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| Àâòîðèçàöèÿ |
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| Ïîèñê ïî óêàçàòåëÿì |
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| Carey F.A. — Organic Chemistry |
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| Ïðåäìåòíûé óêàçàòåëü |
Homologous series 68 84
Homolytic bond cleavage 169
Htickel, Erich 451
Htickel’s rule 451—460 462—463 467
Huffman, Donald 436
Hughes, Edward D. 330 339 361
Hund’s rule 9
Hybrid orbitals see “Orbital hybridization”
Hydration of aldehydes and ketones, equilibria in 712—717 743
Hydration of alkenes acid-catalyzed 247—250 272 626
Hydration of alkenes enzyme-catalyzed, of fumaric acid 299—300
Hydration of alkenes hydroboration-oxidation 250—254 273 626
Hydration of alkenes of alkynes 379—381 385 710
Hydrazine cleavage of peptides 1154
Hydrazine in Wolff — Kishner reduction 487 713
Hydrazine reaction with aldehydes and ketones 727
Hydrazine reaction with N-alkylphthalimides 930
Hydrazones 727
Hydride shift alcohol dehydration 210—211 222
Hydride shift cholesterol biosynthesis 1094—1095
Hydride shift electrophilic addition to alkenes 241—242
Hydride shift in  reactions 345
Hydride shift in reaction of alcohols with hydrogen halides 355
Hydroboration-oxidation 250—254 273 626
Hydroformylation 711—712 787
Hydrogen see also “Hydrogenation”; “Nuclear magnetic resonance spectroscopy”
Hydrogen bonding 148
Hydrogen bonding and solvent effects on rate of nucleophilic substitution 346—347
Hydrogen bonding between ethers and water 668
Hydrogen bonding in 12 60—63
Hydrogen bonding in alcohols 148—151 179
Hydrogen bonding in amines 918—919
Hydrogen bonding in carboxylic acids 794
Hydrogen bonding in DNA 1168—1169
Hydrogen bonding in phenols 995—996
Hydrogen bonding intramolecular in enol of 2,4-pentanedione 762
Hydrogen bonding intramolecular in o-nitrophenol 996
Hydrogen bonding intramolecular in peroxyacetic acid 262
Hydrogen bonding intramolecular in salicylate ion 1007
Hydrogen bonding peptides and proteins 1143—1145
Hydrogen bromide  of 36 39 43
Hydrogen bromide acidity of 43
Hydrogen bromide electrophilic addition to alkenes 235—238
Hydrogen bromide electrophilic addition to alkynes 377 385
Hydrogen bromide electrophilic addition to conjugated dienes 405—407
Hydrogen bromide electrophilic addition to styrene 466
Hydrogen bromide free-radical addition to alkenes 242—245 274 448
Hydrogen bromide free-radical addition to alkynes 379
Hydrogen bromide reaction of with alcohols 151—152 164—165 180 354—355 636
Hydrogen bromide reaction of with epoxides 681 683
Hydrogen bromide reaction of with ethers 674—676 692 1010
Hydrogen carbonate ion see “Bicarbonate”
Hydrogen chloride of 36 39
Hydrogen chloride addition of to alkenes 235 238 241—242 271—272
Hydrogen chloride electrostatic potential map of 236
Hydrogen chloride reaction with alcohols 151—153 153—160 180 355
Hydrogen chloride to alkynes 379
Hydrogen chloride to conjugated dienes 405 417
Hydrogen cyanide of 33 36
Hydrogen cyanide acidity of 33 36 349 777
Hydrogen cyanide addition to  -unsaturated aldehydes and ketones 777
Hydrogen cyanide addition to aldehydes and ketones 717—720 743 867
Hydrogen cyanide geometry of 31
Hydrogen cyanide in Kiliani — Fischer synthesis 1055—1056 1063
Hydrogen cyanide Lewis structure 14
Hydrogen fluoride 13 15
Hydrogen fluoride of 36 39
Hydrogen fluoride addition to alkynes 378
Hydrogen formation of 6
Hydrogen halides see also “Hydrogen bromide”; “Hydrogen chloride”; “Hydrogen fluoride”; “Hydrogen iodide”
Hydrogen halides acidity 39
Hydrogen halides addition of to alkenes 235—245 271—272
Hydrogen halides addition of to alkenylbenzenes 447—448 465
Hydrogen halides addition of to alkynes 377—379 385
Hydrogen halides addition of to conjugated dienes 405—407 417—418
Hydrogen halides reactions of with alcohols 151—153 163—165 180 354—355 357 636
Hydrogen halides with epoxides 681 683
Hydrogen halides with ethers 674—676 692 1010—1011 1018
Hydrogen iodide of 36 39
Hydrogen iodide cleavage of ethers 674 1018
Hydrogen iodide reaction with alcohols 151
Hydrogen nuclear spin states 522—523
Hydrogen peroxide conformations of 104
Hydrogen peroxide oxidation of dialkyl sulfides by 686
Hydrogen peroxide oxidation of organoboranes by 250—251 254—255
Hydrogen sulfide acidity of 349
