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Carey F.A. — Organic Chemistry
Carey F.A. — Organic Chemistry



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Íàçâàíèå: Organic Chemistry

Àâòîð: Carey F.A.

Àííîòàöèÿ:

This respected text is based on the Functional Group approach. The text retains the outstanding problems, pedagogy, depth, and prose of the second edition while providing increased emphasis on molecular modeling, a core concept in organic chemistry.


ßçûê: en

Ðóáðèêà: Õèìèÿ/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Ãîä èçäàíèÿ: 2004

Êîëè÷åñòâî ñòðàíèö: 1191

Äîáàâëåíà â êàòàëîã: 20.04.2006

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Nomenclature IUPAC of nucleosides      1160
Nomenclature IUPAC of organometallic compounds      588 614
Nomenclature IUPAC of sulfides      666
Nomenclature IUPAC of thiols      648
Nomenclature stereochemical notation cis and trans      124
Nomenclature stereochemical notation D-L      293 1027—1032 1061
Nomenclature stereochemical notation E-Z      193—195 220
Nomenclature stereochemical notation erythro and threo      301—302
Nomenclature stereochemical notation R-S      290—293
Nomenclature substitutive      144—145 178
Nomex      868
Nonsteroidal antiinflammatory drugs      1083
Norepinephrine      687—688 1126
Norethindrone      1100
NSAIDs      see “Nonsteroidal antiinflammatory drugs”
Nuclear magnetic resonance spectra carbon 1-chloropentane      548
Nuclear magnetic resonance spectra carbon 1-phenyl-1-pentanone      553-554
Nuclear magnetic resonance spectra carbon 3-heptanone      740
Nuclear magnetic resonance spectra carbon m-cresol      551—552
Nuclear magnetic resonance spectra carbon methanol      953
Nuclear magnetic resonance spectra carbon methylamine      953
Nuclear magnetic resonance spectra proton 1,1-dichloroethane      536
Nuclear magnetic resonance spectra proton 1-chloropentane      548
Nuclear magnetic resonance spectra proton 2,3,4-trichloroanisole      542
Nuclear magnetic resonance spectra proton 2-butanone      739
Nuclear magnetic resonance spectra proton 2-methylpropanal      739
Nuclear magnetic resonance spectra proton 2-phenylethanol      653
Nuclear magnetic resonance spectra proton 4-methylbenzyl alcohol      952—954
Nuclear magnetic resonance spectra proton 4-methylbenzylamine      952—954
Nuclear magnetic resonance spectra proton 4-phenylbutanoic acid      820
Nuclear magnetic resonance spectra proton benzyl alcohol      545
Nuclear magnetic resonance spectra proton chloroform      525
Nuclear magnetic resonance spectra proton dipropyl ether      689
Nuclear magnetic resonance spectra proton ethyl acetate      872 873
Nuclear magnetic resonance spectra proton ethyl bromide      538—539
Nuclear magnetic resonance spectra proton isopropyl chloride      540
Nuclear magnetic resonance spectra proton m-nitrostyrene      543
Nuclear magnetic resonance spectra proton methoxyacetonitrile      532—533
Nuclear magnetic resonance spectra proton methyl propanoate      872 873
Nuclear magnetic resonance spectra proton p-cresol      1015
Nuclear magnetic resonance spectroscopy and magnetic field strength      522—523
Nuclear magnetic resonance spectroscopy carbon      547—559 576—577
Nuclear magnetic resonance spectroscopy carbon alcohols      652
Nuclear magnetic resonance spectroscopy carbon aldehydes and ketones      738 740
Nuclear magnetic resonance spectroscopy carbon amines      953
Nuclear magnetic resonance spectroscopy carbon carboxylic acid derivatives      872—873
Nuclear magnetic resonance spectroscopy carbon carboxylic acids      819—820
Nuclear magnetic resonance spectroscopy carbon chemical shifts      549—551
Nuclear magnetic resonance spectroscopy carbon ethers      690—691
Nuclear magnetic resonance spectroscopy carbon in biosynthetic studies      1092
Nuclear magnetic resonance spectroscopy carbon thiols      652
Nuclear magnetic resonance spectroscopy proton      522—545 575—576
