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| Авторизация |
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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Cyclopentane, conformation 177
Cyclopentane, conformational energy barrier 178
Cyclopentanols, from dimagnesium compounds and esters 1214
Cyclopentanone, conformation 178
Cyclopentenes, from vinylcyclopropanes 1443
Cyclopentenone 321
Cyclopentyne 1160 (ref. 1316) 1392
Cyclopentyne derivatives 187
Cyclophane, “belt” 44
Cyclopolyacenes 67
Cyclopropane and bent bonds 181
Cyclopropane and bonding 181
Cyclopropane and cation rearrangements 1382
Cyclopropane and strain 180—181
Cyclopropane angle strain 181
Cyclopropane cations and allylic cations 1399
Cyclopropane conformation 177
Cyclopropane intermediates, in the Claisen rearrangement 1451
Cyclopropane orbital overlap 181
Cyclopropane protonated intermediates 1382
Cyclopropane reaction with HBr 988
Cyclopropane vinyl, by di  -methane rearrangements 1460
Cyclopropane vinyl, [1,3]-sigmatropic rearrangement 1443
Cyclopropanes addition of radicals 990
Cyclopropanes addition reactions 988—990
Cyclopropanes and homodienyl [1,5]-H sigmatropic rearrangements 1440
Cyclopropanes and Markovnikov’s rale 989
Cyclopropanes by extrusion from pyrazolines 1353
Cyclopropanes by the Simmons — Smith reaction 1088
Cyclopropanes divinyl, Cope rearrangement 1445 1446
Cyclopropanes electrophilic addition, ab initio studies 990
Cyclopropanes from alkenes and carbenes 789
Cyclopropanes from carbenes 248
Cyclopropanes from cyclobutanones 1354
Cyclopropanes from diols 544
Cyclopropanes from metal carbenes 1086
Cyclopropanes from sulfur ylids with aldehydes or ketones 1247
Cyclopropanes hydrogenation of 1012
Cyclopropanes reaction with HX 989
Cyclopropanes relationship to alkene reactivity 988
Cyclopropanes vinyl, from 1,4-dienes 1460
Cyclopropanone, and UV spectra 181
Cyclopropenes 186
Cyclopropenes by extrusion from pyrazoles 1353
Cyclopropenes reaction with chlorosulfonyl isocyanate 1251
Cyclopropenes vinyl 1443
Cyclopropeniumyldiazonium salts 448
Cyclopropenone 58
Cyclopropenyl anion, and antiaromaticity 60—61
Cyclopropenyl cation, and aromaticity 58
Cyclopropyl cation 438
Cyclopropyl cation ring opening 1434
Cyclopropyl groups as stabilizing groups for carbocations 222—223
Cyclopropyl groups, stabilizing effect on carbocations 225
Cyclopropyl tosylate, solvolysis 437
Cyclopropyl, as a neighboring group 410
Cyclopropylalkenes, conformations 182
Cyclopropylcarbene 790
Cyclopropylcarbinyl see “Cyclopropylmethyl”
Cyclopropylcarbinyl cation 408
Cyclopropylcarbinyl halides, and  reactions 423
Cyclopropylcarbinyl radicals 247
Cyclopropylmethyl carbene 1400
Cyclopropylmethyl cations 222—223 408
Cyclopropylmethyl cations and NMR 418
Cyclopropylmethyl cations geometry 417
Cyclopropylmethyl cations rearrangement 417
Cyclopropylmethyl halides, reaction with piperidine 423
Cyclopropylmethyl, neighboring group effects 416
Cycloreversion, of cyclobutanes 1081
Cyclotetradecane, strain energy 214
Cyclo[3.3.3]azine 68
D nomenclature, IUPAC for mechanisms 384
DABCO, and the Baylis ffillman reaction 1212
Dakin reaction 1528
Dakin reaction and the Baeyer — Villiger reaction 1528
Dakin — West reaction 812
Dammaradienol 1019
Darzens glycidic ester condensation 1230
Darzen’s reaction 809 1219
DAST and formation of difluorides 1196
DAST and preparation of acyl fluorides 524
DAST preparation of fluorides from alcohols 519
DBN, and elimination of alkyl halides 1337
DBU alkylation with carboxylic acids 488
DBU and elimination of alkyl halides 1337
DBU and elimination of hydrazonium salts 1348
DBU and epoxidation of conjugated ketones 1052
DBU and formation of sulfones 498
DBU and formation of thioethers 496
DBU and Michael reactions 1023
DCC and amide formation 509
DCC and DMSO for oxidation of alcohols 1516
DCC and ester formation 485
DCC and peptide coupling 509
DCC and reaction of amines with  1192
DCC, dehydrating agent 491
DCC, dehydration of alcohols 480
DCC, reaction with phenols and DMSO 722
DCl, and electrophilic aromatic substitution 679
