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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Cyclopentane, conformation      177
Cyclopentane, conformational energy barrier      178
Cyclopentanols, from dimagnesium compounds and esters      1214
Cyclopentanone, conformation      178
Cyclopentenes, from vinylcyclopropanes      1443
Cyclopentenone      321
Cyclopentyne      1160 (ref. 1316) 1392
Cyclopentyne derivatives      187
Cyclophane, “belt”      44
Cyclopolyacenes      67
Cyclopropane and bent bonds      181
Cyclopropane and bonding      181
Cyclopropane and cation rearrangements      1382
Cyclopropane and strain      180—181
Cyclopropane angle strain      181
Cyclopropane cations and allylic cations      1399
Cyclopropane conformation      177
Cyclopropane intermediates, in the Claisen rearrangement      1451
Cyclopropane orbital overlap      181
Cyclopropane protonated intermediates      1382
Cyclopropane reaction with HBr      988
Cyclopropane vinyl, by di $\pi$-methane rearrangements      1460
Cyclopropane vinyl, [1,3]-sigmatropic rearrangement      1443
Cyclopropanes addition of radicals      990
Cyclopropanes addition reactions      988—990
Cyclopropanes and homodienyl [1,5]-H sigmatropic rearrangements      1440
Cyclopropanes and Markovnikov’s rale      989
Cyclopropanes by extrusion from pyrazolines      1353
Cyclopropanes by the Simmons — Smith reaction      1088
Cyclopropanes divinyl, Cope rearrangement      1445 1446
Cyclopropanes electrophilic addition, ab initio studies      990
Cyclopropanes from alkenes and carbenes      789
Cyclopropanes from carbenes      248
Cyclopropanes from cyclobutanones      1354
Cyclopropanes from diols      544
Cyclopropanes from metal carbenes      1086
Cyclopropanes from sulfur ylids with aldehydes or ketones      1247
Cyclopropanes hydrogenation of      1012
Cyclopropanes reaction with HX      989
Cyclopropanes relationship to alkene reactivity      988
Cyclopropanes vinyl, from 1,4-dienes      1460
Cyclopropanone, and UV spectra      181
Cyclopropenes      186
Cyclopropenes by extrusion from pyrazoles      1353
Cyclopropenes reaction with chlorosulfonyl isocyanate      1251
Cyclopropenes vinyl      1443
Cyclopropeniumyldiazonium salts      448
Cyclopropenone      58
Cyclopropenyl anion, and antiaromaticity      60—61
Cyclopropenyl cation, and aromaticity      58
Cyclopropyl cation      438
Cyclopropyl cation ring opening      1434
Cyclopropyl groups as stabilizing groups for carbocations      222—223
Cyclopropyl groups, stabilizing effect on carbocations      225
Cyclopropyl tosylate, solvolysis      437
Cyclopropyl, as a neighboring group      410
Cyclopropylalkenes, conformations      182
Cyclopropylcarbene      790
Cyclopropylcarbinyl      see “Cyclopropylmethyl”
Cyclopropylcarbinyl cation      408
Cyclopropylcarbinyl halides, and $S_N2’$ reactions      423
Cyclopropylcarbinyl radicals      247
Cyclopropylmethyl carbene      1400
Cyclopropylmethyl cations      222—223 408
Cyclopropylmethyl cations and NMR      418
Cyclopropylmethyl cations geometry      417
Cyclopropylmethyl cations rearrangement      417
Cyclopropylmethyl halides, reaction with piperidine      423
Cyclopropylmethyl, neighboring group effects      416
Cycloreversion, of cyclobutanes      1081
Cyclotetradecane, strain energy      214
Cyclo[3.3.3]azine      68
D nomenclature, IUPAC for mechanisms      384
DABCO, and the Baylis ffillman reaction      1212
Dakin reaction      1528
Dakin reaction and the Baeyer — Villiger reaction      1528
Dakin — West reaction      812
Dammaradienol      1019
Darzens glycidic ester condensation      1230
Darzen’s reaction      809 1219
DAST and formation of difluorides      1196
DAST and preparation of acyl fluorides      524
DAST preparation of fluorides from alcohols      519
DBN, and elimination of alkyl halides      1337
DBU alkylation with carboxylic acids      488
DBU and elimination of alkyl halides      1337
DBU and elimination of hydrazonium salts      1348
DBU and epoxidation of conjugated ketones      1052
DBU and formation of sulfones      498
DBU and formation of thioethers      496
DBU and Michael reactions      1023
DCC and amide formation      509
DCC and DMSO for oxidation of alcohols      1516
DCC and ester formation      485
DCC and peptide coupling      509
DCC and reaction of amines with $CS_2$      1192
DCC, dehydrating agent      491
DCC, dehydration of alcohols      480
DCC, reaction with phenols and DMSO      722
DCl, and electrophilic aromatic substitution      679
DDQ      1511 1531
