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Carey F.A. — Organic Chemistry

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Название: Organic Chemistry

Автор: Carey F.A.

Аннотация:

This respected text is based on the Functional Group approach. The text retains the outstanding problems, pedagogy, depth, and prose of the second edition while providing increased emphasis on molecular modeling, a core concept in organic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 2004

Количество страниц: 1191

Добавлена в каталог: 20.04.2006

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Mechanism nitration of benzene      477—478
Mechanism nucleophilic acyl substitution      830—831 836—838 874—875
Mechanism nucleophilic alkyl substitution       160—161 180 339—345 356
Mechanism nucleophilic alkyl substitution       163—165 181 330—336 356
Mechanism nucleophilic aromatic substitution addition-elimination      977—980 986—987
Mechanism nucleophilic aromatic substitution elimination-addition      981—985 987
Mechanism polymerization of ethylene coordination polymerization      612—613
Mechanism polymerization of ethylene free-radical polymerization      267—268
Mechanism proton transfer      153—156
Mechanism reaction of alcohols with hydrogen halides      153—160 160—162 354—355 357
Mechanism reaction of esters with amines      858
Mechanism reduction of alkynes by sodium in ammonia      376
Mechanism to alkynes      379
Mechanism Wittig reaction      732
Meisenheimer complex      991
Meisenheimer, Jacob      991
Mendel, Gregor      1165
Menthol      183 323 625 1086
Menthyl chloride      228
Mercaptans      see “Thiols”
Mercury (II) oxide      380
Merlic, Craig A.      555
Merrifield, R. Bruce      1141—1143 (see also “Solid-phase peptide synthesis”)
Mesityl oxide      776
Meso stereoisomer      303—305
Messenger RNA      see “Ribonucleic acid messenger”
Meta (m) directing groups      492—494 495 498—500 509 512
Meta (m) disubstituted aromatic compounds      432—433
Metal-ammonia reduction of alkynes      376—377 384
Metal-ammonia reduction of arenas      see “Birch reduction”
Metal-ion complexes of ethers      668
Metallocenes      610 612—613
methane      63—66
Methane of      37 39
Methane acidity of      37 39 368—369 593—594
Methane bonding in      63—65 95
Methane chemical shifts ( $\sideset{^1}{}H$ and $\sideset{^{13}}{}C$ )      549
Methane chlorination      166—167 172—174
Methane clathrates      66
Methane conversion to acetylene      364
Methane electrostatic potential map      28
Methane natural occurrence      66
Methane physical properties      63
Methane structure      13 63—64
Methane VSEPR and molecular geometry of      30
Methanesulfonic acid      351
Methanethiol of      36
Methanethiol electrostatic potential map      649
Methanogens      66
Methanoic acid      see “Formic acid”
Methanol      145 623—624
Methanol $(\sideset{^{13}}{}C NMR)$       953
Methanol of      36 40
Methanol bond distances and bond angles      146
Methanol chemical shifts ( $\sideset{^1}{}H$ and $\sideset{^{13}}{}C$ )      549
Methanol dehydrogenation of      711
Methanol dipole moment of      147
Methanol electrostatic potential map      147 649
Methanol esterification of      810—813
Methanol industrial preparation of      623—624
Methanol nitration of      640
Methanol properties of      624
Methide anion      368
Methine group      67
Methionine enkephalin      1129
Methyl $\alpha-D$ -glucopyranoside      1045 1054
Methyl $\alpha-D$ -glucopyranoside tetra-O-methyl ether      1059
Methyl $\beta$ -D-glucopyranoside      1045
Methyl 2-methylpropenoate hydrolysis      853