Nuclear magnetic resonance spectroscopy proton alcohols      544—545 576 651—652 653 655
Nuclear magnetic resonance spectroscopy proton aldehydes and ketones      738—741
Nuclear magnetic resonance spectroscopy proton amines      952—953
Nuclear magnetic resonance spectroscopy proton and conformations      544—545 576
Nuclear magnetic resonance spectroscopy proton carboxylic acid derivatives      872 873
Nuclear magnetic resonance spectroscopy proton carboxylic acids      819—820
Nuclear magnetic resonance spectroscopy proton chemical shift      525—532 575
Nuclear magnetic resonance spectroscopy proton ethers and epoxides      689—692
Nuclear magnetic resonance spectroscopy proton interpretation      532—535 576
Nuclear magnetic resonance spectroscopy proton nuclear shielding      525—526
Nuclear magnetic resonance spectroscopy proton phenols      1014—1015
Nuclear magnetic resonance spectroscopy proton spin-spin splitting      535—544 576
Nuclear magnetic resonance spectroscopy proton thiols      652
Nuclear magnetic resonance spectroscopy two dimensional (2D NMR)      556—559 577
Nuclear spin states      522—523
Nucleic acids      1165—1166 (see also “Deoxyribonucleic acid”; “Ribonucleic acid”)
Nucleophiles      47 157—158 159—160 163—165 181 327—329
Nucleophiles relative reactivity      336—338
Nucleophiles solvation and reactivity      338 346—347
Nucleophilic acyl substitution      830—885
Nucleophilic acyl substitution defined      830—831
Nucleophilic acyl substitution general mechanism      836—838 874—875
Nucleophilic acyl substitution of acyl chlorides      838—841 875
Nucleophilic acyl substitution of amides      862—867 877
Nucleophilic acyl substitution of carboxylic acid anhydrides      841—842 875
Nucleophilic acyl substitution of esters      848—858 876
Nucleophilic acyl substitution of thioesters      858—859 876
Nucleophilic addition to $\alpha,\beta$-unsaturated aldehydes and ketones      777—779 784 901—902 907
Nucleophilic addition to aldehydes and ketones      712—735 742—744
Nucleophilic alkyl substitution      (see also “$S_N 1</a></span> <span class=subjpages><a href=2$"/> SN”)
Nucleophilic alkyl substitution $\alpha$-halo carboxylic acids      816
Nucleophilic alkyl substitution alcohols      153—166
Nucleophilic alkyl substitution alkyl halides      326—350 733 808 867 894—900
Nucleophilic alkyl substitution alkyl p-toluenesulfonates      350—353 357
Nucleophilic alkyl substitution allylic halides      391—394 416 650 895
Nucleophilic alkyl substitution benzylic halides      444—446
Nucleophilic alkyl substitution crown ether catalysis of      671
Nucleophilic alkyl substitution enzyme-catalyzed      339
Nucleophilic alkyl substitution epoxides      678—684
Nucleophilic alkyl substitution phase-transfer catalysis of      923 926
Nucleophilic aryl substitution      975—985 986—987 1000 1009
Nucleosides      1158—1160
Nucleosomes      1171
nucleotides      1160—1162 1164—1166 1187
Nylon      4 868
O-Acetylsalicylic acid      see “Aspirin”
o-Cresol      1003
o-Hydroxybenzoic acid      792 (see also “Salicylic acid”)
o-Nitroaniline, diazotization of      961
o-Nitrophenol acidity of      998
o-Nitrophenol intramolecular hydrogen bonding      996
o-Nitrophenol reaction with acetic anhydride      1005 1017
o-Nitrophenol reaction with butyl bromide      1018
o-Toluidine      948
o-Xylene      432—433
o-Xylene Birch reduction of      464—465
Octadecanoic acid      792
Octane number of gasoline      80
Octane, relative stability of isomers      85—86
Octet rule      13 47
Off-resonance decoupling      553
Oil of wintergreen      see “Methyl salicylate”
Oils      see “Fats”
Olah, George A.      83
Olefin      189 (see also “Alkenes”)
Oleic acid      193 792 1073
Oligonucleotide      1164
Oligosaccharide      1027
Opsin      729
Optical activity      287—289 316
Optical activity and chemical reactions      297—300 309 316 331—333 342—344 353 354 768—769
Optical purity      288
