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Carey F.A. — Organic Chemistry

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Название: Organic Chemistry

Автор: Carey F.A.

Аннотация:

This respected text is based on the Functional Group approach. The text retains the outstanding problems, pedagogy, depth, and prose of the second edition while providing increased emphasis on molecular modeling, a core concept in organic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 2004

Количество страниц: 1191

Добавлена в каталог: 20.04.2006

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Acetyl chloride electrostatic potential map      830
Acetyl chloride reactions of with arylamines      940
Acetyl chloride reactions of with phenol      1004
Acetyl chloride reactions of with tert-butyl alcohol      656
Acetyl chloride UV absorption      873
Acetyl coenzyme A      1070—1071
Acetyl coenzyme A in fatty acid biosynthesis      1075—1077
Acetyl coenzyme A in terpene biosynthesis      1091
acetylene      58
Acetylene of      37
Acetylene acidity of      37 360 368—370 593
Acetylene alkylation of      360 370—372 383
Acetylene bonding in      14 92—94 99 365—367
Acetylene chemical shifts carbon      550
Acetylene chemical shifts proton      530
Acetylene conversion to cyclooctatetraene      449
Acetylene electrostatic potential map      363 366
Acetylene Grignard reagent of      594
Acetylene hydration of      381
Acetylene preparation of      363—364
Acetylene structure of      92 365—366
Acetylide ion      360 369—370 372
Achiral molecules      282 315
Achiral molecules meso forms      303—305
Achiral molecules symmetry elements in      286—287
Acid anhydrides      see “Carboxylic acid anhydrides”
Acid catalysis of acetal formation and hydrolysis      720—723
Acid catalysis of amide hydrolysis      863—865 877
Acid catalysis of dehydration of alcohols      203 206—211 221 446 636
Acid catalysis of epoxide ring opening      678—679 681—683 694
Acid catalysis of ester hydrolysis      849—852 876
Acid catalysis of esterification      638 656 810—813 823
Acid catalysis of ether formation      635 637—638 656 671—672 693
Acid catalysis of glycoside formation      1045
Acid catalysis of hydration of alkenes      247—250 272
Acid catalysis of hydration of alkynes      379—381 385
Acid catalysis of nitrile hydrolysis      870—871 877
Acid catalysis of nucleophilic acyl substitution      844—845 1005
Acid catalysis of nucleophilic addition to aldehydes and ketones      716—718 742
Acid dissociation constants, and       33 35 36—37 49 360 367 369—370 593 764 801—805 919—923 998
Acid-base properties of amino acids      1117—1121
Acid-base reactions      34 43—45 50 368—370 592—594 649 763—765 919—920
Acidity of $\beta$ -diketones      764
Acidity of $\beta$ -keto esters      887—889 894 905
Acidity of 1,3,5-cycloheptatriene      459
Acidity of 1,3-cyclopentadiene      37 458
Acidity of acetylene and alkynes      360 367 368—370 382 593
Acidity of alcohols      37 40—41
Acidity of aldehydes      764
Acidity of alkanes      37 368—369 593
Acidity of ammonia      37 369—370 903
Acidity of ammonium ions      36 38 919—923
Acidity of benzene      37 593
Acidity of carbonic acid      36 804—805
Acidity of carboxylic acids      795—805 821—822
Acidity of carboxylic acids substituent effects on      41 801—804
Acidity of dicarboxylic acids      804
Acidity of diethyl malonate      35 897
Acidity of diisopropylamine      37 903
Acidity of esters      903
Acidity of ethane      37 367 593
Acidity of ethanol      37 593 795—796
Acidity of ethyl acetoacetate      36 894
Acidity of ethylene      37 367 593
Acidity of hydrocarbons      367—370 593
Acidity of hydrogen fluoride      36 369
Acidity of ketones      764
Acidity of methane      37 368—369 593
Acidity of phenols      996—999 1016
Acidity of representative compounds      36—37 table 593
Acidity of substituted benzoic acids      803—804
