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Carey F.A. — Organic Chemistry

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Название: Organic Chemistry

Автор: Carey F.A.

Аннотация:

This respected text is based on the Functional Group approach. The text retains the outstanding problems, pedagogy, depth, and prose of the second edition while providing increased emphasis on molecular modeling, a core concept in organic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 2004

Количество страниц: 1191

Добавлена в каталог: 20.04.2006

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Ethylene acidity of      37 367 369 593
Ethylene as industrial chemical      189 269 483 644
Ethylene biosynthesis of      189
Ethylene bond dissociation energies in      367
Ethylene bonding in      14 89—92 99 190—191 220
Ethylene dehydrogenation of ethane      189 202
Ethylene dibromide      see “1
Ethylene discovery      189
Ethylene electrostatic potential map      187 236 366
Ethylene glycol      269 634 682
Ethylene glycol electrostatic potential map      623
Ethylene glycol polyesters      868
Ethylene heat of hydrogenation      231 233
Ethylene natural occurrence      189
Ethylene oxide      132 260 269 666
Ethylene oxide dipole moment      667
Ethylene oxide industrial preparation of      269 644
Ethylene oxide reactions with nucleophiles      632—633 654 678—679 681—682
Ethylene oxide structure of      667
Ethylene preparation of dehydration of ethyl alcohol      203
Ethylene reactions of alkylation of benzene      483
Ethylene reactions of dehydrogenation      364
Ethylene reactions of hydration of      249
Ethylene reactions of hydrogenation of      230
Ethylene reactions of oxidation of      644
Ethylene reactions of polymerization of      267—268 271 270 610 612—614 617
Ethylene reactions of structure of      89—90 191 367
Ethylene reactions of with bromine      256
Ethylenebromonium ion      257—258
Ethylmagnesium bromide, reaction of with acetophenone      600
Ethylmagnesium bromide, reaction of with alkynes      598
Ethylmagnesium bromide, reaction of with cyclohexanone      713
Ethyloxonium ion as intermediate in dehydration of ethyl alcohol      208
Ethyloxonium ion as intermediate in formation of diethyl ether      637
Ethyne      see “Acetylene”
Ethynyl group      365
Exergonic      1162
Exothermic reaction      11 83
Exothermic reaction and relation to bond energies      174
Faraday, Michael      408 424
Farnesene      187
Farnesol      1084 1086 1089
Farnesol pyrophosphate      1088
Fats      846 1071—1074
Fatty acids      846 853 1071—1074
Fatty acids biosynthesis of      1075—1077
Fatty acids essential      1080
Fatty acids esters of      846 1077—1079
Fatty acids fats as sources of      846 853 1072
Fatty acids trans      1072 1074
Fehling’s solution      1054
Fermentation      624
Ferrocene      609
Ferrocene electrostatic potential map      587
Fibroin      1144
Fibrous proteins      1145
Field effect      803
Fieser, Louis F.      1032
Fieser, Mary      1032
Fingerprint region of infrared spectrum      559
First point of difference rule, IUPAC nomenclature      76 434 914
Fischer esterification      see “Esterification; Esters”
Fischer projection formulas      293—295 302 304 316 640
Fischer projection formulas $\alpha$ -amino acids      1115—1116 1150
Fischer projection formulas carbohydrates      1027—1028 1061
Fischer projection formulas of meso stereoisomer      304
Fischer projection formulas tartaric acids      310
Fischer, Emil      293
Fischer, Emil determination of glucose structure by      1052 1068
Flagpole hydrogens      117
Fleming, Sir Alexander      4
Fluorinated hydrocarbons      148—150
Fluorine electron-dot structure of       13