DDQ and azide formation      516
DDQ, reaction with silyl enol ethers      1512
DDT, preparation of      719
Deactivating groups, and electrophilic aromatic substitution      681—684 687
Dealkylation, of ammonium salts      503
Deamination, of amines      1548
Debye units      15—16
Decalin      161—162
Decarbonylation of aldehydes, and radical rearrangements      1389
Decarbonylation of aryl aldehydes      732
Decarbonylation of cyclobutanones      1354
Decarbonylation of ketones      1347
Decarboxylation      549
Decarboxylation and Bredt’s rule      810
Decarboxylation and the Henkel reaction      733
Decarboxylation of aryl carboxylic acids      732
Decarboxylation of carboxylate anions      810
Decarboxylation of carboxylic acids      573 808
Decarboxylation of formyl carboxylates      573
Decarboxylation of hydroxy acids      1346
Decarboxylation of keto acids      810
Decarboxylation of lactones      1354
Decarboxylation oxidative      1528
Decarboxylation photochemical      811
Decomposition, photochemical      318
Dediazoniation, reagents for      934—935
Degenerate carbocations      1380
Degenerate Cope rearrangement      1447
Degenerate rearrangements      1380
Degradation, Hofmann      1331
Dehalogenation, of aryl halides      735
Dehydrating agents and formation of acetals or ketals      1180
Dehydrating agents for dehydration of amides      1350
Dehydrating agents for esterification      486
Dehydrating agents isonitriles from formamides      1351
Dehydration of alcohols      480 1326
Dehydration of alkyne alcohols      1327
Dehydration of amides      1327 1350
Dehydration of carboxylic acids      491
Dehydration of keto oximes      1349
Dehydration of oximes      1348
Dehydrobenzenes      see “Benzynes”
Dehydrogenation and dodecahedrane      1514
Dehydrogenation of alcohols      1515
Dehydrogenation of amines      1518
Dehydrogenation of bicyclic amines      1511—1512
Dehydrogenation reagents for      1512
Dehydrohalogenation      see “Halides alkyl elimination”
Dehydrohalogenation, photochemical      1513
Delepine reaction      501
Delocalization and carhocation stability      221
Delocalization types for carbocations      221
Demerol      1405
Demethylation of ethers      496 503 520 528
Demethylation of methyl esters      562
Demethylation of methypyridinium salts      501
Demyanov rearrangement      1399
Demyanov ring contraction or expansion      1398—1400
Dendralenes      39 80
Deoxygenation, of aryl ethers      734
Deracemization, and resolution      154
Derivatization and absolute configuration      142—143
Derivatization and Mosher’s acid      142—143
Dess — Martin periodinane, and oxidation of alcohols      1516
Desulfurization      531
Desulfurization by hydrogenation      940
Desulfurization of thiophene      941
Deuteration of aromatic rings, reagents for      696
Deuteration of hydrocarbons      769
Deuterium exchange, and electrophilic aromatic substitution      695
Deuterium isotope effects      298
Deuterium, catalytic exchange with alkanes      1005
Deuterium, effect on nucleophilic substitution      438
Dewar benzene      1083 1090 1449
Dewar benzenes, by electtocyclic rearrangement      1433
Dewar structure, anthracene      43
Dewar structures      32
Dextro isomers, and chirality      125
DHU      see “Dicyclohexylurea”
Di-$\pi$-methane rearrangement      1460
Di-$\pi$-methane rearrangements, oxa      1461
Di-alkynes      see “diynes
Di-sec-butylmercury, reaction with Grignard reagents      761
Dialdehydes cyclization with rhodium phosphine complex      1564
Dialdehydes radical cyclization      1561
Dialkylboron enol ether      see “Enol borinate”
Diamantane      1396
Diamines cyclic, and the anomeric effect      177
Diamines from aziridines      504 505
Diamines fromalkenes      1056
Diamines ortho-, oxidation with nickel peroxide      1527
Diamines oxidative cleavage      1520
Diaminobiphenyls by the benzidine rearrangement      1455
Diaminobiphenyls from hydrazobenzenes      1455
Diamons carboxylic acid, reaction with esters      572
Diamons from ketones and $CS_2$      1229
Diamons from the acyloin condensation      1562
Diamons of acetoacetic ester      550
Diamons of carboxylic acids, reaction with alkyl halides      555
Diaryl sulfides      see “Thioethers aryl”
Diarylhydrazines      see “Hydrazo compounds”
Diaryls      see “Biaryls”
Diasterane      183
Diastereomer, definition      144
Diastereomers and cis/trans isomers      157—160
Diastereomers and diastereotopic atoms      164—166
Diastereomers and epimers      146
