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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Hydrolysis of borates      796
Hydrolysis of Bunte salts      495 498
Hydrolysis of carbaniates      474
Hydrolysis of cyanohydrins      1179
Hydrolysis of diazo ketones      465
Hydrolysis of dihalides      463
Hydrolysis of enamines      1178
Hydrolysis of enamines in the Thorpe reaction      1238
Hydrolysis of enol esters      474
Hydrolysis of enol ethers      465
Hydrolysis of enol ethers, isotope effects      468
Hydrolysis of enol ethers, isotopic labeling      467
Hydrolysis of enol ethers, mechanism      467
Hydrolysis of epoxides      468
Hydrolysis of epoxides, at high pressure      468
Hydrolysis of epoxides, selectivity with Co-salen catalysts      468
Hydrolysis of epoxides, with enzymes      468
Hydrolysis of esters      371 469—474 1050
Hydrolysis of esters thioethers      1566
Hydrolysis of esters, and freezing point depression      472
Hydrolysis of esters, and microwaves      470
Hydrolysis of esters, and oxygen labeling      425
Hydrolysis of esters, and ring strain      473
Hydrolysis of esters, enzymatic      470
Hydrolysis of esters, isotope effects      472
Hydrolysis of esters, mechanism      470—473
Hydrolysis of esters, phase transfer catalysis      470
Hydrolysis of esters, radiolabeling      472
Hydrolysis of esters, reagents      470
Hydrolysis of esters, saponification      470
Hydrolysis of furans      468
Hydrolysis of hemiacetals      1419
Hydrolysis of hydrazones      1177
Hydrolysis of imine salts      1217
Hydrolysis of imines, to aldehydes      532
Hydrolysis of iminium salts      787 1183
Hydrolysis of inorganic esters      464
Hydrolysis of isothiocyanates      1178
Hydrolysis of ketene dithioketals      468
Hydrolysis of lactones      470
Hydrolysis of nitriles      1179
Hydrolysis of nitro compounds      1178
Hydrolysis of nitrobenzamides      428
Hydrolysis of organometallic compounds      794
Hydrolysis of oximes      938 1177
Hydrolysis of phthalamic acid      427
Hydrolysis of Schiff bases      1177
Hydrolysis of sulfonamides      576
Hydrolysis of sulfonate esters      575
Hydrolysis of sulfonic anhydrides      575
Hydrolysis of sulfonyl chlorides      575
Hydrolysis of thioacetals      467
Hydrolysis of thiocyanates      1179
Hydrolysis ofimines      552 1177 1536
Hydrolysis ofisocyanates      1178 1411
Hydron donor      352
Hydroperoxide anion oxidation of boranes      1016
Hydroperoxide anion reaction with alkyl halides      492
Hydroperoxide anion reaction with boranes      797
Hydroperoxide anion reaction with conjugated compounds      1053
Hydroperoxide anion reaction with conjugated ketones      1509
Hydroperoxides acyl, preparation of      492
Hydroperoxides and DCC, oxidation of carboxylic acids      1542
Hydroperoxides by autoxidation      920
Hydroperoxides from acyl halides      1673
Hydroperoxides from alkenes      1673
Hydroperoxides from alkyl halides      492 1673
Hydroperoxides from autoxidation      1673
Hydroperoxides from Grignard reagents      795
Hydroperoxides from hydrocarbons      920
Hydroperoxides from organometallic reagents      1673
Hydroperoxides from singlet oxygen      1673
Hydroperoxides hydrogenation of      1558
Hydroperoxides reaction with acid      1418
Hydroperoxides reaction with hydrocarbons      922
Hydroperoxides rearrangement of      1418
Hydroperoxides reduction with $LiAlH_4$      1558
Hydroperoxides reduction with $PPh_3$      1558
Hydroquinones and clathrates      110—111
Hydroquinones aromatization reagents      1511
Hydroquinones from reduction of quinones      1198
Hydroxamic acids from acyl halides      507 1673
Hydroxamic acids from esters      510 1673
Hydroxamic acids from hydroxy lamine      1673
Hydroxamic acids from rritro compounds      1673
Hydroxamic acids intermediates in the Nef reaction      1179
Hydroxamic acids O-acyl, rearrangement with base      1413
Hydroxamic acids reaction with aromatic compounds      702
Hydroxide, in the aldol reaction      1218
Hydroxide, reaction with alkyl halides      463
Hydroxy acids by the Favorskii rearrangement      1673
Hydroxy acids conversion to lactones      484
Hydroxy acids decarboxylation      1346
Hydroxy acids from aldehydes      1673
Hydroxy acids from aromatic compounds      1673
Hydroxy acids from aryl iodides      1673
Hydroxy acids from carboxylic acids      1673
Hydroxy acids from cyanohydrins      1673
Hydroxy acids from diethyl oxomalonate      1673
Hydroxy acids from keto aldehydes      1673
Hydroxy acids from ketones      1673
Hydroxy acids from lactones      1673
Hydroxy acids from phenols      1673
Hydroxy acids from rearrangement of $\alpha,\beta$-epoxy ketones      1673
Hydroxy acids from rearrangement of benzils      1673
