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| Àâòîðèçàöèÿ |
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| Ïîèñê ïî óêàçàòåëÿì |
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| Carey F.A. — Organic Chemistry |
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| Ïðåäìåòíûé óêàçàòåëü |
Bromination p-aminobenzoic acid 942
Bromination p-nitrotoluene 502
Bromination phenol 510 1003
Bromine see also “Bromination”
Bromine oxidation of carbohydrates by 1054 1063
Bromobenzene Friedel — Crafts acylation of 974
Bromobenzene preparation of 475 480
Bromobenzene reactions of with lithium 590
Bromobenzene with magnesium 591 974
Bromochlorofluoromethane as a chiral molecule 282
Bromochlorofluoromethane electrostatic potential map 281
Bromochlorofluoromethane Fischer projections 293
Bromoform 526 766 782
Bromohydrin see “Halohydrins”
Bromonium ion see “Halonium ion”
Bronsted acid see “Acidity”
Bronsted base see “Basicity”
Bronsted, Johannes 33
Brown, Herbert C. 250
Buckminsterfullerene 436—437
Butanal aldol reactions 770 772
Butanal dipole moment 776
Butanal heat of combustion 708
Butanal infrared spectrum 739
Butanal reductive amination of 935
Butanamine see “Butylamine”
Butane 71 (see also “n-Butane”)
Butane chlorination of 175—176 298
Butane conformations of 109—112 133
Butanoic acid biosynthesis of 1075—1076
Butanoic acid bromination of 816
Butleroy, Alexander 3
Butyl bromide see also “1-Bromobutane”
Butyl bromide, preparation from 1-butanol 152
Butyl bromide, reaction with sodium cyanide 923 926
Butyl group 74 (see also “n-Butyl group”
Butyl radical 175—176
Butylamine, acylation of 936
Butylamine, infrared spectrum 952
Butyllithium reactions of 592 627
Butyraldehyde see “Butanal”
Butyric acid 806 (see also “Butanoic acid”)
c, speed of light 520
Caffeine 1158
Cahn, R. S. 194
Cahn-Ingold-Prelog (CIP) system of stereochemical notation chiral molecules 290—293 316
Cahn-Ingold-Prelog (CIP) system of stereochemical notation priority rules 193—194 195
Calcium carbide 364
Calicene 471
Camphene 130
Cantharadin 841
Carbamate esters 912
Carbanion 369 589
Carbanion as intermediate in nucleophilic aromatic substitution 977—981
Carbanion basicity of 369 593—594
Carbanion bonding in 369
Carbanion enolate ion 763
Carbenes and carbenoids 606—608 615
Carbenium ions see “Carbocations”
Carbinolamine intermediates 724—726 727
Carbobenzoxy see ‘Benzyloxycarbonyl”
Carbocations acyl cations 484—486
Carbocations alkenyl cations 377—378
Carbocations allylic 390 391—394 405—407 416
Carbocations arenium ions 474 (see also “Cyclohexadienyl cation”)
Carbocations as intermediates in acetal formation 720—721 1044
Carbocations as intermediates in biosynthesis of cholesterol 1093—1094
Carbocations as intermediates in biosynthesis of terpenes 1087-1091
Carbocations as intermediates in glycoside formation 1045
Carbocations as intermediates in reactions of alcohols dehydration 206—211 221—223
Carbocations as intermediates in reactions of alcohols with hydrogen halides 154 156—159 160 179 354—355 357
Carbocations as intermediates in reactions of alkenes acid-catalyzed hydration 247—248
Carbocations as intermediates in reactions of alkenes addition of hydrogen halides 235—236 238—242 272
Carbocations as intermediates in reactions of alkenes addition of hydrogen halides to conjugated dienes 405-407 417—418
Carbocations as intermediates in reactions of alkenes addition of sulfuric acid 246
Carbocations as intermediates in reactions of alkenes polymerization 266—267
