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Carey F.A. — Organic Chemistry

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Название: Organic Chemistry

Автор: Carey F.A.

Аннотация:

This respected text is based on the Functional Group approach. The text retains the outstanding problems, pedagogy, depth, and prose of the second edition while providing increased emphasis on molecular modeling, a core concept in organic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 2004

Количество страниц: 1191

Добавлена в каталог: 20.04.2006

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Предметный указатель

Arylamines basicity of      920—922
Arylamines in reductive amination      934
Arylamines nomenclature of      913-916
Arylamines preparation of      932
Arylamines reactions of acylation      940—942
Arylamines reactions of electrophilic aromatic substitution      497 939—942 959
Arylamines reactions of nitrosation      945—950
Arylamines structure and bonding      916—918
Ascaridole      1104
Ascorbic acid (vitamin C)      54 827 1034 1055
Aspartame      1051—1052 1125
Aspirin      54
Aspirin inhibition of prostaglandin biosynthesis by      1083
Aspirin preparation of      1006—1008
Asymmetric center      see “Chkality center”
Atactic polymers      313 610
Atomic number      7
Atomic number and the sequence rule      193
ATP      see “Adenosine triphosphate”
Avery, Oswald      1166
Axial bonds in cyclohexane      117—120 135
Azeotropic mixture      638 722
Azide ion      31 327 328 338 347 349 779 927
Azo coupling      950—951 1004
Azo dyes      951—952
AZT      see “Zidovudine”
Baeyer strain theory      112—113
Baeyer — Villiger oxidation      736—738 745 847
Barbiturates      900—901
Barton, Sir Derek      116
Base pairs      1166—1168
Base peak      569
Bases, used in elimination reactions      211—213 372—373 383 606
Basicity and nucleophilicity      348—350
Basicity constant and       37—38 50 919
Basicity definition Arrhenius      33
Basicity definition Bronsted — Lowry      33
Basicity definition Lewis      45
Basicity of amines      919—923 955—956
Basicity of Grignard reagents      592—594 598
Basicity of heterocyclic amines      922—923
Basicity of leaving groups      330 352 944
Basicity of organolithium compounds      592—594
Becker, Luann      437
Beeswax      71 80 1079
Bender, Myron      852 855
Bending vibrations in infrared spectroscopy      559—560
Benedict’s reagent      1053—1054 1063
Benzal chloride      442
Benzaldehyde      432
Benzaldehyde diethyl acetal of      720
Benzaldehyde preparation of      711
Benzaldehyde reactions of Claisen — Schmidt condensation      775 783
Benzaldehyde reactions of nitration      498 927
Benzaldehyde reactions of reductive amination      935
Benzaldehyde reactions of with methylamine      724—726 927
Benzaldehyde reactions of with vinyllithium      597
Benzenamine      914 (see also “Aniline”)
benzene      58 424—431 463—464
Benzene, of      37
Benzene, acidity of      593 621
Benzene, as industrial chemical      424
Benzene, Birch reduction of      438—439 440
Benzene, derivatives, nomenclature of      432—434
Benzene, electrophilic aromatic substitution in      475 table
Benzene, electrophilic aromatic substitution in bromination      475 480—481 504 505
Benzene, electrophilic aromatic substitution in chlorination      475 480
Benzene, electrophilic aromatic substitution in Friedel — Crafts acylation      475 484—488 504 505
Benzene, electrophilic aromatic substitution in Friedel — Crafts alkylation      475 481—483 510
Benzene, electrophilic aromatic substitution in nitration      475 477—478 505
Benzene, electrophilic aromatic substitution in sulfonation and disulfonation      475 478—480 500
Benzene, electrostatic potential map      423
Benzene, heat of hydrogenation      428—429
Benzene, isolation and discovery      424
Benzene, mass spectrum      568—569
Benzene, molecular orbitals      430—431 452—453
Benzene, nuclear shielding in      529
Benzene, stability of      428—429 463
Benzene, structure and bonding      424—428
Benzene, structure and bonding Kekule formulation      424—427 463
Benzene, structure and bonding orbital hybridization model      430
Benzene, structure and bonding resonance description      427—428
Benzenecarbaldehyde      see “Benzaldehyde”
Benzenecarboxylic acid      see “Benzoic acid”
Benzenediazonium chloride      946 1004
Benzenediols      994 (see also “Hydroquinone”; “Pyrocatechol”; “Resorcinol”)
Benzenesulfonic acid preparation of      475 478—480
Benzenesulfonic acid reactions of      500 1000
Benzimidazole      461
Benzofuran      460
Benzoic acid      424 432 792
Benzoic acid acidity of      803
Benzoic acid by oxidation of toluene      444
Benzoic acid esterification of      638 810—813
Benzonitrile      832
Benzophenone      706
Benzothiophene      460
Benzotrichloride      442
Benzoyl chloride      500 839 840
Benzoyl peroxide      442
Benzo[a]pyrene      435
Benzyl alcohol      711
Benzyl alcohol $\sideset{^1}{}H NMR$ spectrum      545
Benzyl bromide      434
Benzyl cation      438 445 571
Benzyl chloride, nucleophilic substitution in      672 784 808 841
Benzyl chloride, preparation of      442
Benzyl chloride, reaction of with lithium dimethylcuprate      617
Benzyl chloride, reaction of with magnesium      615
Benzyl chloride, reaction of with N-potassiophthalimide      930
Benzyl group      434
Benzyl radical      438 439 441—442
Benzylamine, preparation of      930
Benzylic      439
Benzylic halides, nucleophilic substitution in      444—446
Benzylic halogenation      439 441—443 466
Benzylic hydrogens $\sideset{^1}{}H NMR$ chemical shifts of      529
Benzyloxycarbonyl protecting group in peptide synthesis      1137—1139 1151
Benzyne as intermediate in nucleophilic aromatic substitution      981—985
Benzyne bonding in      982 984
Benzyne Dieis — Alder reactions of      985—986
Benzyne electrostatic potential map      984
Benzyne generation of      983 985—986 987
Berg, Paul      1181
Bergstrom, Sune      1084
Berthelot, Pierre — Eugene Marcellin      363
Berzelius, Jons Jacob      1—2 23
Bicarbonate      45 805
Bicarbonate of      36
Bicyclic ring systems      130—131 136
Bicyclic ring systems as products in Dieis — Alder reactions      411 986
Big-bang theory      6
Bile acids and bile salts      1097—1098 1103
Bimolecular elementary step      154 158 164
Bimolecular elimination      214—217 (see also “E2 mechanism”)
Bimolecular nucleophilic substitution      see “ $S_N2$

