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Carey F.A. — Organic Chemistry

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Название: Organic Chemistry

Автор: Carey F.A.

Аннотация:

This respected text is based on the Functional Group approach. The text retains the outstanding problems, pedagogy, depth, and prose of the second edition while providing increased emphasis on molecular modeling, a core concept in organic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 2004

Количество страниц: 1191

Добавлена в каталог: 20.04.2006

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Phenylacetic acid $\alpha$ -halogenation      816
Phenylacetic acid preparation of      808
Phenylalanylglycine, synthesis of      1136—1139 1141
Phenylbutazone      911
Phenylhydrazine, reaction of, with aldehydes and ketones      727
Phenylisothiocy anate      1134
Phenylketonuria (PKU disease)      1125
Phenyllithium      590
Phenylmagnesium bromide carboxylation of      808
Phenylmagnesium bromide preparation of      591 974
Phenylmagnesium bromide, reaction of with 1,2-epoxypropane      681
Phenylmagnesium bromide, reaction of with 2-butanone      600
Phenylmagnesium bromide, reaction of with ethyl benzoate      616
Phenylmagnesium bromide, reaction of with methanol      592
Phenylpyruvic acid      1125
Phenylthiohydantoin      1134—1135
Pheromone, aggregating of cockroach      68 71
Pheromone, aggregating of European elm bark beetle      661
Pheromone, alarm pheromone of ant      709
Pheromone, alarm pheromone of bees      709
Pheromone, sex attractant of boll worm moth      881
Pheromone, sex attractant of codling moth      224
Pheromone, sex attractant of female gypsy moth      261
Pheromone, sex attractant of female house fly      194 388
Pheromone, sex attractant of female Japanese beetle      845
Pheromone, sex attractant of female tiger moth      101
Pheromone, sex attractant of female winter moth      750
Pheromone, sex attractant of greater wax moth      709
Pheromone, sex attractant of honeybee      224
Pheromone, sex attractant of male Oriental fruit moth      845
Pheromone, sex attractant of Mediterranean fruit fly      224
Pheromone, sex attractant of Western pine beetle      748
Phosphatidic acid      1077
Phosphatidylcholine      1078—1079
Phosphines as nucleophiles      733
Phosphines optically active      314
Phosphoglucose isomerase      1057
Phosphoglycerides      1078
Phospholipid bilayer      1078—1079
Phospholipids      1077—1079
Phosphoric acid, catalyst for alcohol dehydration      203 204 208
Phosphoric acid, esters of      641 1160—1161
Phosphorous acid esters      641
Phosphorus pentoxide      869
Phosphorus tribromide, reaction with alcohols      165—166 180
Phosphorus ylides      see “Ylides”
Phosphorylation      1161 1163
photochemical chlorination of      185
Photochemical initiation of addition of hydrogen bromide to alkenes      244 274
Photochemical initiation of free-radical reactions      175 244 274
Photon      520
Photosynthesis      1032 1069
Phthalhydrazide      930
Phthalic acid      see “1 acid”
Phthalic anhydride      841 843 862
Phthalimide      862
Phthalimide potassium salt of, in Gabriel synthesis      929—931 956
Physical properties      see “Specific compound class”
Physostigmine      963
Phytane      73
Piperidine      132 839 989
Piperidine basicity      922
Piperidine in reductive amination      935
pKb      37—38 (see also “Basicity”)
PKU disease      see “Phenylketonuria”
Planck, Max      520
Planck’s constant      520
Plane of symmetry      286—287