Carbocations as intermediates in reactions of alkyl diazonium salts 944
Carbocations as intermediates in reactions of alkyl halides  nucleophilic substitution 159—160 339—345 356
Carbocations as intermediates in reactions of alkyl halides E1 elimination 206—208 217—219 223
Carbocations as intermediates in reactions of alkyl halides Friedel — Crafts alkylation 481—483 511
Carbocations benzylic 445 448
Carbocations capture by nucleophiles 157—159 248 340
Carbocations isopropyl cation 160 246
Carbocations methyl cation 160
Carbocations rearrangements 208—211 222—223 241—242 344—345 356 483 511
Carbocations structure, bonding, and stability 160—163 181
Carbocations tert-butyl cation 154 156—159 160 207 248 339—341 481—483
Carbocations tert-pentyl cation 944
Carbocations triphenylmethyl 446
Carbohydrates 1026—1068
Carbohydrates, aldoses 1027
Carbohydrates, amino sugars 1043
Carbohydrates, branched-chain carbohydrates 1043
Carbohydrates, chain extension 1055—1056 1063
Carbohydrates, classification 1026—1027
Carbohydrates, configurations of D-aldoses 1029—1032
Carbohydrates, cyclic hemiacetal formation in 1032—1039
Carbohydrates, deoxy sugars 1042
Carbohydrates, determination of ring size 1059 1060
Carbohydrates, disaccharides 1026—1027 1046—1048 1062
Carbohydrates, Fischer determination of glucose structure 1052 1068
Carbohydrates, Fischer projection formulas 1027—1028 1061
Carbohydrates, furanose forms 1032—1036 1062
Carbohydrates, glycolysis 1056—1058 1069
Carbohydrates, glycoproteins 1050
Carbohydrates, glycosides 1043—1046 1062
Carbohydrates, Haworth formulas 1034
Carbohydrates, ketoses 1027 1041
Carbohydrates, mnemonic for 1032
Carbohydrates, mutarotation in 1040 1062
Carbohydrates, photosynthesis 1032 1069
Carbohydrates, polysaccharides 1048—1050 1062
Carbohydrates, pyranose forms 1036—1039 1062
Carbohydrates, reactions of acylation 1058 1064
Carbohydrates, reactions of cyanohydrin formation 1055—1056 1063
Carbohydrates, reactions of epimerization 1056—1057
Carbohydrates, reactions of ether formation 1059 1064
Carbohydrates, reactions of isomerization 1051 1057
Carbohydrates, reactions of oxidation 1053—1055 1063
Carbohydrates, reactions of periodic acid cleavage 1059—1061 1064
Carbohydrates, reactions of reduction 1052—1053 1063
Carbohydrates, reactions of retro-aldol cleavage 1057—1058
Carbolic acid 996 (see also “Phenol”)
Carbon  isotope nuclear magnetic resonance 547—559
Carbon  isotope as isotopic label in Claisen rearrangement 1011
Carbon isotope as isotopic label in Claisen rearrangement nucleophilic aromatic substitution via benzyne 982 985
Carbon isotope as isotopic label in Claisen rearrangement terpene biosynthesis 1092
Carbon clusters 436—437
Carbon dioxide 14
Carbon dioxide and carbonic acid 805
Carbon dioxide in fatty acid and terpene biosynthesis 1075
Carbon dioxide in industrial preparation of urea 861
Carbon dioxide in Kolbe — Schmitt reaction 1006—1008 1017
Carbon dioxide reaction with Grig nard reagents 806—808 822
Carbon dioxide VSEPR and molecular geometry of 30
Carbon formation in stars 6
Carbon monoxide binding to hemoglobin and myoglobin 1150
Carbon monoxide reactions of 608 624 711—712
Carbon skeleton diagrams 22 (see also “Bond-line formulas”)
Carbon tetrachloride 31—32 150
Carbon tetrafluoride 13
Carbonic acid,  of 36 804—805
Carbonic anhydrase 46 805
Carbonium ions see “Carbocations”
Carbonyl group see also “Acyl chlorides”; “Aldehydes”; “Amides”; “Carboxylic acid anhydrides”; “Carboxylic acids”; “Esters”; “Ketones”
Carbonyl group chemical shifts 549 550—551
