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| Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure |
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| Предметный указатель |
Alkoxides in the aldol reaction 1218
Alkoxides in the Williamson reaction 477
Alkoxides magnesium, thermal decomposition 1328
Alkoxides reaction with  1184
Alkoxides reaction with alkyl halides, MOM and MEM 478
Alkoxides reaction with aryl halides 862
Alkoxides reaction with aziridines 481
Alkoxides reaction with dihalides 477
Alkoxides reaction with epoxides 481
Alkoxides reaction with inorganic esters 478
Alkoxides reaction with methyl sulfate 478
Alkoxides reaction with sulfonate esters 478
Alkoxides reaction with trihalides 477
Alkoxides reduction of 1209
Alkoxides thermolysis of 811
Alkoxy alcohols, alcoholysis of epoxides 481
Alkoxytrimethylsilanes, transetherification 481
Alkyl azides see “Azides alkyl”
Alkyl bromides see “Halides alkyl”
Alkyl chlorides see “Halides alkyl”
Alkyl chloroformates see “Chloroformates alkyl”
Alkyl halides see “Halides alkyl”
Alkyl hydroperoxides see “Hydroperoxides”
Alkyl iodides see “Halides alkyl”
Alkyl tosylates see “Tosylates alkyl”
Alkylation and vinylogy 553
Alkylation enantioselective 552
Alkylation exhaustive 500
Alkylation Friedel — Crafts 707—711
Alkylation of acid salts 494
Alkylation of alkenes 1017 1047
Alkylation of alkoxides 477
Alkylation of alkynes 1026
Alkylation of amine anions. 500
Alkylation of amines 501
Alkylation of aromatic compounds 932
Alkylation of aryl halides 868
Alkylation of carboxylic acid salts 488
Alkylation of cnamincs. 788
Alkylation of dithiane anions 556
Alkylation of enolate anions 548
Alkylation of epoxides 546
Alkylation of ethyl acetoacetate 459
Alkylation of ethyl pyroglutamate 457
Alkylation of heterocycles 871 933
Alkylation of heterocycles, Ziegler alkylation 871
Alkylation of keto sulfoxides 549
Alkylation of malonic esters 549
Alkylation of oxazine anions 558
Alkylation of oximes 495
Alkylation of thiophene 531
Alkylation photochemical, of quinolines 934
Alkylation reductive, of amines 1188
Alkylation regioselectivity with ketone enolates 554
Alkylation with alkyl halides 477
Alkylboranes see “Boranes”
Alkylidene bisamides 1187
Alkylmagnesium compounds see “Organomagnesium”
Alkylmercury compounds see “Organomercury”
Alkylnitrilium ins, reduction of 1204
Alkyloxyphosphoninum perchlorates, reaction with amines 502
Alkyltrimethylsilanes, carbanion formation 229
Alkyne aluminum reagents 1210
Alkyne anions and the Knoevenagel reaction 1225
Alkyne anions copper, reaction with aryl halides 868
Alkyne anions from alkynes 561
Alkyne anions reaction with alkyl halides 561
Alkyne anions reaction with peroxides 796
Alkyne epoxides, elimination tocumulenes 1344
Alkyne esters from alkyne anions 796
Alkyne esters from vinylidine dihalides and amide ion 1652
Alkyne halides, from reaction of acetylide ions with halogens 1652
Alkyne ketones, from epoxy hydrazones 1347
Alkyne, anion, reaction with boranes 1425
Alkyne-alkenes, and the Pauson — Khand reaction 1091
Alkynes addition of alcohols 997
Alkynes addition of azides 1058
Alkynes addition of organometallics 1024—1026
Alkynes and bond migration 771
Alkynes and Normant reagents 1026
Alkynes and the Cadiot — Chodkiewicz reaction 927
Alkynes and the Eglinton reaction 927
Alkynes and the Eschenmoser — Tanabe reaction 1347
Alkynes and the Favorskii reaction 1225
Alkynes and the Glaser reaction 927
Alkynes and the Heck reaction 931
Alkynes and the Nef reaction 1225
Alkynes and thermolysis of aziridines 1062
Alkynes and [2+2]-cycloadditions 1090
Alkynes and [3+2]-cycloadditions 1061
Alkynes by coupling reactions 543
Alkynes by dehydrohalogenation 1337
Alkynes by elimination of alkyl and vinyl halides 1337
Alkynes by the Eglinton reaction 1651
Alkynes by the Ramberg — Backlund reaction 1342
