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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure



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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Alkoxides in the aldol reaction      1218
Alkoxides in the Williamson reaction      477
Alkoxides magnesium, thermal decomposition      1328
Alkoxides reaction with $CO_2$      1184
Alkoxides reaction with alkyl halides, MOM and MEM      478
Alkoxides reaction with aryl halides      862
Alkoxides reaction with aziridines      481
Alkoxides reaction with dihalides      477
Alkoxides reaction with epoxides      481
Alkoxides reaction with inorganic esters      478
Alkoxides reaction with methyl sulfate      478
Alkoxides reaction with sulfonate esters      478
Alkoxides reaction with trihalides      477
Alkoxides reduction of      1209
Alkoxides thermolysis of      811
Alkoxy alcohols, alcoholysis of epoxides      481
Alkoxytrimethylsilanes, transetherification      481
Alkyl azides      see “Azides alkyl”
Alkyl bromides      see “Halides alkyl”
Alkyl chlorides      see “Halides alkyl”
Alkyl chloroformates      see “Chloroformates alkyl”
Alkyl halides      see “Halides alkyl”
Alkyl hydroperoxides      see “Hydroperoxides”
Alkyl iodides      see “Halides alkyl”
Alkyl tosylates      see “Tosylates alkyl”
Alkylation and vinylogy      553
Alkylation enantioselective      552
Alkylation exhaustive      500
Alkylation Friedel — Crafts      707—711
Alkylation of acid salts      494
Alkylation of alkenes      1017 1047
Alkylation of alkoxides      477
Alkylation of alkynes      1026
Alkylation of amine anions.      500
Alkylation of amines      501
Alkylation of aromatic compounds      932
Alkylation of aryl halides      868
Alkylation of carboxylic acid salts      488
Alkylation of cnamincs.      788
Alkylation of dithiane anions      556
Alkylation of enolate anions      548
Alkylation of epoxides      546
Alkylation of ethyl acetoacetate      459
Alkylation of ethyl pyroglutamate      457
Alkylation of heterocycles      871 933
Alkylation of heterocycles, Ziegler alkylation      871
Alkylation of keto sulfoxides      549
Alkylation of malonic esters      549
Alkylation of oxazine anions      558
Alkylation of oximes      495
Alkylation of thiophene      531
Alkylation photochemical, of quinolines      934
Alkylation reductive, of amines      1188
Alkylation regioselectivity with ketone enolates      554
Alkylation with alkyl halides      477
Alkylboranes      see “Boranes”
Alkylidene bisamides      1187
Alkylmagnesium compounds      see “Organomagnesium”
Alkylmercury compounds      see “Organomercury”
Alkylnitrilium ins, reduction of      1204
Alkyloxyphosphoninum perchlorates, reaction with amines      502
Alkyltrimethylsilanes, carbanion formation      229
Alkyne aluminum reagents      1210
Alkyne anions and the Knoevenagel reaction      1225
Alkyne anions copper, reaction with aryl halides      868
Alkyne anions from alkynes      561
Alkyne anions reaction with alkyl halides      561
Alkyne anions reaction with peroxides      796
Alkyne epoxides, elimination tocumulenes      1344
Alkyne esters from alkyne anions      796
Alkyne esters from vinylidine dihalides and amide ion      1652
Alkyne halides, from reaction of acetylide ions with halogens      1652
Alkyne ketones, from epoxy hydrazones      1347
Alkyne, anion, reaction with boranes      1425
Alkyne-alkenes, and the Pauson — Khand reaction      1091
Alkynes addition of alcohols      997
Alkynes addition of azides      1058
Alkynes addition of organometallics      1024—1026
Alkynes and bond migration      771
Alkynes and Normant reagents      1026
Alkynes and the Cadiot — Chodkiewicz reaction      927
Alkynes and the Eglinton reaction      927
Alkynes and the Eschenmoser — Tanabe reaction      1347
Alkynes and the Favorskii reaction      1225
Alkynes and the Glaser reaction      927
Alkynes and the Heck reaction      931
Alkynes and the Nef reaction      1225
Alkynes and thermolysis of aziridines      1062
Alkynes and [2+2]-cycloadditions      1090
Alkynes and [3+2]-cycloadditions      1061
Alkynes by coupling reactions      543
Alkynes by dehydrohalogenation      1337
Alkynes by elimination of alkyl and vinyl halides      1337
Alkynes by the Eglinton reaction      1651
Alkynes by the Ramberg — Backlund reaction      1342
