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Carey F.A. — Organic Chemistry
Carey F.A. — Organic Chemistry



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Íàçâàíèå: Organic Chemistry

Àâòîð: Carey F.A.

Àííîòàöèÿ:

This respected text is based on the Functional Group approach. The text retains the outstanding problems, pedagogy, depth, and prose of the second edition while providing increased emphasis on molecular modeling, a core concept in organic chemistry.


ßçûê: en

Ðóáðèêà: Õèìèÿ/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Ãîä èçäàíèÿ: 2004

Êîëè÷åñòâî ñòðàíèö: 1191

Äîáàâëåíà â êàòàëîã: 20.04.2006

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Electrostatic potential map 18-crown-6      665
Electrostatic potential map 18-crown-6 and $K^+$ complex      669
Electrostatic potential map 2,2,2-trifluoroethanol      41
Electrostatic potential map acetate ion      796 797
Electrostatic potential map acetic acid      794 797
Electrostatic potential map acetone enol      755
Electrostatic potential map acetyl chloride      830
Electrostatic potential map acetylene      363 366
Electrostatic potential map amino acids      1114
Electrostatic potential map aniline      917
Electrostatic potential map benzene      423 477
Electrostatic potential map benzyne      984
Electrostatic potential map bromochlorofluoromethane      281
Electrostatic potential map calicene      471
Electrostatic potential map chloromethane      147
Electrostatic potential map dichlorocarbene      607
Electrostatic potential map diethyl ether-water hydrogen bonding      668
Electrostatic potential map diethyl malonate enolate      886
Electrostatic potential map dodecanoic acid      1069
Electrostatic potential map ethane      57
Electrostatic potential map ethanol      41
Electrostatic potential map ethoxide ion      796
Electrostatic potential map ethyl cation      161
Electrostatic potential map ethylene      187 236 366
Electrostatic potential map ethylene glycol      623
Electrostatic potential map ethylenebromonium ion      230
Electrostatic potential map ferrocene      587
Electrostatic potential map formaldehyde      703
Electrostatic potential map formic acid      792
Electrostatic potential map glucose      1026
Electrostatic potential map hydrogen bonding between phenol and water      996
Electrostatic potential map hydrogen bonding in ethanol      148—149 150—151
Electrostatic potential map hydrogen bonding in phenol      996
Electrostatic potential map hydrogen chloride      236
Electrostatic potential map hydrogen fluoride      15 16
Electrostatic potential map lithium hydride      16
Electrostatic potential map methane      28
Electrostatic potential map methanethiol      649
Electrostatic potential map methanol      147 649
Electrostatic potential map methyl cation      160—161
Electrostatic potential map methyl fluoride      589
Electrostatic potential map methylamine      913
Electrostatic potential map methylenetriphenylphosphorane      730
Electrostatic potential map methyllithium      589
Electrostatic potential map nitronium ion      473 477
electrostatic potential map of      230
Electrostatic potential map phenol      993 996
Electrostatic potential map propanal      707
Electrostatic potential map propanoyl cation      484
Electrostatic potential map sodium stearate      799
Electrostatic potential map sulfur trioxide      479
Electrostatic potential map tert-butyl cation      142
Electrostatic potential map tetramethylsilane      519
Electrostatic potential map urea      1
Electrostatic potential map water      996
Elements of unsaturation      574 (see “Index of hydrogen deficiency”)
Elimination reactions      187—229
Elimination reactions $\alpha$      607
Elimination reactions $\beta$      202—219
Elimination reactions $\beta$ anti      216—217 221
Elimination reactions $\beta$ competition with substitution      348—350 355
Elimination reactions $\beta$ dehydration of alcohols      202—211 221 446
Elimination reactions $\beta$ dehydrohalogenation of alkyl halides      211—219 221 446
Elimination reactions dehydrohalogenation of geminal and vicinal dihalides      372—374 383
Elimination reactions dehydrohalogenation of geminal and vicinal dihalides dehydrogenation of alkanes      189 202 446
Elimination reactions dehydrohalogenation of geminal and vicinal dihalides E1 mechanism      206—208 217—219 223
Elimination reactions dehydrohalogenation of geminal and vicinal dihalides E2 mechanism      206—208 214—217 223 348—350
Elimination reactions dehydrohalogenation of geminal and vicinal dihalides Hofmann elimination      938—940 958
Elimination reactions dehydrohalogenation of geminal and vicinal dihalides in preparation of alkenes      189 202—219 221
Elimination reactions dehydrohalogenation of geminal and vicinal dihalides in preparation of alkenylbenzenes      446
Elimination reactions dehydrohalogenation of geminal and vicinal dihalides in preparation of alkynes      372—374 383
Elimination reactions dehydrohalogenation of geminal and vicinal dihalides in preparation of dienes      404 417
