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Carey F.A. — Organic Chemistry

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Название: Organic Chemistry

Автор: Carey F.A.

Аннотация:

This respected text is based on the Functional Group approach. The text retains the outstanding problems, pedagogy, depth, and prose of the second edition while providing increased emphasis on molecular modeling, a core concept in organic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 2004

Количество страниц: 1191

Добавлена в каталог: 20.04.2006

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Предметный указатель

Chromatography      572—573 1130
Chromic acid oxidation of alcohols      641—643 657 710 807
Chromic acid oxidation of alkylbenzenes      441—442 466 807
Chromic acid oxidation of phenols      1012
Chromophore      567
Chrysanthemic acid      80 1105
Chymotrypsin      1130
Cicutoxin      364
Cimetidine      461
Cinnamaldehyde      193
CIP      see “Cahn — Ingold — Prelog”
Cis and trans descriptors of stereochemistry      124 135—136 192—193 220
cis and trans-2-Butene      192—193
cis and trans-2-Butene, dipole moments of      196
cis and trans-2-Butene, heats of combustion      197
cis and trans-2-Butene, heats of hydrogenation      231—233
cis- and trans-1,4-Dimethylcyclohexane      125—127
cis- and trans-Decalin      131
cis- and trans-l,2-Dimethylcyclohexane      126 127
cis- and trans-l,2-Dimethylcyclopropane      124—125
cis- and trans-l,3-Dimethylcyclohexane      126 128 135—136
cis-9-Tricosene      388
Citral      709 1086
Citric acid      324 828
Citronellal      1092
Citronellol      625
Claisen condensation      887—890 906
Claisen condensation intramolecular      see “Dieckmann reaction”
Claisen condensation mixed      891—892 906
Claisen rearrangement      1011—1012 1018
Claisen — Schmidt condensation      775 783
Claisen, Ludwig      887
Clathrate      66
Clemmensen reduction      486—488 505 713
Cocaine      924
Codon      1175—1176 1178 1188
Coenzymes      1147 1150
Coenzymes acetyl coenzyme A      1070—1071 1091
Coenzymes coenzyme       728
Coenzymes coenzyme $B_{12}$       611
Coenzymes coenzyme Q      see “Ubiquinone”
Coenzymes heme      1147—1148
Coenzymes NAD, NAD +, NADH, NADPH      see “Nicotinamide adenine dinucleotide”
Cofactors      see “Coenzymes”
Coke      363
Collins, Francis S.      1182
Columbus, Christopher      408
Combinatorial synthesis      1142
Combustion of alkanes      83—87 98
Common names      see “Nomenclature”
Concerted reaction      153
Concerted reaction and orbital symmetry      414—415
Concerted reaction bimolecular elimination      214—217 221—223
Concerted reaction bimolecular nucleophilic substitution      163—165 330—336 356
Concerted reaction Dieis — Alder reaction      409
Condensation polymers      868—869
Condensation reaction      635
Condensation reaction aldol      769—775 783
Condensation reaction Claisen      887—890 906
Condensation reaction Claisen — Schmidt      775 783
Condensation reaction ether formation      635 637—638 656 671—672 693
Condensation reaction Fischer esterification      638—639 640 656 810—813 823 847
Condensed structural formulas      21 68
Configuration absolute and relative      289—290 316
Configuration and Fischer projections      293-295 316
Configuration cis and trans      124
Configuration D-L      1027—1032 1061
Configuration erythro and threo      301—302
Configuration notational systems $\alpha$ and $\beta$       1034 1160
Configuration of aldoses      1031
Configuration of alkenes cis and trans      192—193 201 220
Configuration of alkenes E and Z      193—195 201 220
