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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Plane-polarized light, and optical activity      126—127 143—144
Platinum catalyst and hydrogenation of aldehydes or ketones      1198
Platinum catalyst for hydrogenation      1003
Podands      106—107
Podands, as phase transfer catalysts      456
Polar radicals      902
Polarity, of solvent, and rate of reaction      450
Polarized light and reactions      150
Polarized light circularly polarized      143
Polarized light plane      126—127 143—144
Polyalkylation, in Friedel — Crafts alkylation      709
Polycyclic aromatics and Friedel — Crafts acylation      713
Polycyclic aromatics electrophilic aromatic substitution      688—690
Polycyclic small ring compounds, and strain      182—183
Polyenes cationic cyclization      1019
Polyenes radical cyclization      1020
Polyethylene glycol monomethyl ether and ammonium salt pyrolysis      1333
Polyhydrogen fluoride-pyridine and preparation of acyl fluorides      524
Polyhydrogen fluoride-pyridine solvent      519
Polymer-supported synthesis      509
Polymerization and the Kobe reaction      942
Polymerization and the Robinson annulation      1223
Polymerization in the Diels — Alder reaction      1065
Polymerization of imines      1186
Polymers and Friedel — Crafts acylation      720
Polymers and oxidation of alcohols      1515
Polymers Bakelite      720
Polymers from aldehyde addition to alkenes      1034
Polyphosphoric acid      720
Polyphosphoric acid and Friedel — Crafts acylation      713
Polyphosphoric acid reaction with alkene-alcohols      773
Polyurethanes      1183
Potassium amide      see “Amide potassium”
Potassium cyanide      see “Cyanide”
Potassium f-butoxide      see “Butoxide”
Potassium nitrite, reaction with amines      494
Potassium permanganate      see “Permanganate”
Potassium phthalimide      see “Phthalimide”
Potassium superoxide      492
Potassium thiocyanate      see “Thiocyanate’
Potassium triisopropoxyborohydride, and reactions of borane and CO      1424
Potassium, reaction with aryl diethyl phosphates and $KNH_2$      866
Potential energy, and molecular mechanics      179
Pressure, and chemical reactivity      457—458
Pressure, high      see “High pressure”
Prevost method, Woodward modification      1050
Prevost reaction      1049
Prilezhaev reaction      1052
Primary isotope effects      298
Primary sources in literature      1605
Principle of conservation of orbital symmetry      1068
Principle of imperfect synchronization      334
Principle of least motion      1011
Principle of microscopic reversibility      286
Prins reaction      1047 1241
Prins reaction with oxetanes      1241
Prismane      182—183 1449
pro-R and pro-S nomenclature      165
Prochiral centers, and carbanions      233
Prochiral substrates, and catalytic hydrogenation      1003
Prochiral, definition      165
Product spread      421
Propane, bond energy      23
Propargyl cations      222
Propargyl compounds, and allylic rearrangement      423
Propargyl halides coupling      543
Propargyl halides reaction with $LiAlH_4$      525
Propellanes      182—183
Propeller shape, and radicals      244
Protecting groups for amines      697
Protecting groups MEM      478
Protecting groups MOM      478
Protic solvents      450
Proton acceptors, and Bronsted theory      327
Proton donors, and Bronsted theory      327
Proton sponges, base strength      347
Proton-shift tautomerism      75—76 (also see “Tautomerism”)
Protonation enantioselective, of enolate anions      794
Protonation of enolate anions      976
Protonation of vinylboranes      1425
Prototropic rearrangements      771 1377
Pschorr ring closure      929
Pseudo-first order      390
Pseudo-first order mechanisms      293
Pseudoasymmetric carbons      145
Pseudoaxial and pseudoequatorial      178
Pseudomonas putida, and dihydroxylation of aromatic compounds      1050
Pseudorotation and ring conformation      178
Pseudorotation in aromatic hydrocarbons      44
Pummerer rearrangement      1566
Push-pull compounds, and cis/trans isomers      159
Push-pull effect and resonance      60
Push-pull effect in radicals      242
Py scale, and solvent polarity      454
Pyramidal inversion      129
Pyramidal shape and carbanions      232
Pyramidal shape and radicals      244
Pyran      48
Pyran and the anomeric effect      176—177