Carbonyl group and functional groups 144
Carbonyl group infrared absorption frequencies 561 563—564 872
Carbonyl group stabilization by substituents 708 793—794 833—836
Carbonyl group structure and bonding 706—708 742
| Carboxamides see «”Amides”
Carboxylate salts as nucleophiles 327 328 337—338
Carboxylate salts electron delocalization in 42 796—797
Carboxylate salts micelle formation 800
Carboxylate salts nomenclature of 799
Carboxylation of Grignard reagents 806—808 822
Carboxylation of phenol 1006—1008 1017
Carboxylic acid anhydrides Friedel — Crafts acylation with 485—486 502 504 505 510 710 842 974
Carboxylic acid anhydrides infrared absorption 872
Carboxylic acid anhydrides nomenclature of 831
Carboxylic acid anhydrides preparation of 839 841—842
Carboxylic acid anhydrides reactions of hydrolysis 843
Carboxylic acid anhydrides reactions of resonance in 834—835
Carboxylic acid anhydrides reactions of with alcohols 638 656 843—845 847 875
Carboxylic acid anhydrides reactions of with amino acids 1123
Carboxylic acid anhydrides reactions of with ammonia and amines 843 875 940—942
Carboxylic acid anhydrides reactions of with carbohydrates 1058 1064
Carboxylic acid anhydrides reactions of with phenols 1004—1006 1017
Carboxylic acid chlorides see “Acyl chlorides”
Carboxylic acid derivatives 830—885 (see also “Acyl chlorides”; “Amides”; “Carboxylic acid anhydrides”; “Esters”; “Nitriles”)
Carboxylic acid derivatives nomenclature of 831—833
Carboxylic acid derivatives relative reactivity of 833 table
Carboxylic acid derivatives spectroscopic analysis 872—874
Carboxylic acid derivatives structure and bonding 833—836
Carboxylic acids 791—829 (see also “Carbonic acid; Dicarboxylic acids”)
Carboxylic acids acidity of 795—797 801—804 821—822
Carboxylic acids derivatives of 830—885
Carboxylic acids dicarboxylic acids 804 816—817
Carboxylic acids dipole moments 794
Carboxylic acids hydrogen bonding in 794
Carboxylic acids infrared spectra 561 table 819—820
Carboxylic acids nomenclature of 792—793
Carboxylic acids nuclear magnetic resonance spectra 819—820
Carboxylic acids physical properties 794
Carboxylic acids preparation of, by malonic ester synthesis 897—900 907
Carboxylic acids preparation of, carboxylation of Grig nard reagents 806—808 822
Carboxylic acids preparation of, hydrolysis of nitriles 808—809 822 870—871
Carboxylic acids preparation of, oxidation of aldehydes 736 807
Carboxylic acids preparation of, oxidation of alkylbenzenes 443—444 807
Carboxylic acids preparation of, oxidation of primary alcohols 641 657 807
Carboxylic acids protecting group for 1138—1139
Carboxylic acids reactions of 809—819
Carboxylic acids reactions of  -halogenation 815-816 823
Carboxylic acids reactions of decarboxylation 816—819 824
Carboxylic acids reactions of esterification 638—639 656 810—813 823 847
Carboxylic acids reactions of reduction 632 654 711 810
Carboxylic acids reactions of with acyl chlorides 839 875
Carboxylic acids reactions of with thionyl chloride 485 810 838
Carboxylic acids salts of 797—801 822
Carboxylic acids site of protonation in 812-813
Carboxylic acids structure and bonding 793—794 821
Carboxypeptidase A 1145—1147
Carboxypeptidases 1130
Carcinogen 435
Carcinogen benzene 444
Carcinogen polycyclic aromatic hydrocarbons 435
Carotenoids 1100—1101 1103
Carothers, Wallace H. 4 868
Carvone, odors of (R) and (S) enantiomers 295
catalyst 5 (see also “Acid catalysis”; “Enzymes”; “Hydrogenation”)
Cation radicals in mass spectrometry 567
Cech, Thomas 1177
