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Carey F.A. — Organic Chemistry

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Название: Organic Chemistry

Автор: Carey F.A.

Аннотация:

This respected text is based on the Functional Group approach. The text retains the outstanding problems, pedagogy, depth, and prose of the second edition while providing increased emphasis on molecular modeling, a core concept in organic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 2004

Количество страниц: 1191

Добавлена в каталог: 20.04.2006

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Homologous series      68 84
Homolytic bond cleavage      169
Htickel, Erich      451
Htickel’s rule      451—460 462—463 467
Huffman, Donald      436
Hughes, Edward D.      330 339 361
Hund’s rule      9
Hybrid orbitals      see “Orbital hybridization”
Hydration of aldehydes and ketones, equilibria in      712—717 743
Hydration of alkenes acid-catalyzed      247—250 272 626
Hydration of alkenes enzyme-catalyzed, of fumaric acid      299—300
Hydration of alkenes hydroboration-oxidation      250—254 273 626
Hydration of alkenes of alkynes      379—381 385 710
Hydrazine cleavage of peptides      1154
Hydrazine in Wolff — Kishner reduction      487 713
Hydrazine reaction with aldehydes and ketones      727
Hydrazine reaction with N-alkylphthalimides      930
Hydrazones      727
Hydride shift alcohol dehydration      210—211 222
Hydride shift cholesterol biosynthesis      1094—1095
Hydride shift electrophilic addition to alkenes      241—242
Hydride shift in reactions      345
Hydride shift in reaction of alcohols with hydrogen halides      355
Hydroboration-oxidation      250—254 273 626
Hydroformylation      711—712 787
Hydrogen      see also “Hydrogenation”; “Nuclear magnetic resonance spectroscopy”
Hydrogen bonding      148
Hydrogen bonding and solvent effects on rate of nucleophilic substitution      346—347
Hydrogen bonding between ethers and water      668
Hydrogen bonding in      12 60—63
Hydrogen bonding in alcohols      148—151 179
Hydrogen bonding in amines      918—919
Hydrogen bonding in carboxylic acids      794
Hydrogen bonding in DNA      1168—1169
Hydrogen bonding in phenols      995—996
Hydrogen bonding intramolecular in enol of 2,4-pentanedione      762
Hydrogen bonding intramolecular in o-nitrophenol      996
Hydrogen bonding intramolecular in peroxyacetic acid      262
Hydrogen bonding intramolecular in salicylate ion      1007
Hydrogen bonding peptides and proteins      1143—1145
Hydrogen bromide of      36 39 43
Hydrogen bromide acidity of      43
Hydrogen bromide electrophilic addition to alkenes      235—238
Hydrogen bromide electrophilic addition to alkynes      377 385
Hydrogen bromide electrophilic addition to conjugated dienes      405—407
Hydrogen bromide electrophilic addition to styrene      466
Hydrogen bromide free-radical addition to alkenes      242—245 274 448
Hydrogen bromide free-radical addition to alkynes      379
Hydrogen bromide reaction of with alcohols      151—152 164—165 180 354—355 636
Hydrogen bromide reaction of with epoxides      681 683
Hydrogen bromide reaction of with ethers      674—676 692 1010
Hydrogen carbonate ion      see “Bicarbonate”
Hydrogen chloride of      36 39
Hydrogen chloride addition of to alkenes      235 238 241—242 271—272
Hydrogen chloride electrostatic potential map of      236
Hydrogen chloride reaction with alcohols      151—153 153—160 180 355
Hydrogen chloride to alkynes      379
Hydrogen chloride to conjugated dienes      405 417
Hydrogen cyanide of      33 36
Hydrogen cyanide acidity of      33 36 349 777
Hydrogen cyanide addition to $\alpha,\beta$ -unsaturated aldehydes and ketones      777
Hydrogen cyanide addition to aldehydes and ketones      717—720 743 867
Hydrogen cyanide geometry of      31
Hydrogen cyanide in Kiliani — Fischer synthesis      1055—1056 1063
