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| Ïîèñê ïî óêàçàòåëÿì |
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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Ïðåäìåòíûé óêàçàòåëü |
Diazonium coupling 700
Diazonium ions 448 700
Diazonium ions and amide hydrolysis 475
Diazonium ions and the Bamford — Stevens reaction 1335
Diazonium ions ionization to carbocation 1393
Diazonium salts 448
Diazonium salts and ionization to aryl cations 853
Diazonium salts aryl, and isomerization 700
Diazonium salts aryl, coupling 700
Diazonium salts aryl, coupling and acidity 700
Diazonium salts aryl, coupling with alkenes 929—930
Diazonium salts aryl, coupling with arylboronic acids 938
Diazonium salts aryl, formation of 701
Diazonium salts aryl, mechanism of formation 817
Diazonium salts aryl, methylation of 937
Diazonium salts aryl, reaction with  937
Diazonium salts aryl, reaction with  936
Diazonium salts aryl, reaction with  937
Diazonium salts aryl, reaction with aromatic compounds 928
Diazonium salts aryl, reaction with CuCl or CuBr 935—936
Diazonium salts aryl, reaction with CuCN 936
Diazonium salts aryl, reaction with cuprous halides 935
Diazonium salts aryl, reaction with hydrogen sulfide anion 874
Diazonium salts aryl, reaction with hypophosphorous acid 934
Diazonium salts aryl, reaction with iodide 875
Diazonium salts aryl, reaction with oximes 938
Diazonium salts aryl, reaction with sulfur nucleophiles 874
Diazonium salts aryl, reaction with thiol anions 874
Diazonium salts aryl, reaction with water 874
Diazonium salts aryl, reduction of 934
Diazonium salts coupling with alkenes 937
Diazonium salts from amines 1664
Diazonium salts from aromatic compounds 1664
Diazonium salts reaction with active methylene compounds 778
Diazonium salts reaction with enolate anions 778
Diazonium salts reaction with malonic esters 779
Diazonium salts reduction with  1556
Diazonium salts reduction with sodium sulfite 1556
Diazonium tetrafluoroborates, aryl, thermolysis 875
Diazonium, as a leaving group 447
Diazosulfides, as intermediates 874
Diazotization of amines 448 816
Diazotization of amino acids 522
Dibal reduction of alkynes 1007
Dibal reduction of carbonyl compounds 1198
Dibal reduction of oximes 1555
Dibromides from alkenes 1041
Dibromides from hydrazones 1196
Dibromocarbene 249
Dibromoisocyanuric aid, and aromatic bromination 706
Dibromoketones, reaction with organocnprates 539
Dibromomethane, and the Simmons — Smith reaction 1088
Dicaranylborane 1015
Dicarboxyacetylene, reaction with bromine 973
Dicarboxylic acids from cyclic ketones 1521
Dicarboxylic acids oxidative bisdecarboxylation 1530
Dicarboxylic acids pyrolysis with  574
Dicarboxylic acids radical halogenation 909
Dicarboxylic acids reaction with diesters 487
Dicarboxylic acids reaction with lead tetraacetate 1530
Dications 222; see “Carbocations”
Dichlorides, conpling, electrochemical 537
Dichlorine monoxide 914
Dichlorobenzenes and benzyne intermediates 860
Dichloroborane-dimethyl sulfide 1014
Dichlorocarbene 248
Dichlorocarbene formation of 250
Dichloromethyl ethers, reaction with lithium triethylcarboxide 1423
Dichloromethyl methyl ether, reaction with aromatic compounds 717
Dichromate oxidation of alcohols 1514 1515
Dichromate oxidation of aromatic diols 1517
Dichromate reaction with aldehydes 917
Dicobalt octacarbonyl and hydroformylation of alkenes 1037
Dicobalt octacarbonyl reaction with organomercury halides 800
Dicyclohexylcarbodiimide see “DCC”
Dicyclohexylurea, byproduct of esterification with DCC 485
Dieckmann condensation 569—570 (also see “Claisen condensation”)
Dieckmann condensation and the acy loin condensation 1562
Dieckmann condensation mechanism of 570
Dielectric effects, in solvents, algorithm 450
Diels — Alder reactions 289 1092 1062—1075
Diels — Alder reactions a biradical mechanism 1067
Diels — Alder reactions and  1066
Diels — Alder reactions and 3-sulfolene 1066
Diels — Alder reactions and a Moebius strip 1071
Diels — Alder reactions and alkyne trimerization 1090
Diels — Alder reactions and alkynes 1062
Diels — Alder reactions and aromatic compounds 1063
Diels — Alder reactions and cation radicals 1065
Diels — Alder reactions and cisoid conformations of dienes 1064
Diels — Alder reactions and Claisen rearrangement 1450
Diels — Alder reactions and cyclic dienes 1064
Diels — Alder reactions and dienophiles 1062
