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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Íàçâàíèå: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Àâòîðû: Smith M.B., March J.

Àííîòàöèÿ:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


ßçûê: en

Ðóáðèêà: Õèìèÿ/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Èçäàíèå: 5-th edition

Ãîä èçäàíèÿ: 2001

Êîëè÷åñòâî ñòðàíèö: 2083

Äîáàâëåíà â êàòàëîã: 21.02.2007

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Favorskii rearrangement      1225 1403—1405
Favorskii rearrangement quasi-Favorskii      1405
Fehling’s solution, oxidation of aldehydes      917
Felkin — Ahn model      148
Felkin — Ahn rule and radical addition to alkenes      981
Fenton’s reagent      916
Fenton’s reagent and alkane dimerization      927
Ferric bromide, catalyst for aromatic halogenation      704
Ferric chloride, catalyst for aromatic halogenation      704
Ferrocene, bonding and aromaticity      54
Ferrocene, stability of      54
Ferrous sulfate and Fenton’s reagent      916
Ferrous sulfate and oxidation of aromatic compounds      916
Field effects      16—18
Field effects and acid strength      342—343
Field effects and carbanions      231
Field effects and carbocations      220
Field effects and electrophilic aromatic substitution      681
Field effects and hybridization      18
Field effects and structure      363
Field effects aromatic amides      364—365
Field effects for aniline      42
Field effects in alkene addition reactions      987
Field effects with radicals      906
Fieser and Fieser      1627
Finkelstein reaction      517
First order reactions      291
Fischer indole synthesis      1452—1453
Fischer projections and erythro/threo nomenclature      147
Fischer projections and the CIP system      141
Fischer projections definition      137
Fischer — Hepp rearrangement      728
Flash photolysis      321
Flash photolysis of bromoform      249
Flash vacuum pyrolysis, of keto ylids      1334
Flnoride ion and the Tamao — Fleming oxidation      482
Flnoride ion reaction with silanes      482
Fluorene $pK_a$      52
Fluorene reaction with organolithium reagents      791
Fluorescence      313—314
Fluorides aryl, by the Balz — Schiemann reaction      875
Fluorides aryl, by the Schiemann reaction      876
Fluorination of aryl diazonium salts      875
Fluorination of hydrocarbons      908
Fluorination of ketones and aldehydes      775
Fluorine and electrophilic aromatic substitution      707
Fluorine reaction with alkenes      1042
Fluoroethane      see “Ethyl fluoride”
Fluoroxytrifluoromethane      908
Fluxional isomerization      160
Fluxional structures in the Cope rearrangement      1447
Forbidden transitions, and photochemistry      308
Force-field calculations      178
Formal steric enthalpy      190
Formaldehyde and paraformaldehyde and trioxane      1245
Formaldehyde in the Mannich reaction      1189
Formaldehyde reaction with aldehydes      1230 1241
Formaldehyde reaction with aromatic compounds and HCl      721
Formaldehyde reaction with ketones      1230
Formaldehyde reaction with Mannich bases      1189—1190
Formaldehyde reaction with phenols and amines      722
Formaldehyde trimerization of      1245
Formamide conformational analysis      171
Formamide rotational analysis      171
Formamides and formylation of alkenes      785
Formamides dehydration      1350
Formamides from amines      506
Formamides from isonitriles      1251
Formamides reaction with alkenes      1034
Formamides reaction with aromatic compounds      715
Formamides reaction with Grignard reagents      1214
Formamides reaction with organolithium reagents      801
Formamides reaction with phosgene      1350
Formamidine, anion and alkylation      558
Formates      see “Esters formate”
Formic acid and the Koch — Haaf reaction      1035
Formic acid reaction with aldehydes and hydroxylamine      1195
Formic acid reaction with Grignard reagents      801
Formic anhydride      508
Formula periodic table      48
Formyl carboxylates, decarboxylation of      573
Formylation and the Duff reaction      717
Formylation and the Vilsmeier reaction      715
Formylation by the Gatterman reaction      715
Formylation by the Gatterman — Koch reaction      716
Formylation by the Reimer — Tlemann reaction      716
Formylation Friedel — Crafts      713—714
Formylation of alkenes      785
Formylation of alkynes      1048
Formylation of amines      511
Formylation of amines, reagents for      820
Formylation of aromatic compounds      715
Formylation of aromatic rings, reagents      717
Fragmentation of alkene alcohols      1351
Fragmentation of bicyclic lactones      1348
Fragmentation reactions      1345
Fragmentation retro Diels — Alder reactions      1348
Franck — Condon principle      312
Free energy      see “Energy”
Free radicals      see “Radicals”
Freezing point depression, and ester hydrolysis      472
