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| Àâòîðèçàöèÿ |
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| Ïîèñê ïî óêàçàòåëÿì |
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| Carey F.A. — Organic Chemistry |
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| Ïðåäìåòíûé óêàçàòåëü |
Nomenclature IUPAC of nucleosides 1160
Nomenclature IUPAC of organometallic compounds 588 614
Nomenclature IUPAC of sulfides 666
Nomenclature IUPAC of thiols 648
Nomenclature stereochemical notation cis and trans 124
Nomenclature stereochemical notation D-L 293 1027—1032 1061
Nomenclature stereochemical notation E-Z 193—195 220
Nomenclature stereochemical notation erythro and threo 301—302
Nomenclature stereochemical notation R-S 290—293
Nomenclature substitutive 144—145 178
Nomex 868
Nonsteroidal antiinflammatory drugs 1083
Norepinephrine 687—688 1126
Norethindrone 1100
NSAIDs see “Nonsteroidal antiinflammatory drugs”
Nuclear magnetic resonance spectra carbon 1-chloropentane 548
Nuclear magnetic resonance spectra carbon 1-phenyl-1-pentanone 553-554
Nuclear magnetic resonance spectra carbon 3-heptanone 740
Nuclear magnetic resonance spectra carbon m-cresol 551—552
Nuclear magnetic resonance spectra carbon methanol 953
Nuclear magnetic resonance spectra carbon methylamine 953
Nuclear magnetic resonance spectra proton 1,1-dichloroethane 536
Nuclear magnetic resonance spectra proton 1-chloropentane 548
Nuclear magnetic resonance spectra proton 2,3,4-trichloroanisole 542
Nuclear magnetic resonance spectra proton 2-butanone 739
Nuclear magnetic resonance spectra proton 2-methylpropanal 739
Nuclear magnetic resonance spectra proton 2-phenylethanol 653
Nuclear magnetic resonance spectra proton 4-methylbenzyl alcohol 952—954
Nuclear magnetic resonance spectra proton 4-methylbenzylamine 952—954
Nuclear magnetic resonance spectra proton 4-phenylbutanoic acid 820
Nuclear magnetic resonance spectra proton benzyl alcohol 545
Nuclear magnetic resonance spectra proton chloroform 525
Nuclear magnetic resonance spectra proton dipropyl ether 689
Nuclear magnetic resonance spectra proton ethyl acetate 872 873
Nuclear magnetic resonance spectra proton ethyl bromide 538—539
Nuclear magnetic resonance spectra proton isopropyl chloride 540
Nuclear magnetic resonance spectra proton m-nitrostyrene 543
Nuclear magnetic resonance spectra proton methoxyacetonitrile 532—533
Nuclear magnetic resonance spectra proton methyl propanoate 872 873
Nuclear magnetic resonance spectra proton p-cresol 1015
Nuclear magnetic resonance spectroscopy and magnetic field strength 522—523
Nuclear magnetic resonance spectroscopy carbon 547—559 576—577
Nuclear magnetic resonance spectroscopy carbon alcohols 652
Nuclear magnetic resonance spectroscopy carbon aldehydes and ketones 738 740
Nuclear magnetic resonance spectroscopy carbon amines 953
Nuclear magnetic resonance spectroscopy carbon carboxylic acid derivatives 872—873
Nuclear magnetic resonance spectroscopy carbon carboxylic acids 819—820
Nuclear magnetic resonance spectroscopy carbon chemical shifts 549—551
Nuclear magnetic resonance spectroscopy carbon ethers 690—691
Nuclear magnetic resonance spectroscopy carbon in biosynthetic studies 1092
Nuclear magnetic resonance spectroscopy carbon thiols 652
Nuclear magnetic resonance spectroscopy proton 522—545 575—576
Nuclear magnetic resonance spectroscopy proton alcohols 544—545 576 651—652 653 655
