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Patai S. — The Chemistry of Organic Silicon Compounds (part 1-2)
Patai S. — The Chemistry of Organic Silicon Compounds (part 1-2)



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Íàçâàíèå: The Chemistry of Organic Silicon Compounds (part 1-2)

Àâòîð: Patai S.

Àííîòàöèÿ:

Organosilicon compounds are key organometallic compounds (R-Si) which have many uses in materials science and in metallurgy. Their applications include the synthesis of sugars and in the synthesis of organic compounds for the pharmaceutical industry. This volume will contain both updated chapters on key topics included in the original volumes as well as a number of new chapters reflecting the rapid developments made in silicon chemistry and its applications to organometallic chemistry, materials science, and semiconductors, over the last five years. As for the majority of volumes in this series, chapters will be prepared by leading scientists in the field.


ßçûê: en

Ðóáðèêà: Õèìèÿ/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Ãîä èçäàíèÿ: 1989

Êîëè÷åñòâî ñòðàíèö: 1673

Äîáàâëåíà â êàòàëîã: 16.04.2007

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Silenes structural parameters for      236—237
Silenes structure of      1045—1046
Silenes substituted silenes      119—124
Silenes synthesis of      1044—1045 1046—1070
Silenes thermal isomerization/fragmentation of      1070—1081
Silenes thermodynamic stability of      121—122
Silenes transient species      1046—1070
Silenes unimolecular reactions of      1073
Silenyl anion      203
Siletanes      695
Siletes      695
Silicate anions      282—289
Silicenium ions      184—193
Silicenium ions alkylsilicenium ions      188 485
Silicenium ions as electrophiles in cyclization      469—473
Silicenium ions hydroxy-substituted      188
Silicenium ions phosphino-substituted      187
Silicenium ions rearrangements involving      454—465
Silicenium ions silyl-substituted      190
Silicenium ions soivation of      190—191
Silicenium ions stabilities of      449
Silicenium ions substituted      187—190 448—450
Silicenium ions sulfur-substituted      188
Silicide clusters      1423
Silicocations      see «Silyl cations”
Silicocene      162 642
Silicon analytical determination of      394—398
Silicon atomic properties of      70 230
Silicon carbide fibers      43 48 1224 1233—1234
Silicon clusters      102
Silicon clusters transition-metal derivatives      1423—1424
Silicon dihalides, PE spectra of      570—571
Silicon dioxide      139
Silicon electronegativity of      895
Silicon halides enthalpies of formation of      389
Silicon halides PE spectra of      602—607
Silicon hydride cations, stabilities of      446—448
Silicon hydrides as reducing agents      1267 1274—1276
Silicon hydrides enthalpies of formation of      389
Silicon hydrides GC retention times for      421 422
Silicon hydrides NMR spectra of      530 531
Silicon isotope used in NMR      521
Silicon manufacture of      19
Silicon monoxide, PE spectrum of      570
Silicon oxide      139
Silicon sources of      18
Silicon tetrahalides, PE spectra of      604—607
Silicon uses of element      19
Silicon-$29(\sideset{^{29}}{}Si)$ ESR/ENDOR spectroscopy      577
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy      520—550
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy chemical shift ranges listed      523
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy electronegative substituent effect      524
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy organosilicon polymers      1309
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy paramagnetic relaxation reagent used      521
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy polarization transfer used      521 522
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy polysilane polymers      1232—1233
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy reference compounds used      522—523
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy solid-state NMR studies      544
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy spin-lattice relaxation      521 549—550
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy spin-spin couplings      547—549
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy transition-metal silyl complexes      1439 1440—1441
Silicon-$29(\sideset{^{29}}{}Si)$ NMR spectroscopy “sagging” pattern of chemical shifts      524
Silicon-bridged ring systems, photolysis of      981—984
Silicon-silicon bonds      249—254
Silicon-silicon bonds angles of      254
Silicon-silicon bonds dissociation energies of      385
Silicon-silicon bonds interactions, PE spectra affected by      587—593
Silicon-silicon bonds lengths of      249 251 1020