Alkynes by the Stephens — Castro coupling      868
Alkynes complex with hexacarbonyldicobalt      1091
Alkynes coupling with Sm      561
Alkynes dimerization      927
Alkynes dimerization, and Schwartz’s reagent      1020
Alkynes elimination with boranes      1339
Alkynes formylation of      1048
Alkynes from acetylenic acids      1651
Alkynes from acetylenic alcohols      1651
Alkynes from alkyl halides      868 1651
Alkynes from alkynes      561 868 1339 1425 1651
Alkynes from alkynyl borates      1651
Alkynes from alkynyl organometallic compounds      1651
Alkynes from allenic substrates      1651
Alkynes from ammonium hydroxides      1651
Alkynes from aryl iodides      1651
Alkynes from arylation of alkynes      1651
Alkynes from boranes      1651
Alkynes from diaryl alkenes      1651
Alkynes from dihalides      1651
Alkynes from dihalotoluenes      1652
Alkynes from keto-ylids      1334
Alkynes from metathesis of alkynes      1651
Alkynes from selenoxides      1651
Alkynes from tetrahalides      1651
Alkynes from triple-bond migration      1651
Alkynes from vinyl halides      1337 1651
Alkynes fromalkenes      1339 1651
Alkynes fromthiiren-1,1-dioxides      1651
Alkynes halo, reaction with aryltin compounds      561
Alkynes halo, reaction with boranes      1425
Alkynes hydration of      995
Alkynes hydrogenation of      1004—1005
Alkynes in the Diels — Alder reaction      1062
Alkynes in the Pauson — Khand reaction      1091
Alkynes metathesis of      1458
Alkynes oxidation of      1539
Alkynes oxidation to diketones      1540
Alkynes ozonolysis      1523
Alkynes reaction with amines      1000
Alkynes reaction with aminonitrenes      1057
Alkynes reaction with azides      1061
Alkynes reaction with boranes      798 1015
Alkynes reaction with bromine      1042
Alkynes reaction with carbenes      1086
Alkynes reaction with carboxylic acids      998
Alkynes reaction with Dibal      1007
Alkynes reaction with dicobalt octacarbonyl      1089
Alkynes reaction with Grignard reagents      791
Alkynes reaction with HX      975 992
Alkynes reaction with imides      1002
Alkynes reaction with iodine      1042
Alkynes reaction with organocopper reagents      1026
Alkynes reaction with ozone      1540
Alkynes reaction with selenium dioxide      1540
Alkynes reaction with strong bases      561
Alkynes reaction with water      995
Alkynes reagents for reduction      1007
Alkynes rearrangement to allenes      771
Alkynes trimerization      1089
Alkynes trimerization and the Diels — Alder reaction      1090
Alkynes vinyl cyclopropyl and alkene metathesis      1458
Alkynyl cations      430
Allene oxides      1144 (ref. 1049)
Allenes and restricted rotation      133—134
Allenes and the Paterno — Buechi reaction      1250
Allenes cyclic      187
Allenes from alkylation of propargyl halides      1652
Allenes from alkylation of propargyl tosylates      1652
Allenes from alkynes      771
Allenes from carbenes      1400
Allenes from contraction of three-membered rings      1652
Allenes from dehalogenation of dihaloalkenes      1652
Allenes from dehalogenation of tetrahalides      1652
Allenes from dehydrohalogenation of dihalides      1652
Allenes from Petasis alkenylation      1652
Allenes from propargyl acetates      545
Allenes from propargyl alcohols      772
Allenes from propargyl esters      1652
Allenes from propargyl ethers      546 1652
Allenes from pyrolysis of $\beta$-hydroxy alkynes      1652
Allenes from reaction of phosphoranes with $CO_2$      1652
Allenes from reaction of phosphoranes with ketenes      1652
Allenes from rearrangement of alkynes      771 1652
Allenes from rearrangement of propargylic vinyl compounds      1652
Allenes from reduction of propargyl acetates      1652
Allenes from reduction of propargyl halides      1652
Allenes from Tebbe alkenylation      1652
Allenes hydration of      996
Allenes in [2+2]-cycloadditions      1077
Allenes reaction with aldehydes or ketones      1250
Allenes reaction with carbenes      1086
Allenes reaction with chlorosulfonyl isocyanate      1251
Allenes reaction with ketenes      1077
Allophanates      1183
Allylic acetates      see “Acetates allylic”
Allylic cations      221
Allylic chlorination      914
Allylic oxidation      915
Allylic phenols from allyl aryl ethers      1449
Allylic phenols, by Claisen rearrangement      1449
Allylic radicals      see “Radicals allylic”