Acidity of thiols      649 778
Acidity of water      36 369 593
Acidity quantitative relationships      798
Acidity structural effects on      38—43
Acids and bases definitions Arrhenius      32—33 49
Acids and bases definitions Bronsted — Lowry      33—37 49
Acids and bases definitions Lewis      45—47 50
Aconitic acid      324 828
Acrolein      409 776 779 784
Acrylic acid      792 803
Acrylonitrile      14 270 870
Activated complex      108 (see also “Transition state”)
Activation energy      108 (see also “Energy of activation”)
Active ester      1139
Acyclovir      1158
Acyl carrier protein      1075—1077
Acyl cations      484 842
Acyl chlorides carbon-chlorine bond distance      834
Acyl chlorides enolization      816
Acyl chlorides infrared absorption frequency      561 872
Acyl chlorides nomenclature of      831
Acyl chlorides preparation of      485 810 838
Acyl chlorides reactions of      838—841 874—877
Acyl chlorides reactions of Friedel — Crafts acylation with      484—488 510 838 1004
Acyl chlorides reactions of with alcohols      639 640 656 839 847
Acyl chlorides reactions of with ammonia and amines      839 860 875 936 940
Acyl chlorides reactions of with carboxylic acids      839
Acyl chlorides reactions of with phenols      1004—1005
Acyl chlorides reactions of with water      839 840
Acyl chlorides resonance in      834
Acyl group      703 831
Acyl halides      831 (see also “Acyl chlorides”)
Acyl transfer reactions      see “Nucleophilic acyl substitution”
Acylation      see “Friedel — Crafts acylation”; “Nucleophilic acyl substitution”
Addition polymers      270
Addition reactions      (see also “Aldehydes”; “Alkenes”; “Alkynes”; “Diene”; “Ketones”)
Addition reactions 1,2 addition versus 1,4 addition      405—407 417—418 777—779
Addition reactions and Markovnikov’s rule alkenes      236—241 274
Addition reactions and Markovnikov’s rule alkynes      377—378 380 385
Addition reactions anti addition      234 256 258 259—260 273 308 376—377 381
Addition reactions Dieis — Alder cycloaddition      409—415 985—986
Addition reactions electrophilic to alkenes      235—242 245—265 266—267 271—273 307—310
Addition reactions electrophilic to alkenylbenzenes      447—448 466
Addition reactions electrophilic to alkynes      377—381 385
Addition reactions electrophilic to conjugated dienes      405—407 417—418
Addition reactions free-radical, to alkenes      242—245 267—268 274
Addition reactions hydrogenation of alkenes      230—235 271 272 309
Addition reactions hydrogenation of alkenylbenzenes      447
Addition reactions hydrogenation of alkynes      374—375 384
Addition reactions hydrogenation of dienes      399—400
Addition reactions nucleophilic to $\alpha,\beta$ -unsaturated aldehydes and ketones      777—779 783
Addition reactions nucleophilic to aldehydes and ketones      712—754
Addition reactions syn addition      234 252 262 273 309 310 375
Addition-elimination mechanism of nucleophilic aromatic substitution      977—981 987
Adenine      461 1156 1157 1158
Adenosine      1044 1159
Adenosine 3’-5’-cyclic monophosphate (cyclic AMP)      1161
Adenosine 5’-diphosphate      1161
Adenosine 5’-monophosphate      1160
Adenosine triphosphate      1161 1187
Adenosine triphosphate as an energy source      1162—1164
Adenosine triphosphate reaction with methionine      687
Adipic acid polyamides from      895
ADP      see “Adenosine diphosphate”
Adrenaline      295 297 688
Agent Orange      1009—1010
AIDS      1179—1180 1186 1189
Alanine      1111 1113 1119
Alanine biosynthesis of      1124 1125
Alanine electrophoresis of      1120—1121
Alanine electrostatic potential map      1114
Alanine ethyl ester      1123
Alanine synthesis      1121
Alanyglycine      1126—1127
Alcohols acidity of      37 40—41 795—796 997
Alcohols as Bronsted bases      153—154
Alcohols biological oxidation of      645—647
Alcohols bonding      146—147
Alcohols classification of      146 179