Configuration of disubstituted cycloalkanes, cis and trans      124—129 135—136
Configuration R-S      290—293 316
Conformation and nuclear magnetic resonance spectroscopy      545
Conformation chiral      305
Conformation eclipsed      105 106 133
Conformation of 1,3-butadiene      401—402 417—418
Conformation of heterocyclic compounds      131—132 667
Conformation of hydrogen peroxide      104
Conformation pyranose forms of carbohydrates      1038—1039
Conformation staggered      105—107 133
Conformation(s)      104
Conformational analysis      see “Conformation”
Conformations of alkanes butane      109—112 133
Conformations of alkanes ethane      105—109 133
Conformations of alkanes higher alkanes      110—112 134
Conformations of cycloalkanes      114—129 134—136
Conformations of cycloalkanes cyclobutane      114 134
Conformations of cycloalkanes cyclohexane and derivatives      116—124 125—129 134—136 305 545
Conformations of cycloalkanes cyclopentane      108 134
Conformations of cycloalkanes medium and large rings      129
Conformations of ethers      667
Conformations peptides and proteins      1126—1128 1143—1145
Conformations s-cis and s-trans      401—402 417
Conformer      105 (see also “Conformation”)
Coniine      924
Conjugate acids and bases      33—38 368—370 593 763 797 919—920
Conjugate addition      see also “Michael reaction”
Conjugate addition of bromine to 1,3-butadiene      407
Conjugate addition of hydrogen bromide to 1,3-butadiene      407
Conjugate addition to $\alpha,\beta$ -unsaturated aldehydes and ketones      777—780 783—784 901—902 907
Conjugation energy      399—400
Conjugation in $\alpha,\beta$ -unsaturated aldehydes and ketones      775-777
Conjugation in alkenylbenzenes      447—448
Conjugation in allylic systems      391—398 405—407 416
Conjugation in benzylic carbocations      445
Conjugation in benzylic free radicals      441
Conjugation in dienes      398—402 565—566 conjugated”)
Connectivity      see “Constitution”
Constitution      20 21 48
Constitutional isomers      23 48 192 315
Constitutional isomers of alkanes, number of      69 table
Coordination polymerization      271 408 610 612—614 617
Copolymer      408
Copper (I) salts in preparation of lithium dialkylcuprate      602—603 615
Copper (I) salts reactions with aryl diazonium ions      946 948 961 973
Corey, Elias J.      598 895
Corey, Robert B.      1143
Correlated spectroscopy COSY      556—559 577
Correlated spectroscopy HETCOR      558—559 577
Corticosteroids (cortisol and cortisone)      1098 1103
COSY      see Correlated spectroscopy
Couper, Archibald S.      3
Coupling constant (J)      538 541 543—544
Coupling constant (J)dihedral angle dependence      580
covalent bond      12—13 47
COX-1and COX-2      see “Cyclooxygenase”
Cracking, in petroleum refining      79
Crafts, James M.      481
Crick, Francis H. C.      1166—1170 1172
Critical micelle concentration      800
Crown ethers      668—671 692
Crown ethers electrostatic potential map      665 669
Cubane      140
Cumene      269 1023
Cumulated diene      see “Allenes Dienes”
Cuprates      see “Lithium diorganocuprates”
Curl, Robert F.      436
Curved arrows      34
Curved arrows and resonance structures      25 392
Curved arrows fishhook      169
Cyanide ion as nucleophile      327 328 338 347—348 349 352 777—779
Cyanide ion basicity of      349 777
Cyanide ion in formation of cyanohydrins      717—720
Cyanohydrins and carbohydrate chain extension      1055—1056 1063
Cyanohydrins hydrolysis of      809
Cyanohydrins naturally occurring      720
Cyanohydrins preparation of      717—720 743 867
Cyclic AMP      1161—1162