Cellobiose 1046—1047
Cellulose 1048—1049
Cembrene 1086
Center of symmetry 286—287
Center of symmetry in meso-2,3-butanediol 304
Cephalexin 861
Cephalosporins 861
Cerebrosides 1105
Chair conformation of cyclohexane and derivatives 116—124 125—129 134—136 545
Chair conformation of piperidine 132
Chair conformation of pyranose forms of carbohydrates 1038—1039
Chair conformation of tetrahydropyran 667
Chargaff, Erwin 1166 1168
Chemical Abstracts Service survey 78
Chemical shift equivalence and replacement test for 533—535
Chemical shift of carbon 549—551 576
Chemical shift of protons 525—535 544 545 575
Chemical shift scale  525—526
Chemical shift tables 528  549
Chiral axis see “Chirality axis”
Chiral center see “Chirality center
Chiral drugs 296
Chiral molecules 281—285 314
Chiral molecules and R,S notation 290—293 316
Chiral molecules with multiple chirality centers 300—310 317
Chiral molecules with one chirality center 282—285 315
Chiral molecules, absolute configuration 289 316
Chiral molecules, Fischer projection formulas 293—295 302 304 316
Chiral molecules, formation of in chemical reactions 297—300 307—310 316—317
Chiral molecules, optical activity in 287—289 316
Chiral recognition 295
Chiral, definition of 281
Chirality axis 403
Chirality center 282—285 300—307 314
Chirality center absolute configuration 290—293
Chirality center and Fischer projections 293—295 302 316 1027—1028 1061 1115—1116
Chirality center formation of in chemical reactions 297—300 307—310
Chirality center in 2-butanol 284 289—291
Chirality center in chiral molecules 282—285 290 293 300
Chirality center phosphorus 314
Chirality center sulfur 314
Chitin 1043
Chloral 715
Chlorination see also “Chlorine”
Chlorination electrophilic of 2-methylacetanilide 942
Chlorination electrophilic of acetophenone 505
Chlorination electrophilic of aldehydes and ketones 757—759 765 767 782
Chlorination electrophilic of benzene 475
Chlorination electrophilic of benzoyl chloride 500
Chlorination free-radical of alkanes 166 172—178 180 181 298
Chlorination free-radical of ethane 173
Chlorination free-radical of methane 166—167 172—173 174
Chlorination free-radical of propene 396
Chlorination free-radical of toluene 441—442
Chlorine see also “Chlorination”
Chlorine addition of to alkenes 256
Chlorine addition of to conjugated dienes 407
Chlorine addition of to propyne 381
Chlorine oxidation of alcohols by 645
Chlorobenzene carbon-chlorine bond energy 972
Chlorobenzene conversion to phenol 975 985 1000
Chlorobenzene dipole moment of 972
Chlorobenzene mass spectrum 570
Chlorobenzene nitration of 500—501
Chlorobenzene nucleophilic aromatic substitution in 975—976 985
Chlorocyclobutane 175
Chlorocyclohexane see also “Cyclohexyl chloride”
Chlorocyclohexane dipole moment 972
Chloroethane 175 972
Chlorofluorocarbons (CFCs) 167
Chloroform 150 (see also “Trichloromethane”)
Chloroform chemical shift 527
Chloroform nuclear magnetic resonance spectrum of 525
Chloroform biosynthesis of 767
Chloroform-d, solvent for NMR spectroscopy 526
Chlorohydrin see “Halohydrins”
Chloromethane 166—167 (see also “Methyl chloride”)
Chloromethane biosynthesis of 767
Chloromethane boiling point of 150
Chloromethane dipole moment of 147
Chloromethane electrostatic potential map 147
Chloronium ion see “Halonium ion”
Chlortetracycline 974
Cholesterol 625 1093—1096 1103
Cholesterol 7-dehydro 1096—1097
Cholesterol biosynthesis of 1093—1095
Cholic acid 131 306—307 1097—1098
choline 1078
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