DDQ 1511 1531
DDQ and azide formation 516
DDQ, reaction with silyl enol ethers 1512
DDT, preparation of 719
Deactivating groups, and electrophilic aromatic substitution 681—684 687
Dealkylation, of ammonium salts 503
Deamination, of amines 1548
Debye units 15—16
Decalin 161—162
Decarbonylation of aldehydes, and radical rearrangements 1389
Decarbonylation of aryl aldehydes 732
Decarbonylation of cyclobutanones 1354
Decarbonylation of ketones 1347
Decarboxylation 549
Decarboxylation and Bredt’s rule 810
Decarboxylation and the Henkel reaction 733
Decarboxylation of aryl carboxylic acids 732
Decarboxylation of carboxylate anions 810
Decarboxylation of carboxylic acids 573 808
Decarboxylation of formyl carboxylates 573
Decarboxylation of hydroxy acids 1346
Decarboxylation of keto acids 810
Decarboxylation of lactones 1354
Decarboxylation oxidative 1528
Decarboxylation photochemical 811
Decomposition, photochemical 318
Dediazoniation, reagents for 934—935
Degenerate carbocations 1380
Degenerate Cope rearrangement 1447
Degenerate rearrangements 1380
Degradation, Hofmann 1331
Dehalogenation, of aryl halides 735
Dehydrating agents and formation of acetals or ketals 1180
Dehydrating agents for dehydration of amides 1350
Dehydrating agents for esterification 486
Dehydrating agents isonitriles from formamides 1351
Dehydration of alcohols 480 1326
Dehydration of alkyne alcohols 1327
Dehydration of amides 1327 1350
Dehydration of carboxylic acids 491
Dehydration of keto oximes 1349
Dehydration of oximes 1348
Dehydrobenzenes see “Benzynes”
Dehydrogenation and dodecahedrane 1514
Dehydrogenation of alcohols 1515
Dehydrogenation of amines 1518
Dehydrogenation of bicyclic amines 1511—1512
Dehydrogenation reagents for 1512
Dehydrohalogenation see “Halides alkyl elimination”
Dehydrohalogenation, photochemical 1513
| Delepine reaction 501
Delocalization and carhocation stability 221
Delocalization types for carbocations 221
Demerol 1405
Demethylation of ethers 496 503 520 528
Demethylation of methyl esters 562
Demethylation of methypyridinium salts 501
Demyanov rearrangement 1399
Demyanov ring contraction or expansion 1398—1400
Dendralenes 39 80
Deoxygenation, of aryl ethers 734
Deracemization, and resolution 154
Derivatization and absolute configuration 142—143
Derivatization and Mosher’s acid 142—143
Dess — Martin periodinane, and oxidation of alcohols 1516
Desulfurization 531
Desulfurization by hydrogenation 940
Desulfurization of thiophene 941
Deuteration of aromatic rings, reagents for 696
Deuteration of hydrocarbons 769
Deuterium exchange, and electrophilic aromatic substitution 695
Deuterium isotope effects 298
Deuterium, catalytic exchange with alkanes 1005
Deuterium, effect on nucleophilic substitution 438
Dewar benzene 1083 1090 1449
Dewar benzenes, by electtocyclic rearrangement 1433
Dewar structure, anthracene 43
Dewar structures 32
Dextro isomers, and chirality 125
DHU see “Dicyclohexylurea”
Di--methane rearrangement 1460
Di--methane rearrangements, oxa 1461
Di-alkynes see “diynes
Di-sec-butylmercury, reaction with Grignard reagents 761
Dialdehydes cyclization with rhodium phosphine complex 1564
Dialdehydes radical cyclization 1561
Dialkylboron enol ether see “Enol borinate”
Diamantane 1396
Diamines cyclic, and the anomeric effect 177
Diamines from aziridines 504 505
Diamines fromalkenes 1056
Diamines ortho-, oxidation with nickel peroxide 1527
Diamines oxidative cleavage 1520
Diaminobiphenyls by the benzidine rearrangement 1455
Diaminobiphenyls from hydrazobenzenes 1455
Diamons carboxylic acid, reaction with esters 572
Diamons from ketones and 1229
Diamons from the acyloin condensation 1562
Diamons of acetoacetic ester 550
Diamons of carboxylic acids, reaction with alkyl halides 555
Diaryl sulfides see “Thioethers aryl”
Diarylhydrazines see “Hydrazo compounds”
Diaryls see “Biaryls”
Diasterane 183
Diastereomer, definition 144
Diastereomers and cis/trans isomers 157—160
Diastereomers and diastereotopic atoms 164—166
Diastereomers and epimers 146
Diastereomers and isomer formation in elimination reactions 1318
