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Àâòîðèçàöèÿ |
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Ïîèñê ïî óêàçàòåëÿì |
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Carey F.A. — Organic Chemistry |
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Ïðåäìåòíûé óêàçàòåëü |
Chromatography 572—573 1130
Chromic acid oxidation of alcohols 641—643 657 710 807
Chromic acid oxidation of alkylbenzenes 441—442 466 807
Chromic acid oxidation of phenols 1012
Chromophore 567
Chrysanthemic acid 80 1105
Chymotrypsin 1130
Cicutoxin 364
Cimetidine 461
Cinnamaldehyde 193
CIP see “Cahn — Ingold — Prelog”
Cis and trans descriptors of stereochemistry 124 135—136 192—193 220
cis and trans-2-Butene 192—193
cis and trans-2-Butene, dipole moments of 196
cis and trans-2-Butene, heats of combustion 197
cis and trans-2-Butene, heats of hydrogenation 231—233
cis- and trans-1,4-Dimethylcyclohexane 125—127
cis- and trans-Decalin 131
cis- and trans-l,2-Dimethylcyclohexane 126 127
cis- and trans-l,2-Dimethylcyclopropane 124—125
cis- and trans-l,3-Dimethylcyclohexane 126 128 135—136
cis-9-Tricosene 388
Citral 709 1086
Citric acid 324 828
Citronellal 1092
Citronellol 625
Claisen condensation 887—890 906
Claisen condensation intramolecular see “Dieckmann reaction”
Claisen condensation mixed 891—892 906
Claisen rearrangement 1011—1012 1018
Claisen — Schmidt condensation 775 783
Claisen, Ludwig 887
Clathrate 66
Clemmensen reduction 486—488 505 713
Cocaine 924
Codon 1175—1176 1178 1188
Coenzymes 1147 1150
Coenzymes acetyl coenzyme A 1070—1071 1091
Coenzymes coenzyme 728
Coenzymes coenzyme 611
Coenzymes coenzyme Q see “Ubiquinone”
Coenzymes heme 1147—1148
Coenzymes NAD, NAD +, NADH, NADPH see “Nicotinamide adenine dinucleotide”
Cofactors see “Coenzymes”
Coke 363
Collins, Francis S. 1182
Columbus, Christopher 408
Combinatorial synthesis 1142
Combustion of alkanes 83—87 98
Common names see “Nomenclature”
Concerted reaction 153
Concerted reaction and orbital symmetry 414—415
Concerted reaction bimolecular elimination 214—217 221—223
Concerted reaction bimolecular nucleophilic substitution 163—165 330—336 356
Concerted reaction Dieis — Alder reaction 409
Condensation polymers 868—869
Condensation reaction 635
Condensation reaction aldol 769—775 783
Condensation reaction Claisen 887—890 906
Condensation reaction Claisen — Schmidt 775 783
Condensation reaction ether formation 635 637—638 656 671—672 693
Condensation reaction Fischer esterification 638—639 640 656 810—813 823 847
Condensed structural formulas 21 68
Configuration absolute and relative 289—290 316
Configuration and Fischer projections 293-295 316
Configuration cis and trans 124
Configuration D-L 1027—1032 1061
Configuration erythro and threo 301—302
Configuration notational systems and 1034 1160
Configuration of aldoses 1031
Configuration of alkenes cis and trans 192—193 201 220
Configuration of alkenes E and Z 193—195 201 220
Configuration of disubstituted cycloalkanes, cis and trans 124—129 135—136
Configuration R-S 290—293 316
Conformation and nuclear magnetic resonance spectroscopy 545
Conformation chiral 305
Conformation eclipsed 105 106 133
Conformation of 1,3-butadiene 401—402 417—418
Conformation of heterocyclic compounds 131—132 667
Conformation of hydrogen peroxide 104
Conformation pyranose forms of carbohydrates 1038—1039
Conformation staggered 105—107 133
Conformation(s) 104
Conformational analysis see “Conformation”
Conformations of alkanes butane 109—112 133
Conformations of alkanes ethane 105—109 133
Conformations of alkanes higher alkanes 110—112 134
Conformations of cycloalkanes 114—129 134—136
Conformations of cycloalkanes cyclobutane 114 134
Conformations of cycloalkanes cyclohexane and derivatives 116—124 125—129 134—136 305 545
Conformations of cycloalkanes cyclopentane 108 134
Conformations of cycloalkanes medium and large rings 129
Conformations of ethers 667