Hydrogen sulfide anion of as a nucleophile 327 328 338 349
Hydrogen sulfide anion of basicity of 349
Hydrogen sulfide boiling point 649
Hydrogen-deuterium exchange in alcohols 186 544—545
Hydrogen-deuterium exchange in carboxylic acids 819
Hydrogen-deuterium exchange in cyclopentanone 768
Hydrogenation see also “Heat of hydrogenation”; “Hydrogenolysis”
Hydrogenation catalysts for 230—231 374—375
Hydrogenation mechanism 232 1074
Hydrogenation of aldehydes and ketones 627—628 654
Hydrogenation of alkadienes 399—400
Hydrogenation of alkenes 230—235 271
Hydrogenation of alkenylbenzenes 447—448 466
Hydrogenation of alkyl azides 931
Hydrogenation of alkynes 374—375 384
Hydrogenation of benzene 428—429
Hydrogenation of carbohydrates 1052 1063
Hydrogenation of carbon monoxide 624
Hydrogenation of esters 632
Hydrogenation of imines 934—935
Hydrogenation of ketones 628 654
Hydrogenation of nitriles 932
Hydrogenation of nitroarenes 932
Hydrogenation of vege tableoils 1072 1074
Hydrogenation stereochemistry of 234—235 309—310
Hydrogenolysis, of benzyl esters 1137—1139
Hydrolysis of 2-bromooctane, stereochemistry of 331—333 343-344
Hydrolysis of a-bromo carboxylic acids 816
Hydrolysis of acetals 722—723 724
Hydrolysis of acyl chlorides 839 840
Hydrolysis of alkyl halides 336—337 339—342 626
Hydrolysis of alkyl hydrogen sulfates 246
Hydrolysis of amides 862—867 941—942
Hydrolysis of carboxylic acid anhydrides 843
Hydrolysis of carboxylic acid derivatives, relative rate 833 table
Hydrolysis of cyanohydrins 809
Hydrolysis of epoxides 681—682 684
Hydrolysis of esters 849—856 876
Hydrolysis of nitriles 808—809 822 870—871
Hydrolysis of peptides and proteins 1130
Hydrolysis of tert-butyl bromide 339—341
Hydronium ion 34 (see also “Oxonium ion”)
Hydronium ion of 36 43
Hydrophilic 800
Hydrophobic effect 83
Hydroquinone 994 1012
Hydroxide ion as base 45 46 212 369 649 763 797
Hydroxide ion as nucleophile 329 330—334 337—338 716 766 852—856 866
Hydroxylamine 727
Hydroxylation of alkenes anti 683—684
Hydroxylation of alkenes syn 635
Hyperconjugation 161—162
Hypophosphorous acid 948—949 961
Hz (symbol for Hertz), unit of frequency 520
Ibuprofen 183 296 824 1083
Icosane 71
Icosanoic acid 1073
Icosanoids 1080—1084
Ignarro, L. J. 1149
Iijima, Sumio 437
Imidazole 461 922—923
Imides 862
Imines as intermediates in reductive amination 934—935
Imines in addition of Grignard reagents to nitriles 871
| Imines in biological chemistry 728—729 1125
Imines preparation of 724—727 744
Imines stereoisomers 748
Iminium ion 935
Imino acid 870—871
Indene 447—448
Index of hydrogen deficiency 574
Indigo 4 113 914
Indole 460—461
Induced dipole-induced dipole forces 81—83 147—150
Inductive effect 41 50 161
Inductive effect and acidity of alcohols 40—41
Inductive effect and acidity of carboxylic acids 41 795—796 801—804
Inductive effect of alkyl groups in aldehydes and ketones 708 713—715
Inductive effect of alkyl groups in alkenes 196—199 221
Inductive effect of alkyl groups in alkynes 374
Inductive effect of alkyl groups in carbocations 161 181 341—342
Inductive effect of alkyl groups of trifluoromethyl group 41 492 715
Industrial preparation 1,2-epoxypropane 678
Industrial preparation 1,3-butadiene 404
Industrial preparation acetaldehyde 644 711
Industrial preparation acetic acid 806
Industrial preparation acetic anhydride 841
Industrial preparation acetone 711 1000 1023
Industrial preparation acetylene 364
Industrial preparation aldehydes 711—712
Industrial preparation benzene 424
Industrial preparation chloromethanes 167
Industrial preparation ethylene 189 202
Industrial preparation ethylene oxide 269 644
Industrial preparation formaldehyde 624 711
Industrial preparation isopropyl alcohol 246
Industrial preparation methanol 623—624
Industrial preparation phenol 975 1000 1023
Industrial preparation propene 188 202
Industrial preparation styrene 446 483
Industrial preparation terephthalic acid 806
Industrial preparation urea 861
Infrared spectra see also “Infrared spectroscopy”
Infrared spectra 1-hexene 560—561
Infrared spectra 2-hexanol 560 563
Infrared spectra 2-hexanone 563—564
Infrared spectra 4-phenylbutanoic acid 820
Infrared spectra butanal 739
Infrared spectra butylamine 952
Infrared spectra cyclohexanol 651 652
Infrared spectra diethylamine 952
Infrared spectra dipropyl ether 688