Alcohols hydrogen bonding in      148 150 179 346—347
Alcohols hydrogen-deuterium exchange in      186 544—545
Alcohols in Friedel — Crafts reactions      1003
Alcohols infrared spectra      561 table
Alcohols inorganic esters of      640—641 656
Alcohols mass spectra      652—653
Alcohols naturally occurring      625
Alcohols nomenclature of      145 178 188
Alcohols nuclear magnetic resonance spectra carbon      652
Alcohols nuclear magnetic resonance spectra proton      544—545 651—652 653
Alcohols physical properties      147—151 179
Alcohols preparation of by hydration of alkenes      247—250 272 626
Alcohols preparation of by hydroboration-oxidation      250—254 273 626
Alcohols preparation of by hydrolysis of alkyl halides      626
Alcohols preparation of by reduction of carbonyl compounds      625 653—654 848
Alcohols preparation of from epoxides      632—633 654 678 681
Alcohols preparation of from Grignard reagents      594—602 616 617 626 627 654 848
Alcohols preparation of from organolithium reagents      597 616 617 627 654
Alcohols preparation of via alkyl hydrogen sulfates      245—247
Alcohols reactions of      636 table 656
Alcohols reactions of conversion to ethers      635—638 656 671—672 693
Alcohols reactions of dehydration      202 206—211 221 404 446 636
Alcohols reactions of esterification      638—641 656 810—813 823 847
Alcohols reactions of oxidation      641—647 657
Alcohols reactions of with acyl chlorides      639—640 656 839
Alcohols reactions of with aldehydes and ketones      720—724 744
Alcohols reactions of with carboxylic acid anhydrides      639 656 843—845
Alcohols reactions of with hydrogen halides      151—165 180 354—355 357 636
Alcohols reactions of with inorganic acids      640—641 656
Alcohols reactions of with p-toluenesulfonyl chloride      351 357 636
Alcohols reactions of with phosphorus tribromide      165—166 180 636
Alcohols reactions of with thioesters      856—857
Alcohols reactions of with thionyl chloride      165 180 636
Alcohols solubility in water      150—151
Aldaric acids      1054
Aldehydes acidity of      764
Aldehydes aldol condensation      769—775 783
Aldehydes classification of carbons in      756
Aldehydes enolization of      759—761 782
Aldehydes in reductive amination      934—935 957
Aldehydes in Strecker synthesis of amino acids      1121
Aldehydes infrared spectra      561 563 738 739
Aldehydes mass spectra      741
Aldehydes naturally occurring      709
Aldehydes nomenclature of      703—705 741
Aldehydes nuclear magnetic resonance spectra      528 549 738—740
Aldehydes nucleophilic addition to      712—735
Aldehydes physical properties      707
Aldehydes preparation of hydroformylation of alkenes      711—712 787
Aldehydes preparation of oxidation of primary alcohols      642 657 710 711
Aldehydes preparation of ozonolysis of alkenes      263—264 710
Aldehydes reactions of acetal formation      720—724 744
Aldehydes reactions of cyanohydrin formation      717—720 743
Aldehydes reactions of halogenation      757—759 782
Aldehydes reactions of hydration      712—717 743
Aldehydes reactions of hydrogenation      627—628 713
Aldehydes reactions of oxidation      736 745
Aldehydes reactions of reduction      713
Aldehydes reactions of with amines      724—730 744 936
Aldehydes reactions of with derivatives of ammonia      727
Aldehydes reactions of with Grignard reagents      596 616 617 713 777
Aldehydes reactions of with organolithium reagents      597 616 617 713
Aldehydes reactions of with Wittig reagents      730—734 744
Aldehydes structure and bonding      706—708 742
Alder, Kurt      409
Alditols      1052
Aldohexose      1030—1032
Aldol condensation      769—775 783
Aldol condensation intramolecular      773 779 783