Diels — Alder reactions and high pressure 457 1066
Diels — Alder reactions and Hueckel systems 1071
Diels — Alder reactions and isotope effects 1067
Diels — Alder reactions and Lewis acid complexes 1065
Diels — Alder reactions and microwaves 1065
Diels — Alder reactions and Mobius systems 1071
Diels — Alder reactions and orbital symmetry 1068
Diels — Alder reactions and photochemical reactions 1071
Diels — Alder reactions and polymerization 1065
Diels — Alder reactions and rate 1065
Diels — Alder reactions and reaction of oxygen with dienes 1055
Diels — Alder reactions and the cyclic mechanism 979
Diels — Alder reactions and the Mobius — Hiickel method 1070
Diels — Alder reactions and the Woodward — Hoffmann rules 1068
Diels — Alder reactions and thermal reactions 1071
Diels — Alder reactions and transoid conformations of dienes 1063
Diels — Alder reactions and ultrasound 1075
Diels — Alder reactions and [2+2]-cycloadditions 1077
Diels — Alder reactions antarafacial additions 1073
Diels — Alder reactions antibody catalyzed 1065
Diels — Alder reactions basis sets 1070
Diels — Alder reactions cationic 1065
Diels — Alder reactions cleavage of adducts 1069
Diels — Alder reactions concertedness 1068
Diels — Alder reactions dienophiles and [3+2]-cycloaddition 1061
Diels — Alder reactions enantioselectivity 1065
Diels — Alder reactions encapsulation 1066
Diels — Alder reactions exo/endo selectivity 1064
Diels — Alder reactions frontier-orbital method 1068—1070
Diels — Alder reactions heteroatom 1075
Diels — Alder reactions heteroatom, enantioselectivity 1075
Diels — Alder reactions HOMO and LUMO 1070
Diels — Alder reactions homo Diels — Alder reaction 1063
Diels — Alder reactions HOMO-LUMO interactions 1074
Diels — Alder reactions in aqueous media 1066
Diels — Alder reactions in supercritical  1066
Diels — Alder reactions intramolecular 1066
Diels — Alder reactions inverse electron demand 1067
Diels — Alder reactions Lewis acid catalysis 1065
Diels — Alder reactions mechanism 1066—1067
Diels — Alder reactions normal 1073
Diels — Alder reactions of cyclobutadiene 59
Diels — Alder reactions on alumina 1066
Diels — Alder reactions on zeolites 1066
Diels — Alder reactions orbital overlaps 1074
Diels — Alder reactions photochemical 1065
Diels — Alder reactions rate acceleration 1065—1066
Diels — Alder reactions regioselectivity 1063
Diels — Alder reactions regioselectivity and MO 1064
Diels — Alder reactions retro 1066 1348
Diels — Alder reactions retro, CO extrusion 1347
Diels — Alder reactions retro, in water 1066
Diels — Alder reactions reversibility 1066
Diels — Alder reactions solvent effects 1065
Diels — Alder reactions stereochemistry 1064
Diels — Alder reactions substituent effects 1067
Diels — Alder reactions suprafacial addition 1072
| Diels — Alder reactions twisted 1073
Diels — Alder reactions with anthracene 1063
Diels — Alder reactions with azadienes 1075
Diels — Alder reactions with benzynes 855 1062
Diels — Alder reactions with furans 1075
Diels — Alder reactions with maleic anhydride 1062
Diels — Alder reactions with phenyl vinyl sulfone 1062
Diels — Alder reactions with quinones 1062
Diene alcohols, and the oxy-Cope rearrangement 1445
Diene ketones, and the Nazarov cyclization 1021
Diene, conjugated, from vinylboranes 1425
Dienes addition of carbanions 1018
Dienes and isomerization of double bonds 991
Dienes and orbital symmetry 1428
Dienes and UV absorption 310
Dienes aza see “Azadienes”
Dienes by conjugate elimination 1326
Dienes by coupling of allylic halides 541
Dienes by extrusion of CO 1347
Dienes by isomerization of alkynes 773
Dienes by the Cope rearrangement 1666
Dienes by the Ramberg — Backlund reaction 1342
Dienes by the Stille reaction 931—932 1666
Dienes chiral and the Diels — Alder reaction 1065
Dienes cisoid and the Diels — Alder reaction 1064
Dienes conjugated and reaction with alkyl halides 1047
Dienes conjugated, acylation of 784
Dienes cyclic in the Diels — Alder reaction 1064
Dienes dimerization 1091
Dienes from alkenes 1666
Dienes from alkyne alcohols 1327
Dienes from alkynes 1020 1666
Dienes from alkynes and Schwartz’s reagent 1020
Dienes from allylic halides 1666
Dienes from bicyclobutanes 1460
Dienes from dienes 1437
Dienes from hydrogenation of aromatic compounds 1666
Dienes from pyrolysis of allylic acetates 1330
Dienes from sigmatropic rearrangements of 1,5-dienes 1666
