Patai S. — The Chemistry of Organic Silicon Compounds (part 1-2) :: Электронная библиотека попечительского совета мехмата МГУ

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Patai S. — The Chemistry of Organic Silicon Compounds (part 1-2)

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Название: The Chemistry of Organic Silicon Compounds (part 1-2)

Автор: Patai S.

Аннотация:

Organosilicon compounds are key organometallic compounds (R-Si) which have many uses in materials science and in metallurgy. Their applications include the synthesis of sugars and in the synthesis of organic compounds for the pharmaceutical industry. This volume will contain both updated chapters on key topics included in the original volumes as well as a number of new chapters reflecting the rapid developments made in silicon chemistry and its applications to organometallic chemistry, materials science, and semiconductors, over the last five years. As for the majority of volumes in this series, chapters will be prepared by leading scientists in the field.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 1989

Количество страниц: 1673

Добавлена в каталог: 16.04.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Showatka, K.H.      420 (332) 441
Shrinkage correction      259
Shrinkage correction $e-\pi$ - conjugation      see «Hyperconjugation”
Shrinkage correction e constants      525 526
Shtifman, L.M.      412 (184) 438
Shubert, D.C.      784 (93 94) 806
Shull, E.R.      414 415 438
Shulyat’eva, T.I.      426 (403) 442
Shumann, C.      548 (141) 553
Shvyrkova, L.A.      406 (119 120) 407 436
Shymanska, M.V.      921 (151) 959
Si-C spin-spin couplings      548
Si-H spin-spin couplings      548 (see also “Alkyl...”; “Alkyny...”; “Allyl...”; “Aryl...”; “Cyclosilanes”; “Disilanes”; “Optically active...”; “Poly...”; “Vinylsilanes”)
Sibermann, J.      334(114) 368
Sibille, S.      682 (140) 754
Sidorkin, V.F.      538 (95) 552
Sidorov, V.D.I.      1493 (83) 1522
Sidorov, V.I.      903 (75) 918 958 959 1515 1524
Siebel, D.      403 404 436
Siebel, G.H.R.      403 404 436
Siegbahn, K.      557 (27 28) 558 28) 615 28) 645
Siegbahn, P.E.M.      205 207 225
Siegel, D.A.      35 (191a) 54 532 552 1019 1020 1033 1133
Sievers, R.      260 (231) 299
Siganama, K.      1234 (122) 1240
Siggia, S.      405 (106) 436
Sigmatropic shifts disilenes      1034
Sigmatropic shifts silenes      1046—1049 1061 1066—1067 1076—1079
Sigwalt, P.      1303 (56 60) 1304 66 68) 1307 79) 1357 1358
Siklosi, M.P.      698 699 705 755
Sila-drugs      276—279 1159—1183
Silaacetylene      145—146
Silaacetylenes      see «Silynes”
Silaacyl complexes      1453—1458
Silaaldehydes      see «Silanones”
Silaalkenes      see «Silenes”
Silaalkynes      see «Silynes”
Silaallenes      125 128
Silaallenes dimerization of      1101
Silaallenes formation during photolysis      975
Silaaromatics photochemical generation of      1102
Silaaromatics photochemical reactivity of      1108
Silaaromatics preparation in solution      1106
Silaaromatics reactivity of      1107—1108
Silaaromatics synthesis of      1102—1106
Silaaromatics thermal generation of      1102—1105
Silaaromatics thermal reactivity of      1107—1108
Silabenzene      151—153
Silabenzene PE spectra of      560—563
Silabenzene silylene isomers      152
Silabenzenes      151—161
Silabenzenes degree of aromaticity of      152
Silabenzenes disilabenzenes      155—158
Silabenzenes hexasilabenzene      158—161
Silabenzenes ipso-substituted silabenzenes      155 156
Silabenzenes PE ionization energies of      624—627
Silabenzenes reactivity of      1107
Silabenzenes substituted silabenzenes      153—155
Silabenzenes synthesis of      1102—1106
Silabicyclo[1.1.0]butanes      100—101