Pyrazoles extrusion reactions      1353
Pyrazoles from diketones      1193
Pyrazolines extrusion of nitrogen      1353
Pyrazolines from keto esters      1193
Pyridine and aromaticity      48
Pyridine and chromium, Collins’ reagent      1514
Pyridine and electrophilic aromatic substitution      689
Pyridine as a nucleophilic catalyst      576
Pyridine base strength      350
Pyridine eduction with samarium iodide      1011
Pyridine N-oxides, and the Boekelheide reaction      421
Pyridine reaction with amide anion      873
Pyridine reaction with organolithium reagents      871
Pyridines 2-hydroxy, from pyridine N-oxides      1421
Pyridines from pyrroles      1088
Pyridines oxidation of alcohols      1514
Pyridines reaction with carboxylic aids      933
Pyridinium chlorochromate      1531
Pyridinium compounds, as leaving groups      447
Pyridinium dichromate, oxidation of alcohols      1514
Pyridinium ions and E1cB elimination      1311
Pyridinium ions and electrophilic aromatic substitution      689
Pyridinium-N-phenolbetamine, electronic peaks      454
Pyridone thiols, and tautomerism      76
Pyridone, and tautomerism      76
Pyrocalciferols      1432
Pyroglutamate, ethyl ester, N-alkylation      457
Pyrolysis      also see “Thermochemistry”
Pyrolysis of 1-chlorocyclopropene      1400
Pyrolysis of alkyl azides      1412
Pyrolysis of amme oxides      1333
Pyrolysis of carboxylic acids      1327
Pyrolysis of carboxylic acids with $THO_2$      573
Pyrolysis of cyclic sulfones      1354—1355
Pyrolysis of enol ethers      1329
Pyrolysis of esters      1329
Pyrolysis of hydroxy alkenes      1351
Pyrolysis of ketoylids      1334
Pyrolysis of lactones      1330
Pyrolysis of sulfoxides      1336
Pyrrole and aromaticity      51
Pyrrole base strength      350
Pyrrole electrophilic aromatic substitution      689
Pyrrole resonance energy      51
Pyrroles from amines      1000
Pyrroles from diynes      1000
Pyrroles reaction with carbenes      1087
Pyrrolidines by the Hofmann — Loeffler reaction      1462
Pyrrolidines from aziridines      1061
Pyrrolidinone 5-carboethoxy, N-alkylation      457
Pyrrolines, from amino ketones      1186
Pyrylium ions and aromaticity      48
Pyrylium ions as leaving groups      447
Pyrylium ions reaction with ammonia or amines      1186
Quadricyclane      1082 1083
Quadropole echo spectroscopy, and urea      110
Quantum yield and radicals      896
Quantum yield definition      322
Quasi — Favorskii rearrangement      1405
Quasi — Favorskii rearrangement and pinacol rearrangement      1405
Quaternary ammonium salts      see “Ammonium salts”
Quaterphenyl      898
Quinines and the Paterno — Biichi reaction      1249
Quinines reaction with carboxylic acids      933
Quinoline $pK_a$      347
Quinoline and electrophilic aromatic substitution      689
Quinoline methylation of      872
Quinoline photochemical alkylation      934
Quinolines by the Friedlander quinoline synthesis      1186
Quinolines fromindoles      1088
Quinones by Fremy’s salt oxidation      1518
Quinones by Friedel — Crafts acylation      1686
Quinones from aromatic amines      1686
Quinones from aromatic diols      1517—1518
Quinones from aromatic hydrocarbons      1686
Quinones from hydroquinones      1511
Quinones from phenols      1686
Quinones from polycyclic aromatics      1535
Quinones in the Diels — Alder reaction      1062
Quinones reaction with Grignard reagents      1205
Quinones reduction of      1198 1548
Quino[7,8-h]quinoline      347
r and c nomenclature      161
Racemates      see “Enantiomers racemates”
Racemic mixture, and enantiotopic faces      166
Racemic mixtures      see “Enantiomers racemates”
Racemization and ion pairs      399—400
Racemization and keto-enol tautomerism      774
Racemization and radical substitution      897
Racemization and the $S_E1$ reaction      763
Radical addition      also see “Addition radical”
Radical addition, to alkenes      977—979
Radical cations aminium      909
Radical cations and the benzidine rearrangement      1456
Radical chain reaction, and pyrolytic elimination      1324
Radical cyclization      also see “Cyclization radicals”
Radical cyclization and Baldwin’s rales      1040
Radical cyclization iodo-ester alkenes      1047
Radical ions      247 901
Radical ions and Birch reduction      1010
Radical ions and formation of Griguard reagents      806
Radical ions and the SET mechanism      402—404