Alkynes by the Stephens — Castro coupling 868
Alkynes complex with hexacarbonyldicobalt 1091
Alkynes coupling with Sm 561
Alkynes dimerization 927
Alkynes dimerization, and Schwartz’s reagent 1020
Alkynes elimination with boranes 1339
Alkynes formylation of 1048
Alkynes from acetylenic acids 1651
Alkynes from acetylenic alcohols 1651
Alkynes from alkyl halides 868 1651
Alkynes from alkynes 561 868 1339 1425 1651
Alkynes from alkynyl borates 1651
Alkynes from alkynyl organometallic compounds 1651
Alkynes from allenic substrates 1651
Alkynes from ammonium hydroxides 1651
Alkynes from aryl iodides 1651
Alkynes from arylation of alkynes 1651
Alkynes from boranes 1651
Alkynes from diaryl alkenes 1651
Alkynes from dihalides 1651
Alkynes from dihalotoluenes 1652
Alkynes from keto-ylids 1334
Alkynes from metathesis of alkynes 1651
Alkynes from selenoxides 1651
Alkynes from tetrahalides 1651
Alkynes from triple-bond migration 1651
Alkynes from vinyl halides 1337 1651
Alkynes fromalkenes 1339 1651
Alkynes fromthiiren-1,1-dioxides 1651
Alkynes halo, reaction with aryltin compounds 561
Alkynes halo, reaction with boranes 1425
Alkynes hydration of 995
Alkynes hydrogenation of 1004—1005
Alkynes in the Diels — Alder reaction 1062
Alkynes in the Pauson — Khand reaction 1091
Alkynes metathesis of 1458
Alkynes oxidation of 1539
Alkynes oxidation to diketones 1540
Alkynes ozonolysis 1523
Alkynes reaction with amines 1000
Alkynes reaction with aminonitrenes 1057
Alkynes reaction with azides 1061
Alkynes reaction with boranes 798 1015
Alkynes reaction with bromine 1042
Alkynes reaction with carbenes 1086
Alkynes reaction with carboxylic acids 998
Alkynes reaction with Dibal 1007
Alkynes reaction with dicobalt octacarbonyl 1089
Alkynes reaction with Grignard reagents 791
Alkynes reaction with HX 975 992
Alkynes reaction with imides 1002
Alkynes reaction with iodine 1042
Alkynes reaction with organocopper reagents 1026
Alkynes reaction with ozone 1540
Alkynes reaction with selenium dioxide 1540
| Alkynes reaction with strong bases 561
Alkynes reaction with water 995
Alkynes reagents for reduction 1007
Alkynes rearrangement to allenes 771
Alkynes trimerization 1089
Alkynes trimerization and the Diels — Alder reaction 1090
Alkynes vinyl cyclopropyl and alkene metathesis 1458
Alkynyl cations 430
Allene oxides 1144 (ref. 1049)
Allenes and restricted rotation 133—134
Allenes and the Paterno — Buechi reaction 1250
Allenes cyclic 187
Allenes from alkylation of propargyl halides 1652
Allenes from alkylation of propargyl tosylates 1652
Allenes from alkynes 771
Allenes from carbenes 1400
Allenes from contraction of three-membered rings 1652
Allenes from dehalogenation of dihaloalkenes 1652
Allenes from dehalogenation of tetrahalides 1652
Allenes from dehydrohalogenation of dihalides 1652
Allenes from Petasis alkenylation 1652
Allenes from propargyl acetates 545
Allenes from propargyl alcohols 772
Allenes from propargyl esters 1652
Allenes from propargyl ethers 546 1652
Allenes from pyrolysis of  -hydroxy alkynes 1652
Allenes from reaction of phosphoranes with 1652
Allenes from reaction of phosphoranes with ketenes 1652
Allenes from rearrangement of alkynes 771 1652
Allenes from rearrangement of propargylic vinyl compounds 1652
Allenes from reduction of propargyl acetates 1652
Allenes from reduction of propargyl halides 1652
Allenes from Tebbe alkenylation 1652
Allenes hydration of 996
Allenes in [2+2]-cycloadditions 1077
Allenes reaction with aldehydes or ketones 1250
Allenes reaction with carbenes 1086
Allenes reaction with chlorosulfonyl isocyanate 1251
Allenes reaction with ketenes 1077
Allophanates 1183
Allylic acetates see “Acetates allylic”
Allylic cations 221
Allylic chlorination 914
Allylic oxidation 915
Allylic phenols from allyl aryl ethers 1449
Allylic phenols, by Claisen rearrangement 1449
Allylic radicals see “Radicals allylic”