Fremy’s salt, and oxidation of alcohols      1515
Fremy’s salt, and oxidation of aromatic diols      1518
Frequency factor      296
Friedel — Crafts acylation      712—714
Friedel — Crafts acylation and Fries rearrangement      726
Friedel — Crafts acylation and polymers      720
Friedel — Crafts acylation and ring closure      713
Friedel — Crafts acylation and ring closure with ketones      720
Friedel — Crafts acylation and the Bischler — Napieralski reaction      721
Friedel — Crafts acylation and the Bradsher reaction      720
Friedel — Crafts acylation and the Haworth reaction      714
Friedel — Crafts acylation formylation      713—714
Friedel — Crafts acylation of alkenes      784
Friedel — Crafts acylation reversibility      732
Friedel — Crafts acylation the Hoesch reaction      722
Friedel — Crafts acylation the Houben — Hoesch reaction      722
Friedel — Crafts acylation with anhydrides      713
Friedel — Crafts acylation with cyclic anhydrides      713—714
Friedel — Crafts acylation with polycyclic aromatics      713
Friedel — Crafts acylation with polyphosphoric acid      713
Friedel — Crafts alkylation      707—711 1379
Friedel — Crafts alkylation and Claisen rearrangement      1452
Friedel — Crafts alkylation and heterocyclic amines      872
Friedel — Crafts alkylation and ion pairs      711
Friedel — Crafts alkylation and polyalkylation      709
Friedel — Crafts alkylation and polycyclic aromatics      709
Friedel — Crafts alkylation and rearrangements      709
Friedel — Crafts alkylation and ring closure      710
Friedel — Crafts alkylation and the Hofmann — Martius reaction      729
Friedel — Crafts alkylation of alkenes      708 1017
Friedel — Crafts alkylation with dihalides      710
Friedel — Crafts arylation      711
Friedel — Crafts arylation and the Scholl reaction      711
Friedel — Crafts catalysts      708
Friedel — Crafts catalysts and addition of alkyl halides to alkenes      1047
Friedel — Crafts catalysts and dehalogenation of aryl halides      735
Friedel — Crafts catalysts and sulfonylation reactions      704
Friedel — Crafts catalysts and sulfurization      703
Friedelene      1395
Friedlander quinoline synthesis      1186
Fries rearrangement      725
Fries rearrangement crossover experiments      727
Fries rearrangement photo      see “Photo-Fries”
Frontier orbital methods and Diels — Alder reactions      1068—1070
Frontier orbital methods and electrocyclic rearrangements      1428
Frontier orbital methods and ring closure of dienes      1429
Frontier orbital methods and sigmatropic rearrangements      1438
FSE      see “Formal steric enthalpy”
Fullerenes and aromaticity      70—71
Fullerenes and corannulene      71
Fullerenes and rotaxanes      114
Fullerenes and the ene reaction      1021
Fumaric acid, properties      159
Functional groups and field effects      17
Functional groups categorized by oxidation state      1507
Functional groups ease of reduction      1545—1546
Furan and aromaticity      51
Furan electrophilic aromatic substitution      688
Furan resonance energy      51
Furans from 1,4-diketones      1181
Furans hydrolysis of      468
Furans in Diels — Alder reactions      1075
Fused ring aromatics, and electrophilic aromatic substitution      689—690
Fused ring compounds, cis/trans isomers      161—163
Fuson-type enols      74
Gabriel synthesis      500 513 864
Gas phase reactions, of esters      473
Gas phase, acidity      350
Gatterman amide synthesis      718
Gatterman method      937
Gatterman reaction      715 936
Gatterman — Koch reaction      716
Gatterman — Koch reaction reverse      732
Gauche conformation      169 184
Gauche conformation and cyclohexane derivatives      174
Gauche conformation and reactivity      366
Gauche conformation solvent effects      170—171
Gauche effect      170
Geared molecules      189
Gegenion, definition      219
Gem dihalides      see “Dihalides”
Gem-difluoro compounds      1196
Gem-dinitriles, reduction to nitrile      528
Gem-diols      see “Hydrates”
General acid catalysis      337
General catalysis      336—337
General catalysis gerade and photochemistry      309
Gif system      1533
Gilman reagents      539; see “Organocuprates”
Girard’s reagent P or T, reaction with aldehydes or ketones      1193
Glaser reaction      927
Glyceraldehyde and absolute configuration      138
Glyceraldehyde and x-ray analysis      139
Glycidic acids, decarboxylation of      809
Glycidic esters      1230
Glycidic esters by the Darzens reactions      1670
Glycidic esters from $\alpha$-halo esters      1670
Glycidic esters from $\alpha,\beta$-unsaturated esters      1670
Glycidic esters from aldehydes      1670
Glycidic esters from amides      1670
Glycidic esters from amines      1670
Glycidic esters from ketones      1670
Glycols      see “Diols”
Glyoxals, and the benzoin condensation      1243