mechanism”
Bioenergetics      1162—1164
Biological isoprene unit      see “Isopentenyl pyrophosphate”
Biosynthesis of amino acids, by transamination      1123—1125
Biosynthesis of cholesterol      1093—1095
Biosynthesis of ethylene      189
Biosynthesis of fatty acids      1075—1077
Biosynthesis of organohalogen compounds      767
Biosynthesis of phenols      1001—1002
Biosynthesis of prostaglandins      1081
Biosynthesis of terpenes      1087—1093
Biot, Jean Baptiste      287
Biphenyl      434 497 517
Birch reduction      438—439 440 464—465
Birch, Arthur J.      439

Bisabolene      1104
Bloch, Felix      522
Bloch, Konrad      1093—1094
Boat conformation of cyclohexane      116—117 134
BOC      see “tert-Butoxycarbony”
Boiling points and intermolecular attractive forces      80—83 147—150 708
Boiling points and intramolecular hydrogen bonds      996
Boiling points of alcohols      147—149 179 846
Boiling points of alkanes      63 80—83 846
Boiling points of alkyl halides      147—150 179
Boiling points of amines      918—919
Boiling points of carboxylic acids      794
Boiling points of esters      846
Boiling points of thiols      649
Bond angles acetaldehyde      706
Bond angles acetone      706
Bond angles acetylene      365—366 367
Bond angles ammonia      31
Bond angles and electron-pair repulsions      29
Bond angles aniline      916
Bond angles benzene      427
Bond angles boron trifluoride      31
Bond angles carbon dioxide      31
Bond angles cyclohexane      116
Bond angles cyclopropane      113 114
Bond angles dialkyl ethers      667
Bond angles enol of 2,4-pentanedione      762
Bond angles ethane      64 367
Bond angles ethylene      38—40 90 191 367
Bond angles ethylene oxide      667
Bond angles formaldehyde      31 706
Bond angles formic acid      793
Bond angles methane      31 64—65
Bond angles methanol      146—147 667 994
Bond angles methylamine      916 917
Bond angles phenol      994
Bond angles water      31 667
Bond angles [10]annulene      454
Bond dissociation energy      12 169—172 174
Bond dissociation energy 2-methylpropane      170—171 439
Bond dissociation energy acetylene      367
Bond dissociation energy and halogenation of methane      174
Bond dissociation energy aryl halides      972
Bond dissociation energy benzene      972
Bond dissociation energy ethane      169 170 367 972
Bond dissociation energy ethyl halides      972
Bond dissociation energy ethylene      191 367 972
Bond dissociation energy peroxides      242
Bond dissociation energy propane      169 170
Bond dissociation energy propene      395 439
Bond dissociation energy table      170
Bond dissociation energy vinyl halides      972
Bond distances 1,3-butadiene      400
Bond distances acetic acid      797
Bond distances acetylene      92 365—366 367
Bond distances alkyl halides      146
Bond distances allene      402
Bond distances ammonium acetate      797
Bond distances and strain      111 132
Bond distances benzene      427
Bond distances carbon-chlorine      834
Bond distances cyclobutadiene      451
Bond distances cyclooctatetraene      450
Bond distances dimethyl ether      667
Bond distances enol of 2,4-pentanedione      762
Bond distances ethane      64 367
Bond distances ethyl chloride      972
Bond distances ethylene      90 191 367
