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| Àâòîðèçàöèÿ |
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| Ïîèñê ïî óêàçàòåëÿì |
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| Carey F.A. — Organic Chemistry |
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| Ïðåäìåòíûé óêàçàòåëü |
Ethylene acidity of 37 367 369 593
Ethylene as industrial chemical 189 269 483 644
Ethylene biosynthesis of 189
Ethylene bond dissociation energies in 367
Ethylene bonding in 14 89—92 99 190—191 220
Ethylene dehydrogenation of ethane 189 202
Ethylene dibromide see “1
Ethylene discovery 189
Ethylene electrostatic potential map 187 236 366
Ethylene glycol 269 634 682
Ethylene glycol electrostatic potential map 623
Ethylene glycol polyesters 868
Ethylene heat of hydrogenation 231 233
Ethylene natural occurrence 189
Ethylene oxide 132 260 269 666
Ethylene oxide dipole moment 667
Ethylene oxide industrial preparation of 269 644
Ethylene oxide reactions with nucleophiles 632—633 654 678—679 681—682
Ethylene oxide structure of 667
Ethylene preparation of dehydration of ethyl alcohol 203
Ethylene reactions of alkylation of benzene 483
Ethylene reactions of dehydrogenation 364
Ethylene reactions of hydration of 249
Ethylene reactions of hydrogenation of 230
Ethylene reactions of oxidation of 644
Ethylene reactions of polymerization of 267—268 271 270 610 612—614 617
Ethylene reactions of structure of 89—90 191 367
Ethylene reactions of with bromine 256
Ethylenebromonium ion 257—258
Ethylmagnesium bromide, reaction of with acetophenone 600
Ethylmagnesium bromide, reaction of with alkynes 598
Ethylmagnesium bromide, reaction of with cyclohexanone 713
Ethyloxonium ion as intermediate in dehydration of ethyl alcohol 208
Ethyloxonium ion as intermediate in formation of diethyl ether 637
Ethyne see “Acetylene”
Ethynyl group 365
Exergonic 1162
Exothermic reaction 11 83
Exothermic reaction and relation to bond energies 174
Faraday, Michael 408 424
Farnesene 187
Farnesol 1084 1086 1089
Farnesol pyrophosphate 1088
Fats 846 1071—1074
Fatty acids 846 853 1071—1074
Fatty acids biosynthesis of 1075—1077
Fatty acids essential 1080
Fatty acids esters of 846 1077—1079
Fatty acids fats as sources of 846 853 1072
Fatty acids trans 1072 1074
Fehling’s solution 1054
Fermentation 624
Ferrocene 609
Ferrocene electrostatic potential map 587
Fibroin 1144
Fibrous proteins 1145
Field effect 803
Fieser, Louis F. 1032
Fieser, Mary 1032
Fingerprint region of infrared spectrum 559
First point of difference rule, IUPAC nomenclature 76 434 914
Fischer esterification see “Esterification; Esters”
Fischer projection formulas 293—295 302 304 316 640
Fischer projection formulas  -amino acids 1115—1116 1150
Fischer projection formulas carbohydrates 1027—1028 1061
Fischer projection formulas of meso stereoisomer 304
Fischer projection formulas tartaric acids 310
Fischer, Emil 293
Fischer, Emil determination of glucose structure by 1052 1068
Flagpole hydrogens 117
Fleming, Sir Alexander 4
Fluorinated hydrocarbons 148—150
Fluorine electron-dot structure of  13
Fluorine electronegativity 15
Fluorine magnetic resonance spectroscopy of  580
Fluorine reaction with alkanes 166 174
Fluorobenzene physical properties 995
Fluorobenzene preparation of 973
Fluorocyclohexane 123
Fluoroethane, attractive forces in 148
Fluoromethane see “Methyl fluoride”
Formal charge 17—21 48
Formaldehyde 263 703
Formaldehyde electrostatic potential map 703
Formaldehyde hydration of 714 715
Formaldehyde in mixed aldol addition 774
Formaldehyde industrial preparation of 624 710
Formaldehyde reaction with Grignard reagents 596 599 616
Formaldehyde structure and bonding 14 706—707
Formaldehyde VSEPR and molecular geometry of 30
Formic acid 54 792
Formic acid natural occurrence 806
Formic acid structure and bonding 793—794
Fourier-transform spectroscopy infrared (FF-IR) 559