Silabicyclo[2.2.2]octadienes      1056—1057
Silabolin, pharmacological properties of      1147—1148
Silabutadienes      125
Silabutadienes electrocyclic interconversion of      1079
Silacyclic compounds, enthalpies of formation of      378
Silacyclobutadiene      165—166
Silacyclobutadiene formation during photolysis      998
Silacyclobutane      101
Silacyclobutanes gas-phase reactions of      498
Silacyclobutanes photolysis of      971—972
Silacyclobutanes silenes synthesized from      1044 1050 1054—1056
Silacyclobutanes synthesis of      695
Silacyclobutenes      128
Silacyclobutenes electrocyclic interconversion of      1079
Silacyclobutenes photolysis of      972
Silacyclobutenes synthesis of      695
Silacyclohexadienes PE spectra of      562
Silacyclohexadienes photolysis of      980
Silacyclohexane derivatives, synthesis of      698
Silacyclopentadienyl anion      162—164 203 1010
Silacyclopentenes formation of      969
Silacyclopentenes photochemical reactions of      970—971
Silacyclopentenes synthesis of      696
Silacyclopropane      101
Silacyclopropanes      93 245
Silacyclopropanes formation of      974
Silacyclopropanes NMR spectra of      517—518 536
Silacyclopropanes photochemical rearrangements of      968—970
Silacyclopropanes photolysis of      997
Silacyclopropenes      101 102 126 245
Silacyclopropenes formation during photolysis      974
Silacyclopropenes NMR spectra of      536 537
Silacyclopropenes photochemical reactions of      995
Silacyclopropenium cation      162—163
Silacyclpphanes, synthesis of      705—706
Silaethene, PE spectrum of      563
Silaethenes      see «Silenes”
Silaethylene      106—119
Silaethylene $\pi$ -bond strength in      109—112
Silaethylene addition of to      117
Silaethylene addition of HCl to      117 118
Silaethylene addition reactions of      117—119
Silaethylene dimerization of      116—117
Silaethylene electronic structure of      112—113
Silaethylene geometry of      106 108—109
Silaethylene higher energy states of      109
Silaethylene hydrogenation of      119
Silaethylene infrared vibrational frequencies of      108—109 110
Silaethylene isomerization of      113—116
Silaethylene polarity of      112
Silaethylene reactions of      116—119
Silaethylene relative stability of      113—116
Silaethylene substituted silaethylenes      119—123
Silaethylene triplet states of      109
Silaethylenes      see «Silenes”
Silaethynes      see «Silynes”
Silaimines      see «Silanimines”
Silaindanes, formation of      974
Silaindenes, formation during photolysis      995
Silaisonitriles      150—151 1131—1133
Silaisonitriles phosphorus analogues of      151
Silaketimine adducts      240
Silaketimines      239—240
Silaketones      see «Silanones
Silalkynes, photochemical reactions of      995
Silamantane, PE spectrum of      616 617
Silamebrobamate derivatives, metabolic fate of      1185
Silameprobamate and derivatives      1159
Silameprobamate and derivatives metabolism of      1185
Silane      78
Silane bond dissociation energies of      388
Silane hydride affinity of      451—452
Silane ion      447
Silane PE spectrum of      590
Silane square-planar form      211
Silane tetrahedral form      211
Silanediol      81—83
Silanediols, synthesis of      724
Silanephosphimines      41 138—139 1116—1117
Silanephosphimines inversion at phosphorus atom      139
Silanes ionization energies of      618
Silanes ketones reduced by      776
Silanes nucleophile interactions      876—880
Silanes PE spectra of      588—593
Silaneselenones      1130—1131
Silanethiols      1403—1404
Silanethiols acidity of      813
Silanethiols synthesis of      745—746
Silanethione      143—145
Silanethione $\pi$ -bond in      143 145

