Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure :: Электронная библиотека попечительского совета мехмата МГУ

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Smith M.B., March J. — March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

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Название: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Авторы: Smith M.B., March J.

Аннотация:

"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 5-th edition

Год издания: 2001

Количество страниц: 2083

Добавлена в каталог: 21.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Organometallic compounds addition to C=N compounds      1216
Organometallic compounds and NMR      234
Organometallic compounds definition of      227
Organometallic compounds from alkenes      791 1016 1683
Organometallic compounds from alkyl halides      805 1683
Organometallic compounds from aryl halides      736 805 1683
Organometallic compounds from carboxylic acid salts      1683
Organometallic compounds from halides      1683
Organometallic compounds from hydrocarbons      793
Organometallic compounds from metallation with metals      1683
Organometallic compounds from metallation with organometallic compounds      1683
Organometallic compounds from metallation with strong bases      1683
Organometallic compounds from organocopper compounds      1683
Organometallic compounds from organometallic compounds      802 1683
Organometallic compounds from rearrangement of Grignard reagents      1683
Organometallic compounds fromsulfides      1683
Organometallic compounds hydrolysis of      794
Organometallic compounds reaction with acids      736 784
Organometallic compounds reaction with alkyl halides      807
Organometallic compounds reaction with azides      799
Organometallic compounds reaction with aziridines      548
Organometallic compounds reaction with hydroxylamines      799
Organometallic compounds reaction with iodine      798
Organometallic compounds reaction with oxygen      795
Organometallic compounds reaction with peroxides      796
Organometallic compounds structure of      234—237
Organometallic compounds transmetallation      803 804
Organosamarium compounds, allylic, reaction with imines      1216
Organostannanes      see “Organotin”
Organotin reagents      1210
Organotin reagents allylic, reaction with imines      1216
Organotin reagents reaction with alkyl halides, CO and Pd catalyst      801
Organotin reagents vinyl, reaction with isocyanates      1218
Organotin reagents vinyltin and the Stille reaction      931
Organotitanium reagents      1208
Organozinc reagents      1210
Organozirconium complex, reaction with alkenes      1026
Organozirconium reagents      1208
Organozirconium reagents, and Schwartz’s reagent      1020
Ortho effect      688
Ortho effect and reaction rate      375
Ortho esters by the Williamson ether synthesis      1683
Ortho esters from addition of alcohols to formic acid      1683
Ortho esters from reaction of alkoxides with 1,1,1-trihalides      1683
Ortho esters from transetherification      1683
Ortho esters from trihalides and alkoxides      477
Ortho esters reaction with Grignard reagents      545
Ortho esters transetherification      480
ortho- Substitution      681
Ortho/para ratio and electrophilic aromatic substitution      685
Ortho/para ratio Fries rearrangement      726
Ortho/para ratio in the Orton rearrangement      729
Ortho/para ratio ortho effect      688
Ortho/para ratio rate of reaction      690
Ortho/para ratio with multiple substituents      687
Orthoformates, reaction with sulfonic acids      576
Orton rearrangement      728—729
Orton rearrangement photochemical      729
Osazones, from hydroxy aldehydes or ketones and hydrazines      1193
Osmium tetroxide and reaction of alkenes with Chloramme-T      1056
Osmium tetroxide reaction with alkenes      1049
Osmium tetroxide with Jones reagent, and oxidative cleavage      1526
