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| Авторизация |
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| Поиск по указателям |
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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Elimination extrusion reactions 1352
Elimination from alkyl halides 1336—1337
Elimination from alkyl halides and Hofmann’s rule 1337
Elimination from alkyl halides and Zaitsev’s rule 1337
Elimination from alkyl halides, solvent effects 1337
Elimination from ammonium hydroxides and Zaitsev’s rule 1331
Elimination from ammonium hydroxides, and Hofmann’s rule 1331
Elimination from ammonium salts, and cis/trans isomers 1333
Elimination from boranes, Zaitsev’s rule 1339
Elimination from dihalides 1195
Elimination from halides and enantioselectivity 1338
Elimination from hydroxy acids 1346
Elimination from organometallics and alkyl halides 807
Elimination Hofmann 1316—1317 1331
Elimination isomer formation and diastereomers 1318
Elimination IUPAC nomenclature for mechanism 383
Elimination mechanisms 276
Elimination reactions, definition 1299
Elimination reactivity 1318—1322
Elimination solvent effects 1321
Elimination substituent effects 1319
Elimination to form carbenes 249
Elimination to form nitrenes 253
Elimination, E1 1306—1308
Elimination, E1 and dehydration of alcohols 1328
Elimination, E1 and dehydrohalogenation 1337
Elimination, E1 and E2 elimination 1308
Elimination, E1 and fragmentation reactions 1345
Elimination, E1 and ion pairs 1308
Elimination, E1 and leaving groups 1307
Elimination, E1 and Zaitsev’s rule 1308
Elimination, E1 IUPAC nomenclature 1307
Elimination, E1cB 1308—1312
Elimination, E1cB and ion pairs 1312
Elimination, E1cB andbenzynes 1310
Elimination, E1cB IUPAC nomenclature 1308
Elimination, E1cB leaving group effects 1310—1311
Elimination, E1cB substrate effects 1310
Elimination, E2 1300—1306
Elimination, E2 and dehydrohalogenation 1337
Elimination, E2 and fragmentation reactions 1345
Elimination, E2 and Hofmann elimination 1331
Elimination, E2 and Hofmann’s rule 1315
Elimination, E2 and ion pairs 1306
Elimination, E2 and isotope effects 1304
Elimination, E2 and reactivity 366
Elimination, E2 and the Peterson alkenylation reaction 1228
Elimination, E2 and Zaitsev’s rule 1303
Elimination, E2 anti-periplanar conformation 1300
Elimination, E2 formation of stereoisomers 1301
Elimination, E2 from cyclic halides 1302
Elimination, E2 IUPAC nomenclature 1300
Elimination, E2 structural requirements 1315
Elimination, E2 syn-anti dichotomy 1304
Elimination, E2 with bicyclo[2.2.2] compounds 1303
Elimination, E2C 1313—1314
Elimination, E2C and the Bronsted equation 1313
Elimination, E2C E2C, and Zaitsev’s rule 1314
Elimination, E2C effect of base 1320
Elimination, E2C effects of the medium 1321
Elimination, Ei and dehydrohalogenation 1337
Elimination, Ei and the Chugaev reaction 1330
Elimination, Ei and the Peterson alkenylation reaction 1228
Elimination, Ei andpyrolysis of esters 1330
Elimination, pyrolytic 1322—1326
Elimination, pyrolytic and Bredt’s rule 1325
Elimination, pyrolytic and Hofmann’s rule 1325
Elimination, pyrolytic and radical intermediates 1324
Elimination, pyrolytic and syn elimination 1323
Elimination, pyrolytic and Woodward — Hoffmann rules 1324
Elimination, pyrolytic and Zaitsev’s rule 1325
Elimination, pyrolytic regioselectivity 1325
Elimination, syn 1300
Elimination, syn and catalytic elimination of acyl halides 1339
Elimination, syn and pyrolytic elimination 1323
Elimination, syn and the Knoevenagel reaction 1226
Elimination, syn and the Peterson alkenylation reaction 1228
Elimination-addition mechanisms 430
Emde reduction 530
Emission spectroscopy, and mechanism 321
Emission, and radicals, in NMR 240
Enamine acylation of 788
Enamine alkylation of 787
Enamine-imine tautomerism 1000
Enamines also see “Stork enamine reaction”
Enamines and drying agents 1187
Enamines and formation by azeotropic distillation 1187
Enamines and formation with microwaves 1186
Enamines and the Bucherer reaction 865
Enamines and the Simmons — Smith reaction 1089
Enamines and the Thorpe reaction 1238
Enamines and the Thorpe — Ziegler reaction 1239
Enamines formation of 787
Enamines formation on clays 1186
Enamines from aldehydes 1187 1667