Optical resolution      see “Resolution’
Orbital hybridization $sp^2$ in alkadienes      400—402
Orbital hybridization $sp^2$ in aniline      917—918
Orbital hybridization $sp^2$ in benzene      430
Orbital hybridization $sp^2$ in carbenes      607
Orbital hybridization $sp^2$ in carbocations      156 161 181
Orbital hybridization $sp^2$ in ethylene and alkenes      89—92 95 190—192 220
Orbital hybridization $sp^2$ in formaldehyde      706—707
Orbital hybridization $sp^2$ in free radicals      168 181
Orbital hybridization $sp^3$ in alkyl halides      146
Orbital hybridization $sp^3$ in ethane      67 95
Orbital hybridization $sp^3$ in methane      63—65 95
Orbital hybridization $sp^3$ in methanol      146
Orbital hybridization $sp^3$ in methylamine      916 917
Orbital hybridization model for bonding      63—65 95
Orbital hybridization sp in acetylene and alkynes      92—94 95 365—367 382
Orbital hybridization sp in allenes      402—404
Orbital symmetry, and Diets — Alder reaction      414—415
Orbitals atomic      7—10 47
Orbitals hybrid orbitals      63—65 89—92 92—94 95
Organic chemistry definition      1
Organic chemistry historical background of      1—6
Organic Structure Elucidation      555
Organoboranes      250—251 252—254
Organocopper compounds      see “Lithium diorganocuprates”
Organolithium reagents basicity of      592—594 614
Organolithium reagents preparation of      589—590 615
Organolithium reagents reaction of with aldehydes and ketones      594—596 616 617 626
Organolithium reagents reaction of with epoxides      632—633
Organolithium reagents reaction of with nitriles      872
Organomagnesium compounds      see “Grignard reagents”
Organometallic compounds      587—622 (see also “Grignard reagents”; “Lithium diorganocuprates”; “Organolithium reagents”; “Organozinc compounds”)
Organozinc compounds      604—606 615
Ortho (o), disubstituted organic compounds      432—433
Ortho-para directing groups      488—492 494—497 495 500—501
Osmium tetraoxide      634—635 654
Oxalic acid      54 804
Oxane      637 666
Oxaphosphetane      732
Oxazole      461
Oxidation      (see also “Epoxidation”; “Hydroxylation of alkenes”; “Ozonolysis”)
Oxidation biological      285 435 444 645—647
Oxidation of alcohols      641—648 657 709—711 807
Oxidation of aldehydes      736 745 807
Oxidation of alkylbenzenes      443—444 466 806 807
Oxidation of carbohydrates      1053—1055 1063
Oxidation of ketones      736—738 745
Oxidation of phenols      1012—1013 1018
Oxidation of vicinal diols      647—648 655
Oxidation-reduction in organic chemistry      87—89 98
Oximes      727
Oxkane      666 (see also “Ethylene oxide”)
Oxo process      see “Hydroformylation”
Oxolane      666 (see also “Tetrahydrofuran”)
Oxonium ion      34 (see also “Hydronium ion”)
Oxygen biological storage and transport of      1148 1150
Oxygen isotopic labels      810 852 854—855
Oxytocin      1129
Ozone, bonding in      24—25 262
Ozonide      263
Ozonolysis of alkenes      262—264 274 710
Ozonolysis of alkynes      381—382
p-(Trifluoromethyl)aniline      921
p-Aminobenzoic acid      942 951
p-Chloronitrobenzene, nucleophilic substitution in      975—977
p-Chloronitrobenzene, nucleophilic substitution in electrostatic potential map      971
p-Cresol, $\sideset{^1}{}H NMR$ spectrum      1014—1015
p-Cresol, acidity of      998
p-Cresol, carboxylation      1008
p-Cresol, infrared spectrum      1014
p-Cresol, nitration of      1003
p-Cresol, preparation of      1000
p-Fluoronitrobenzene, nucleophilic aromatic substitution in      976—979 1009
p-Fluorophenol, O-acylation      1005
p-Nitroaniline basicity of      921
p-Nitroaniline bromination of      959
p-Nitroaniline preparation of      941—942
p-Nitrophenol acidity of      998
p-Nitrophenol esters of, in peptide bond formation      1139 1141
p-Toluenesulfonic acid as acid catalyst      722
p-Toluenesulfonic acid, acidity of      351