Conformations peptides and proteins 1126—1128 1143—1145
Conformations s-cis and s-trans 401—402 417
Conformer 105 (see also “Conformation”)
Coniine 924
Conjugate acids and bases 33—38 368—370 593 763 797 919—920
Conjugate addition see also “Michael reaction”
Conjugate addition of bromine to 1,3-butadiene 407
Conjugate addition of hydrogen bromide to 1,3-butadiene 407
Conjugate addition to -unsaturated aldehydes and ketones 777—780 783—784 901—902 907
Conjugation energy 399—400
Conjugation in -unsaturated aldehydes and ketones 775-777
Conjugation in alkenylbenzenes 447—448
Conjugation in allylic systems 391—398 405—407 416
Conjugation in benzylic carbocations 445
Conjugation in benzylic free radicals 441
Conjugation in dienes 398—402 565—566 conjugated”)
Connectivity see “Constitution”
Constitution 20 21 48
Constitutional isomers 23 48 192 315
Constitutional isomers of alkanes, number of 69 table
Coordination polymerization 271 408 610 612—614 617
Copolymer 408
Copper (I) salts in preparation of lithium dialkylcuprate 602—603 615
Copper (I) salts reactions with aryl diazonium ions 946 948 961 973
Corey, Elias J. 598 895
Corey, Robert B. 1143
Correlated spectroscopy COSY 556—559 577
Correlated spectroscopy HETCOR 558—559 577
Corticosteroids (cortisol and cortisone) 1098 1103
COSY see Correlated spectroscopy
Couper, Archibald S. 3
Coupling constant (J) 538 541 543—544
Coupling constant (J)dihedral angle dependence 580
covalent bond 12—13 47
COX-1and COX-2 see “Cyclooxygenase”
Cracking, in petroleum refining 79
Crafts, James M. 481
Crick, Francis H. C. 1166—1170 1172
Critical micelle concentration 800
Crown ethers 668—671 692
Crown ethers electrostatic potential map 665 669
Cubane 140
Cumene 269 1023
Cumulated diene see “Allenes Dienes”
Cuprates see “Lithium diorganocuprates”
Curl, Robert F. 436
Curved arrows 34
Curved arrows and resonance structures 25 392
Curved arrows fishhook 169
Cyanide ion as nucleophile 327 328 338 347—348 349 352 777—779
Cyanide ion basicity of 349 777
Cyanide ion in formation of cyanohydrins 717—720
Cyanohydrins and carbohydrate chain extension 1055—1056 1063
Cyanohydrins hydrolysis of 809
Cyanohydrins naturally occurring 720
Cyanohydrins preparation of 717—720 743 867
Cyclic AMP 1161—1162
| Cycloaddition 409
Cycloaddition molecular orbital treatment of 414—415
Cycloalkanes 77—79 114—129 134—136
Cycloalkanes angle strain in 113 114—116
Cycloalkanes bicyclic and spirocyclic 129—131 136
Cycloalkanes conformations of 114—129 134—136
Cycloalkanes heats of combustion 113 table
Cycloalkanes nomenclature of 77—79
Cycloalkanes sources of 79—80
Cycloalkenes 190 200—201
Cycloalkenes nomenclature of 190
Cycloalkenes stereoisomeric 200—201 213
Cycloalkynes 365 368
Cycloamylose 1050
Cyclobutadiene 449—451 467
Cyclobutane angle strain in 113 115
Cyclobutane chlorination of 175
Cyclobutane conformations of 115
Cyclobutane heat of combustion of 113
Cyclobutyl chloride 175
Cyclodecane 113 180
Cyclodecyl bromide 213
Cyclodecyl chloride 180
Cyclodextrins 1049
Cycloheptatriene 457
Cycloheptatrienide anion 459
Cycloheptatrienyl cation 456—457 467 571
Cyclohexadienone-phenol rearrangement 1022
Cyclohexadienyl anion intermediate in nucleophilic aromatic substitution 977—981 987
Cyclohexadienyl cation intermediate in electrophilic aromatic substitution 474—476 478 479 481 482 485 489—494 496—497 501 506—507 509 980
Cyclohexane 77 80
Cyclohexane bond angles in 116
Cyclohexane conformational analysis of 116—120 134—135
Cyclohexane conformational analysis of disubstituted derivatives 125—129 135—136 305
Cyclohexane conformational analysis of monosubstituted derivatives 120—124 135
Cyclohexane drawing chair conformation of 118
Cyclohexane heat of combustion 113
Cyclohexane spectrum of 545
Cyclohexanol infrared spectrum 651 652
Cyclohexanol preparation of 247
Cyclohexanol reactions of dehydration 203
Cyclohexanol reactions of oxidation 642
Cyclohexanol reactions of with hydrogen bromide 152