Silicon-silicon double bonds      234—236
Silicon-silicon double bonds length of      129—130
Silicon-X bonds bond dissociation energies of      77
Silicon-X bonds lengths of      71 74 1245
Silicon-X bonds strengths of      74—78
Silicon-X double bonds      103
Silicon-X multiple bonds in neutral compounds      481—483
Silicon-X multiple bonds ions containing      475—481
Siliconate anions, pentacoordinated form of      1265
Silicone oils, NMR spectra of      1318
Silicone polymers      31
Silicone polymers analysis of      410 413 415 419
Silicone polymers formation of      31 1013
Silicone polymers NMR spectra of      545—547 1318
Silicone polymers toxicological behavior of      1184
Silicones      see also «Organofunctional siloxanes”
Siliconic acids      33
Siliconium ions, pentacoordinated      191
Silidyne groups, analysis of      406—407
Silines      698
Siliranes      694
Silirenes      694
Silkina, N.N.      483 (123) 508
Silolanes      697
Silole derivatives      696 697
Silolenes      696
Silolidines      718
Siloxane copolymers air-liquid interface behavior of      1354—1355
Siloxane copolymers composition of      1313—1314
Siloxane copolymers degradation of      1333—1335
Siloxane copolymers direct (thermodynamic) analysis of      1316—1319
Siloxane copolymers kinetic-chain analysis for      1315
Siloxane copolymers macrostructure of      1311—1314
Siloxane copolymers microstructure of      1314—1319
Siloxane copolymers number average sequence length of      1315—1316
Siloxane groupings, analysis of      415
Siloxane polymers degradation of      1319—1341
Siloxane polymers molecular weights of      1301
Siloxane polymers NMR spectra of      545—547 1318
Siloxane polymers redistribution reactions in      1301—1302
Siloxane polymers surface activity of      1351—1354 1355—1356
Siloxane polymers toxicological behavior of      1184
Siloxanes analysis of      394 395 398 406 408 409 418—419
Siloxanes basicity of      822
Siloxanes biological activity of      1154—1155
Siloxanes enthalpies of formation of      381—382
Siloxanes GC separation of      428—429
Siloxanes IR analysis of      418—419
Siloxanes NMR spectra of      534—536
Siloxanes ring-chain equilibria of      1292—1294
Siloxanes synthesis of      724—725 (see also “Cyclosiloxanes”; “Organofunctional siloxanes”; “Polysiloxanes”)
Siloxetenes, formation during photolysis      990
Siloxiranes, formation during photolysis      977
Siloxthianes      1402
Siloxy transfer      460
Siloxycarbenes, formation during photolysis      985
Silthianes cage silthianes      1401
Silthianes cyclic silthianes      1401—1403
Silthianes linear silthianes      1400—1401
Silver, J.M.      130 (209b) 220
Silver, S.M.      945 (267) 962
Silverman, G.      188 (316) 223 449 506
Silverman, M.A.      309 351 366
Silyamines, acidity of      814
Silyisilylenium ion      190
Silyl acetate      831
Silyl acetate derivatives      458
Silyl anion reagents      1420 1424
Silyl anions      201—204
Silyl anions barrier to inversion of      1008
Silyl anions configurational stability of      1008—1009
Silyl anions lone-pair conjugation in      1009—1010
Silyl anions NMR spectra of      514
Silyl anions nomenclature of      1007
Silyl anions PE spectrum of      1008
Silyl anions preparation of      450 1007—1008
Silyl anions pyramidal inversion of      1008
Silyl anions reaction with imines      951
Silyl anions reactivity of      495
Silyl anions structure of      1008
Silyl anions substituted      201—204
Silyl arenes, GC separation of      430
Silyl arsines      1387—1389
Silyl bismuthines      1390
Silyl cations nomenclature of      1010
Silyl cations preparation of      1010—1011
Silyl cations structure of      1011—1013 (see also “Silylenium ions”)
Silyl chloride      180
Silyl chloride hydride attack on      208
Silyl enol ethers      732—737 1452 1467 1470
Silyl ester migration      469
Silyl esters as reagents      801—802
Silyl esters hydrolysis of      887—888
Silyl ethers basicity of      826
Silyl ethers GC separation of      429
Silyl ethers PE ionization energies of      636—639
Silyl fluoride      180
Silyl fluoride hydride attack on      208
Silyl Grignard reagents      330 1443
Silyl groups, electronic effects of      895—899
Silyl halides, PE ionization energies of      639—640
Silyl isocyanate      832 833
Silyl nitronates      830—831
Silyl peroxides, as reagents      802—803
Silyl radicals      198—200
Silyl radicals abstraction of hydrogen by      200
Silyl radicals PE spectra of      571
Silyl stibines      1389—1390
Silyl sulfides GC separation of      429
Silyl sulfides PE ionization energies of      636 638
Silyl thioacetate      832
Silyl thioethers, GC separation of      429
Silyl trioxides, as reagents      802
Silyl-nitrogen-X fragments, structural parameters of      258