Fourier-transform spectroscopy nuclear magnetic resonance (FF-NMR) 524 553
Fragment condensation in peptide synthesis 1141
Fragmentation in mass spectrometry 570—571
Franklin, Rosalind 1167
Free energy, relation to equilibrium constant 122—123 795—796
Free energy, relation to equilibrium constant and bioenergetics 1162—1164
Free radical 167—178 181—182
Free radical allylic 390 396—398 416
Free radical as intermediates in addition of hydrogen bromide to alkenes 242—245 274
Free radical as intermediates in allylic halogenation 396—398 416
Free radical as intermediates in benzylic halogenation 441—443
Free radical as intermediates in halogenation of alkanes 166—178 181—182
Free radical as intermediates in polymerization of alkenes 267—268
Free radical benzylic 439 440
Free radical bonding in 168 181
Free radical chain reactions of 172—178 181—182
Free radical stabilization by alkyl groups 168—169 181
Freons 51
Friedel — Crafts acylation mechanism of 485
Friedel — Crafts acylation of 2-ethylacetanilide 942
Friedel — Crafts acylation of anisole 510 710
Friedel — Crafts acylation of benzene 484—488 504 505
Friedel — Crafts acylation of bromobenzene 504 974
Friedel — Crafts acylation of furan 508
Friedel — Crafts acylation of naphthalene 506—507
Friedel — Crafts acylation of p-xylene 502
Friedel — Crafts acylation of phenol 1004
Friedel — Crafts acylation scope and limitations 511 table
Friedel — Crafts acylation with acyl chlorides 475 484—485 838 1004
Friedel — Crafts acylation with carboxylic acid anhydrides 485—486 842 974
Friedel — Crafts alkylation 483 511
Friedel — Crafts alkylation of benzene 481—483 510
Friedel — Crafts alkylation of o-cresol 1003
Friedel — Crafts alkylation scope and limitations 511 table
Friedel — Crafts alkylation with alcohols 1003
Friedel — Crafts alkylation with alkenes 483
Friedel — Crafts alkylation with alkyl halides 475 481—483 510
Friedel, Charles 481
Fries rearrangement 1006
Frontier orbitals 412
Frost, Arthur A. 452
Frost’s circle 452 454
Fukui, Kenichi 415
Fullerenes 436—437
Fumarase 299—300
Fumaric acid 202 299—300
Functional class nomenclature of alcohols 145
Functional class nomenclature of alkyl halides 144—145
Functional groups 142—144 178
Functional groups and infrared spectroscopy 519 559 577
Functional groups tables of, inside front cover 143
Functional groups transformation of, by nucleophilic substitution 327—329
Furan 460
Furan 2-mercaptomethyl 649
Furan bonding in 462
Furan electrophilic aromatic substitution in 507—508
| Furanose forms of carbohydrates 1032—1036
Furchgott, Robert F. 1149
Furfural 460 736 807
G (symbol for free energy) 122
GABA see “ -Aminobutyric acid”
Gabriel synthesis 929—931 956
Gabriel, Siegmund 929
Gas chromatography (GC) 572—573
Gasoline 79—80
Gauche butane interactions 121—122
Gauche conformation 106
Gauche conformation in preparation of alkynes 372—374 383
Gauche conformation of butane 109 133
Gel electrophoresis see “Electrophoresis”
Geminal coupling 542
Geminal dihalides by hydrogen halide addition to alkynes 378 385
Geminal diols see “Diols”
Generic names of drugs 78
genetic code 1175
Geneva rules 78
Genomics 1183
Geometric isomers 124 (see also “Stereoisomers”)
Geraniol 224 1088
Geraniol pyrophosphate 1088—1089
Geranylgeraniol 1089
Gilbert, Walter 1181
Globular proteins 1145
Glutathione 651
Glycals 1046
Glycerol see also “Phosphoglycerides”
Glycerol esters 846 853 1071—1072 1077—1079 1101 1102
Glycine 1111 1113 1115
Glycine acetylation 1123
Glycine acid-base properties 36 1117—1119
Glycine electrostatic potential map 1114
Glycine ethyl ester 1139 1141
Glycogen 1050
Glycolysis 1056—1058
Glycoproteins 1050
Glycosides 1043—1046 1062
Goodyear, Charles 408
Grain alcohol 145 (see also “Ethanol”)
graphite 436
Green chemistry 644
Grignard reagents acetylenic 594 597—598
Grignard reagents basicity of 592—594 614
Grignard reagents preparation of 591—592 615
Grignard reagents reactions of carboxylation 806—808 822