Enamines from alkenes 1000
Enamines from alkylation of enamines 1667
Enamines from alkynes 1667
Enamines from aminals 1187
Enamines from amines 1000 1187 1667 1668
Enamines from formamides 1667
Enamines from Grignard reagents 1667
Enamines from Petasis alkenylation 1668
Enamines from phosphonates 1667
Enamines from Tebbe alkenylation 1668
Enamines fromketones 1187 1667
Enamines halogenation, reagents for 788
Enamines hydrolysis and the Thorpe reaction 1238
Enamines hydrolysis of 1178
Enamines in [2+2]-cycloadditions 1077
Enamines reaction with 9-BBN 1014
Enamines reaction with acyl halides 788
Enamines reaction with alkyl halides 555 787
Enamines reaction with anhydrides 788
Enamines reaction with boranes 530
Enamines reaction with CNBr, CNCl, or CNI 788
Enamines reaction with ethyl chloroformate 788
Enamines reaction with isocyanates 1250
Enamines reaction with strong base 558
Enamines reduction, reagents for 530
Enamines salts, alkylation of 788
Enamines Stork enamine synthesis 555
Enamines tautomerism with imines 77
Enamino ketones 1187
Enantiomeric composition, by derivatization 142—143
Enantiomers and enantiotopic atoms 164—166
Enantiomers and optical antipodes 125
Enantiomers and optical purity 155—156
Enantiomers and optical rotation 126—127
Enantiomers and physical properties 125—126
Enantiomers and planes of symmetry 127—128
Enantiomers and reaction rates 126
Enantiomers and specific rotation 127
Enantiomers and the E2 reaction 1301
Enantiomers definition 125
Enantiomers levo and dextro isomers 125
Enantiomers racemates, definition 126
Enantiomers racemic mixture, definition 126
Enantiomers resolution of 151—155
Enantiomers resolution, definition 126
Enantiomorphs see “Enantiomer”
Enantioselective protonation, of enolate anions 794
Enantioselective reactions, definition 150
Enantioselectivity addition of HCN to aldehydes or ketones 1239
Enantioselectivity addition of organolithium reagents to imines 1216
Enantioselectivity and dehydrohalogenation 1338
Enantioselectivity and epoxide elimination 1329
Enantioselectivity and reduction of ketones 1200
Enantioselectivity and the Baeyer — Villiger rearrangement 1417
Enantioselectivity and the Heck reaction 931
| Enantioselectivity and the Knoevenagel reaction 1225
Enantioselectivity and [3+2]-cycloadditions 1061
Enantioselectivity enolate unions, and organopalladium compounds 551
Enantioselectivity epoxides from sulfur ylids and aldehydes or ketones 1248
Enantioselectivity in boronic esters with organolithium reagents 1424
Enantioselectivity in catalytic hydrogenation 1003
Enantioselectivity in conjugate additions 1029
Enantioselectivity in heteroatom Diels — Alder reactions 1075
Enantioselectivity in reaction of imines and diazoalkanes 1217
Enantioselectivity in reaction of imines and HCN 1240
Enantioselectivity in reaction of organometallics with aldehydes or ketones 1206
Enantioselectivity in reactions of aldehydes with allylsilanes 1211
Enantioselectivity in reactions of CO, alkenes and water 1035
Enantioselectivity in reactions of organometallics with ketones 1210
Enantioselectivity in reduction of imines 1203
Enantioselectivity in reduction of oximes 1554
Enantioselectivity in the aldol reaction 1221
Enantioselectivity in the Baylis — Hillman reaction 1212
Enantioselectivity in the Darzen’s glycidic ester condensation 1230
Enantioselectivity in the Diels — Alder reaction 1065
Enantioselectivity in the Ireland — Claisen rearrangement 1452
Enantioselectivity in the Mukaiyama aldol reaction 1223
Enantioselectivity in the Pauson — Khand reaction 1091
Enantioselectivity in the Prins reaction 1242
Enantioselectivity in the Pummerer rearrangement 1566
Enantioselectivity in the Reformatsky reaction 1212
Enantioselectivity in the Stork enamine reaction 788
Enantioselectivity in [2,3]-sigmatropic rearrangement 1454
Enantioselectivity ketene reactions with aldehydes or ketones 1249
Enantioselectivity ketone enolate anions and alkyl halides 552
Enantioselectivity with metal carbenes 1086
Enantiotopic atoms 164—166
Enantiotopic atoms and prochiral 165
Enantiotopic atoms and radiolabeling 164
Enantiotopic atoms and the Krebs cycle 164
Enantiotopic atoms re/si nomenclature 166
Enantiotopic faces 166
Enantiotopic, definition 164
Encounter complex 680