Goldberg reaction      864 928
Gomberg — Bachmann pinacol synthesis      928 1560
Graphite ribbons      see “Phenacenes”
Grignard reactions      1205—1209
Grignard reactions and ESR      1208
Grignard reactions chemoselectivity      1206
Grignard reactions formation of diols      1208
Grignard reactions intramolecular      1206
Grignard reactions with dihalides      1206
Grignard reagents addition to alkenes      1017
Grignard reagents addition to aromatic compounds      1030
Grignard reagents addition to C=N compounds      1216
Grignard reagents and CIDNP      806
Grignard reagents and conjugate addition      1028
Grignard reagents and enolization      1207
Grignard reagents and ether solvents      546
Grignard reagents and inversion of configuration      236
Grignard reagents and NMR      235—236
Grignard reagents and optical activity      762
Grignard reagents and radicals      806
Grignard reagents and reduction      1207
Grignard reagents and solvents      806
Grignard reagents and the Bouveault reaction      1214
Grignard reagents and the Schlenk equilibrium      234
Grignard reagents and the SET mechanism      1208
Grignard reagents and transmetallation      803
Grignard reagents and xray diffraction      235
Grignard reagents bonding      234
Grignard reagents by hydrogen-metal exchange      807
Grignard reagents comparison with the Reformatsky reaction      1213
Grignard reagents coupling reactions      535 938
Grignard reagents coupling with alkyl halides, reagents for      537
Grignard reagents coupling with allylic alcohols      545
Grignard reagents coupling with phosphonic esters      544
Grignard reagents coupling with sulfonate esters      543
Grignard reagents dialkylmagnesiums      235
Grignard reagents dimerization of      938
Grignard reagents formation of      805
Grignard reagents from alkyl halides      805
Grignard reagents from aryl halides      805
Grignard reagents from dihalides      805
Grignard reagents halogenation of      798
Grignard reagents ketyl intermediates      1208
Grignard reagents mechanism of formation      806
Grignard reagents mechanism of reaction      1208
Grignard reagents reaction with $(ArCH=N)_2SO_2$      1216
Grignard reagents reaction with $CO_2$      1215
Grignard reagents reaction with $CS_2$      1215
Grignard reagents reaction with acetals      545
Grignard reagents reaction with acid      736
Grignard reagents reaction with acid derivatives      1214
Grignard reagents reaction with acyl halides      567
Grignard reagents reaction with air and water      806
Grignard reagents reaction with alcohols      526
Grignard reagents reaction with aldehydes      1205—1209
Grignard reagents reaction with alkynes      791
Grignard reagents reaction with allylic amines      1025
Grignard reagents reaction with allylic epoxides      547
Grignard reagents reaction with allylic ethers      546
Grignard reagents reaction with amino ethers      546
Grignard reagents reaction with anhydrides      567
Grignard reagents reaction with aryl oxazolines      868
Grignard reagents reaction with aziridines      548
Grignard reagents reaction with benzil      1208
Grignard reagents reaction with bromohydrins      1399
Grignard reagents reaction with cadmium chloride      566
Grignard reagents reaction with carbamates      568
Grignard reagents reaction with di-sec-butylmercury      761
Grignard reagents reaction with epoxides      546
Grignard reagents reaction with esters      567 1214
Grignard reagents reaction with ethoxy lactams      546
Grignard reagents reaction with formamides      1214
Grignard reagents reaction with formic acid      801
Grignard reagents reaction with halo nitriles      1217
Grignard reagents reaction with iminium salts      1216
Grignard reagents reaction with iodine      798
Grignard reagents reaction with iron pentacarbonyl      801
Grignard reagents reaction with isocyanates      1217
Grignard reagents reaction with isonitriles      1252
Grignard reagents reaction with isothiocyanates      1218
Grignard reagents reaction with ketals      545
Grignard reagents reaction with nitriles      1217
Grignard reagents reaction with ortho esters      545
Grignard reagents reaction with oxazine iminium salts      559
Grignard reagents reaction with oxygen      795
Grignard reagents reaction with peroxides      796
Grignard reagents reaction with propargyl ethers      546
Grignard reagents reaction with quinones      1205
Grignard reagents reaction with silyl enol ethers      546
Grignard reagents reaction with sulfonate esters      574
Grignard reagents reaction with sulfonyl chlorides      577—578
Grignard reagents reaction with sulfur      797
Grignard reagents reaction with sulfuryl chloride      797
Grignard reagents reaction with vinyl epoxides      547
Grignard reagents reaction with vinyl ethers      546
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