Infrared spectra hexane 560
Infrared spectra p-cresol 1014
Infrared spectra tert-butylbenzene 560—561
Infrared spectroscopy 559—564 577
Infrared spectroscopy absorption frequencies table 561
Infrared spectroscopy alcohols 560 561 651
Infrared spectroscopy aldehydes and ketones 561 563 738 739
Infrared spectroscopy amines 951—952
Infrared spectroscopy carboxylic acids and derivatives 561 819—820 872
Infrared spectroscopy ethers and epoxides 688 690
Infrared spectroscopy nitriles 561 872
Infrared spectroscopy phenols 1014
Ingold, Sir Christopher 3
Ingold, Sir Christopher and stereochemical notation 194 290—293
Ingold, Sir Christopher and studies of reaction mechanisms electrophilic aromatic substitution 477
Ingold, Sir Christopher and studies of reaction mechanisms elimination 214—216
Ingold, Sir Christopher and studies of reaction mechanisms nucleophilic substitution 160 164 330 339
Initiation step 167 172 243—244 268
Initiators of free-radical reactions 242—244 268 442-443
Insulin 1129 1131—1133 1141
Integration and NMR peak area measurement 532—533
International Union of Pure and Applied Chemistry see ”IUPAC”
Inversion of configuration complete, in  reactions 331—333 356
Inversion of configuration partial, reactions 342—344 356
Iodination 166 256 480
iodobenzene 604 973
Iodomethane see “Methyl iodide”
Iodomethylzinc iodide 604—606 615 616
Ion-exchange chromatography 1130
Ionic bonds 10—12 47
Ionization constant see “Acid dissociation constants”
Ionization energy 11
Ionization potential see “Ionization energy”
Ionophore 670 1078—1079
Iron(III) salts as catalysts in halogenation of arenes 475 480—481
Iron, reduction of nitroarenes by 932
Isoamyl acetate, in bananas 183 845
Isobutane 67 (see also “2-Methylpropane”)
Isobutene see “2-Methylpropene”
Isobutyl chloride 177 482
Isobutyl group 74 (see also “2-Methylpropyl group”)
Isobutylene 187 (see also “2-Methylpropene”
Isocitric acid 828
Isoelectric point 1118—1120
Isoelectronic 50
Isoionic point see “Isoelectric point”
Isolated diene 398 416
Isomerism see “Isomers”
Isomers 2 48
Isomers, alkanes 67 69—70 71—73 96
Isomers, alkenes 192—194 220
Isomers, classification 315 table
Isomers, constitutional 23 48 67
Isomers, keto-enol 379 759—761
Isomers, number of 69
Isomers, stereoisomers see “Stereoisomers”
Isopentane 69—70 (see also “2-Methylbutane”
Isopentenyl pyrophophate 1087—1093 1102
Isoprene 408 1084
Isoprene rule 1084—1086
Isoprenoid compounds see “Terpenes”
Isopropenyl group 190
Isopropyl alcohol 20 145
Isopropyl alcohol of 37 40
Isopropyl alcohol industrial preparation of 246
Isopropyl alcohol properties of 624
Isopropyl chloride,  spectrum 540
Isopropyl group 74 (see also “1-Methylethyl group”)
Isopropyl group size of 123 334—335
Isopropyl group spin-spin splitting in 540
Isopropyl hydrogen sulfate 245—246
Isopropyl radical 169 170
Isopropylbenzene see also “Cumene”
Isopropylbenzene conversion to phenol 1000 1023
Isopropylbenzene nitration 932
Isopropylbenzene preparation of 931
Isopropylcyclohexane 123
Isoquinoline 460
Isotactic polymers 313—314 612
Isotopes see also “Carbon”; “Hydrogen-deuterium exchange”
Isotopes H-D exchange in alcohols 186 544—545
Isotopes H-D exchange in carboxylic acids 819
Isotopes H-D exchange in cyclopentanone 768
Isotopes in biosynthetic studies 1092—1093
Isotopes in study of reaction mechanisms bromine addition to alkenes 256
Isotopes in study of reaction mechanisms Claisen rearrangement 1011
Isotopes in study of reaction mechanisms ester hydrolysis 852 854—855
Isotopes in study of reaction mechanisms esterification 810
Isotopes in study of reaction mechanisms hydrolysis of chlorobenzene 985
Isotopes in study of reaction mechanisms nucleophilic aliphatic substitution 361
Isotopes in study of reaction mechanisms nucleophilic aromatic substitution 982 985
Isotopic clusters in mass spectrometry 569—570
IUPAC (International Union of Pure and Applied Chemistry) 78 (see also “Nomenclature” “IUPAC”)
J (symbol for coupling constant) 538
Japanese National Institute of Advanced Industrial Science and Technology 555
Joule (SI unit of energy) 11
K (symbol for equilibrium constant) relation to  122—123
Karplus, Martin 580
Kazan, University of 3
Keku16, August 3 424—427
Kendrew, John C. 1146
Ketals see “Acetals”
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