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Carey F.A. — Organic Chemistry

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Название: Organic Chemistry

Автор: Carey F.A.

Аннотация:

This respected text is based on the Functional Group approach. The text retains the outstanding problems, pedagogy, depth, and prose of the second edition while providing increased emphasis on molecular modeling, a core concept in organic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 2004

Количество страниц: 1191

Добавлена в каталог: 20.04.2006

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

D-Mannose, conversion to D-fructose      1057
D-Mannose, epimerization of      1056
D-Ribose      1030 1031
D-Ribose 2-deoxy      1042 1064
D-Ribose cyanohydrin      1063
D-Ribose furanose and pyranose forms      1035—1036 1039 1062
D-Ribulose      1041
D-Talose      1031
D-Threose      1029
D-Xylonic acid      1054
D-Xylose      1031
D-Xylose furanose forms      1036
D-Xylose oxidation      1054
Dacron      868
Darwin, Charles      1165
DCCI      see “N
DDT (dichlorodiphenyltrichloroethane)      992
de Broglie, Louis      7
Deamination reactions      944 949—950 961
Debye unit      17
Debye, Peter J. W.      17
Decane      71
Decane mass spectrum of      570—571
Decarboxylation $\alpha$ -amino acids      1125—1126
Decarboxylation $\beta$ -keto acids      818—819 824 893 895—896 905
Decarboxylation malonic acid derivatives      816—818 824 897 898—900 907 1122
Decoupling in $\sideset{^{13}}{}C NMR$       553
Decoupling of alcohol protons in $\sideset{^1}{}H NMR$       544—545 576
Dehydration in aldol condensation      772—773 775
Dehydration in preparation of alkenes from alcohols      202-211 221 404 446 636
Dehydration in preparation of cyclic anhydrides      842
Dehydration in preparation of dienes      404 417
Dehydration in preparation of nitriles from amides      867—870
Dehydrogenation biological      202
Dehydrogenation of alcohols      710
Dehydrogenation of butane      404
Dehydrogenation of ethane      189 202
Dehydrogenation of ethylbenzene      446 483
Dehydrogenation of ethylene      364
Dehydrogenation of propane      189 202
Dehydrohalogenation      see also “Elimination reactions”
Dehydrohalogenation in preparation of alkenes      212—219 221
Dehydrohalogenation in preparation of alkenylbenzenes      446
Dehydrohalogenation in preparation of alkynes      372—374 383
Dehydrohalogenation in preparation of dienes      404
Dehydrohalogenation of 1-chloro-1-methylcyclohexane      221
Dehydrohalogenation of 1-chlorooctadecane      212
Dehydrohalogenation of 2-bromo-2-methylbutane      212 218
Dehydrohalogenation of 5-bromononane      213
Dehydrohalogenation of alkyl halides      211—219 221 446
Dehydrohalogenation of bromocyclodecane      213
Dehydrohalogenation of cis- and trans-4-tert-butylcyclohexyl bromide      216—217
Dehydrohalogenation of cyclohexyl chloride      212
Dehydrohalogenation of dihalides      372—374 383
Dehydrohalogenation of menthyl and neomenthyl chloride      228
Delocalization energy      399 (see also “Resonance energy”)
Denaturation of ethanol      624
Denaturation of proteins      1146
Dendrolasin      1104
Deoxy sugars      1042 1062
Deoxyribonucleic acid (DNA) A-, B-, and Z-DNA      1169
Deoxyribonucleic acid (DNA) and protein biosynthesis      1178
Deoxyribonucleic acid (DNA) profiling and PCR      1183—1186 1189
Deoxyribonucleic acid (DNA) purine and pyrimidine bases in      1155—1158
Deoxyribonucleic acid (DNA) replication of      1172—1173 1188
Deoxyribonucleic acid (DNA) sequencing of      1180—1183 1189
Deoxyribonucleic acid (DNA) structure of      1166—1172 1188