Elimination reactions Zaitsev rule      204—205 212 221
Elimination-addition mechanism      981—985 987
Emulsin      1047
Enamines, preparation of      727—728 744
Enantiomeric excess      288
Enantiomers      281—282 315
Enantiomers and Fischer projections      293—295 316 1028
Enantiomers configurational notation D-L      1027--1028
Enantiomers configurational notation R-S      290—293
Enantiomers conformational      305
Enantiomers formation of      297—300
Enantiomers of 2-butanol      289—291
Enantiomers of bromochlorofluoromethane      282 293
Enantiomers optical rotations      288—289
Enantiomers physical properties of      295—297
Enantioselective synthesis      1122
Enantiotopic      297 299 535
End group analysis      1131—1135
Endergonic      1162
Endorphins      1129
Endothermic reaction      11
Endothermic reaction and relation to bond energies      174
Enediols, as intermediates in reactions of carbohydrates      1053 1056—1057 1064
Enediyne antibiotics      368
Energy of activation      108
Energy of activation and carbocation stability      162—163 341—342
Energy of activation and free-radical stability      176
Energy of activation and single-bond rotation      108 401—402
Energy of activation and temperature      108—109
Energy of activation for pyramidal inversion      314
Energy of activation for rotation about double bond      193
Energy of activation in reaction of alcohols with hydrogen halides      155 158 159—160 162—163
Energy, units of      11
Enkephalins      1128—1129
Enol of acetyl coenzyme A      1070
Enolate ions      763—765 782
Enolate ions acylation of      887—893 906
Enolate ions alkylation of      779 781 784 894—900 905 907
Enolate ions and hydrogen-deuterium exchange      768
Enolate ions intermediate in aldol condensation      769—775 783
Enolate ions intermediate in conjugate addition to $\alpha.\beta$-unsaturated carbonyl compounds      777 783—784
Enolate ions intermediate in haloform reaction      765—766 782
Enolate ions of esters      886—912
Enolate ions of esters in Claisen condensation      887—890 906
Enolate ions of esters in Dieckmann reaction      890 906
Enolization      759—762 782
Enolization acid catalyzed      760
Enolization base catalyzed      763
Enols as intermediate $\alpha$ halogenation of aldehydes and ketones      757—761 782
Enols as intermediate in conjugate addition to $\alpha,\beta$ unsaturated aldehydes and ketones      777
Enols content of aldehydes and ketones      759—762 782
Enols content of aldehydes and ketones of 1, 3-diketones      761—762
Entgegen (E)      193—195 220
Enthalpy      84 122—123 174
entropy      122
Entropy and ionization of carboxylic acids      803
Envelope conformation      115 134
Environmentally benign synthesis      644—645
Enzymatic resolution      312
Enzymes aconitase      828
Enzymes alcohol dehydrogenase      645
Enzymes aldolase      1057—1058
Enzymes carbonic anhydrase      46 805
Enzymes carboxypeptidases      1130 1145—1147
Enzymes chymotrypsin      1130
Enzymes cyclooxygenases      1080—1083
Enzymes emulsin      1047
Enzymes fatty acid synthetase      1075
Enzymes fumarase      299—300
Enzymes haloalkane dehalogenase      339
Enzymes kinases      1161
Enzymes lactase      1048
Enzymes lactic acid dehydrogenase      647 735
Enzymes lipase      312
Enzymes maltase      1047
Enzymes monooxygenases      684 738
Enzymes nitric oxide synthase      1149
Enzymes pepsin      1130
Enzymes phosphoglucose isomerase      1057
Enzymes restriction enzymes      1180
Enzymes reverse transcriptase      1179
Enzymes RNA polymerase      1175
Enzymes succinate dehydrogenase      202
Enzymes Taq polymerase      1186
Enzymes triose phosphate isomerase      1058
Enzymes trypsin      1130
Ephedrine      4
Epichlorohydrin      183
Epimers      1056
Epinephrine      687—688 924—925 1126
Epoxidation biological of arenes      1002 1124
Epoxidation biological of squalene      684
Epoxidation of (E)- and (Z)-2-butene      309
Epoxidation of alkenes      260—262 273 676 693
Epoxidation propene      297
Epoxides biosynthesis of      684 1124
Epoxides nomenclature of      260—261 666
Epoxides preparation of      260—262 273 297 676—678 693
Epoxides reactions of      678—684
Epoxides reactions of in biological processes      684—685
Epoxides reactions of with ammonia      680
Epoxides reactions of with Grignard reagents      632—633 654 678 681
Epoxides reactions of with lithium aluminum hydride      681
Epoxides reactions of with nucleophilic reagents      678—684 694
Equatorial bonds in cyclohexane      117—120 135
Equilibrium constants for enolization      760 782
Equilibrium constants for hydration of aldehydes and ketones      713 table
Equilibrium constants relation to $\Delta G^{\circ}$      122
Ergosterol      1097
Ernst, Richard R.      524
Erythro, stereochemical prefix      301—302
Erythromycin      814
Eschenmoser, Albert      1177
Essential amino acids      1110—1112
Essential fatty acids      1080
Essential oils      1084
Esterification      see also “Esters”