Nuclear magnetic resonance spectroscopy proton aldehydes and ketones 738—741
Nuclear magnetic resonance spectroscopy proton amines 952—953
Nuclear magnetic resonance spectroscopy proton and conformations 544—545 576
Nuclear magnetic resonance spectroscopy proton carboxylic acid derivatives 872 873
Nuclear magnetic resonance spectroscopy proton carboxylic acids 819—820
Nuclear magnetic resonance spectroscopy proton chemical shift 525—532 575
Nuclear magnetic resonance spectroscopy proton ethers and epoxides 689—692
Nuclear magnetic resonance spectroscopy proton interpretation 532—535 576
Nuclear magnetic resonance spectroscopy proton nuclear shielding 525—526
Nuclear magnetic resonance spectroscopy proton phenols 1014—1015
Nuclear magnetic resonance spectroscopy proton spin-spin splitting 535—544 576
Nuclear magnetic resonance spectroscopy proton thiols 652
Nuclear magnetic resonance spectroscopy two dimensional (2D NMR) 556—559 577
Nuclear spin states 522—523
Nucleic acids 1165—1166 (see also “Deoxyribonucleic acid”; “Ribonucleic acid”)
Nucleophiles 47 157—158 159—160 163—165 181 327—329
Nucleophiles relative reactivity 336—338
Nucleophiles solvation and reactivity 338 346—347
Nucleophilic acyl substitution 830—885
Nucleophilic acyl substitution defined 830—831
Nucleophilic acyl substitution general mechanism 836—838 874—875
Nucleophilic acyl substitution of acyl chlorides 838—841 875
Nucleophilic acyl substitution of amides 862—867 877
Nucleophilic acyl substitution of carboxylic acid anhydrides 841—842 875
Nucleophilic acyl substitution of esters 848—858 876
Nucleophilic acyl substitution of thioesters 858—859 876
Nucleophilic addition to  -unsaturated aldehydes and ketones 777—779 784 901—902 907
Nucleophilic addition to aldehydes and ketones 712—735 742—744
Nucleophilic alkyl substitution (see also “ 2$"/> SN”)
Nucleophilic alkyl substitution  -halo carboxylic acids 816
Nucleophilic alkyl substitution alcohols 153—166
Nucleophilic alkyl substitution alkyl halides 326—350 733 808 867 894—900
Nucleophilic alkyl substitution alkyl p-toluenesulfonates 350—353 357
Nucleophilic alkyl substitution allylic halides 391—394 416 650 895
Nucleophilic alkyl substitution benzylic halides 444—446
Nucleophilic alkyl substitution crown ether catalysis of 671
Nucleophilic alkyl substitution enzyme-catalyzed 339
Nucleophilic alkyl substitution epoxides 678—684
Nucleophilic alkyl substitution phase-transfer catalysis of 923 926
Nucleophilic aryl substitution 975—985 986—987 1000 1009
Nucleosides 1158—1160
Nucleosomes 1171
nucleotides 1160—1162 1164—1166 1187
Nylon 4 868
O-Acetylsalicylic acid see “Aspirin”
o-Cresol 1003
o-Hydroxybenzoic acid 792 (see also “Salicylic acid”)
o-Nitroaniline, diazotization of 961
o-Nitrophenol acidity of 998
o-Nitrophenol intramolecular hydrogen bonding 996
o-Nitrophenol reaction with acetic anhydride 1005 1017
o-Nitrophenol reaction with butyl bromide 1018
o-Toluidine 948
o-Xylene 432—433
o-Xylene Birch reduction of 464—465
Octadecanoic acid 792
Octane number of gasoline 80
Octane, relative stability of isomers 85—86
Octet rule 13 47
Off-resonance decoupling 553
Oil of wintergreen see “Methyl salicylate”
Oils see “Fats”
Olah, George A. 83
Olefin 189 (see also “Alkenes”)
Oleic acid 193 792 1073
Oligonucleotide 1164
Oligosaccharide 1027
Opsin 729
Optical activity 287—289 316
Optical activity and chemical reactions 297—300 309 316 331—333 342—344 353 354 768—769
Optical purity 288
Optical resolution see “Resolution’