Out-in isomers and out-out isomers      163
Oxa-di- $\pi$ -methane rearrangements      1461
Oxacyclooctane, conformation      178
Oxalyl chloride reaction with amides      515
Oxalyl chloride reaction with carboxylic acids      523
Oxalyl chloride with DMSO for oxidation of alcohols      1516
Oxaphosphetanes, and the Wittig reaction      1234
Oxazine anions, reaction with alkyl halides      558—559
Oxazine iminium salts alkylation of      559
Oxazine iminium salts reaction with Grignard reagents      559
Oxazines and the Meyers synthesis      558
Oxazines conversion to aldehydes      558
Oxazines conversion to ketones      559
Oxazines reaction with organolithium reagents      558
Oxazoborolidines, and asymmetric reduction of aldehydes or ketones      1201
Oxazolines aryl, reaction with Grignard reagents      868
Oxazolines reaction with organolithium reagents      559
Oxepin, and Cope rearrangement      1448
Oxetane, conformation      177
Oxetanes and the Prins reaction      1241
Oxetanes by the Paterno — Buchi reaction      1249
Oxetanes from reaction of alkenes with aldehydes or ketones      1249
Oxetanes of alkanes, by the Gif system      1533
Oxetanes reaction with amines      505
Oxetanes reaction with organolithium reagents      546
Oxetanes reaction with trimethylsilyl cyanide      506
Oxetanes spirocyclic, by the Paterno — Biichi reaction      1249
Oxidation allylic      915
Oxidation asymmetric, with bacterial monooxygenases      1590 (ref. 457)
Oxidation definition      1506
Oxidation enzymatic      1517
Oxidation Lavoisier’s definition      1506
Oxidation of alkenes with       290
Oxidation of alkenes, reaction for      914
Oxidation of amines by nitric acid      697
Oxidation of aromatic aldehydes or ketones      1528
Oxidation of aromatic amines      724
Oxidation of boranes      1014
Oxidation of hydrocarbons, by the Gif system      1533
Oxidation of phenols      724
Oxidation polymer supported      1515
Oxidation remote      1513
Oxidation state and functional groups      1507
Oxidation-reduction mechanisms addition-elimination      1509
Oxidation-reduction mechanisms and direct electron transfer      1508
Oxidation-reduction mechanisms and ester intermediate      1508
Oxidation-reduction mechanisms displacement      1509
Oxidation-reduction mechanisms hydride transfer      1508
Oxidation-reduction mechanisms hydrogen atom transfer      1508
Oxidation-reduction mechanisms SET      1508
Oxidative cleavage      see “Cleavage”
Oxime esters, and the Beckmann rearrangement      1415
Oxime tosylates and the Neber rearrangement      1410
Oxime tosylates fragmentation to nitriles      1349
Oxime tosylates rearrangement with base      1410
Oximes and high pressure      1194
Oximes by the Barton reaction      1684
Oximes catalytic hydrogenation      1554
Oximes conversion to gem-difluoridea      1197
Oximes dehydration      1348
Oximes formation and pH      1194
Oximes from $\alpha$ -nitro alkenes      1558
Oximes from alcohols      1684
Oximes from aldehydes      1194 1684
Oximes from alkenes      1684
Oximes from amines      1684
Oximes from cyclic ketones      1684
Oximes from Grignard reagents      1684
Oximes from hydroxylamine      1684
Oximes from ketones      1194 1684
Oximes from nitrites      1684
Oximes from nitro compounds      1558 1684
Oximes from oximes      938
Oximes hydrolysis of      938 1177 1463
Oximes oxidation of      1539
Oximes reaction with       1349 1415
Oximes reaction with alkyl halides      494
Oximes reaction with anhydrides      1348
Oximes reaction with aryl diazonium salts      938
Oximes reaction with HCN      1240
Oximes reaction with organolithium reagents      1216
Oximes reaction with Oxone      1540
Oximes reaction with peroxyacids      1539
Oximes reduction of      1203 1554
Oximes reduction with       1554—1555
Oximes reduction with Bakers yeast      1554
Oximes reduction with Dibal      1555
Oximinoketones, from ketones      780