Fluorine electronegativity      15
Fluorine magnetic resonance spectroscopy of $\sideset{^{19}}{}F$       580
Fluorine reaction with alkanes      166 174
Fluorobenzene physical properties      995
Fluorobenzene preparation of      973
Fluorocyclohexane      123
Fluoroethane, attractive forces in      148
Fluoromethane      see “Methyl fluoride”
Formal charge      17—21 48
Formaldehyde      263 703
Formaldehyde electrostatic potential map      703
Formaldehyde hydration of      714 715
Formaldehyde in mixed aldol addition      774
Formaldehyde industrial preparation of      624 710
Formaldehyde reaction with Grignard reagents      596 599 616
Formaldehyde structure and bonding      14 706—707
Formaldehyde VSEPR and molecular geometry of      30
Formic acid      54 792
Formic acid natural occurrence      806
Formic acid structure and bonding      793—794
Fourier-transform spectroscopy infrared (FF-IR)      559
Fourier-transform spectroscopy nuclear magnetic resonance (FF-NMR)      524 553
Fragment condensation in peptide synthesis      1141
Fragmentation in mass spectrometry      570—571
Franklin, Rosalind      1167
Free energy, relation to equilibrium constant      122—123 795—796
Free energy, relation to equilibrium constant and bioenergetics      1162—1164
Free radical      167—178 181—182
Free radical allylic      390 396—398 416
Free radical as intermediates in addition of hydrogen bromide to alkenes      242—245 274
Free radical as intermediates in allylic halogenation      396—398 416
Free radical as intermediates in benzylic halogenation      441—443
Free radical as intermediates in halogenation of alkanes      166—178 181—182
Free radical as intermediates in polymerization of alkenes      267—268
Free radical benzylic      439 440
Free radical bonding in      168 181
Free radical chain reactions of      172—178 181—182
Free radical stabilization by alkyl groups      168—169 181
Freons      51
Friedel — Crafts acylation mechanism of      485
Friedel — Crafts acylation of 2-ethylacetanilide      942
Friedel — Crafts acylation of anisole      510 710
Friedel — Crafts acylation of benzene      484—488 504 505
Friedel — Crafts acylation of bromobenzene      504 974
Friedel — Crafts acylation of furan      508
Friedel — Crafts acylation of naphthalene      506—507
Friedel — Crafts acylation of p-xylene      502
Friedel — Crafts acylation of phenol      1004
Friedel — Crafts acylation scope and limitations      511 table
Friedel — Crafts acylation with acyl chlorides      475 484—485 838 1004
Friedel — Crafts acylation with carboxylic acid anhydrides      485—486 842 974
Friedel — Crafts alkylation      483 511
Friedel — Crafts alkylation of benzene      481—483 510
Friedel — Crafts alkylation of o-cresol      1003
Friedel — Crafts alkylation scope and limitations      511 table
Friedel — Crafts alkylation with alcohols      1003
Friedel — Crafts alkylation with alkenes      483
Friedel — Crafts alkylation with alkyl halides      475 481—483 510
Friedel, Charles      481
Fries rearrangement      1006
Frontier orbitals      412
Frost, Arthur A.      452
Frost’s circle      452 454
Fukui, Kenichi      415
Fullerenes      436—437
Fumarase      299—300
Fumaric acid      202 299—300
Functional class nomenclature of alcohols      145
Functional class nomenclature of alkyl halides      144—145
Functional groups      142—144 178
Functional groups and infrared spectroscopy      519 559 577
Functional groups tables of, inside front cover      143
Functional groups transformation of, by nucleophilic substitution      327—329
Furan      460
Furan 2-mercaptomethyl      649
Furan bonding in      462
Furan electrophilic aromatic substitution in      507—508