Radical probes, and SET mechanisms      403
Radical, aromatic substitution      897—899
Radical, aryl, rearrangement intermediate      1390
Radical, definition      238
Radical, halogenation and dicarboxylic acids      909
Radical, halogenation and the Hofmann — Loeffler reaction      909
Radical, initiator, and addition of aldehydes to alkenes      1034
Radical, mechanism      275
Radicals      also see “Cyclization radicals”
Radicals and acyloxylation of hydrocarbons      923
Radicals and addition of alkanes to alkenes      1017
Radicals and addition of alkyl halides to alkenes      1039
Radicals and addition of HBr to alkenes      991
Radicals and addition of thiols to alkenes      998
Radicals and addition to alkenes by silane tethers      1032
Radicals and AIBN initiation      912
Radicals and all carbon [3+2]-cycloadditions      1076
Radicals and aminium radical ions      701
Radicals and arylation of aryl halides      933
Radicals and autoxidation      920—921
Radicals and Bergman cyclization      1432
Radicals and Birch reduction      1010
Radicals and bond dissociation energy      900 911
Radicals and captodative effect      242
Radicals and carbene insertion reactions      790
Radicals and chain reactions      895
Radicals and coupling of aryl halides with enolate anions      870
Radicals and cyclization      403
Radicals and decarbonylation aldehydes      944
Radicals and dehydrohalogenation      1337
Radicals and disproportionation      246
Radicals and electron withdrawing substituents      902
Radicals and ESR      239
Radicals and formation of Griguard reagents      806
Radicals and hyperconjugation      241
Radicals and inhibitors      896
Radicals and Meerwein arylation      930
Radicals and Michael addition      1024
Radicals and NMR      239
Radicals and Norrish cleavage      318—319
Radicals and optical activity      244
Radicals and oxidative decarboxylation      1529
Radicals and photochemical dimerization of ketones      1560
Radicals and photochemistry      312
Radicals and push-pull effects      242
Radicals and pyrolytic elimination      1324
Radicals and quantum yield      896
Radicals and reaction of aromatic compounds with acylperoxides      932
Radicals and reaction of aryl diazonium salts with water      874
Radicals and remote oxidation      1513
Radicals and resonance stabilization      241—242
Radicals and ring enlargement      1400
Radicals and SET mechanisms      239 402—404
Radicals and steric effects      900
Radicals and the Barton reaction      1463
Radicals and the Cope rearrangement      1447
Radicals and the Gif system      1533
Radicals and the Hofmann — Loeffler reaction      1462
Radicals and the Kolbe reaction      942
Radicals and the Paterno — Bilchi reaction      1249
Radicals and the SrnI mechanism      856
Radicals and the Stevens rearrangements      1420
Radicals and thiohydroxamic esters      942
Radicals and triplets      245
Radicals aryl      904
Radicals aryl, and electron withdrawing groups      905
Radicals aryl, and ipso substitution      905
Radicals aryl, complex formation      906
Radicals aryl, partial rate factors      905
Radicals aryl, substituent effects      904
Radicals as initiators      896
Radicals as intermediates      288
Radicals benzylic      902
Radicals benzylic and radical bromination      912
Radicals bonding      244
Radicals bridged      899
Radicals bridgehead      244*
Radicals bromine, reaction with trichloropropene      1391
Radicals cation, and the Diels — Alder reaction      1065
Radicals chain reaction and substitution      403
Radicals chain reactions, initiation step      894
Radicals chain reactions, propagation steps      246 895
Radicals chain reactions, termination steps      246 894
Radicals cubylcarbinyl      1390
Radicals cyclopropylcarbinyl      901
Radicals decomposition of      246
Radicals destruction of      894
Radicals diand rearrangement      1390
Radicals dimerization      242
Radicals diradicals      244
Radicals diradicals and cyclopropane rearrangement      1400
Radicals dissociation energy, table      243
Radicals electrophilic      987
Radicals enolate      242
Radicals fate of      245—247
Radicals formation by photochemistry      318
Radicals from azo compounds      245
Radicals from carbanions      238
Radicals from peroxides      245
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