DEPT      553—554 577
Detergents      801
Deuterium oxide      186 544—545 768 819
Dextrins      1049
Dextrorotatory      288
Diacetylene      364
Dianabol      1099
Diastereomers      300—312 315 317
Diastereomers formation of      307—310
Diastereotopic protons      534 542
Diazonium salts      944—951 959—961
Diazonium salts azo coupling of      950—951 990
Diazonium salts conversion to arenes      949—950 961
Diazonium salts conversion to aryl cyanides      948 961
Diazonium salts conversion to aryl halides      946—948 960—961 973
Diazonium salts conversion to phenols      946 960 1001 1016
Diazonium salts preparation of      944—946
Diborane      251 (see also “Hydroboration-oxidation”)
Dibromocarbene      606—608
Dibromoindigo      974
Dibutyl ether      635 671
Dicarboxylic acids acidity of      804
Dicarboxylic acids cyclic anhydrides from      842
Dicarboxylic acids decarboxylation      816—818 824 897 898—900 907
Dicarboxylic acids in preparation of polyamides and polyesters      868—869
Dicarboxylic acids nomenclature of      793
Dichlorocarbene      606 607
Dichlorocyclohexane isomers      305
Dichlorodiphenyltrichloroethane      see “DDT”
Dichloromethane      31—32 150 166—167
Dieckmann reaction      890—891 906
Dieis — Alder reaction      409—415 418
Dieis — Alder reaction of benzyne      985—986
Dieis — Alder reaction orbital symmetry analysis of      414—415 418
Dielectric constant and rate of nucleophilic substitution      345—347 356
Dielectric constant of various solvents      345 table
Diels, Otto      409
Dienes      see also “Alkadienes”
Dienes conjugated      390 398—402 565—566
Dienes conjugated 1,2 and 1,4 addition to      405—407 417—418
Dienes conjugated conformations of      401—402 417
Dienes conjugated Dieis — Alder reactions of      409—415 418
Dienes conjugated electron delocalization in      399—402
Dienes conjugated electrophilic addition reactions of      405—407 417—418
Dienes conjugated polymers      408
Dienes conjugated preparation of      404 417
Dienes conjugated resonance energy      399
Dienes cumulated      398 402—404
Dienes heats of hydrogenation      399—400 428—429
Dienes isolated      398 404
Dienes stability of various classes      399—402 416
Dienophiles      409—411 986
Diethyl acetamidomalonate      1122
Diethyl adipate      see “Diethyl hexanedioate”
Diethyl carbonate, acylation of ketones with      891—892
Diethyl ether      665
Diethyl ether as solvent for Grignard reagents      591
Diethyl ether cleavage by hydrogen bromide      675
Diethyl ether conformation of      667
Diethyl ether dipole moment of      668
Diethyl ether hydrogen bonding to water electrostatic potential map      668
Diethyl ether peroxide formation in      674
Diethyl ether physical properties of      668
Diethyl ether preparation of      637
Diethyl hexanedioate Dieckmann cyclization of      890
Diethyl malonate of      36
Diethyl malonate acidity of      897
Diethyl malonate barbiturates from      900—901
Diethyl malonate enol content      909
Diethyl malonate enolate electrostatic potential map      886
Diethyl malonate in malonic ester synthesis      897—900 907
Diethyl malonate Michael addition to methyl vinyl ketone      901—902
Diethyl malonate preparation of      857
Diethylamine basicity      920
Diethylamine infrared spectrum      952
Diethylene glycol dimethyl ether      see “Diglyme”
Diethylstilbestrol (DES)      1108
Diglyme      251 666
Dihaloalkanes alkynes from      372—374 383
Dihaloalkanes geminal      372—374 383
Dihaloalkanes reaction with diethyl malonate      899—900
Dihaloalkanes vicinal      254 372—374 383
Dihedral angle      see “Torsion angle”