Allylic rearrangement see “Rearrangement allylic” “Substitution
Allylic silanes see “Silanes”
Allylic systems, orbital diagram 38
Allylsilanes, reaction with aldehydes 1211
Alnminum amalgam for reduction of conjugated sulfones 1206
Alnminum amalgam for reduction of nitro compounds 1552
Alpha effect, an nucleophilic strength 445
Alpha effect, formation of amides 510
Alpine-borane, reduction of ketones 1201
Alternant hydrocarbons 55—57
Alternate hydrocarbons and electrophilic aromatic substitution 690
Alumina and Diels — Alder reactions 1066
Aluminates, dimerization 940
Aluminum alkynyl reagents 1210
Aluminum and pinacol coupling 1560
Aluminum chloride 339
Aluminum hydride reagents, and reaction with alkyl halides 525
Amberlyst 15
Amberlyst and acetal hydrolysis 467
Amberlyst and csterification 486
Amberlyst and reduction of lactones 1548
Ambident nucleophiles 458—461
Ambident substrates, definition 461
AMI method 34
Amidation, of aromatic compounds 702
Amide anion, reaction with heterocycles 873
Amide bases and formation of ketone etiolates 551
Amide bases and keto-enol tautomerism 775
Amide bases and the Haller-Bauer reaction 814
Amide bases as nucleophiles 500
Amide bases cleavage of ketones 814
Amide bases formation of 500
Amide bases reaction with amines 503
Amide bases reaction with ammonium salts 1419
Amide bases reaction with esters 510
Amide bases reaction with ethers 1328
Amide bases reaction with phosphonium salts 1231
Amide hydrolysis intermediate 365
Amide hydrolysis transition state 365
Amide kctones, from alkenes 1653
Amides also see “Acetamides” “Formamides”
Amides alcoholysis of 488
Amides alkylation with diazo componnds 514
Amides and acidity 344
Amides and conformations 171
Amides and DCC coupling 509
Amides and Hofmann rearrangement 1411
Amides and hydrogen bonding 102
Amides and leaving groups 449
Amides and the Bouveault reaction 1214
Amides aromatic, resonance and field effects 364—365
Amides by Orton rearrangement 1653
Amides by tetracarbonylferrate 565
Amides by the Arndt — Eistert rearrangement 1653
Amides by the Beckmann rearrangement 1415 1653
Amides by the Chapman rearrangement 1464 1653
Amides by the Dakin — West reaction 1653
Amides by the Favorskii rearrangement 1653
Amides by the Gatterman reaction 718 1652
Amides by the Haller — Bauer reaction 814 1653
Amides by the Leuckart reaction 1653
Amides by the Mitsnnobu reaction 513
Amides by the Ritter reaction 1244 1653
Amides by the Schmidt reaction 1653
Amides by the Schotten — Baumann procedure 507
Amides by the Willgerodt reaction 1567 1653
Amides dealkylation 1559
Amides dehydration 1350
Amides from acid derivatives 512 1652
Amides from acid salts 508
Amides from acyl halides 506 1652
Amides from alcohols 1244
Amides from aldehydes 925 1653
Amides from alkenes 1001 1035 1244 1653
Amides from alkyl halides 513 1652
Amides from alkynes 1653
Amides from amides 503 512 1652 1653
Amides from amines 503 1535 1652 1653
Amides from amino acids 1653
Amides from anhydrides 507 1653 1652
Amides from aromatic compounds 719 1652
Amides from aryl halides 513 1653
Amides from aryl ketones 1653
Amides from boranes 801
Amides from carboxylic acids 1413 1652
Amides from cyano amides 1653
Amides from esters 510
Amides from heterocycles 1653
Amides from hydration of ynamines 1653
Amides from hydrocarbons 925
Amides from imines 1653
Amides from imino esters 1464
Amides from isocyanates 1217 1413 1653
Amides from isonitriles 1251 1653
Amides from ketones 1414 1567 1653 1653
Amides from nitrenes 1653
Amides from nitriles 1179 1192 1244 1653
Amides from oxime esters 1415
Amides from oximes 1415
Amides from rearrangement of a-halo ketones 1653
Amides from rearrangement of aryl imidates 1653
Amides from rearrangement of diazo ketones 1653
Amides from rearrangement of N-halo-N-acyl aromatic amines 1653
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