Silanethione addition of to      145
Silanethione dimerization of      145
Silanethiones      42 143—145 1127—1130
Silanetriol      33
Silanimine      137
Silanimines      40—41 136—138
Silanimines $\pi$ -bond strength in      137
Silanimines 2+2 cycloaddition to      1114—1115
Silanimines 2+3 cycloaddition to      1115
Silanimines ene addition to      1115
Silanimines formation during photolysis      993
Silanimines hydrogenation reaction of      138
Silanimines inversion at nitrogen atom      137
Silanimines isolable silanimines      1109—1110
Silanimines nucleophilic addition to      1112—1114
Silanimines nucleophilic attack on      1112—1115
Silanimines nucleophilic cycloaddition to      1114—1115
Silanimines observation in solution      1110—1111
Silanimines photochemical generation of      1111—1112
Silanimines reactivity of      1112—1116
Silanimines structure of      1110
Silanimines synthesis of      1108—1112
Silanimines thermal generation of      1112
Silanimines transient species      1111—1112
Silanitriles      150—151 1131—1133
Silanitriles phosphorus analogues of      151
Silanol      79 180
Silanol enthalpy of formation of      381
Silanol square-planar form      211
Silanolate anions, structural parameters of      263 264
Silanols acidity of      812—813
Silanols analysis of      409—410 419
Silanols basicity of      822
Silanols biological activity of      1152—1154
Silanols GC separation of      430
Silanols reactions of      31
Silanols synthesis of      722—724
Silanone      140
Silanone addition of to      142
Silanone bond strength in      140
Silanone dimerization of      142—143
Silanone triplet state of      140
Silanone unimolecular decomposition of      141
Silanones      42 139—143
Silanones by cycloreversion      1123—1124
Silanones by oxygen atom transfer      1124—1126
Silanones by silanolate fragmentation      1124
Silanones formation during photolysis      999
Silanones matrix-isolated silanones      1118—1119
Silanones nucleophilic addition to      1126—1127
Silanones nucleophilic cycloaddition to      1127
Silanones photochemical generation of      1119—1120
Silanones reactions of      141—143
Silanones reactivity of      1126—1127
Silanones substituted silanones      140—141
Silanones synthesis of      1117—1126
Silanones thermal generation of      1120—1126
Silanones transient species      1119—1126
Silanorbornene derivatives NMR spectra of      537 538
Silanorbornene derivatives reactions of      1057 1071
Silaolefins      see «Silenes”
Silaoxacycloalkanes      739—741
Silaoxaparacyclophanes      742
Silaphosphenes      1383
Silaprocyclidine      1174
Silaprocyclidine metabolic fate of      1188
Silapropadiene, formation during photolysis      974
Silaspiropentanes      102
Silatetrahedrane      101
Silathioketene      129
Silatoluene      151 153
Silatoluene PE ionization energy of      624
Silatoluene PE spectra of      560—563
Silatranes      229 279 289—290 829
Silatranes biological activity of      1150—1152
Silatranes enthalpies of formation of      383
Silatranes NMR spectra of      537—538
Silatranes structure of      1244
Silatranes synthesis of      737—739
Silatranes toxicity of      1151 1183
Silatranones, NMR spectra of      540
Silazanes NMR spectra of      547
Silazanes synthesis of      709—710
Silenate adducts, formation of      1044—1045 1083—1085
Silene adducts      39 40 238
Silene complexes, transition-metal derivatives      1432—1433
Silenes      38—40 105—129 245
Silenes 1,2-shift of      1072—1076
Silenes 2+2 cycloadditions to      1090—1093
Silenes 3+2 cycloadditions to      1093—1094
Silenes 4+2 cycloadditions to      1090—1093
Silenes addition of to      123—124
Silenes addition of HCl to      123—124
Silenes addition reactions of      117—119
Silenes adducts formed      39 40
Silenes bimolecular reactions of      1083—1102
Silenes by 1,2-elimination      1062 1067—1070
Silenes by 1,2-shift      1046
Silenes by 2+2 cycloreversion      1050 1063—1064
Silenes by 2+3 cycloreversion      1053—1056
Silenes by 4+2 cycloreversion      1056—1057 1064
Silenes by addition of CO to silylenes      1051
Silenes by dehalogenation      1062
Silenes by dehydrogenation      1062—1063
Silenes by electrophilic ring opening      1049—1050
Silenes by hydrogen atom abstraction      1050—1051
Silenes by pericyclic processes      1061—1062
Silenes by photofragmentation of silanes/disilanes      1051
Silenes by pyrolysis      1051—1063
Silenes by radical disproportionation/fragmentation      1062
Silenes by rearrangement of carbenes/silylenes      1058—1061
Silenes by retro-ene fragmentation      1057—1058
Silenes by sigmatropic shifts      1046—1049 1061 1066—1067
Silenes by silylcarbene-to-silene rearrangement      1060—1061 1064—1066
Silenes by silylene-to-silene rearrangement      1059—1060
Silenes by substituent transposition on alkenes      1070
Silenes by thermal reactions in solution      1063—1070
Silenes deprotonation of      1102
Silenes dimerization of      116—117 1100—1101
Silenes electrocyclic interconversion in      1079
Silenes enereactions of      1079—1080
Silenes formation during photolysis      971 973 987 991
Silenes geometrical isomerization of      1070—1072
Silenes geometries of      119—121
Silenes intramolecular hydrogen atom abstraction reactions of      1080—1081
Silenes intramolecular nucleophilic attack in      1081
Silenes isolable      1044—1046
Silenes isomerization to silylenes      1072—1076
Silenes Lewis basicity towards      39
Silenes metathesis reaction of      143
Silenes NMR spectra of      518 519 520 532—533
Silenes nucleophilic addition to      1085—1090
Silenes nucleophilic cycloaddition to      1090—1094
Silenes nucleophilic ene reactions of      1095
Silenes one-electron reduction of      1036—1037
Silenes PE ionization energies of      619—620
Silenes pericyclic reactions of      1095—1099
Silenes photochemical generation of      1046—1051
Silenes photochemical isomerization of      1082—1083
Silenes photochemical reactions of      991—992
Silenes photochemical synthesis of      971—972
Silenes preparation of      38—39 1044—1045 1046—1070
Silenes prochiral silenes      314
Silenes radical attack on      1101
Silenes reactions of      39 40 122—124
Silenes reactivity of      1070—1102
Silenes rearrangements of      991
Silenes retro-ene reactions of      1079—1080
Silenes sigmatropic shifts in      1076—1079
Silenes silenate formation from      1083—1085

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