Diiodomethane      605
Diisopropyl ether      671 674
Diketones, intromolecular aldol condensation o      773 779 783
Dimer      266
Dimethyl ether bond distances and bond angles      667
Dimethyl sulfate      641
Dimethyl sulfide      263
Dimethyl sulfoxide as solvent in elimination reactions      212 373
Dimethyl sulfoxide as solvent in nucleophilic substitution reactions      327 347 352 808
Dimethyl sulfoxide as solvent in Wittig reaction      730 733
Dimethylallyl pyrophosphate      1087
Dimethylamine of conjugate acid      36
Dimethylamine nitrosation of      943
Dimethylamine reaction with esters      858
Diols cyclic acetals from      722 723
Diols cyclic ethers from      637
Diols geminal      712—717
Diols nomenclature of      634
Diols oxidative cleavage of      647—648 655
Diols polyesters from      868
Diols preparation of      633—635
Diols vicinal      see “Vicinal diols”
Dioxane      666
Dioxin      1009—1010
Diphenylamine, basicity of      921
Diphenylmethane, acidity of      621
Dipole moment      16—17 49
Dipole moment and molecular geometry      31—32
Dipole moment of 1, 2-dichloroethane      141
Dipole moment of alcohols      147
Dipole moment of aldehydes and ketones      707 776
Dipole moment of alkanes      81
Dipole moment of alkyl halides      147
Dipole moment of carbon tetrachloride      31—32
Dipole moment of carboxylic acids      794
Dipole moment of chlorobenzene      972
Dipole moment of chlorocyclohexane      972
Dipole moment of chloroethene      196
Dipole moment of chloromethane      147
Dipole moment of dichloromethane      31—32
Dipole moment of diethyl ether      668
Dipole moment of esters      846
Dipole moment of ethanol      148
Dipole moment of ethylene      196
Dipole moment of ethylene oxide      668
Dipole moment of fluoroethane      148
Dipole moment of four-carbon alkenes      197
Dipole moment of methanol      147
Dipole moment of propanal      707
Dipole moment of propane      148
Dipole moment of propene      196
Dipole moment of tetrahydrofuran      668
Dipole moment of trans-l-chloropropene      196
Dipole moment of water      147
Dipole — induced dipole attractions      81 147—148
Dipole-dipole attractions      81 147—148
Dipole-dipole attractions and hydrogen bonding      147—151 668
Dipole-dipole attractions in esters      846
Dipole-dipole attractions in ethyl fluoride      148
Dipropyl ether $\sideset{^1}{}H$ and $\sideset{^{13}}{}C NMR$ spectra      689
Dipropyl ether infrared spectrum      688
Dipropyl ether preparation of      693
Directing effects of substituents      see “Electrophilic aromatic substitution”
Disaccharide      1027 1046—1048 1062
Disparlure      261
Distortionless enhancement of polarization transfer      see “DEPT”
Disulfides $\alpha$ -keratin      1144
Disulfides carboxypeptidase A      1146
Disulfides glutathione      651
Disulfides lipoic acid      132 650
Disulfides oxytocin      1129
Disulfides preparation of      650—651
Diterpenes      1085
DMF      see “N
DNA      see “Deoxyribonucleic acid”
DNA sequenator      1181
Dodecane      71
Dopamine      1126
Double bond      14 89—91 99 190—192
Double helix      1166—1170 1188
drugs      see also “AIDS; Antibiotics”
Drugs chiral      296
Drugs generic names of      78
Dyes      951—952
E (stereochemical prefix)      193—195 220
E1 mechanism      206—208 217—219
E2 mechanism      206—208 212—217 223 348—350
Eclipsed conformations      105—107 112 133
Eclipsed conformations and Fischer projections      302 304
Ectocarpene      322
Edman degradation      1133—1135
Edman sequenator      1135
Edman, Pehr      1134
Eicosanoic acid      see “Icosanoic acid”
Eigen, Manfred      155
Elastomer      408
Electromagnetic radiation      520—521
Electron affinity      11
Electron configuration      8—10 62
Electron configuration and orbital hybridization      64—65 90 93
Electron configuration and resonance      24—27 42 49
Electron configuration in $\alpha,\beta$ unsaturated aldehydes and ketones      775-777
Electron configuration in allylic radicals      395
Electron configuration in benzylic carbocations      445
Electron configuration in benzylic radicals      441
Electron configuration in carbocations      161—162
Electron configuration in carboxylate ions      42 796—797 836
Electron configuration in carboxylic acid derivatives      833—838
Electron configuration in conjugated dienes      399—402
Electron configuration in enolates      763—765 887 894 897 905
Electron configuration in nitrate ion      42
Electron delocalization configuration in allylic carbocations      391—394 405—407
Electron-dot structures      see “Lewis structural formulas”
Electronegativity      15 48
Electronegativity $n\to,\pi^*$       567
Electronegativity $\pi\to,\pi^*$       565—566
Electronegativity and acid strength      39—41
Electronegativity and chemical shift      526—527 549—550
Electronegativity and polar covalent bonds      14—17
Electronegativity nuclear shielding by      525 526—527
Electronegativity of selected elements      15 table 588
Electronegativity quantum numbers      8
Electronegativity relation to s character at carbon      367
Electronegativity valence      9
Electronegativity wave properties of      7 59
Electronic effects      199
Electrons excitation of      565—567
Electrophile      47 156
Electrophilic addition      see “Addition reactions”
Electrophilic aromatic substitution      473—518
Electrophilic aromatic substitution azo coupling      950—951 1004
Electrophilic aromatic substitution in phenols      494 1002—1004
Electrophilic aromatic substitution mechanism      474—476
Electrophilic aromatic substitution mechanism of Friedel — Crafts acylation      484—485
Electrophilic aromatic substitution mechanism of Friedel — Crafts alkylation      481—482
Electrophilic aromatic substitution mechanism of halogenation      480—481
Electrophilic aromatic substitution mechanism of nitration      477—478
Electrophilic aromatic substitution mechanism of sulfonation      478—480
Electrophilic aromatic substitution of arylamines      939—942
Electrophilic aromatic substitution of benzene      474—488
Electrophilic aromatic substitution substituent effects in      488—506 495 509 511—512
Electrophilic aromatic substitution summary tables      475 510 1003—1004
Electrophoresis and nucleic acid sequencing      1181
Electrophoresis of amino acids      1120—1121
Electropositive      15
Electrostatic potential map      15—16
Electrostatic potential map transition state      326
Electrostatic potential map 1,3-butadiene      390
Electrostatic potential map 1-butene      707
Electrostatic potential map 1-chloro-4-nitrobenzene      971

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