Cyclohexanone chlorination of 757
Cyclohexanone and ethylene glycol, cyclic acetal from 722
Cyclohexanone preparation of 642
Cyclohexanone reaction of reductive amination of 934
Cyclohexanone reaction of with ethylmagnesium bromide 713
Cyclohexanone reaction of with isobutylamine 673
Cyclohexanone reaction of with methylenetriphenylphosphorane 730
Cyclohexanone reaction of with morpholine 744
Cyclohexanone reaction of with pyrrolidine 936
Cyclohexanone reaction of with sodium acetylide 597
Cyclohexene derivatives of, preparation by Dieis — Alder reaction 409—415
Cyclohexene preparation of dehydration of cyclohexanol 203
Cyclohexene preparation of dehydrohalogenation 212
Cyclohexene preparation of reactions of alkylation of benzene with 483
Cyclohexene preparation of reactions of epoxidation 684
Cyclohexene preparation of reactions of hydroxylation 635 684
Cyclohexene preparation of reactions of trans stereoisomer 201
Cyclohexene preparation of reactions of with dibromocarbene 607
Cyclohexene preparation of reactions of with N-bromosuccinimide 397
Cyclohexene preparation of reactions of with sulfuric acid 247
Cyclohexyl chloride see also “Chlorocyclohexane”
Cyclohexyl chloride -elimination of 212
Cyclohexyl chloride Grignard reagent from 591 596
Cyclohexylamine 914
Cyclohexylamine basicity of 920
Cyclohexylamine preparation of 934
Cyclohexylamine reductive amination by 957
Cyclononyne 365
Cyclooctane 113
Cyclooctatetraene 449—451 452—453 465 467
Cyclooctatetraene dianion 459
Cyclooctene addition of chlorine to 256
Cyclooctene epoxidation of 261
Cyclooctene trans stereoisomer 201
Cyclooctyne 365
Cyclooxygenase 1080—1083
Cyclopentadiene acidity of 458—459
Cyclopentadiene Dieis — Alder reactions of 411
Cyclopentadiene reaction with hydrogen chloride 405
Cyclopentadienide anion 458 467
Cyclopentane 80
Cyclopentane conformations of 115 134
Cyclopentane heat of combustion 113
Cyclopentanol nitrate ester 656
Cyclopentanol preparation of 628
Cyclopentanol reaction with phosphorus tribromide 166
Cyclopentanone Baeyer — Villiger oxidation of 749
Cyclopentanone enamine of 728
Cyclopentanone enol content of 782
Cyclopentanone hydrogen-deuterium exchange in 768
Cyclopentanone hydrogenation of 628
Cyclopentanone reaction with methylmagnesium chloride 596
Cyclopentene bromine addition to 256
Cyclopentene halohydrins of 259—260
Cyclopentyl bromide 166 510
Cyclopentyl cyanide 328
Cyclopentylmethanol 626 636
Cyclopropane 1,1-dihalo 607
Cyclopropane heat of combustion of 113
Cyclopropane preparation of 604—606 615
Cyclopropane structure of 114
Cyclopropane torsional strain in 114
Cyclopropane(s) 77
Cyclopropanecarboxylic acid 632
Cyclopropanes angle strain and bonding in 113 114
Cyclopropanes cis and trans-l,2-dimethyl 124—125
Cyclopropene 200
Cyclopropenyl cation 459
Cyclopropyllithium 616
Cytidine 1159
Cytosine 1157 1166 1168
D-Alloisoleucine 1116
D-Allose 1031
D-Altrose 1031
D-Apiose 1043 1065
D-Arabinitol 1063
D-Arabinose 1031 1060—1061 1063
D-Erythrose 1029
D-Erythrose furanose forms 1033—1034
D-Fructose 1027 1041 1057
D-Fructose 6-phosphate 1057—1058
D-Galactal 1046
D-Galactitol 1052 1054
D-Galactose 1031
D-Galactose natural occurrence 1032
D-Galactose pyranose form 1038—1039
D-Galactose reduction of 1052
D-Glucose 140 625 1027 1032
D-Glucose 6-phosphate 1057 1161
D-Glucose conversion to D-fructose 1051 1057
D-Glucose electrostatic potential map 1026
D-Glucose epimerization of 1056—1057
D-Glucose Fischer determination of structure 1052 1068
D-Glucose hydrogenation of 658
D-Glucose metabolism 1069
D-Glucose methyl glycosides 1045—1046
D-Glucose mutarotation of 1040
D-Glucose natural occurrence 1032
D-Glucose oxidation of 1055
D-Glucose pyranose form 1037—1038
D-Glucuronic acid 1055
D-Glyceraldehyde 3-phosphate 1058
D-Glyceraldehyde Fischer projection formula 1028
D-Gulose 1031
D-Idose 1031
D-Lyxose 1031
D-Mannose 1031
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