Cycloaddition      409
Cycloaddition molecular orbital treatment of      414—415
Cycloalkanes      77—79 114—129 134—136
Cycloalkanes angle strain in      113 114—116
Cycloalkanes bicyclic and spirocyclic      129—131 136
Cycloalkanes conformations of      114—129 134—136
Cycloalkanes heats of combustion      113 table
Cycloalkanes nomenclature of      77—79
Cycloalkanes sources of      79—80
Cycloalkenes      190 200—201
Cycloalkenes nomenclature of      190
Cycloalkenes stereoisomeric      200—201 213
Cycloalkynes      365 368
Cycloamylose      1050
Cyclobutadiene      449—451 467
Cyclobutane angle strain in      113 115
Cyclobutane chlorination of      175
Cyclobutane conformations of      115
Cyclobutane heat of combustion of      113
Cyclobutyl chloride      175
Cyclodecane      113 180
Cyclodecyl bromide      213
Cyclodecyl chloride      180
Cyclodextrins      1049
Cycloheptatriene      457
Cycloheptatrienide anion      459
Cycloheptatrienyl cation      456—457 467 571
Cyclohexadienone-phenol rearrangement      1022
Cyclohexadienyl anion intermediate in nucleophilic aromatic substitution      977—981 987
Cyclohexadienyl cation intermediate in electrophilic aromatic substitution      474—476 478 479 481 482 485 489—494 496—497 501 506—507 509 980
Cyclohexane      77 80
Cyclohexane bond angles in      116
Cyclohexane conformational analysis of      116—120 134—135
Cyclohexane conformational analysis of disubstituted derivatives      125—129 135—136 305
Cyclohexane conformational analysis of monosubstituted derivatives      120—124 135
Cyclohexane drawing chair conformation of      118
Cyclohexane heat of combustion      113
Cyclohexane $\sideset{^1}{}H NMR$ spectrum of      545
Cyclohexanol infrared spectrum      651 652
Cyclohexanol preparation of      247
Cyclohexanol reactions of dehydration      203
Cyclohexanol reactions of oxidation      642
Cyclohexanol reactions of with hydrogen bromide      152
Cyclohexanone $\alpha$ chlorination of      757
Cyclohexanone and ethylene glycol, cyclic acetal from      722
Cyclohexanone preparation of      642
Cyclohexanone reaction of reductive amination of      934
Cyclohexanone reaction of with ethylmagnesium bromide      713
Cyclohexanone reaction of with isobutylamine      673
Cyclohexanone reaction of with methylenetriphenylphosphorane      730
Cyclohexanone reaction of with morpholine      744
Cyclohexanone reaction of with pyrrolidine      936
Cyclohexanone reaction of with sodium acetylide      597
Cyclohexene derivatives of, preparation by Dieis — Alder reaction      409—415
Cyclohexene preparation of dehydration of cyclohexanol      203
Cyclohexene preparation of dehydrohalogenation      212
Cyclohexene preparation of reactions of alkylation of benzene with      483
Cyclohexene preparation of reactions of epoxidation      684
Cyclohexene preparation of reactions of hydroxylation      635 684
Cyclohexene preparation of reactions of trans stereoisomer      201
Cyclohexene preparation of reactions of with dibromocarbene      607
Cyclohexene preparation of reactions of with N-bromosuccinimide      397
Cyclohexene preparation of reactions of with sulfuric acid      247
Cyclohexyl chloride      see also “Chlorocyclohexane”
Cyclohexyl chloride $\beta$ -elimination of      212
Cyclohexyl chloride Grignard reagent from      591 596
Cyclohexylamine      914
Cyclohexylamine basicity of      920
Cyclohexylamine preparation of      934
Cyclohexylamine reductive amination by      957
Cyclononyne      365
Cyclooctane      113
Cyclooctatetraene      449—451 452—453 465 467
Cyclooctatetraene dianion      459
Cyclooctene addition of chlorine to      256
Cyclooctene epoxidation of      261
Cyclooctene trans stereoisomer      201
Cyclooctyne      365
Cyclooxygenase      1080—1083
Cyclopentadiene acidity of      458—459
Cyclopentadiene Dieis — Alder reactions of      411
Cyclopentadiene reaction with hydrogen chloride      405
Cyclopentadienide anion      458 467
Cyclopentane      80
Cyclopentane conformations of      115 134
Cyclopentane heat of combustion      113
Cyclopentanol nitrate ester      656
Cyclopentanol preparation of      628
Cyclopentanol reaction with phosphorus tribromide      166
Cyclopentanone Baeyer — Villiger oxidation of      749
Cyclopentanone enamine of      728
Cyclopentanone enol content of      782
Cyclopentanone hydrogen-deuterium exchange in      768
Cyclopentanone hydrogenation of      628
Cyclopentanone reaction with methylmagnesium chloride      596
Cyclopentene bromine addition to      256
Cyclopentene halohydrins of      259—260
Cyclopentyl bromide      166 510
Cyclopentyl cyanide      328
Cyclopentylmethanol      626 636
Cyclopropane 1,1-dihalo      607
Cyclopropane heat of combustion of      113
Cyclopropane preparation of      604—606 615
Cyclopropane structure of      114
Cyclopropane torsional strain in      114
Cyclopropane(s)      77
Cyclopropanecarboxylic acid      632
Cyclopropanes angle strain and bonding in      113 114
Cyclopropanes cis and trans-l,2-dimethyl      124—125
Cyclopropene      200
Cyclopropenyl cation      459
Cyclopropyllithium      616
Cytidine      1159
Cytosine      1157 1166 1168
D-Alloisoleucine      1116
D-Allose      1031
D-Altrose      1031
D-Apiose      1043 1065
D-Arabinitol      1063
D-Arabinose      1031 1060—1061 1063
D-Erythrose      1029
D-Erythrose furanose forms      1033—1034
D-Fructose      1027 1041 1057
D-Fructose 6-phosphate      1057—1058
D-Galactal      1046
D-Galactitol      1052 1054
D-Galactose      1031
D-Galactose natural occurrence      1032
D-Galactose pyranose form      1038—1039
D-Galactose reduction of      1052
D-Glucose      140 625 1027 1032
D-Glucose 6-phosphate      1057 1161
D-Glucose conversion to D-fructose      1051 1057
D-Glucose electrostatic potential map      1026
D-Glucose epimerization of      1056—1057
D-Glucose Fischer determination of structure      1052 1068
D-Glucose hydrogenation of      658
D-Glucose metabolism      1069
D-Glucose methyl glycosides      1045—1046
D-Glucose mutarotation of      1040
D-Glucose natural occurrence      1032
D-Glucose oxidation of      1055
D-Glucose pyranose form      1037—1038
D-Glucuronic acid      1055
D-Glyceraldehyde 3-phosphate      1058
D-Glyceraldehyde Fischer projection formula      1028
D-Gulose      1031
D-Idose      1031
D-Lyxose      1031
D-Mannose      1031

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