Hydroxy acids from zinc carboxylates      1673
Hydroxy aldehydes by the acyloin condensation      1674
Hydroxy aldehydes by the aldol condensation      1674
Hydroxy aldehydes by the benzoin condensation      1674
Hydroxy aldehydes by the Fries rearrangement      1674
Hydroxy aldehydes by the Knoevenagel reaction      1674
Hydroxy aldehydes by the Mukaiyama aldol reactions      1674
Hydroxy aldehydes by the Tollens reaction      1674
Hydroxy aldehydes from aldehydes      1218—1223 1674
Hydroxy aldehydes from alkenes      1674
Hydroxy aldehydes from dithiane salts      1673
Hydroxy aldehydes from enamines      1674
Hydroxy aldehydes from epoxides      1673 1674
Hydroxy aldehydes from esters      1674
Hydroxy aldehydes from formaldehyde      1674
Hydroxy aldehydes from halo aldehydes      1535
Hydroxy aldehydes from halo ketones      1674
Hydroxy aldehydes from imine anions      1222
Hydroxy aldehydes from imines      1674
Hydroxy aldehydes from ketones      1222 1674
Hydroxy aldehydes from oxazines      1674
Hydroxy aldehydes from rearrangement of $\alpha$-hydroxy aldehydes      1674
Hydroxy aldehydes from rearrangement of epoxy silyl ethers      1674
Hydroxy aldehydes from rearrangement of ketones      1674
Hydroxy aldehydes from rearrangement of phenolic esters      1674
Hydroxy aldehydes oxidative cleavage      1520
Hydroxy aldehydes reaction with hydrazines      1193
Hydroxy aldehydes rearrangement of      1401
Hydroxy alkylation and the Lederer — Manasse reaction      719
Hydroxy alkylation of aromatic rings      719
Hydroxy amides from aldehydes or ketones, zinc, and halo amides      1674
Hydroxy amides from alkenes      1056
Hydroxy amides from amides      1674
Hydroxy amides from silyloxy isocyanides      1674
Hydroxy amines by the Bamberger rearrangement      1674
Hydroxy amines from aldehydes      1674
Hydroxy amines from alkenes      1674
Hydroxy amines from amides      1674
Hydroxy amines from amines      1674
Hydroxy amines from ammonia      1674
Hydroxy amines from epoxides      1674
Hydroxy amines from imines      1674
Hydroxy amines from isocyanides      1674
Hydroxy amines from ketones      1674
Hydroxy amines from O-methyl oximes      1674
Hydroxy amines from oxetanes      1674
Hydroxy amines from phenols      1674
Hydroxy amines from rearrangement of aryl hydroxylamines      1674
Hydroxy amines reaction with nitrous acid      1399
Hydroxy benzoic acids, $pK_a$      346
Hydroxy esters alcoholysis of lactones      487
Hydroxy esters by the Baylis — Hillman reaction      1675
Hydroxy esters by the Reformatsky reaction      1212 1675
Hydroxy esters from $\alpha$-halo esters      1675
Hydroxy esters from $\alpha$-metalated esters to ketones      1675
Hydroxy esters from aldehydes      1223 1675
Hydroxy esters from conjugated alkenes      1675
Hydroxy esters from epoxides      1674
Hydroxy esters from esters      1223 1674 1675
Hydroxy esters from ketones      1223 1675
Hydroxy esters from transesterification of lactones      1674
Hydroxy ethers as solvents      481
Hydroxy ethers from alcoholysis of epoxides      481 1675
Hydroxy ketones by sulfonyloxaziridines      916
Hydroxy ketones by the acyloin condensation      1674
Hydroxy ketones by the aldol condensation      1674
Hydroxy ketones by the benzoin condensation      1243 1674
Hydroxy ketones by the Fries rearrangement      1674
Hydroxy ketones by the Knoevenagel reaction      1674
Hydroxy ketones by the Mukaiyama aldol reaction      1674
Hydroxy ketones by the Tollens reaction      1674
Hydroxy ketones from $\alpha$-diketones      1674
Hydroxy ketones from aldehydes      1674
Hydroxy ketones from alkenes      1674
Hydroxy ketones from diazo ketones      1673
Hydroxy ketones from dithiane salts      1674
Hydroxy ketones from enamines      1674
Hydroxy ketones from epoxides      1674
Hydroxy ketones from epoxy alcohols      1398
Hydroxy ketones from esters      1674
Hydroxy ketones from formaldehyde      1674
Hydroxy ketones from halo ketones      1535 1674
Hydroxy ketones from imines      1674
Hydroxy ketones from ketones      1207 1218—1223 1533 1674
Hydroxy ketones from organolithium reagents      1207 1674
Hydroxy ketones from oxazines      1674
Hydroxy ketones from rearrangement of $\alpha$-hydroxy aldehydes      1674
Hydroxy ketones from rearrangement of epoxy silyl ethers      1674
Hydroxy ketones from rearrangement of ketones      1674
Hydroxy ketones from rearrangement of phenolic esters      1674
Hydroxy ketones oxidative cleavage      1520
Hydroxy ketones preparation of      916
Hydroxy ketones reaction with dimethyldioxirane      916
Hydroxy ketones reaction with hydrazines      1193
Hydroxy ketones rearrangement of      1401
Hydroxy nitriles from aldehydes      1675