Orbital hybridization  in alkadienes 400—402
Orbital hybridization in aniline 917—918
Orbital hybridization in benzene 430
Orbital hybridization in carbenes 607
Orbital hybridization in carbocations 156 161 181
Orbital hybridization in ethylene and alkenes 89—92 95 190—192 220
Orbital hybridization in formaldehyde 706—707
Orbital hybridization in free radicals 168 181
Orbital hybridization  in alkyl halides 146
Orbital hybridization in ethane 67 95
Orbital hybridization in methane 63—65 95
Orbital hybridization in methanol 146
Orbital hybridization in methylamine 916 917
Orbital hybridization model for bonding 63—65 95
Orbital hybridization sp in acetylene and alkynes 92—94 95 365—367 382
Orbital hybridization sp in allenes 402—404
Orbital symmetry, and Diets — Alder reaction 414—415
Orbitals atomic 7—10 47
Orbitals hybrid orbitals 63—65 89—92 92—94 95
Organic chemistry definition 1
Organic chemistry historical background of 1—6
Organic Structure Elucidation 555
Organoboranes 250—251 252—254
Organocopper compounds see “Lithium diorganocuprates”
Organolithium reagents basicity of 592—594 614
| Organolithium reagents preparation of 589—590 615
Organolithium reagents reaction of with aldehydes and ketones 594—596 616 617 626
Organolithium reagents reaction of with epoxides 632—633
Organolithium reagents reaction of with nitriles 872
Organomagnesium compounds see “Grignard reagents”
Organometallic compounds 587—622 (see also “Grignard reagents”; “Lithium diorganocuprates”; “Organolithium reagents”; “Organozinc compounds”)
Organozinc compounds 604—606 615
Ortho (o), disubstituted organic compounds 432—433
Ortho-para directing groups 488—492 494—497 495 500—501
Osmium tetraoxide 634—635 654
Oxalic acid 54 804
Oxane 637 666
Oxaphosphetane 732
Oxazole 461
Oxidation (see also “Epoxidation”; “Hydroxylation of alkenes”; “Ozonolysis”)
Oxidation biological 285 435 444 645—647
Oxidation of alcohols 641—648 657 709—711 807
Oxidation of aldehydes 736 745 807
Oxidation of alkylbenzenes 443—444 466 806 807
Oxidation of carbohydrates 1053—1055 1063
Oxidation of ketones 736—738 745
Oxidation of phenols 1012—1013 1018
Oxidation of vicinal diols 647—648 655
Oxidation-reduction in organic chemistry 87—89 98
Oximes 727
Oxkane 666 (see also “Ethylene oxide”)
Oxo process see “Hydroformylation”
Oxolane 666 (see also “Tetrahydrofuran”)
Oxonium ion 34 (see also “Hydronium ion”)
Oxygen biological storage and transport of 1148 1150
Oxygen isotopic labels 810 852 854—855
Oxytocin 1129
Ozone, bonding in 24—25 262
Ozonide 263
Ozonolysis of alkenes 262—264 274 710
Ozonolysis of alkynes 381—382
p-(Trifluoromethyl)aniline 921
p-Aminobenzoic acid 942 951
p-Chloronitrobenzene, nucleophilic substitution in 975—977
p-Chloronitrobenzene, nucleophilic substitution in electrostatic potential map 971
p-Cresol,  spectrum 1014—1015
p-Cresol, acidity of 998
p-Cresol, carboxylation 1008
p-Cresol, infrared spectrum 1014
p-Cresol, nitration of 1003
p-Cresol, preparation of 1000
p-Fluoronitrobenzene, nucleophilic aromatic substitution in 976—979 1009
p-Fluorophenol, O-acylation 1005
p-Nitroaniline basicity of 921
p-Nitroaniline bromination of 959
p-Nitroaniline preparation of 941—942
p-Nitrophenol acidity of 998
p-Nitrophenol esters of, in peptide bond formation 1139 1141
p-Toluenesulfonic acid as acid catalyst 722
p-Toluenesulfonic acid, acidity of 351
p-Toluenesulfonic acid, esters as substrates in nucleophilic aliphatic substitution 350—353 357