Encyclopedia of Reagents for Organic Synthesis (EROS) 1624
Endo addition, in the Diels — Alder reaction 1064
Ene reaction 1021
Ene reaction and fullerenes 1021
Ene reaction catalysts for 1022
Ene reaction retro 1022
Ene-diynes and Bergman cyclization 1432
Energy  reaction of chloromethane and chloride ion 394
Energy activation, of radicals 906
Energy alternant hydrocarbons 56
Energy and photochemistry 307—308
Energy barrier and conformation 169
Energy barrier for cyclopentane conformation 178
Energy barrier to chair-to-chair interconversion 173
Energy bond 22—24 312
Energy bond dissociation energy 22
Energy bond dissociation for C-H vs. C-D 297
Energy bond dissociation, and radicals 900 911
Energy bond dissociation, for HX and RX 911
Energy bond energy and steric influences 23
Energy bond, delocalized bonds 35—36
Energy bond, in benzene 35
Energy bond, table 24
Energy cascade and photochemistry 313
Energy conformations of butane 169—170
Energy conformations of ethane 168
Energy diagram and photochemistry 307—308
Energy diagrams 282
Energy dissociation energy of carbocations 224
Energy dissociation, table of radicals 243
Energy enthalpy 277—278
Energy enthalpy of activation 280
Energy entropy 277—278
Energy entropy and ring closing 280
Energy entropy of activation 280
Energy formal steric enthalpy 190
Energy free 277—278
Energy free and acid strength 336
Energy free and catalysis 289
Energy free and kinetics 278—279
Energy free and Marcus theory 286—287
Energy free and resonance effects 365
Energy free and solvent effects 452
Energy free and the Hammett equation 369—370
Energy free of activation 278—279
Energy heat of atomization 22
Energy heat of combustion 22
Energy levels, benzyl intermediates 56
Energy of activation and activated complex 279
Energy of activation and Marcus theory 286
Energy of activation and reaction coordinate 279
Energy of activation and transition state 279
Energy resonance 32
Energy resonance for butadiene 37
Energy resonance in benzene 35
Energy singlet vs. triplet carbenes 248
Energy solvation, in reactions 394
Energy strain 180
Energy strain, calculation 180
Energy strain, cyclotetradecane 214
Energy transfer and photochemistry 316
Enlargement, of rings, by carbenes 250—51
Enol acetates and the Mukaiyama aldol reaction 1223
Enol acetates iodination of 777
Enol acetates reaction with methyllithium 554
Enol borates, and the aldol reaction 1221
Enol borinates and borane reactions with halo carbonyls 560
Enol borinates and the aldol reaction 1221
Enol borinates reaction with conjugated compounds 1031
Enol borinates reaction with methyllithium 554
Enol carbamates, from alkynes, CO and an amine 1668
Enol esters from alkynes 998
Enol esters hydrolysis of 474
Enol esters reaction with alcohols 487
Enol esters reaction with carboxylic acids 491
Enol ethers and formation of Mannich bases 1191
Enol ethers and the Mukaiyama aldol reaction 1223
Enol ethers and the Simmons — Smith reaction 1089
Enol ethers by Petasis alkenylation 1237—1238
Enol ethers by Tebbe alkenylation 1237—1238 1668
Enol ethers by transesterification 1668
Enol ethers by transetherification 481 1668
Enol ethers dialkylboron see “Enol borinates”
Enol ethers from  -alkoxy phosphoranes 1668
Enol ethers from  -halo acetals 1668
Enol ethers from 1,3-dicarbonyl compounds 1668
Enol ethers from acetals 1329
Enol ethers from active hydrogen compounds 1668
Enol ethers from acyl halides 1668
Enol ethers from alcohols 1668
Enol ethers from aldehydes 1668
Enol ethers from alkynes 1668
Enol ethers from anhydrides 1668
Enol ethers from carboxylic acids 1668
Enol ethers from cleavage of acetals 1668
Enol ethers from diazo alkanes 1668
Enol ethers from diketones 481
Enol ethers from esters 1668
Enol ethers from formation of acetals and ketals 1181
Enol ethers from ketenes 1668
Enol ethers from metal carbene complexes 1668
Enol ethers from ortho esters 1668
Enol ethers from Petasis alkenylation 1668
Enol ethers from phenols 1668
Enol ethers from vinyl halides 1668
Enol ethers hydrolysis and isotopic labeling 467
Enol ethers hydrolysis mechanism 467
Enol ethers hydrolysis of 465
Enol ethers hydrolysis, isotope effects 468
Enol ethers hydrolysis, mechanism 467
Enol ethers oxidation of 1539
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