Hydrogen cyanide Lewis structure      14
Hydrogen fluoride      13 15
Hydrogen fluoride of      36 39
Hydrogen fluoride addition to alkynes      378
Hydrogen formation of      6
Hydrogen halides      see also “Hydrogen bromide”; “Hydrogen chloride”; “Hydrogen fluoride”; “Hydrogen iodide”
Hydrogen halides acidity      39
Hydrogen halides addition of to alkenes      235—245 271—272
Hydrogen halides addition of to alkenylbenzenes      447—448 465
Hydrogen halides addition of to alkynes      377—379 385
Hydrogen halides addition of to conjugated dienes      405—407 417—418
Hydrogen halides reactions of with alcohols      151—153 163—165 180 354—355 357 636
Hydrogen halides with epoxides      681 683
Hydrogen halides with ethers      674—676 692 1010—1011 1018
Hydrogen iodide of      36 39
Hydrogen iodide cleavage of ethers      674 1018
Hydrogen iodide reaction with alcohols      151
Hydrogen nuclear spin states      522—523
Hydrogen peroxide conformations of      104
Hydrogen peroxide oxidation of dialkyl sulfides by      686
Hydrogen peroxide oxidation of organoboranes by      250—251 254—255
Hydrogen sulfide acidity of      349
Hydrogen sulfide anion of as a nucleophile      327 328 338 349
Hydrogen sulfide anion of basicity of      349
Hydrogen sulfide boiling point      649
Hydrogen-deuterium exchange in alcohols      186 544—545
Hydrogen-deuterium exchange in carboxylic acids      819
Hydrogen-deuterium exchange in cyclopentanone      768
Hydrogenation      see also “Heat of hydrogenation”; “Hydrogenolysis”
Hydrogenation catalysts for      230—231 374—375
Hydrogenation mechanism      232 1074
Hydrogenation of aldehydes and ketones      627—628 654
Hydrogenation of alkadienes      399—400
Hydrogenation of alkenes      230—235 271
Hydrogenation of alkenylbenzenes      447—448 466
Hydrogenation of alkyl azides      931
Hydrogenation of alkynes      374—375 384
Hydrogenation of benzene      428—429
Hydrogenation of carbohydrates      1052 1063
Hydrogenation of carbon monoxide      624
Hydrogenation of esters      632
Hydrogenation of imines      934—935
Hydrogenation of ketones      628 654
Hydrogenation of nitriles      932
Hydrogenation of nitroarenes      932
Hydrogenation of vege tableoils      1072 1074
Hydrogenation stereochemistry of      234—235 309—310
Hydrogenolysis, of benzyl esters      1137—1139
Hydrolysis of 2-bromooctane, stereochemistry of      331—333 343-344
Hydrolysis of a-bromo carboxylic acids      816
Hydrolysis of acetals      722—723 724
Hydrolysis of acyl chlorides      839 840
Hydrolysis of alkyl halides      336—337 339—342 626
Hydrolysis of alkyl hydrogen sulfates      246
Hydrolysis of amides      862—867 941—942
Hydrolysis of carboxylic acid anhydrides      843
Hydrolysis of carboxylic acid derivatives, relative rate      833 table
Hydrolysis of cyanohydrins      809
Hydrolysis of epoxides      681—682 684
Hydrolysis of esters      849—856 876
Hydrolysis of nitriles      808—809 822 870—871
Hydrolysis of peptides and proteins      1130
Hydrolysis of tert-butyl bromide      339—341
Hydronium ion      34 (see also “Oxonium ion”)
Hydronium ion of      36 43
Hydrophilic      800
Hydrophobic effect      83
Hydroquinone      994 1012
Hydroxide ion as base      45 46 212 369 649 763 797
Hydroxide ion as nucleophile      329 330—334 337—338 716 766 852—856 866
Hydroxylamine      727
Hydroxylation of alkenes anti      683—684
Hydroxylation of alkenes syn      635
Hyperconjugation      161—162
Hypophosphorous acid      948—949 961
Hz (symbol for Hertz), unit of frequency      520
Ibuprofen      183 296 824 1083
Icosane      71
Icosanoic acid      1073
Icosanoids      1080—1084
Ignarro, L. J.      1149
Iijima, Sumio      437
Imidazole      461 922—923
Imides      862
Imines as intermediates in reductive amination      934—935
Imines in addition of Grignard reagents to nitriles      871