Oxiranes      see “Epoxides”
Oxirenes, trapping in argon      1054
Oxoammonium salts, and oxidation of alcohols      1515
Oxone and hydrolysis of nitriles      1179
Oxone reaction with aldehydes      917
Oxone reaction with amines      1539
Oxone reaction with oximes      1540
Oxonin, and aromaticity      63
Oxonium salts from alkyl halides      492
Oxonium salts from ethers      492
Oxonium salts from ketones      492
Oxonium salts from oxonium salts      492
Oxonium salts reaction with ethers      492
Oxy — Cope rearrangement      1445 1452
Oxygen and coupling of organocuprates      939
Oxygen photosensitization      921
Oxygen radiolabeled, solvolysis      398
Oxygen reaction with dienes      1054
Oxygen reaction with Grignard reagents      795
Oxygen reaction with organolithium reagents      795
Oxygen reaction with organometallic compounds      795
Oxygen reaction with phenanthrene      1054
Oxygen reaction with terpinene      1055
Oxygen singlet      see “Singlet oxygen”
Oxygen valence electrons      12—13
Oxygenation, radical, of alkenes      914
Oxymercuration, of alkenes      993
Ozone      see “Ozonolysis”
Ozone as a 1,3-dipole      1060
Ozone oxidation of alkynes      1540
Ozone reaction with alkenes      914 1522—1525
Ozone reaction with alkynes      1523
Ozone reaction with amines      1539
Ozonides      1522
Ozonolysis      1532
Ozonolysis and bisperoxide intermediates      1523
Ozonolysis and dioxirane      1525
Ozonolysis and labeling experiments      1525
Ozonolysis and stereochemistry of alkenes      1524
Ozonolysis of alkynes      1523
Ozonolysis of benzene      1523
Ozonolysis oxidation of ozonides      1522
Ozonolysis reduction of ozonide      1522
Ozonolysis substituent effects      1522
p Character, and strain      181
p-Aminobenzophenone      1560
p-Bromobenzenesulfonate, leaving group      446
p-Bromotoluene, nitration and the ortho effect      688
p-Chlorobenzhydryl chloride      399
p-Dinitrobenzene, dipole moment      16
p-Nitrobenzenesulfonate, leaving group      446
p-Nitrotoluene, dipole moment      16
p-Toluenesulfonate, leaving group      446
Pagodane      183
Palladium and dehydrogenation of amines      1519
Palladium catalysts and $\sigma$ -bond rearrangements      1460
Palladium catalysts and addition of amines to alkenes      1001
Palladium catalysts and all carbon [3+2]-cycloadditions      1076
Palladium catalysts and carbonylation of halides      464
Palladium catalysts and coupling reactions      540
Palladium catalysts and diamination of alkenes      1057
Palladium catalysts and diamine formation      502
Palladium catalysts and formation of thioethers      496
Palladium catalysts and preparation of sulfones      498
Palladium catalysts and reaction of aryl triflates and zinc cyanide      724
Palladium catalysts and reaction of organotin, CO, alkyl halides      801
Palladium catalysts and rearrangement of epoxy ketones      1398
Palladium catalysts and Suzuki coupling      868
Palladium catalysts and the Heck reaction      930
Palladium catalysts and the Hurtley reaction      869
Palladium catalysts and the Stille reaction      932
Palladium catalysts for alkylation of amines      500
Palladium catalysts for coupling allylic acetates with acids      944
Palladium catalysts for hydrogenation      1003
Palladium catalysts for isomerization of alkynes to dienes      773
Palladium catalysts for the Cope rearrangement      1446
Palladium chloride, and oxidation of alkenes with water      1537—1538
Palladium compounds, and enolate anions      551
Palladium elimination from allylic acetates      1330
Pancreatic porcine lipase, formation of lactams      508
para-Claisen rearrangement      1449
para-Substitution      681
Paracyclophanes and NMR      47
Paracyclophanes and optical activity      135—136
Paracyclophanes and ring current      47
Paracyclophanes by acyloin condensation      1562
Paracyclophanes structural distortion      43—44
Paraformaldehyde      1245
Paramagnetic ring current, and antiaromaticity      67
Paratropic, NMR and antiaromaticity      68
Partial bond fixation      49
Partial rate factors and aryl radicals      905
Partial rate factors and electrophilic aromatic substitution      685 690
Partition factor      677
Partitioning effect      677
Partitioning effect and the reaction      852
Passerini reaction      1252
Pasteur tweezer method, and resolution      153
Patents      1607
Paterno — Buechi reaction      1249
Paterno — Buechi reaction diastereoselectivity      1250
Paterno — Buechi reaction photosensitization      1250
Pauli exclusion principle      3
Pauli principle, and radicals      238
Pauling electronegativity      14
Pauson — Khand reaction      1091
Payne rearrangement      481
Pentacyclo $[3.3.2.0^{2,4}.0^{3,7}.0^{6,8}]$ decane      1459
Pentacyclododecanes      183
Pentacyclohexadeca-l,7-dienes      188
Pentacyclooctanes      183
Pentahaloethanes, and ElcB elimination      1309
Pentalene and aromaticity      54
Pentalene derivatives      55
Pentalene dianion, and aromaticity      5
Pentamethylbenzenonium ion      678
Pentamethylhexane, formal steric enthalpy      190
Pentane, bond energy      23
Pentaprismane      183
Peptide synthesis, and DCC      509
Peptide synthesizers      510
Peracyclene      69
Pericyclic, mechanism      275
Periodate, sodium, on silica gel with microwaves      1589 (ref. 449)
Periodic acid and in oxidative cleavage      1526
Periodic acid and oxidative cleavage of diols      1520
Periodic table and acid strength      345
Periodic table and Lewis acids      345
Periodic table and nucleophilic strength      439
Periodinane, and oxidation of alcohols      1516
Peristylanes      183
Perkln reaction      1219 1229
Permanganate potassium and oxidation of alcohols      1515
Permanganate potassium and oxidation of sulfoxides      1541
Permanganate potassium oxidation of alkyl groups on aromatic compounds      1527
Permanganate potassium oxidative cleave with crown ethers      1526
Permanganate potassium reaction with aldehydes      918
Permanganate potassium reaction with alkenes      290 1049
Permanganate potassium reaction with amines      1539
Peroxide, hydrogen, reaction with alkenes      1049
Peroxides      also see “Hydroperoxides” “Peroxyacids”
Peroxides acyl, reaction with aromatic compounds      932
Peroxides acyl, reaction with Grignard reagents      796
Peroxides and addition of HBr to alkenes      992
Peroxides and extrusion of       1354
Peroxides and NBS bromination      911
Peroxides and the Prins reaction      1242
Peroxides and the Story synthesis      1355
Peroxides diacyl, preparation of      492
Peroxides dialkyl, from hydroperoxides      492

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