Methyl 2-methylpropenoate reaction with ammonia      857
Methyl acetate UV absorption      874
Methyl alcohol      145 (see also “Methanol”)
Methyl benzoate in mixed Claisen condensation      891
Methyl benzoate preparation of      638 810—813
Methyl bromide nucleophilic substitution in      330—331
Methyl bromide reaction with triphenylphosphine      733
Methyl cation      160—161
Methyl chloride      150 (see also “Chloromethane”)
Methyl chloride $\sideset{^1}{}H$ chemical shift      527
Methyl chloride nucleophilic substitution in      334
Methyl fluoride chemical shifts carbon      549
Methyl fluoride chemical shifts proton      526
Methyl fluoride electrostatic potential map      589
Methyl group      67
Methyl iodide      see also “Iodomethane”
Methyl iodide nucleophilic substitution      337 383 781
Methyl iodide reaction with amines      937—938
Methyl methacrylate      see “Methyl2-methylpropenoate”
Methyl migration in alcohol dehydration      208—211
Methyl migration in cholesterol biosynthesis      1094—1095
Methyl nitrate      640
Methyl nitrite      20 23 27
Methyl propanoate $\sideset{^1}{}H NMR$ spectrum      872 873
Methyl propanoate in mixed Claisen condensation      891
Methyl radical dimerization      173
Methyl radical intermediate in chlorination of methane      172—173
Methyl radical structure and stability      168
Methyl salicylate      845 996
Methyl vinyl ketone in Robinson annulation      779 783
Methyl vinyl ketone reaction with diethyl malonate      901—902
Methylalumoxane (MAO)      612—613
Methylamine $\sideset{^{13}}{}C NMR$       953
Methylamine basicity of      919 920
Methylamine chemical shifts ( $\sideset{^1}{}H$ and $\sideset{^{13}}{}C$ )      549
Methylamine electrostatic potential map      913
Methylamine reaction with benzaldehyde      927
Methylamine structure and bonding      916—918
Methylcyclohexane, conformations of      120—122
Methylene chloride      see also “Dichloromethane”
Methylene chloride $\sideset{^1}{}H$ chemical shift      527
Methylene group      67
Methylene prefix      190
Methylenecyclohexane      730
Methylenetriphenylphosphorane      730 734
Methyllithium      594
Methyllithium electrostatic potential map      589
Methylmagnesium halides reaction of with 1-phenyl-l-propanone      600
Methylmagnesium halides reaction of with butanal      616
Methylmagnesium halides reaction of with cyclopentanone      596
Methylmagnesium halides reaction of with methyl 2-methylpropanoate      602
Methyltrioctylammonium chloride      923
Mevalonic acid      814 1087 1091—1092 1103
Mevalonolactone      815 828
Micelle      800 853
Michael reaction      779 901—902 907
Michael, Arthur      779
Microscopic reversibility      249
Microwaves      520 586
Miescher, Johann      1165
Mitscherlich, Eilhardt      424
MM3      112
Models      see “Molecular models and modeling”
Molar absorptivity      565
Molecular dipole moments      see “Dipole moment”
Molecular formula      20 48 54 573—575
Molecular ion      567
Molecular models and modeling      28—29 111—112
Molecular orbitals $\pi$ and $\pi^*$       412—413 565—566
Molecular orbitals $\sigma$ and $\sigma^*$       61—62 412
Molecular orbitals 1,3-butadiene      413—414
Molecular orbitals allyl cation      422
Molecular orbitals benzene      430—431 452—453
Molecular orbitals bonding and antibonding      61—62
Molecular orbitals cis, trans-l,3-cyclooctadiene      565
Molecular orbitals cyclobutadiene      452—453
Molecular orbitals cycloheptatrienyl cation      456—457
Molecular orbitals cyclooctatetraene      452—453
Molecular orbitals cyclopentadienyl anion      458
Molecular orbitals ethylene      412—413
Molecular orbitals frontier      412