p-Toluenesulfonic acid, esters as substrates in nucleophilic aliphatic substitution      350—353 357
p-Toluenesulfonic acid, esters preparation of      351 357 636
p-Toluenesulfonic acid, nucleophilic aromatic substitution in      1000
p-Toluenesulfonyl chloride, reaction with alcohols      351 357 636
p-Xylene      432—433
p-Xylene Friedel — Crafts acylation of      502
p-Xylene oxidation of      806
Palladium hydrogenation catalyst      230 231 627—628
Palladium Lindlar      374—375 384
Palmitic acid      1073
Papain      1130
Para (p), disubstituted organic compounds      432—433
Paraffin hydrocarbon      83 (see also “Alkanes”)
Partial rate factors      490—491 502 517
Pasteur, Louis      310
Pauli exclusion principle      8—9
Pauling, Linus      3 15
Pauling, Linus and orbital hybridization      64
Pauling, Linus and peptide structure      1143—1145
Pauling, Linus electronegativity scale      15
PCBs      see “Polychlorinated biphenyls”
PCC      see “Pyridinium chlorochromate”
PCR      see “Polymerase chain reaction”
PDC      see “Pyridinium dichromate”
Pedersen, Charles J.      669
Penicillin G      861—862
pentaacetate      1058
Pentane      71 82
Pentane conformation of      110 112
Pentanenitrile hydrogenation of      932
Pentanenitrile preparation of      923 926
Pentobarbital      900
Pentothal sodium      901
Pentyl azide      927
Pepsin      1130
Peptide bond      1109 1126
Peptide bond geometry of      1127—1128
Peptide bond preparation of      1139—1143
Peptides      1126—1147 (see also “Proteins”)
Peptides amino acid analysis      1130
Peptides classification of      1109
Peptides end-group analysis of      1131—1135
Peptides hydrolysis of      1130
Peptides structure of      1109 1126—1129
Peptides synthesis of      1135—1143
Pericyclic reactions      409 1012
Periodic acid cleavage of carbohydrates      1059—1061 1064
Periodic acid cleavage of vicihal diols      647—648 655
Perkin, William Henry      4
Peroxide effect      243
Peroxides by oxidation of ethers      674
Peroxides initiators of free-radical reactions      242—244 442-443
Peroxides intermediates in icosanoid biosynthesis      1081—1082
Peroxyacetic acid      796
Peroxyacetic acid epoxidation of alkenes      261—262 273 676 693
Peroxybenzoic acid      736—738
Perutz, Max F.      1146
Petrochemicals      5 189
Petroleum      79—80
Pharmacology      952
Phase-transfer catalysis      923 926 956
Phenacetin      1021
Phenanthrene      434—435
Phenobarbital      901
Phenol(s)      993—1025
Phenol, $pK_a$ of      36
Phenol, acidity of      45 996—999 1016
Phenol, electrostatic potential maps      993 996
Phenol, formation of, in Claisen rearrangement      1011 1018
Phenol, hydrogen bonding      995—996
Phenol, naturally occurring      1001—1002
Phenol, nomenclature of      432 993—994
Phenol, physical properties      995—996
Phenol, preparation from aryl diazonium salts      946 960 1001 1016
Phenol, preparation from benzenesulfonic acid      1000
Phenol, preparation from chlorobenzene      975 1000
Phenol, preparation from cumene      1000
Phenol, reactions of azo coupling      1004
Phenol, reactions of bromination      1002—1003
Phenol, reactions of carboxylation      1006—1008 1017
Phenol, reactions of electrophilic aromatic substitution      494 1002—1004
Phenol, reactions of esterification      1005 1006 1017
Phenol, reactions of Friedel — Crafts acylation      1004 1005
Phenol, reactions of Friedel — Crafts alkylation      1003
Phenol, reactions of Kolbe — Schmitt reaction      1006—1008 1017
Phenol, reactions of nitration      494 1003
Phenol, reactions of nitrosation      1003
Phenol, reactions of O-alkylation      1008 1018
Phenol, reactions of oxidation      1012—1014 1018
Phenol, reactions of sulfonation      1003
Phenol, resonance in      995
Phenol, spectroscopic analysis      1014—1015
Phenol, structure and bonding      994—995
Phenyl benzoate, Fries rearrangement of      1006
Phenyl group      434
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