Hydroxy nitriles from epoxides      1675
Hydroxy nitriles from halo nitriles      1675
Hydroxy nitriles from ketones      1675
Hydroxy nitriles from nitriles      1675
Hydroxy pyridine, and tautomerism      76
Hydroxy silanes, by the Peterson alkenylation reaction      1228
Hydroxy sulfonic acids, from bisulfite addition to aldehydes      1675
Hydroxy sulfonic acids, from bisulfite addition to ketones      1675
Hydroxy thioethers      481
Hydroxy thioethers from alkenes      1055
Hydroxy thioethers from epoxides and thiolate ions      1675
Hydroxy thioethers from thioalkylation of phenols      1675
Hydroxy thiols from addition of $H_2S$ to aldehydes      1675
Hydroxy thiols from addition of $H_2S$ to ketones      1675
Hydroxy thiols from epoxides and NaSH      1675
Hydroxy thiols from hydroxysulfenylation of alkenes      1675
Hydroxylamine reaction with acyl halides      507
Hydroxylamine reaction with aldehydes and formic acid      1195
Hydroxylamine reaction with aldehydes or ketones      1194
Hydroxylamine reaction with esters      510
Hydroxylamine-O-sulfonic acid reaction with acyl halides      1413
Hydroxylamine-O-sulfonic acid reaction with amines      530
Hydroxylamines aromatic, reaction with acids      878
Hydroxylamines by the Cope reaction      1675
Hydroxylamines by the Meisenheimer rearrangement      1675
Hydroxylamines from alkenes      1675
Hydroxylamines from cleavage of amine oxides      1675
Hydroxylamines from nitro compounds      1553 1554 1675
Hydroxylamines from organolithium reagents      1675
Hydroxylamines from oxetanes      506
Hydroxylamines from oxidation of amines      1675
Hydroxylamines from oximes      1203 1675
Hydroxylamines from rearrangement of N-oxides      1675
Hydroxylamines O-substituted, by Meisenheimer rearrangement      1420
Hydroxylamines O-substituted, from amine oxides      1420
Hydroxylamines reaction with nitroso compounds      819
Hydroxylamines rearrangement of      878
Hydroxylamines reduction with Zn/HCl      1554
Hydroxylation of aromatic compounds      724
Hydroxylation of aromatic compounds, by the Elbs reaction      724
Hydroxylation of ketones, reagents for      916
Hydroxylation of silanes      482
Hydrozirconation, of alkenes      1016
Hyperconjugation      39 71—73
Hyperconjugation and addition to alkenes      987
Hyperconjugation and carbocations      220
Hyperconjugation and isotope effects      299
Hyperconjugation and radicals      241
Hyperconjugation and the anomeric effect      177
Hyperconjugation and the Baker — Nathan effect      72
Hyperconjugation and the resonance effect      363
Hyperconjugation double      220
Hyperconjugation isovalent      73
Hyperconjugation sacrificial      73
Hypervalent iodine      see “Iodine”
Hypobromite, sodium reaction with amides      1411
Hypobromite, sodium reaction with amines      819
Hypobromous acid, reaction with alkenes      1044
Hypochlorite, sodium oxidative cleavage of cyclic ketones      1522
Hypochlorite, sodium reaction with ammonia and boranes      799
Hypochlorites reaction with alkenes      1044
Hypochlorites sodium, reaction with amines      819
Hypochlorous acid, reaction with alkenes      1043
Hypoiodous acid, reaction with alkenes      1044
Hypophosphorus acid      45
Hypophosphorus acid reaction with aryl diazonium salts      934
Hypostrophene      1448
I Effect      also see “Field effects”
I effect +I and-I effects      17—18
I effect and electrophilic aromatic substitution      682—683
I effect stabilization of Wheland intermediates      682—683
I strain      366 (also see “Strain”)
I strain and hydrates      1176
I strain and nucleophilic substitution      437
Imidates, reaction with amines      510
Imidazoles, reaction with $LiAlH_4$      534
Imidazoles, reduction      534
Imidazolide amides, reaction with alcohols      488
Imides by the Curtius rearrangement      1676
Imides by the Hofmann rearrangement      1676
Imides from acyl halides      514 1675
Imides from alkenes      1676
Imides from amides      1676
Imides from amines      508
Imides from anhydrides      508 1675
Imides from imides      1676
Imides from lactams      1676
Imides from rearrangement of acyl azides      1676
Imides from unsaturated amides      1676
Imides reaction with alkenes      1002
Imides reaction with alkynes      1002
Imides reaction with phosphorus ylids      1237
Imidines, from dinitriles      1192
Imido selenium compounds, reaction with alkenes      782
Imido sulfur compounds, reaction with alkenes      782
Imine anions, reaction with aldehydes      1222
Imine salts from bicyclic amines      1512
Imine salts from isocyanates and Grignard reagents      1217
Imine salts from nitriles and Grignard reagents      1217
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