Molecular orbitals highest occupied (HOMO)      412 565
Molecular orbitals hydrogen      61—62
Molecular orbitals lowest unoccupied (LUMO)      412 565
Molecular orbitals [10]annulene      454
Moncado, S.      1149
Monensin      670
Monosaccharide      1026 (see also “Carbohydrates”)
Monoterpene      1085
Morphine      924
Morpholine      744
MRI      see “Magnetic resonance imaging”
Mullis, Kary B.      1183
Multifidene      322
Multiplets      see also “Spin-spin splitting”
Multiplets in $\sideset{^1}{}H NMR$ spectra      535—544 577
Multiplets in $\sideset{^{13}}{}C NMR$ spectra      553 576
Murad, F.      1149
Muscarine      322
Mutarotation      1040 1062
Myoglobin      1148
myosin      1144
Myrcene      1084
Myristic acid      1073
n (prefix)      67 71
n + 1 splitting rule      535 544
N,N-Dimethylformamide      347 930
N,N’-Dicy clohexylcarbodiimide in preparation of esters      1141
N,N’-Dicy clohexylcarbodiimide in preparation of peptides      1139—1140 1142—1143 1152
N-Acetyl-D-galactosamine      1050
N-Acetyl-D-glucosamine      1043
N-Bromosuccinimide, reagent for allylic bromination      397 416
N-Bromosuccinimide, reagent for benzylic bromination      442—443 466
n-Butane      67 (see also “Butane”)
n-Butyl alcohol      See “1-Butanol”
n-Butyl chloride.      see “1-Chlorobutane”
n-Butyl group      74 (see also “Butyl group”
n-Hexane      68 71
N-Methylpyrrolidone      861
N-Nitrosodimethylamine      943
N-Nitrosonornicotine      943
N-Nitrosopyrrolidine      943
n-Pentane      68 (see also “Pentane”)
NAD, NAD +, NADH, NADPH      see “Nicotinamide adenine dinucleotide”
Nanotubes      437
naphthalene      423 434—435
Naphthalene electrophilic aromatic substitution in      506—507
Natta, Giulio      271 610 612—614 617
Natural gas      63 66
Nembutal      900
Neomenthol      183
Neomenthyl chloride      228
Neopentane      69 (see also “2
Neopentyl group      75 (see also “2 group”)
Neopentyl halides, nucleophilic substitution in      336
Neoprene      4 408
Neryl pyrophosphate      1089
Neurotransmitters      924—925 1126
Newman projections      105—106 109 116
Newman, Melvin S.      105
Nickel carbonyl      608
Nickel, hydrogenation catalyst      230 231 428 627—628
Nicotinamide adenine dinucleotide coenzyme in epoxidation of alkenes      684
Nicotinamide adenine dinucleotide coenzyme in fatty acid biosynthesis      1076—1077
Nicotinamide adenine dinucleotide coenzyme in formation of acetyl coenzyme A      1070
Nicotinamide adenine dinucleotide coenzyme in oxidation of alcohols      645—647
Nicotinamide adenine dinucleotide coenzyme in reduction of pyruvic acid      735
Nicotinamide adenine dinucleotide structure of      646
Nicotine      54 295 297 924
Ninhydrin      1123
Nirenberg, Marshall      1191
Nitration of (trifluoromethyl) benzene      489 492—494
Nitration of acetanilide      941—942
Nitration of acetophenone      504
Nitration of benzaldehyde      498 927
Nitration of benzene      475 477—478 504
Nitration of chlorobenzene      500—501
Nitration of fluorobenzene      510
Nitration of m-xylene      503
Nitration of p-cresol      1003
Nitration of p-isopropylacetanilide      941
Nitration of p-methylbenzoic acid      504
Nitration of p-tert-butyltoluene      503
Nitration of phenol      494
Nitration of toluene      488—492 506
Nitric acid of      36 42
Nitric acid formal charges in      18
Nitric acid nitration of arenes by      477—478
Nitric acid oxidation of carbohydrates      1055
Nitric acid oxidation of p-xylene      806
Nitric acid reaction with alcohols      640 656
Nitric oxide      see “Nitrogen monoxide”
Nitriles      (see also “Cyanohydrins”)
Nitriles $\alpha$ -amino, as intermediates in Strecker synthesis      1121
Nitriles hydrolysis of      808—809 822 870—871
Nitriles infrared absorption      872
Nitriles nomenclature of      832
Nitriles preparation of by dehydration of amides      869
Nitriles preparation of from alkyl halides      328 349 808 867
Nitriles preparation of from aryl diazonium salts      948 961
Nitriles reaction with Grig nard reagents      871—872
Nitriles reduction      932 957
Nitro group electron-withdrawing effect of      500 980 998—999
Nitro group reduction      932 957
Nitrobenzene electrophilic aromatic substitution in      500 973
Nitrobenzene preparation of      475 477—478 506
Nitrogen monoxide      1149
Nitrogen rule      573
Nitromethane      23 26—27
Nitronium cation      477—478
Nitrosamines      943
Nitrosation amines      943—946 959—961
Nitrosation phenols      1003
Nitrous acid      943—950 (see also “Nitrosation”)
Nobel, Alfred      640
Noble gas electron configuration      10
Nodal properties of $\pi$ orbitals and pericyclic reactions      412—415
Nodal properties p orbitals      9
Nodal properties surfaces      9
Nomenclature common names of alcohols      145
Nomenclature common names of alkanes      70
Nomenclature common names of alkenes      187—190
Nomenclature common names of alkenyl groups      190
Nomenclature common names of alkyl groups      73—75 98 144
Nomenclature common names of carboxylic acids      792—793
Nomenclature functional class      144—145 178
Nomenclature historical development of      78
Nomenclature IUPAC of $\beta$ -keto esters      887
Nomenclature IUPAC of acyl halides      831
Nomenclature IUPAC of alcohols      145 178
Nomenclature IUPAC of aldehydes      703—705 741
Nomenclature IUPAC of alkadienes      399
Nomenclature IUPAC of alkanes      70—79 96—97
Nomenclature IUPAC of alkenes      187—190 220
Nomenclature IUPAC of alkyl groups      73—75 98
Nomenclature IUPAC of alkyl halides      144—145 178
Nomenclature IUPAC of alkynes      364—365
Nomenclature IUPAC of amides      832
Nomenclature IUPAC of amines      913—916 955
Nomenclature IUPAC of benzene derivatives      432—434
Nomenclature IUPAC of bicyclic ring systems      130—131
Nomenclature IUPAC of carboxylic acid anhydrides      831
Nomenclature IUPAC of carboxylic acids      792—793
Nomenclature IUPAC of cycloalkanes      77—79 97
Nomenclature IUPAC of diols      634
Nomenclature IUPAC of epoxides      260 666
Nomenclature IUPAC of esters      831—832
Nomenclature IUPAC of ethers      665-666
Nomenclature IUPAC of ketones      705—706 741
Nomenclature IUPAC of lactones      814—815
Nomenclature IUPAC of nitriles      832

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