Plane of symmetry cis-1,2-dibromocyclopropane      304
Plane of symmetry in meso-2,3-butanediol      303—304
Plane-polarized light      287—289
Platinum, hydrogenation catalyst      230 231 271—272 428 627—628
Pleated $\beta$ -sheet      1144
Poison ivy, allergens in      1022
Polar covalent bonds      see “Bonds polar
Polar solvents      329 345—348
Polarimeter      287—289
Polarizability      149—150
Poly(vinyl alcohol)      883
Poly(vinyl chloride)      190 269 270
Polyamides      868—869
Polyamines      925
Polychlorinated biphenyls      992
Polycyclic hydrocarbons aliphatic      129—131
Polycyclic hydrocarbons aromatic      434—435 506—507
Polycyclic hydrocarbons aromatic and cancer      435
Polyesters      868
Polyethers      668—671
Polyethylene      267—268 269 270 271 610 612—614 617
Polyisoprene      270 408
Polymerase chain reaction (PCR)      1183—1186
Polymerization cationic      266
Polymerization condensation polymers      868—869
Polymerization coordination      271 312—314 408 610 612—614 617
Polymerization free-radical      267—268
Polymers      266—270
Polymers of dienes      408
Polymers polyamides      868—869
Polymers polyesters      868
Polymers stereoregular      312—314 317—318 610 612—614 617
Polymers vinyl      270
Polynucleotides      1164 (see also “Nucleic acids”)
Polypeptide      1109 (see also “Peptides”; “Proteins”)
Polypropylene      269 270 271 312—314 612
Polysaccharide      1027 1048—1050 1062
polystyrene      269 270 449
Polyurethanes      269
Poreda, Robert J.      437
Porphyrin      1147
Postage stamps      1—5
Potassiophthalimide      see “Phthalimide”
Potassium dichromate      (see also “Chromic acid oxidation”)
Potassium dichromate of alcohols      641 643
Potassium dichromate of aldehydes      736 807
Potassium permanganate oxidation of alcohols      641 807
Potassium permanganate oxidation of aldehydes      807
Potassium permanganate oxidation of alkylbenzenes      443 466 807
Potassium tert-butoxide base in elimination reactions      212 373 606 607
potential energy      85
Potential energy and heat of combustion      85—87 124—125 197
Potential energy and heat of hydrogenation      232
Potential energy diagrams      155—159
Potential energy diagrams addition of hydrogen bromide to 1,3-butadiene      407
Potential energy diagrams and Markovnikov’s rule      239
Potential energy diagrams bimolecular elimination (E2)      215
Potential energy diagrams bimolecular nucleophilic substitution       333
Potential energy diagrams branched versus unbranched alkanes      85
Potential energy diagrams carbocation formation      157
Potential energy diagrams carbocation rearrangement      210
Potential energy diagrams conformations of 1,3-butadiene      401—402
Potential energy diagrams conformations of butane      110
Potential energy diagrams conformations of cyclohexane      120
Potential energy diagrams conformations of ethane      107
Potential energy diagrams electrophilic aromatic substitution      475 491 494
Potential energy diagrams hydration of aldehydes and ketones      717
Potential energy diagrams proton transfer      155
Potential energy diagrams reaction of tert-butyl alcohol with hydrogen chloride      159
Potential energy diagrams unimolecular nucleophilic substitution ()      159 341
Pott, Sir Percivall      435
Prelog, Vladimir      194
Priestley, Joseph      408
Primary carbon      74
principal quantum number      8
Pristane      183
Prochiral      297 299
Progesterone      1100
Prontosil      951
Propagation step      172—173 175 182 243—244 442
Propanal      707
Propane attractive forces in      148