Diastereomers and isomer formation in elimination reactions      1318
Diastereomers and Michael addition      977
Diastereomers and pseudo asymmetric carbons      145
Diastereomers and resolution      151—152
Diastereomers and substitution reactions      405
Diastereomers and the $2^n$ rale      145
Diastereomers differences in reactivity      366
Diastereomers erythro, from electrophilic addition to alkenes      971
Diastereomers erythro/threo nomenclature      146—147
Diastereomers meso compounds      145
Diastereomers nomenclature      146
Diastereomers physical properties      144
Diastereomers syn/anti nomenclature      147
Diastereomers threo, from electrophilic addition to alkenes      971
Diastereomers torsional      133
Diastereoselectivity and Cram’s rale      147—148
Diastereoselectivity and the Felkin — Ahn model      148
Diastereoselectivity and the Paterno — Biichi reaction      1250
Diastereoselectivity electrophilic addition to alkenes      971
Diastereoselectivity erythro/threo, in the aldol reaction      1221
Diastereoselectivity exo/endo, and addition to alkenes      987
Diastereoselectivity in addition to aldehydes or ketones      1206
Diastereoselectivity in conjugate additions      1029
Diastereoselectivity in Mannich reactions      1191
Diastereoselectivity in reduction of aldehydes and ketones      1201
Diastereoselectivity in the aldol reaction      1221
Diastereoselectivity in the Knoevenagel reaction      1225
Diastereoselectivity in the Prins reaction      1242
Diastereoselectivity in the Reformatsky reaction      1212
Diastereoselectivity syn/anti, in the aldol reaction      1221
Diastereotopic atoms      164—166
Diastereotopic atoms and isochronous atoms      165
Diastereotopic faces      166
Diastereotopic, definition      165
Diatopic compounds, definition      46
Diazirines, decomposition of      250
Diazo alkanes, from nitroso compounds      1352
Diazo compounds from $\alpha$-amino esters      1664
Diazo compounds from active hydrogen compounds      1664
Diazo compounds from acyl halides      1664
Diazo compounds from aldehydes      1664
Diazo compounds from aliphatic amines      816
Diazo compounds from amines      816
Diazo compounds from diazo esters      1664
Diazo compounds from hydrazones      1664
Diazo compounds from N-nitroso-N-alkyl compounds      1664
Diazo compounds photooxidation and ozonolysis      1524
Diazo compounds protonation      447
Diazo compounds reaction with alcohols      479
Diazo compounds reaction with amines      504
Diazo compounds reaction with boranes      561
Diazo compounds reaction with carboxylic acids      490
Diazo compounds reaction with phenols      479
Diazo esters reaction with aldehydes      785
Diazo esters reaction with boranes      561
Diazo ketones and ketene formation      1250
Diazo ketones and the Arndt — Eistert synthesis      1405
Diazo ketones and Wolff rearrangement      1406
Diazo ketones conformations of      1407
Diazo ketones hydrolysis of      465
Diazo ketones intermediates in the Schmidt reaction      1414
Diazo ketones photolysis of with alcohols      1406
Diazo ketones reaction with aldehydes or ketones      1248
Diazo ketones reaction with HBr      522
Diazo ketones reaction with imines      1217
Diazo ketones reaction with sulfur      1248
Diazo ketones reaction with thioketones      1248
Diazo ketones rearrangement of      1414
Diazo ketones rearrangement with water and $Ag_2O$      1405
Diazo ketones s- (E) and s- (Z) conformations      1407
Diazo ketones thermolysis of      1250
Diazo transfer reaction      781
Diazoalkanes as 1,3-dipoles      1060
Diazoketones by the Arndt — Eistert synthesis      574
Diazoketones from acyl halides      573
Diazoketones reaction with boranes      561
Diazomethane and carbenes      248 249
Diazomethane and homologation of aldehydes and ketones      1407
Diazomethane conversion to methylene carbene      789
Diazomethane decomposition of      250
Diazomethane photolysis of      789
Diazomethane rate of decomposition      1087
Diazomethane reaction with acyl halides      573 1405
Diazomethane reaction with alcohols      479
Diazomethane reaction with aldehydes or ketones      1248
Diazomethane reaction with amines      504
Diazomethane reaction with carboxylic acids      490
Diazomethane reaction with sulfonyl halides      1249
Diazonium compounds aryl      816
Diazonium compounds by diazo transfer reactions      781
Diazonium compounds from active methylene compounds      780
Diazonium compounds stability of      816
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