Imines in biological chemistry      728—729 1125
Imines preparation of      724—727 744
Imines stereoisomers      748
Iminium ion      935
Imino acid      870—871
Indene      447—448
Index of hydrogen deficiency      574
Indigo      4 113 914
Indole      460—461
Induced dipole-induced dipole forces      81—83 147—150
Inductive effect      41 50 161
Inductive effect and acidity of alcohols      40—41
Inductive effect and acidity of carboxylic acids      41 795—796 801—804
Inductive effect of alkyl groups in aldehydes and ketones      708 713—715
Inductive effect of alkyl groups in alkenes      196—199 221
Inductive effect of alkyl groups in alkynes      374
Inductive effect of alkyl groups in carbocations      161 181 341—342
Inductive effect of alkyl groups of trifluoromethyl group      41 492 715
Industrial preparation 1,2-epoxypropane      678
Industrial preparation 1,3-butadiene      404
Industrial preparation acetaldehyde      644 711
Industrial preparation acetic acid      806
Industrial preparation acetic anhydride      841
Industrial preparation acetone      711 1000 1023
Industrial preparation acetylene      364
Industrial preparation aldehydes      711—712
Industrial preparation benzene      424
Industrial preparation chloromethanes      167
Industrial preparation ethylene      189 202
Industrial preparation ethylene oxide      269 644
Industrial preparation formaldehyde      624 711
Industrial preparation isopropyl alcohol      246
Industrial preparation methanol      623—624
Industrial preparation phenol      975 1000 1023
Industrial preparation propene      188 202
Industrial preparation styrene      446 483
Industrial preparation terephthalic acid      806
Industrial preparation urea      861
Infrared spectra      see also “Infrared spectroscopy”
Infrared spectra 1-hexene      560—561
Infrared spectra 2-hexanol      560 563
Infrared spectra 2-hexanone      563—564
Infrared spectra 4-phenylbutanoic acid      820
Infrared spectra butanal      739
Infrared spectra butylamine      952
Infrared spectra cyclohexanol      651 652
Infrared spectra diethylamine      952
Infrared spectra dipropyl ether      688
Infrared spectra hexane      560
Infrared spectra p-cresol      1014
Infrared spectra tert-butylbenzene      560—561
Infrared spectroscopy      559—564 577
Infrared spectroscopy absorption frequencies table      561
Infrared spectroscopy alcohols      560 561 651
Infrared spectroscopy aldehydes and ketones      561 563 738 739
Infrared spectroscopy amines      951—952
Infrared spectroscopy carboxylic acids and derivatives      561 819—820 872
Infrared spectroscopy ethers and epoxides      688 690
Infrared spectroscopy nitriles      561 872
Infrared spectroscopy phenols      1014
Ingold, Sir Christopher      3
Ingold, Sir Christopher and stereochemical notation      194 290—293
Ingold, Sir Christopher and studies of reaction mechanisms electrophilic aromatic substitution      477
Ingold, Sir Christopher and studies of reaction mechanisms elimination      214—216
Ingold, Sir Christopher and studies of reaction mechanisms nucleophilic substitution      160 164 330 339
Initiation step      167 172 243—244 268
Initiators of free-radical reactions      242—244 268 442-443
Insulin      1129 1131—1133 1141
Integration and NMR peak area measurement      532—533
International Union of Pure and Applied Chemistry      see ”IUPAC”
Inversion of configuration complete, in reactions      331—333 356
Inversion of configuration partial, reactions      342—344 356