Bond distances ethylene oxide      667
Bond distances formic acid      793
Bond distances methane      63
Bond distances methanol      146
Bond distances methylamine      916 917
Bond distances phenol      994
Bond distances propene      191 367
Bond distances propyne      367
Bond distances vinyl halides      972
Bond lengths      see “Bond distances”
Bond-line formulas      21 68 191
Bonding in $\alpha,\beta$ -unsaturated aldehydes and ketones      775-777
Bonding in acetylene      14 92—93 99 365—367 382
Bonding in alcohols      146—147
Bonding in aldehydes and ketones      706—708 742
Bonding in alkenes      89—92 99 190—192 220
Bonding in alkyl halides      146—147
Bonding in alkynes      365—367 382
Bonding in allene      402—404
Bonding in amines      916—918
Bonding in aryl halides      971—972
Bonding in benzene      427—428 430—431 452—453
Bonding in benzyne      982 984
Bonding in carbocations      160—162
Bonding in carboxylic acid derivatives      833—836
Bonding in carboxylic acids      793—794
Bonding in conjugated dienes      400
Bonding in ethane      67 95
Bonding in ethers and epoxides      667
Bonding in ethylene      14 89—91 99 190—191
Bonding in formaldehyde      14 706
Bonding in free radicals      167—168
Bonding in hydrogen      12 58—63
Bonding in methane      13 63—65
Bonding in phenols      994—995
Bonding models, comparison of      63 92—93 99
Bonds $\pi$ in acetylene      92—93 99 365—366
Bonds $\pi$ in ethylene      89—92 99 190—191 220
Bonds $\pi$ in formaldehyde      706
Bonds axial and equatorial      117—120 135
Bonds bent, in cyclopropane      114
Bonds carbon-metal      587—589
Bonds covalent      12—13
Bonds double      14 191 220
Bonds hydrogen bonds      148 150—151 668
Bonds ionic      10—12
Bonds partial      155
Bonds polar $\sigma$ in acetylene      92—93 99 365—366
Bonds polar $\sigma$ in ethylene      89—92 99 190—191 220
Bonds polar $\sigma$ in methane and alkanes      63—65 67
Bonds polar covalent      14—17
Bonds polar dipole moments of      17 table
Bonds polar three-center two-electron      252
Bonds polar triple      14 365—366
Borane      251
Borneol      1090
Borodin, Aleksandr      769
Borohydride ion      19 (see also “Sodium borohydride”)
Boron trifluoride Lewis acid/base complex with diethyl ether      46
Boron trifluoride VSEPR and molecular geometry of      30
Bradykinin      1135
Branched-chain carbohydrates      1043
Brevicomin      748
Broadband decoupling      553
Bromination 3-benzyl-2,6-dimethylphenol      1004
Bromination 4-chlor o-N-me thylaniline      503
Bromination aniline      497 950
Bromination anisole      495
Bromination benzene      475 480—481 504
Bromination benzylic, of alkylbenzenes      442—443 466
Bromination electrophilic aromatic substitution acetophenone      504
Bromination m-fluorophenol      1002
Bromination nitrobenzene      500 973
Bromination of aldehydes      757—759
Bromination of alkanes      177—178 180
Bromination of alkenes electrophilic      254—259 273 307—310 447-448
Bromination of alkenes free-radical      396—398 416
Bromination of alkynes      381
Bromination of benzene      475 480—481
Bromination of carboxylic acids      815—816 823
Bromination of conjugated dienes      407
Bromination of ketones      757—759 782

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