p-Toluenesulfonic acid, esters preparation of 351 357 636
p-Toluenesulfonic acid, nucleophilic aromatic substitution in 1000
p-Toluenesulfonyl chloride, reaction with alcohols 351 357 636
p-Xylene 432—433
p-Xylene Friedel — Crafts acylation of 502
p-Xylene oxidation of 806
Palladium hydrogenation catalyst 230 231 627—628
Palladium Lindlar 374—375 384
Palmitic acid 1073
Papain 1130
Para (p), disubstituted organic compounds 432—433
Paraffin hydrocarbon 83 (see also “Alkanes”)
Partial rate factors 490—491 502 517
Pasteur, Louis 310
Pauli exclusion principle 8—9
Pauling, Linus 3 15
Pauling, Linus and orbital hybridization 64
Pauling, Linus and peptide structure 1143—1145
Pauling, Linus electronegativity scale 15
PCBs see “Polychlorinated biphenyls”
PCC see “Pyridinium chlorochromate”
PCR see “Polymerase chain reaction”
PDC see “Pyridinium dichromate”
Pedersen, Charles J. 669
Penicillin G 861—862
pentaacetate 1058
Pentane 71 82
Pentane conformation of 110 112
Pentanenitrile hydrogenation of 932
Pentanenitrile preparation of 923 926
Pentobarbital 900
Pentothal sodium 901
Pentyl azide 927
Pepsin 1130
Peptide bond 1109 1126
Peptide bond geometry of 1127—1128
Peptide bond preparation of 1139—1143
Peptides 1126—1147 (see also “Proteins”)
Peptides amino acid analysis 1130
Peptides classification of 1109
Peptides end-group analysis of 1131—1135
Peptides hydrolysis of 1130
Peptides structure of 1109 1126—1129
Peptides synthesis of 1135—1143
Pericyclic reactions 409 1012
Periodic acid cleavage of carbohydrates 1059—1061 1064
Periodic acid cleavage of vicihal diols 647—648 655
Perkin, William Henry 4
Peroxide effect 243
Peroxides by oxidation of ethers 674
Peroxides initiators of free-radical reactions 242—244 442-443
Peroxides intermediates in icosanoid biosynthesis 1081—1082
Peroxyacetic acid 796
Peroxyacetic acid epoxidation of alkenes 261—262 273 676 693
Peroxybenzoic acid 736—738
Perutz, Max F. 1146
Petrochemicals 5 189
Petroleum 79—80
Pharmacology 952
Phase-transfer catalysis 923 926 956
Phenacetin 1021
Phenanthrene 434—435
Phenobarbital 901
Phenol(s) 993—1025
Phenol,  of 36
Phenol, acidity of 45 996—999 1016
Phenol, electrostatic potential maps 993 996
Phenol, formation of, in Claisen rearrangement 1011 1018
Phenol, hydrogen bonding 995—996
Phenol, naturally occurring 1001—1002
Phenol, nomenclature of 432 993—994
Phenol, physical properties 995—996
Phenol, preparation from aryl diazonium salts 946 960 1001 1016
Phenol, preparation from benzenesulfonic acid 1000
Phenol, preparation from chlorobenzene 975 1000
Phenol, preparation from cumene 1000
Phenol, reactions of azo coupling 1004
Phenol, reactions of bromination 1002—1003
Phenol, reactions of carboxylation 1006—1008 1017
Phenol, reactions of electrophilic aromatic substitution 494 1002—1004
Phenol, reactions of esterification 1005 1006 1017
Phenol, reactions of Friedel — Crafts acylation 1004 1005
Phenol, reactions of Friedel — Crafts alkylation 1003
Phenol, reactions of Kolbe — Schmitt reaction 1006—1008 1017
Phenol, reactions of nitration 494 1003
Phenol, reactions of nitrosation 1003
Phenol, reactions of O-alkylation 1008 1018
Phenol, reactions of oxidation 1012—1014 1018
Phenol, reactions of sulfonation 1003
Phenol, resonance in 995
Phenol, spectroscopic analysis 1014—1015
Phenol, structure and bonding 994—995
Phenyl benzoate, Fries rearrangement of 1006
Phenyl group 434
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