Esterification Fischer      638—639 656 810—813 823 847
Esterification of glycerol      1077
Esterification of phenols      1004—1006 1017
Esterification ofamino acids      1123 1138—1139
Esters enolates of      886—912
Esters infrared spectra      561 table 872
Esters lactones      814—815 845
Esters naturally occurring      845—846
Esters nomenclature of      831—833
Esters nuclear magnetic resonance spectra      872
Esters of inorganic acids      640—641 656
Esters physical properties      846
Esters preparation by Baeyer — Villiger oxidation      736—738 745 847
Esters preparation from alcohols with acyl chlorides      639 640 656 839 847 875
Esters preparation from alcohols with acyl chlorides by Fischer esterification      638—639 640 656 810—813 823 847
Esters preparation from alcohols with acyl chlorides with carboxylic acid anhydrides      639 656 843—845 847 875
Esters reactions      848—858
Esters reactions Claisen condensation      887—890 891—892 906
Esters reactions Dieckmann reaction      890—891 906
Esters reactions hydrolysis of, acid catalyzed      849—852 876
Esters reactions hydrolysis of, base promoted      849 852—857 876
Esters reactions reduction of      632 848
Esters reactions with ammonia and amines      849 857—858
Esters reactions with Grignard reagents      601—602 616 627 848
Esters resonance in      835
Esters thioesters      858—859
Esters waxes      1079
Estradiol      1100
Estrogens      1100
ethane      63 64
Ethane $pK_a$ of      37
Ethane acidity of      37 367 369 593
Ethane biochemical oxidation of      285
Ethane bond angles and bond distances in      64 367
Ethane bond dissociation energies in      367
Ethane bonding in      67 95
Ethane chemical shifts carbon      550
Ethane chemical shifts proton      526 530
Ethane chlorination of      175
Ethane conformations of      105—108 133
Ethane dehydrogenation of      189
Ethane electrostatic potential map      57
Ethane in natural gas      63
Ethanoic acid      see “Acetic acid”
Ethanol      145 148 624
Ethanol $pK_a$ of      37 40
Ethanol acidity of      37 795—796
Ethanol and benzaldehyde, acetal from      720
Ethanol biological oxidation of      645—647
Ethanol by fermentation      624
Ethanol conversion to diethyl ether      637
Ethanol dehydration of      203
Ethanol dipole moment of      148 918
Ethanol hydrogen bonding in      148—149
Ethanol industrial preparation of      624
Ethanol physical properties of      148—151 624
Ethanol reduction of aryl diazonium salts by      948—949 961
Ethers      665—702 1008—1012
Ethers $\sideset{^1}{}H$ chemical shifts      690 695
Ethers as anesthetics      695 698
Ethers crown ethers      668—671 692
Ethers infrared spectra      688 690
Ethers mass spectra      691
Ethers nomenclature of      665—666
Ethers physical properties of      668
Ethers polyethers      668—671
Ethers preparation of from alcohols      635—638 656 671—672 693
Ethers preparation of from carbohydrates      1059 1064
Ethers preparation of Williamson ether synthesis      672—673 693 1008 1018
Ethers reactions of Claisen rearrangement of allyl aryl ethers      1011—1012 1018
Ethers reactions of cleavage by hydrogen halides      674—676 692 1010—1011 1018
Ethers reactions of oxidation of      674
Ethers structure and bonding in      667
Ethoxide ion electrostatic potential map      796
Ethoxide ion Ethene      187 (see also “Ethylene”)
Ethyl 3-oxobutanoate      see “Ethyl acetoacetate”
Ethyl acetate $pK_a$ of      36
Ethyl acetate $\sideset{^1}{}H NMR$ spectrum      872 873
Ethyl acetate Claisen condensation of      887—890
Ethyl acetate enolate addition to $\alpha,\beta$-unsaturated ketones      902
Ethyl acetate enolate of      888—889 904
Ethyl acetate preparation of      887—890
Ethyl acetate reaction with pentylmagnesium bromide      627
Ethyl acetate saponification      854
Ethyl acetoacetate in acetoacetic ester synthesis      894—896 907
Ethyl alcohol      see “Ethanol”
Ethyl benzoate acylation of ketone enolates by      892—893
Ethyl benzoate hydrolysis of      852
Ethyl benzoate reaction with phenylmagnesium bromide      616
Ethyl benzoate reduction of      632 848
Ethyl bromide, $\sideset{^1}{}H NMR$spectrum      538—539
Ethyl butanoate, Claisen condensation of      906
Ethyl chloride      51 175
Ethyl cinnamate      845
Ethyl cyanoacetate      857
Ethyl fluoroacetate reaction with ammonia and amines      849 857
Ethyl group      73
Ethyl group spin-spin splitting in      538—539
Ethyl p-toluenesulfonate      351
Ethyl pentanoate, Claisen condensation of      893
Ethyl propanoate Claisen condensation of      890
Ethyl propanoate saponification      854
Ethyl thioacetate      833
Ethylamine, basicity of      920
Ethylbenzene $\sideset{^1}{}H NMR$chemical shifts      529
Ethylbenzene benzylic bromination of      443
Ethylbenzene dehydrogenation of      446 483
ethylene      58 188 189
Ethylene $pK_a$ of      37
Ethylene $\pi$ molecular orbitals of      412—413
Ethylene $\sideset{^1}{}H$ chemical shift      529
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