Silyl-oxygen double bond, strength of      140
Silyl-oxygen-X fragments, structural parameters of      263
Silyl-substituted pentacoordinated silicon anions      206
Silyl-substituted phenyl cation      197
Silylacetylene      126 128 203
Silylacetylene radical cation, hyperconjugation in      593—596
Silylacetylenes      see «Silynes”
Silylamine      79 180
Silylamines basicity of      817 819—822 825
Silylamines bond angles of      13
Silylamines enthalpies of formation of      382—383
Silylamines IR analysis of      421
Silylamines PE ionization energies of      628—631
Silylamines proton affinities of      820—822
Silylamines structural parameters of      254—256
Silylamines synthesis of      1515—1516
Silylated penta-3,4-diene-l-ynes      680
Silylation methods nitrogen-containing compounds      715
Silylation methods oxygen-containing compounds      742—744
Silylbarbarlane, photolysis of      981
Silylcarbenes formation during photolysis      989 990
Silylcarbenes siienes synthesized from      1060—1061
Silylcarbonylation      1518—1520
Silyldiazoalkanes, photolysis of      989—990
Silyldisilene      89 136 172
Silylene      167—169
Silylene addition to ethylene      182
Silylene complexes      42 180 183
Silylene complexes indirect evidence for      1427—1429
Silylene complexes synthesis attempted for      1429—1432
Silylene dissociation of      182
Silylene fluorosilane      180
Silylene heat of formation of      168—169
Silylene hydrogen      176—179
Silylene hydrogen abstraction by triplet silylene      181
Silylene hydrogen chloride      180
Silylene hydrogen fluoride      180
Silylene hydrogen sulfide      180
Silylene insertion into ammonia      180
Silylene ion      448
Silylene methane      178
Silylene phosphine      180
Silylene silanc      178
Silylene singlet-triplet energy difference      167—168
Silylene water      180
Silylenes      35 167—184
Silylenes cyclic      185
Silylenes dimerization of      175—176 977 1021 1027
Silylenes enthalpies of formation of      387
Silylenes expulsion from cyclic di-/tri-silenes      979
Silylenes formation during photolysis      978 998
Silylenes insertion reactions of      176—183
Silylenes ionic species      483
Silylenes multisilylenes      185
Silylenes noncyclic      185
Silylenes PE spectra of      563—568
Silylenes reactions of      175—183
Silylenes rearrangement to disilenes      1024—1025 1027—1029
Silylenes silenes synthesized from      1059—1060
Silylenes singlet-triplet energy differences      167—173
Silylenes stereochemistry of expulsion process      979—980
Silylenes substituent effects      169—170
Silylenes substituted silylenes      169—173
Silylenes synthesis of      976
Silylenes thermochemistry of      377
Silylenes UV-visible spectra of      173—175 (see also “Transition-metal silylene compounds”)
Silylenium cation      186
Silylenium cation heat of formation of      186—187
Silylenium ions      184—193
Silylenium ions heat of formation of      191
Silylenium ions preparation of      1010—1011
Silylenium ions structure of      1011—1013
Silylethylenes      see «Silenes”
Silylethynes      see «Silynes”
Silylidene      146—147
Silylisonitrile      80
Silyllithium derivatives      80 269 270 636 787—789 1425
Silylmercury derivatives      269 270—272 330 540 636 641 1440
Silylmethanol      80
Silylmethyl cation      194
Silylmethyl ketone      196
Silylmethylene      113
Silylnitrile      80
Silylolefins      see «Silenes”
Silyloxazoles      690
Silyloxysilaethylene      119—123
Silyloxysilene      86
Silylphosphine      79 180
Silylphosphines acidity of      814
Silylphosphines reactions of      1365—1369
Silylphosphines structural parameters of      260
Silylphosphines synthesis of      1364
Silylphosphinometal derivatives      1384—1387
Silylpolyphosphines      1375—1376
Silylpolysulfides      1404
Silylpyridazines      693
Silylpyridines      692—693
Silylquinolizines      693—694
Silylsiiaethylene      119—123
Silylsilanone      140—141
Silylsilylene      131—133 172 178
Silynes      145—147 245
Silynes NMR spectra of      518
Silynes PE ionization energies of      620—622
Silynes synthesis of      677
Simchen, G.      682 693 734 754 759 800(152) 807
Simha, R.f.      1315 (141) 1359
Simhon, E.D.      1401 1408 1411
Simon, A.      48 (281) 56 246 249 296
Simon, G.L.      273 (346) 302
Simon, I.      419 (312) 440
Simonis, A.M.      1160 (143) 1202
Simons, J.H.      432 (411) 444
Simpson, C.C.      421 422 441
Simpson, J.      273 (344 345 349) 302 1418 1420 48 49) 1423 1434 134 135) 1435 1437 135) 1470 1471 1473
Simpson, K.A.      272 290 291 301 302 327 367 1437 1473
Simpson, P.      330 (97 99) 367
Simpson, R.N.F.      275 (369) 302 1434 1473
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