Allylic rearrangement      see “Rearrangement allylic” “Substitution
Allylic silanes      see “Silanes”
Allylic systems, orbital diagram      38
Allylsilanes, reaction with aldehydes      1211
Alnminum amalgam for reduction of conjugated sulfones      1206
Alnminum amalgam for reduction of nitro compounds      1552
Alpha effect, an nucleophilic strength      445
Alpha effect, formation of amides      510
Alpine-borane, reduction of ketones      1201
Alternant hydrocarbons      55—57
Alternate hydrocarbons and electrophilic aromatic substitution      690
Alumina and Diels — Alder reactions      1066
Aluminates, dimerization      940
Aluminum alkynyl reagents      1210
Aluminum and pinacol coupling      1560
Aluminum chloride      339
Aluminum hydride reagents, and reaction with alkyl halides      525
Amberlyst      15
Amberlyst and acetal hydrolysis      467
Amberlyst and csterification      486
Amberlyst and reduction of lactones      1548
Ambident nucleophiles      458—461
Ambident substrates, definition      461
AMI method      34
Amidation, of aromatic compounds      702
Amide anion, reaction with heterocycles      873
Amide bases and formation of ketone etiolates      551
Amide bases and keto-enol tautomerism      775
Amide bases and the Haller-Bauer reaction      814
Amide bases as nucleophiles      500
Amide bases cleavage of ketones      814
Amide bases formation of      500
Amide bases reaction with amines      503
Amide bases reaction with ammonium salts      1419
Amide bases reaction with esters      510
Amide bases reaction with ethers      1328
Amide bases reaction with phosphonium salts      1231
Amide hydrolysis intermediate      365
Amide hydrolysis transition state      365
Amide kctones, from alkenes      1653
Amides      also see “Acetamides” “Formamides”
Amides alcoholysis of      488
Amides alkylation with diazo componnds      514
Amides and acidity      344
Amides and conformations      171
Amides and DCC coupling      509
Amides and Hofmann rearrangement      1411
Amides and hydrogen bonding      102
Amides and leaving groups      449
Amides and the Bouveault reaction      1214
Amides aromatic, resonance and field effects      364—365
Amides by Orton rearrangement      1653
Amides by tetracarbonylferrate      565
Amides by the Arndt — Eistert rearrangement      1653
Amides by the Beckmann rearrangement      1415 1653
Amides by the Chapman rearrangement      1464 1653
Amides by the Dakin — West reaction      1653
Amides by the Favorskii rearrangement      1653
Amides by the Gatterman reaction      718 1652
Amides by the Haller — Bauer reaction      814 1653
Amides by the Leuckart reaction      1653
Amides by the Mitsnnobu reaction      513
Amides by the Ritter reaction      1244 1653
Amides by the Schmidt reaction      1653
Amides by the Schotten — Baumann procedure      507
Amides by the Willgerodt reaction      1567 1653
Amides dealkylation      1559
Amides dehydration      1350
Amides from acid derivatives      512 1652
Amides from acid salts      508
Amides from acyl halides      506 1652
Amides from alcohols      1244
Amides from aldehydes      925 1653
Amides from alkenes      1001 1035 1244 1653
Amides from alkyl halides      513 1652
Amides from alkynes      1653
Amides from amides      503 512 1652 1653
Amides from amines      503 1535 1652 1653
Amides from amino acids      1653
Amides from anhydrides      507 1653 1652
Amides from aromatic compounds      719 1652
Amides from aryl halides      513 1653
Amides from aryl ketones      1653
Amides from boranes      801
Amides from carboxylic acids      1413 1652
Amides from cyano amides      1653
Amides from esters      510
Amides from heterocycles      1653
Amides from hydration of ynamines      1653
Amides from hydrocarbons      925
Amides from imines      1653
Amides from imino esters      1464
Amides from isocyanates      1217 1413 1653
Amides from isonitriles      1251 1653
Amides from ketones      1414 1567 1653 1653
Amides from nitrenes      1653
Amides from nitriles      1179 1192 1244 1653
Amides from oxime esters      1415
Amides from oximes      1415
Amides from rearrangement of a-halo ketones      1653
Amides from rearrangement of aryl imidates      1653
Amides from rearrangement of diazo ketones      1653
Amides from rearrangement of N-halo-N-acyl aromatic amines      1653
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