Iodination      166 256 480
iodobenzene      604 973
Iodomethane      see “Methyl iodide”
Iodomethylzinc iodide      604—606 615 616
Ion-exchange chromatography      1130
Ionic bonds      10—12 47
Ionization constant      see “Acid dissociation constants”
Ionization energy      11
Ionization potential      see “Ionization energy”
Ionophore      670 1078—1079
Iron(III) salts as catalysts in halogenation of arenes      475 480—481
Iron, reduction of nitroarenes by      932
Isoamyl acetate, in bananas      183 845
Isobutane      67 (see also “2-Methylpropane”)
Isobutene      see “2-Methylpropene”
Isobutyl chloride      177 482
Isobutyl group      74 (see also “2-Methylpropyl group”)
Isobutylene      187 (see also “2-Methylpropene”
Isocitric acid      828
Isoelectric point      1118—1120
Isoelectronic      50
Isoionic point      see “Isoelectric point”
Isolated diene      398 416
Isomerism      see “Isomers”
Isomers      2 48
Isomers, alkanes      67 69—70 71—73 96
Isomers, alkenes      192—194 220
Isomers, classification      315 table
Isomers, constitutional      23 48 67
Isomers, keto-enol      379 759—761
Isomers, number of      69
Isomers, stereoisomers      see “Stereoisomers”
Isopentane      69—70 (see also “2-Methylbutane”
Isopentenyl pyrophophate      1087—1093 1102
Isoprene      408 1084
Isoprene rule      1084—1086
Isoprenoid compounds      see “Terpenes”
Isopropenyl group      190
Isopropyl alcohol      20 145
Isopropyl alcohol of      37 40
Isopropyl alcohol industrial preparation of      246
Isopropyl alcohol properties of      624
Isopropyl chloride, $\sideset{^1}{}H NMR$ spectrum      540
Isopropyl group      74 (see also “1-Methylethyl group”)
Isopropyl group size of      123 334—335
Isopropyl group spin-spin splitting in      540
Isopropyl hydrogen sulfate      245—246
Isopropyl radical      169 170
Isopropylbenzene      see also “Cumene”
Isopropylbenzene conversion to phenol      1000 1023
Isopropylbenzene nitration      932
Isopropylbenzene preparation of      931
Isopropylcyclohexane      123
Isoquinoline      460
Isotactic polymers      313—314 612
Isotopes      see also “Carbon”; “Hydrogen-deuterium exchange”
Isotopes H-D exchange in alcohols      186 544—545
Isotopes H-D exchange in carboxylic acids      819
Isotopes H-D exchange in cyclopentanone      768
Isotopes in biosynthetic studies      1092—1093
Isotopes in study of reaction mechanisms bromine addition to alkenes      256
Isotopes in study of reaction mechanisms Claisen rearrangement      1011
Isotopes in study of reaction mechanisms ester hydrolysis      852 854—855
Isotopes in study of reaction mechanisms esterification      810
Isotopes in study of reaction mechanisms hydrolysis of chlorobenzene      985
Isotopes in study of reaction mechanisms nucleophilic aliphatic substitution      361
Isotopes in study of reaction mechanisms nucleophilic aromatic substitution      982 985
Isotopic clusters in mass spectrometry      569—570
IUPAC (International Union of Pure and Applied Chemistry)      78 (see also “Nomenclature” “IUPAC”)
J (symbol for coupling constant)      538
Japanese National Institute of Advanced Industrial Science and Technology      555
Joule (SI unit of energy)      11
K (symbol for equilibrium constant) relation to $\Delta G^{\circ}$       122—123
Karplus, Martin      580
Kazan, University of      3
Keku16, August      3 424—427
Kendrew, John C.      1146
Ketals      see “Acetals”

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