Dienes from thermolysis of 3-sulfolene 1066
Dienes from vinyl boranes 939 1666
Dienes from vinyl Inflates 931
Dienes from vinyltin compounds 931 1666
Dienes gas phase addition of HI 992
Dienes heteroatom, reaction with alkenes 1075
Dienes HOMO and LUMO of 1070
Dienes hydrogenation of 1005
Dienes intramolecular alkene addition 1019
Dienes molecular orbitals of 1070
Dienes photolysis of 1426
Dienes radical addition to 978
Dienes reaction with alkenes 1062—1075
Dienes reaction with boranes 1015
Dienes reaction with carbenes 1985
Dienes reaction with chlorosulfonyl isocyanate 1251
Dienes reaction with heteroatom alkenes 1075
Dienes reaction with organozirconium compounds 1039
Dienes reaction with oxygen 1054
Dienes reaction with silanes 1039
Dienes ring closure, and the frontier orbital method 1429
Dienes transoid and the Diels — Alder reaction 1063
Dienes trimerization of 1091
Dienophiles 1062; also see “Alkenes”
Dienophiles and regioselectivity in the Diels — Alder reaction 1063
Dienophiles chiral in the Diels — Alder reaction 1065
Diesters from alkenes 1049
Diesters reaction with dicarboxylic acids 487
Diethyl azodicarboxylate (DEAD), and formation of allenes 772
Diethyl azodicarboxylate and dehydration of diols 480
Diethyl azodicarboxylate and elimination of hydroxy acids 1346
Diethyl azodicarboxylate and Mitsunobu esterification 486
Diethyl azodicarboxylate in esterification reactions 486
Diethyl diazoacetate, reaction with aldehydes 785
Diethylaminosulfur trifluoride see “DAST”
Diethylene glycol 481
Diethylene glycol as a solvent for  764
Diethylmercury 237
Diethylzinc, and the Simmons — Smith reaction 1089
Diethylzinc, reaction with aldehydes 1211
Differential absorption and resolution 152
Diffusion control and kinetics 279
Difluorides from oximes 1197
Difluoro compounds 1196
Difluoroamine, reaction with amines 530
dig and Baldwin’s rules 283—284
Dihalides and elimination reactions 1343
Dihalides and Friedel — Crafts alkylation 710
Dihalides and the E2reaction 1301
Dihalides and the Wurtz reaction 536
Dihalides by radical halogenation 1666
Dihalides by the haloform reaction 1666
Dihalides elimination 1343
Dihalides formation of Grignard reagents 805
Dihalides from  1666
Dihalides from aldehydes 1195 1666
Dihalides from alkenes 1041 1666
Dihalides from alkyl nitrites 1666
Dihalides from alkynes 992 1666
Dihalides from amines 1666
Dihalides from aryl nitro compounds 1666
Dihalides from epoxides 1666
Dihalides from trihalides 1666
Dihalides from trihalo acids 1666
Dihalides fromketones 1195 1666
Dihalides Grignard reactions of 1206
Dihalides hydrolysis of 463
Dihalides mixed from alkenes 1041
Dihalides reaction with malonate anion 550
Dihalides reaction with sulfide ion 497
Dihedral angle and conformation 168
Dihydrophenanthrene, intermediate in photocyclization of stilbene 1436
Dihydropyran, reaction with alcohols 996
Dihydroquinidines and dihydroxylation of alkenes 1050
Dihydroxylation and kinetic resolution 154
Dihydroxylation catalytic, of alkenes 1049
Dihydroxylation of alkenes 1048—1051
Dihydroxylation of alkenes, diastereoselectivity 1050
Dihydroxylation of alkenes, enantioselectivity 1050
Dihydroxylation of alkenes, with peroxide 1049
Dihydroxylation of aromatic compounds 1050
Dihydroxylation of benzene 1050
Dihydroxylation Sharpless asymmetric 1050
Diimide, dimerization 254
Diimide, reaction of azo compounds 1556
Diimide, reaction with alkenes 1007
Diiodomethane, and the Simmons — Smith reaction 1088
Diions and ketene — imine cycloaddition 1250
Diions in the benzidine rearrangement 1456
Diions in [2+2]-cycloadditions 1080
Diisobutylaluminum hydride see “Dibal”
Diisopinocampheylborane 154 1014
Diisopropyl azodicarboxylate, reaction with alcohols 502
Diisopropylacetylene, trimerization of 1089
Diketones acyl halides 568
Diketones cleavage of 812
Diketones conversion to enol ethers 481
Diketones from alkynes 1523 1540
Diketones from aromatic carboxylic aids 1563
Diketones from bis imidazole of oxalic acid 1215
Diketones from epoxy ketones 1398
Diketones fromketones 1531
Diketones oxidative cleavage 1520
Diketones reaction with hydrazines 1193
Dilongifolylborane 1015
Dimer mechanisms, for  reactions 852
Dimerization in radical addition to alkenes 977
Dimerization of alkanes 926
Dimerization of alkenes 1077
Dimerization of alkynes 927 1020
Dimerization of carbenes 252
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