Aldol condensation mixed      774—775 783
Aldol condensation retro      1057—1058
Aldolase      1057—1058
Aldonic acids      1054
Aldopentose      1030—1032
Aldoses      1027 1061
Aldoses Fischer projection formulas of      1031
Aldotetrose      1029—1030
Alicyclic hydrocarbons      77 (see also “Cycloalkanes”)
Aliphatic hydrocarbon, definition of      57 424
Alizarin      1012
Alkadienes      398—415 (see also “Dienes”)
Alkadienes preparation of      404
Alkadienes relative stabilities      399—400
Alkadienes ultraviolet-visible spectra      565—567
Alkaloids      924
Alkanes      57—103
Alkanes acidity of      368—369 593
Alkanes chiral      284
Alkanes conformations of      104—112 132—134
Alkanes infrared spectra      559—560
Alkanes IUPAC names of unbranched      71 table
Alkanes mass spectra      570—571
Alkanes nomenclature of      70—77
Alkanes physical properties      80—83
Alkanes preparation of hydrogenation of alkenes      230—231 265
Alkanes preparation of hydrogenation of alkynes      374
Alkanes preparation of using organocopper reagents      602—604 617
Alkanes reactions of combustion      83—87
Alkanes reactions of dehydrogenation      189 202
Alkanes reactions of halogenation      166 172—178 180 181—182
Alkanes relative stability of isomers      85—86
Alkatetraene      399
Alkatriene      399
Alkenes      57—58 187—280
Alkenes acidity of      369
Alkenes as dienophiles      409
Alkenes bonding in      89—92 99 190—192 220
Alkenes cycloalkenes      190 200—201 221
Alkenes E-Z notation      193—195 220
Alkenes electrophilic addition to      235—242 245—265 266—267 271 272 297 307—310
Alkenes free-radical addition to      242—245 267—268 274
Alkenes heats of combustion      197
Alkenes heats of hydrogenation      231—234
Alkenes in Friedel — Crafts reactions      483
Alkenes infrared spectra      561 table 560—561
Alkenes isomers      192—201 220
Alkenes naturally occurring      187 189
Alkenes nomenclature of      187—190 220
Alkenes physical properties of      196—197
Alkenes preparation of      189 202—219 221
Alkenes preparation of dehydration of alcohols      202—211 221 446 636
Alkenes preparation of dehydrogenation of alkanes      189 202 446
Alkenes preparation of dehydrohalogenation of alkyl halides      211—219 221 446
Alkenes preparation of from alkynes      374—377 384
Alkenes preparation of Hofmann elimination      938—940 958
Alkenes preparation of Wittig reaction      730—734 744
Alkenes reactions of      230—280
Alkenes reactions of allylic halogenation      396—398 416
Alkenes reactions of Dieis — Alder reaction      409—415
Alkenes reactions of epoxidation      260—262 273 297 676 693
Alkenes reactions of halogen addition      254—259 273 447
Alkenes reactions of halohydrin formation      259—260 273 676—677
Alkenes reactions of hydration      247—250 272
Alkenes reactions of hydroboration-oxidation      250—254 273
Alkenes reactions of hydroformylation      711—712
Alkenes reactions of hydrogenation      230—235 271 272 309 447
Alkenes reactions of hydroxylation      635 683—684
Alkenes reactions of ozonolysis      262—264 274 710
Alkenes reactions of polymerization      266—270 274 312—314 449 610 612—614 617
Alkenes reactions of with dibromocarbene      607—608
Alkenes reactions of with hydrogen halides      235—245 271—272 297—298 447—448
Alkenes reactions of with iodomethylzinc iodide      604—605 615
Alkenes reactions of with sulfuric acid      245—247 272
Alkenes relative stabilities of      197—201 221
Alkenes stereoisomerism in      192—195 220 307
Alkenyl cations      377—378
Alkenyl groups      190
Alkenyl halides      327
Alkenyl radical      376—377
Alkenylbenzenes      447—448 466

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