Furanose forms of carbohydrates      1032—1036
Furchgott, Robert F.      1149
Furfural      460 736 807
G (symbol for free energy)      122
GABA      see “ $\gamma$ -Aminobutyric acid”
Gabriel synthesis      929—931 956
Gabriel, Siegmund      929
Gas chromatography (GC)      572—573
Gasoline      79—80
Gauche butane interactions      121—122
Gauche conformation      106
Gauche conformation in preparation of alkynes      372—374 383
Gauche conformation of butane      109 133
Gel electrophoresis      see “Electrophoresis”
Geminal coupling      542
Geminal dihalides by hydrogen halide addition to alkynes      378 385
Geminal diols      see “Diols”
Generic names of drugs      78
genetic code      1175
Geneva rules      78
Genomics      1183
Geometric isomers      124 (see also “Stereoisomers”)
Geraniol      224 1088
Geraniol pyrophosphate      1088—1089
Geranylgeraniol      1089
Gilbert, Walter      1181
Globular proteins      1145
Glutathione      651
Glycals      1046
Glycerol      see also “Phosphoglycerides”
Glycerol esters      846 853 1071—1072 1077—1079 1101 1102
Glycine      1111 1113 1115
Glycine acetylation      1123
Glycine acid-base properties      36 1117—1119
Glycine electrostatic potential map      1114
Glycine ethyl ester      1139 1141
Glycogen      1050
Glycolysis      1056—1058
Glycoproteins      1050
Glycosides      1043—1046 1062
Goodyear, Charles      408
Grain alcohol      145 (see also “Ethanol”)
graphite      436
Green chemistry      644
Grignard reagents acetylenic      594 597—598
Grignard reagents basicity of      592—594 614
Grignard reagents preparation of      591—592 615
Grignard reagents reactions of carboxylation      806—808 822
Grignard reagents reactions of with $\alpha,\beta$ -unsaturated aldehydes and ketones      777
Grignard reagents reactions of with aldehydes      596 616 711 713
Grignard reagents reactions of with epoxides      632—633 654 678 681
Grignard reagents reactions of with esters      601—602 616 627 848
Grignard reagents reactions of with formaldehyde      596 599 616 626
Grignard reagents reactions of with ketones      596 600 616 713
Grignard reagents reactions of with nitriles      871—872 877
Grignard, Victor      591
Guaiacol      1010
Guanine      1157 1166—1168
Guanosine      1159
Gum benzoin      424
Gutta percha      408
Gutte, Bernd      1142
H (symbol for enthalpy)      84
h (symbol for Planck’s constant)      520
Half-chair conformation      120
Halides      see “Acyl chlorides”; “Alkenyl halides”; “Alkyl halides”; “Aryl halides”
Halogen addition      see also “Bromine; Chlorine”
Halogen addition to alkenes      254—259 273 307—310
Halogen addition to alkynes      381 385
Halogen addition to conjugated dienes      407
Halogenation      see also “Bromination; Chlorination”
Halogenation aldehydes and ketones      757—759 767 782
Halogenation carboxylic acids      815—816 823
Halogenation electrophilic aromatic substitution      475 480—481 497 499 500—502 503 504 505 510 973
Halogenation free radical allylic      396—398 416
Halogenation free radical benzylic      439 441—443
Halogenation free radical of alkanes      166—178 181—182
Halohydrins conversion to epoxides      676—678 693
Halohydrins from epoxides      683
Halohydrins preparation of, from alkenes      259—260 273
Halonium ion      257—259 259—260 273
Halothane      51
Hammond, George S.      155
Hammond’s postulate      156
Hassel, Odd      116
Haworth formulas      1034
Haworth, Sir Norman      1034
Heat of combustion      84
Heat of combustion aldehydes and ketones      708
Heat of combustion alkanes      84—87
Heat of combustion alkenes      197—198
Heat of combustion cis and travis-1,2-dimethylcyclopropane      124—125
Heat of combustion cycloalkanes      113 table
Heat of combustion dimethylcyclohexanes      126 table
Heat of formation      86
Heat of hydrogenation      231
Heat of hydrogenation (Z)- 1,3,5-hexatriene      429
Heat of hydrogenation 1,3-cyclohexadiene      429
Heat of hydrogenation alkadienes      399—400
Heat of hydrogenation alkenes      231—234
Heat of hydrogenation alkynes      374—375
Heat of hydrogenation allene      400
Heat of hydrogenation benzene      429
Heat of hydrogenation butene isomers      231—233
Heat of reaction      86 174
Hell — Volhard — Zelinsky reaction      815—816 823
Heme      1147—1148
Hemiacetal      720
Hemiacetal cyclic, of carbohydrates      1032—1039
Hemiketal      see “Hemiacetal”
Hemoglobin      1148 1150
Henderson — Hasselbalch equation      798 919
Heptanal cyclic acetal of      722
Heptanal in reductive amination      934
Heptanal oxime      727
Heptanal preparation of      642
Heptane      71
Heptane chlorination of      185
Heroin      924
Hertz, Heinrich R.      520
HETCOR      see “Correlated spectroscopy”
Heterocyclic compounds      see also “Furan”; “Purine”; “Pyridine”; “Pyrimidine; “Pyrrole”
Heterocyclic compounds aliphatic      131—132 136 666
Heterocyclic compounds amines      922—923
Heterocyclic compounds aromatic      460—463 467 1155—1160
Heterocyclic compounds aromatic electrophilic aromatic substitution in      507—508
Heterocyclic compounds aromatic nucleophilic aromatic substitution in      981
Heterogeneous reaction      231
Heterolytic bond cleavage      169 327
Hexachlorophene      54
Hexafiuorobenzene      980 1020
Hexafluoroacetone      715
Hexafluoroethane      150
Hexane      71
Hexane conformation of      110 112
Hexane infrared spectrum      560
Hexylmagnesium bromide, reaction of with acetaldehyde      596
Hexylmagnesium bromide, reaction of with ethylene oxide      633
High-density lipoprotein      1096
Highest occupied molecular orbital      see “HOMO”
Histamine      1126
Histone      1171
Hodgkin, Dorothy Crowfoot      611
Hofmann elimination      938—940 958
Hofmann rule      938
Hofmann, August W.      424 938
Holley, Robert W.      1175
HOMO (highest occupied molecular orbital)      412
HOMO-LUMO interactions in pericyclic reactions cycloaddition      414—415
HOMO-LUMO transitions in ultraviolet-visible spectroscopy      565—566

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