyl cation      1383
Equilibrium and the benzoin condensation      1243
Equilibrium and the Hammett equation      368
Equilibrium and the Meerwein — Ponndorf — Verley reduction      1199
Equilibrium and the Oppenauer oxidation      1199
Equilibrium and the Sommelet — Hauser rearrangement      878
Equilibrium and thermodynamic control      284—285
Equilibrium boranes and alkenes      1338
Equilibrium constants and acid strength      336
Equilibrium constants and carbocations      220
Equilibrium constants and transition states      279
Equilibrium cyclobutenes-l,3-dienes      1426
Equilibrium cyclohexadiene-trienes      1426
Equilibrium hydrates and carbonyl compounds      1176
Equilibrium in alkene metathesis      1457
Equilibrium in reactions of HCN with aldehydes or ketones      1239
Equilibrium in reactions of organometallics      802
Equilibrium in the aldol reaction      1220
Equilibrium Schlenk      234
Equilibrium structure and reactivity      368
Equilibrium thermal alkylborane migration      1409
Ergost-7-en-3-one      367
Erythro diastereomers, from electrophilic addition to alkenes      971
Erythro nomenclature      146—147
Erythro/threo diastereomers and E2 elimination      1301
Erythro/threo diastereomers in the aldol reaction      1221
ESCA and carbocation rearrangements      419
Eschenmoser — Tanabe ring cleavage      1347
Eschenmoser’s salt      1191
Eschweiler — Clarke reaction      1188
ESR and captodative effects      242
ESR and coupling of organometallics with RX      538
ESR and doublets      239
ESR and Grignard reagents      1208
ESR and radical addition to alkenes      979
ESR and radicals      239 244
ESR and SET mechanisms      403
ESR and the Mills — Nixon effect      690
Ester hydrolysis      see “Esters hydrolysis “Hydrolysis esters”
Ester intermediates, in oxidation- reduction      1508
Ester thioethers, by the Pummerer rearrangement      1566
Esterase, pig liver and ester hydrolysis      470
Esterification and Amberlyst-15      486
Esterification and microwaves      484
Esterification and steric hindrance      485
Esterification dehydrating agents      486
Esterification Mitsunobu      486
Esterification of carboxylic acids      484—486
Esterification with 2,2,2-trichloroacetimidate      486
Esters acylation of      569—570
Esters acyloin condensation      1562
Esters alcoholysis of      486
Esters alkynyl, from acetylides and peroxides      796
Esters allylic      also see “Acetates allylic”
Esters allylic, reaction with organocuprates      545
Esters and acidity      344
Esters and azeotropic distillation      484
Esters and leaving groups      449
Esters and the Barton — McCombie reaction      527
Esters and the Claisen reaction      1224
Esters and transesterification      486
Esters aryl, from aryl halides      870
Esters aryl, reaction with Leis acids      727
Esters aryl, reagents for formation      870
Esters bromo and the Blaise reaction      1213
Esters bromo in the Reformatsky reaction      1212
Esters by Katritzky pyrylium-pyridinium method      489
Esters by reactions of tetracarbonylferrate      565
Esters by the Arndt — Eistert rearrangement      1663
Esters by the Baeyer — Villiger reaction      1417 1663
Esters by the Favorskii rearrangement      1663
Esters by the Pinner synthesis      1183
Esters by the Schotten — Baumann procedure      482
Esters by the Simonini reaction      943 1662
Esters by the Tishchenko reaction      1565 1663
Esters carbonate, from alkoxides and $CO_2$      1184
Esters chloro, reaction with aldehydes      1230
Esters chloro, reaction with ketones      1230
Esters cleavage with thiols      496
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