Diastereomers and Michael addition 977
Diastereomers and pseudo asymmetric carbons 145
Diastereomers and resolution 151—152
Diastereomers and substitution reactions 405
Diastereomers and the  rale 145
Diastereomers differences in reactivity 366
Diastereomers erythro, from electrophilic addition to alkenes 971
Diastereomers erythro/threo nomenclature 146—147
Diastereomers meso compounds 145
Diastereomers nomenclature 146
Diastereomers physical properties 144
Diastereomers syn/anti nomenclature 147
Diastereomers threo, from electrophilic addition to alkenes 971
Diastereomers torsional 133
Diastereoselectivity and Cram’s rale 147—148
Diastereoselectivity and the Felkin — Ahn model 148
Diastereoselectivity and the Paterno — Biichi reaction 1250
Diastereoselectivity electrophilic addition to alkenes 971
Diastereoselectivity erythro/threo, in the aldol reaction 1221
Diastereoselectivity exo/endo, and addition to alkenes 987
Diastereoselectivity in addition to aldehydes or ketones 1206
Diastereoselectivity in conjugate additions 1029
Diastereoselectivity in Mannich reactions 1191
Diastereoselectivity in reduction of aldehydes and ketones 1201
Diastereoselectivity in the aldol reaction 1221
Diastereoselectivity in the Knoevenagel reaction 1225
Diastereoselectivity in the Prins reaction 1242
Diastereoselectivity in the Reformatsky reaction 1212
Diastereoselectivity syn/anti, in the aldol reaction 1221
Diastereotopic atoms 164—166
Diastereotopic atoms and isochronous atoms 165
Diastereotopic faces 166
Diastereotopic, definition 165
Diatopic compounds, definition 46
Diazirines, decomposition of 250
Diazo alkanes, from nitroso compounds 1352
Diazo compounds from  -amino esters 1664
Diazo compounds from active hydrogen compounds 1664
Diazo compounds from acyl halides 1664
Diazo compounds from aldehydes 1664
Diazo compounds from aliphatic amines 816
Diazo compounds from amines 816
Diazo compounds from diazo esters 1664
Diazo compounds from hydrazones 1664
Diazo compounds from N-nitroso-N-alkyl compounds 1664
Diazo compounds photooxidation and ozonolysis 1524
Diazo compounds protonation 447
Diazo compounds reaction with alcohols 479
Diazo compounds reaction with amines 504
Diazo compounds reaction with boranes 561
Diazo compounds reaction with carboxylic acids 490
Diazo compounds reaction with phenols 479
Diazo esters reaction with aldehydes 785
Diazo esters reaction with boranes 561
Diazo ketones and ketene formation 1250
Diazo ketones and the Arndt — Eistert synthesis 1405
Diazo ketones and Wolff rearrangement 1406
Diazo ketones conformations of 1407
Diazo ketones hydrolysis of 465
Diazo ketones intermediates in the Schmidt reaction 1414
Diazo ketones photolysis of with alcohols 1406
Diazo ketones reaction with aldehydes or ketones 1248
Diazo ketones reaction with HBr 522
Diazo ketones reaction with imines 1217
Diazo ketones reaction with sulfur 1248
Diazo ketones reaction with thioketones 1248
Diazo ketones rearrangement of 1414
Diazo ketones rearrangement with water and  1405
Diazo ketones s- (E) and s- (Z) conformations 1407
Diazo ketones thermolysis of 1250
Diazo transfer reaction 781
Diazoalkanes as 1,3-dipoles 1060
Diazoketones by the Arndt — Eistert synthesis 574
Diazoketones from acyl halides 573
Diazoketones reaction with boranes 561
Diazomethane and carbenes 248 249
Diazomethane and homologation of aldehydes and ketones 1407
Diazomethane conversion to methylene carbene 789
Diazomethane decomposition of 250
Diazomethane photolysis of 789
Diazomethane rate of decomposition 1087
Diazomethane reaction with acyl halides 573 1405
Diazomethane reaction with alcohols 479
Diazomethane reaction with aldehydes or ketones 1248
Diazomethane reaction with amines 504
Diazomethane reaction with carboxylic acids 490
Diazomethane reaction with sulfonyl halides 1249
Diazonium compounds aryl 816
Diazonium compounds by diazo transfer reactions 781
Diazonium compounds from active methylene compounds 780
Diazonium compounds stability of 816
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