Grignard reagents reactions of with  -unsaturated aldehydes and ketones 777
Grignard reagents reactions of with aldehydes 596 616 711 713
Grignard reagents reactions of with epoxides 632—633 654 678 681
Grignard reagents reactions of with esters 601—602 616 627 848
Grignard reagents reactions of with formaldehyde 596 599 616 626
Grignard reagents reactions of with ketones 596 600 616 713
Grignard reagents reactions of with nitriles 871—872 877
Grignard, Victor 591
Guaiacol 1010
Guanine 1157 1166—1168
Guanosine 1159
Gum benzoin 424
Gutta percha 408
Gutte, Bernd 1142
H (symbol for enthalpy) 84
h (symbol for Planck’s constant) 520
Half-chair conformation 120
Halides see “Acyl chlorides”; “Alkenyl halides”; “Alkyl halides”; “Aryl halides”
Halogen addition see also “Bromine; Chlorine”
Halogen addition to alkenes 254—259 273 307—310
Halogen addition to alkynes 381 385
Halogen addition to conjugated dienes 407
Halogenation see also “Bromination; Chlorination”
Halogenation aldehydes and ketones 757—759 767 782
Halogenation carboxylic acids 815—816 823
Halogenation electrophilic aromatic substitution 475 480—481 497 499 500—502 503 504 505 510 973
Halogenation free radical allylic 396—398 416
Halogenation free radical benzylic 439 441—443
Halogenation free radical of alkanes 166—178 181—182
Halohydrins conversion to epoxides 676—678 693
Halohydrins from epoxides 683
Halohydrins preparation of, from alkenes 259—260 273
Halonium ion 257—259 259—260 273
Halothane 51
Hammond, George S. 155
Hammond’s postulate 156
Hassel, Odd 116
Haworth formulas 1034
Haworth, Sir Norman 1034
Heat of combustion 84
Heat of combustion aldehydes and ketones 708
Heat of combustion alkanes 84—87
Heat of combustion alkenes 197—198
Heat of combustion cis and travis-1,2-dimethylcyclopropane 124—125
Heat of combustion cycloalkanes 113 table
Heat of combustion dimethylcyclohexanes 126 table
Heat of formation 86
Heat of hydrogenation 231
Heat of hydrogenation (Z)- 1,3,5-hexatriene 429
Heat of hydrogenation 1,3-cyclohexadiene 429
Heat of hydrogenation alkadienes 399—400
Heat of hydrogenation alkenes 231—234
Heat of hydrogenation alkynes 374—375
Heat of hydrogenation allene 400
Heat of hydrogenation benzene 429
Heat of hydrogenation butene isomers 231—233
Heat of reaction 86 174
Hell — Volhard — Zelinsky reaction 815—816 823
Heme 1147—1148
Hemiacetal 720
Hemiacetal cyclic, of carbohydrates 1032—1039
Hemiketal see “Hemiacetal”
Hemoglobin 1148 1150
Henderson — Hasselbalch equation 798 919
Heptanal cyclic acetal of 722
Heptanal in reductive amination 934
Heptanal oxime 727
Heptanal preparation of 642
Heptane 71
Heptane chlorination of 185
Heroin 924
Hertz, Heinrich R. 520
HETCOR see “Correlated spectroscopy”
Heterocyclic compounds see also “Furan”; “Purine”; “Pyridine”; “Pyrimidine; “Pyrrole”
Heterocyclic compounds aliphatic 131—132 136 666
Heterocyclic compounds amines 922—923
Heterocyclic compounds aromatic 460—463 467 1155—1160
Heterocyclic compounds aromatic electrophilic aromatic substitution in 507—508
Heterocyclic compounds aromatic nucleophilic aromatic substitution in 981
Heterogeneous reaction 231
Heterolytic bond cleavage 169 327
Hexachlorophene 54
Hexafiuorobenzene 980 1020
Hexafluoroacetone 715
Hexafluoroethane 150
Hexane 71
Hexane conformation of 110 112
Hexane infrared spectrum 560
Hexylmagnesium bromide, reaction of with acetaldehyde 596
Hexylmagnesium bromide, reaction of with ethylene oxide 633
High-density lipoprotein 1096
Highest occupied molecular orbital see “HOMO”
Histamine 1126
Histone 1171
Hodgkin, Dorothy Crowfoot 611
Hofmann elimination 938—940 958
Hofmann rule 938
Hofmann, August W. 424 938
Holley, Robert W. 1175
HOMO (highest occupied molecular orbital) 412
HOMO-LUMO interactions in pericyclic reactions cycloaddition 414—415
HOMO-LUMO transitions in ultraviolet-visible spectroscopy 565—566
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