Propane bond dissociation energies in      169 170
Propane chemical shifts carbon      549
Propane chemical shifts proton      527
Propane conformational analysis of      110
Propane dehydrogenation of      189 202
Propane dipole moment of      148 918
Propane in natural gas      63
Propene      187—188
Propene as industrial chemical      269
Propene, addition of sulfuric acid to      246
Propene, allylic chlorination of      396
Propene, bond dissociation energy of      395 439
Propene, bond distances in      191 367 400
Propene, dipole moment of      196
Propene, epoxidation of      297
Propene, heat of hydrogenation of      233 399—400
Propene, hydration rate of      249
Propene, polymerization of      271 312—314 612
Propene, structure      191
Propyl group      74
Propyl radical      169
Propylene      187 (see also “Propene”)
Propylene glycol      634
Propylene oxide      269 (see also “1
Prostacyclins      1082
Prostaglandins      144 791 1080—1084
Prosthetic groups      see “Coenzymes”
Protease inhibitors      1180
Protecting groups acetals as      723—724
Protecting groups for amino acids      1137—1139
Protecting groups for arylamines      940—942
Protein Data Bank      1146
Proteins amino acid analysis of      1130
Proteins biosynthesis of      1178 1179
Proteins glycoproteins      1050
Proteins, hydrolysis of      1130
Proteins, structure of primary      1129—1135 1151
Proteins, structure of quaternary      1148 1150 1152
Proteins, structure of secondary      1143—1145 1152
Proteins, structure of tertiary      1145—1148 1152
Proteins, synthesis of      1135—1143
Protic solvents      346—347
Proton magnetic resonance spectra      see “Nuclear magnetic resonance spectra”
Proton magnetic resonance spectroscopy      see “Nuclear magnetic resonance spectroscopy”
Proton-transfer reactions      see “Acid-base reactions”
Pseudoionone      1107
Purcell, Edward      522
Purines      461 1155—1158 1186
Purines, hydrogen bonding in      1166 1168
Purines, nucleosides of      1158—1160 1187
Purines, nucleotides of      1160—1162 1187
Purines, polynucleotides of      1164—1166 1188
Putrescine      925
Pyramidal inversion      314
Pyranose forms of carbohydrates      1036—1039 1062
Pyrethrins      1105
Pyridine      460
Pyridine, of conjugate acid      36 38
Pyridine, acylation catalyst      639 839 841
Pyridine, basicity of      37—38 922
Pyridine, bonding in      462—463
Pyridine, electrophilic aromatic substitution in      507—508
Pyridinium chlorochromate (PCC)      642 657 710
Pyridinium dichromate (PDC)      642 657 710
Pyridoxal phosphate      728
Pyrimidines      1155—1158 1186
Pyrimidines, hydrogen bonding in      1166 1168
Pyrimidines, nucleosides of      1158—1160 1187
Pyrimidines, nucleotides of      1160—1162 1187
Pyrimidines, polynucleotides of      1164—1166 1188
Pyrocatechol      994 1010
Pyrrole      460
Pyrrole, bonding in      462—463
Pyrrole, electrophilic aromatic substitution in      507—508
Pyrrolidine      132
Pyrrolidine, acetylation of      928
Pyrrolidine, enamine of      730 936
Pyruvic acid, acetyl coenzyme A from      1070
Pyruvic acid, biological reduction of      735
Pyruvic acid, biosynthesis of      647 1069
Pyruvic acid, conversion to L-alanine      1123—1125
Quantized energy states      521
Quantum      520
Quantum numbers      8
Quaternary ammonium salts      916
Quaternary ammonium salts as phase-transfer catalysts      923 926 956
Quaternary ammonium salts hydroxides, Hofmann elimination of      938—940 958
Quaternary ammonium salts, preparation of      928 937—938
Quaternary carbon      74
Quaternary struture of proteins      1148 1150
Quinine      924
Quinoline      460
Quinones      1012—1013 1018
R-S-notational system      290—293 316
Racemic mixture      288 297 316
Racemic mixture, resolution of      310—312 317
Racemization and chair-chair interconversion      305
Racemization in reactions      342—344
Racemization via enol      768—769
Radio waves      520
Random coils      1145
Rare gas      see “Noble gas electron configuration”
Rate constant      163
Rate of reaction      (see also «Substituent effects”)
Rate of reaction and carbocation stability      159—163 341—342
Rate of reaction, effect of catalyst on      231
Rate of reaction, effect of temperature on      108—109 163
Rate-determining step      159 853
Rearrangement allylic      394 406—407 416
Rearrangement Claisen rearrangement      1011—1012 1018
Rearrangement Fries rearrangement      1006
Rearrangement in reactions      344—345
Rearrangement in alcohol dehydration      208—211 222—223
Rearrangement in Baeyer — Villiger oxidation      736—738 847
Rearrangement in electrophilic addition to alkenes      241—242
Rearrangement in Friedel — Crafts alkylation      482—483 511
Rearrangement in reactions of alcohols with hydrogen halides      355 357
Reducing sugar      1053
Reduction      87—89 (see also “Hydrogenation”; “Hydrogenolysis”)
Reduction Birch reduction      438—439 440 464—465
Reduction Clemmensen      486—488 505 713
Reduction metal-ammonia reduction of alkynes      376—377
Reduction of aldehydes and ketones      627—631 634 654 713
Reduction of amides      933 957
Reduction of aryl diazonium salts      948—950 961
Reduction of azides      931 957
Reduction of carbohydrates      1052—1053 1063
Reduction of carbonyl groups, agents for      654 table
Reduction of carboxylic acids      632 654 711 810
Reduction of esters      632 654
Reduction of imines      934—935
Reduction of nitriles      932 957
Reduction of nitro groups      932 957
Reduction Wolff — Kishner      487 713
Reductive amination      934—935 957
Refining of petroleum      79—80
Reforming, in petroleum refining      80
Regioselectivity addition of bromine to 1,3-butadiene      407
Regioselectivity addition of hydrogen halides to 1,3-butadiene      405-407
Regioselectivity allylic halogenation      396—398 416
Regioselectivity and Markovnikov’s rule      238—241 272 273
Regioselectivity and regiospecificity      310
Regioselectivity and Zaitsev’s rule      204—205 221
Regioselectivity dehydration of alcohols      204 221 404 417 446
Regioselectivity dehydrohalogenation of alkyl halides      212—213 218 223 404 446
Regioselectivity electrophilic addition to alkenes      238—241 246 247—252 259—260 272 273
Regioselectivity electrophilic aromatic substitution      488—508
Regioselectivity epoxide ring opening      678—684 694
Regioselectivity Hofmann elimination      938—940 958
Regioselectivity hydration of alkynes      379—381 385

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