Fuhrhop J., Penzlin G. — Organic Synthesis: Concepts, Methods, Starting materials :: Электронная библиотека попечительского совета мехмата МГУ

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Fuhrhop J., Penzlin G. — Organic Synthesis: Concepts, Methods, Starting materials

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Название: Organic Synthesis: Concepts, Methods, Starting materials

Авторы: Fuhrhop J., Penzlin G.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: second edition, rewise and enlarged

Год издания: 1994

Количество страниц: 432

Добавлена в каталог: 29.10.2005

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Предметный указатель

Urea, heterocycles from      148 306
Urea, N-acyl-, undesired by-product      144 234
Uric acid, synthesis      306
Uroporphyrins, synthesis      251—252 255
Valium      307
Vesicles, bilayer membrane (BLM) vesicles from lipids or surfactants      350—351
Vesicles, covalent      354—356
Vesicles, monolayer membrane (MLM) vesicles      351
Vibramycin      317
Vilsmeier reagents (tert. carboxamides + $\mathrm{POCl_{3}}$ ), $a^{1}$ -synthons      16 18
Vilsmeier reagents (tert. carboxamides + $\mathrm{POCl_{3}}$ ), alkaloid syntheses via      293
Vilsmeier reagents (tert. carboxamides + $\mathrm{POCl_{3}}$ ), formylation of arenes      255
Vincoside (natural alkaloid precursor)      292
Vinyl      see “Alkenes” etc.
Vinylmagnesium bromide      see “Magnesium bromoethenyl-”
Vinylogous carboxylic acid derivs., vinylogous acids      156 317
Vinylogous carboxylic acid derivs., vinylogous amides      79 249
Vinylogous carboxylic acid derivs., vinylogous thioesters      156
Vinylogous principle      15—16 71
Viruses, vehicles for gene transfer      242
Vitamin $\mathrm{B^{12}}$ , parent system of      259
Vitamin $\mathrm{D_{2}}$ = 9,10-Seco-ergosta-5,7,10(19),22-tetraen-3-ol, $(3\beta,5Z,7E,22E)$ -      289
Vitamin $\mathrm{D_{3}}$ = 9,10-Secocholesta-5,7-10(19)-trien-3-ol, $(3\beta,5Z,7E)$ -      31—32
Vitamin $\mathrm{D_{3}}$ = 9,10-Secocholesta-5,7-10(19)-trien-3-ol, $1\alpha,25-dihydroxy$ -, total synthesis      281—283
Vitamin A      see “Retinol” “Carotene”
Vitamin D, provitamins, pr.      284
Vitamin D, provitamins, ring opening      289
Von Braun reaction      see “Cyanogen bromide”
Wadsworth — Emmons olefination = Horner olefination      28—30 32—33
Wilkinson type catalysts      97 102—103
Wittig and Wittig — Horner olefination      28—33 (see also “Phosphonium ...”)
Wittig and Wittig — Horner olefination with phosphine oxides      281
Wittig and Wittig — Horner olefination with phosphonic diamides      328—329
Wittig and Wittig — Horner olefination, cis-selectivity      28—31
Wittig and Wittig — Horner olefination, sensitivity to steric hindrance      33—34
Wolff rearrangement of $\alpha$ -diazo ketones      337
Wolff — Kishner type reduction      97 98 109
Woodward glycolization      128
Woodward — Hoffmann rules, examples      262 289
Woodward’s chlorophyll synthesis      258—259
Woodward’s reagent K      236
Wurtz coupling      36
Xanthates      see “Carbonodithioates”
Xanthine = 3,7-dthydro-1H-purine-2,6-dione, synthesis and methylation      306
Xanthine alkaloids, caffeine      306
Xanthine alkaloids, pr.      290
Ylenes = Ylides      6—7
Ylides      see “Phosphonium” “Sulfonium”
Yohimbine, pr.      290
Yohimbine, synthesis steps      292—293
Z (benzyloxycarbonyl)      see “Protection of amines”
Z-Selectivity      see “cis/trans-selectivity”

Zinc or zinc-copper, reactions, carbenoid generation from $\mathrm{CH_{2}I_{2}}$       74—75 83
Zinc or zinc-copper, reactions, Clemmensen reduction      98 109
Zinc or zinc-copper, reactions, pinacol coupling      53
Zinc or zinc-copper, reactions, reduction of haloalkanes      83 276 335—336
Zinc or zinc-copper, reactions, reduction of hydroperoxides      121
Zinc or zinc-copper, reactions, reduction of nitroso groups      268
Zinc or zinc-copper, reactions, reductive $\beta$ -elimination with, of 1,2-dihalides      119 156—157
Zinc or zinc-copper, reactions, reductive $\beta$ -elimination with, of glycosyl halides      268
Zinc or zinc-copper, reactions, reductive $\beta$ -elimination with, of oxiranes (deepoxidation)      156—157
Zinc or zinc-copper, reactions, reductive $\beta$ -elimination with, of p-iodo ethers      326—327
Zinc or zinc-copper, reactions, reductive $\beta$ -elimination with, of trichloroacetyl chloride      83
Zinc or zinc-copper, reactions, reductive cleavage of 2,2,2-trihaloethyl esters, Tbeoc- and Tceoc-alcohols      157—158
Zinc or zinc-copper, reactions, reductive cleavage of 2,2,2-trihaloethyl esters, Tbeoc- and Tceoc-amines      162—163
Zinc or zinc-copper, reactions, reductive cleavage of 2,2,2-trihaloethyl esters, Tce esters      165
Zinc or zinc-copper, reactions, reductive cleavage of 2,2,2-trihaloethyl esters, Tce phosphates      166—167 216 218
Zinc or zinc-copper, reactions, reductive opening of cyclopropanes      76
Zinc or zinc-copper, reactions, Reformatsky reactions with      44—45 301
Zinc(2+) acetate, chelation of linear porphyrin precursors      349
Zinc(2+) borohydride      see “Borate(1-) tetrahydro- zinc”
Zinc(2+) halides, (1-haloalkyl)cyclopropane opening      69—70 77
Zinc(2+) halides, acetalization catalysts      268
Zinc(2+) halides, Mitsunobu reactions with      160—161
Zinc, alkylchloro-, alkylation of acyl halides      46
Zinc, diethyl-, Simmons — Smith reaction with      75
Zinc, dimethyl-, carbosulfenylation of alkenes      21
Zirconium, $chlorobis(\eta^{5}-2,4-cyclopentadien-1-yl)-hydro$ - ( $\mathrm{Cp_{2}ZrClH}$ ), hydrozirconation of alkynes with      132 325
Zirconium, $dichlorobis(\eta^{5}-2,4-cyclopentadien-1-yl)$ -, activation of glycosyl fluorides with $\mathrm{Cp_{2}ZrCl_{2}/Ag^{+}}$       270
Zwitterions (betalnes) in Wittig olefination      29—30
[10]Annulene, (all-Z)- and (E,Z,E,Z,Z)-      332
[18]Annulene      40 100
[24]Annulene, 1,2,3,4,7,8,9,10,13,14,15,16,19,20,21,22-hexadecadehydro-      155
[5,6]Fullerene- $\mathrm{C_{60}-I_{k}}$       357
“Binap”, chiral bis-phosphine ligand      102—103
“Capping” of free OH on solid support      221
“Capping” of non-reacted terminal nucleosides      223
“Chiral pool”, low-cost reagents (”chirons”), $\alpha$ -amino acids      178 184—185 299
“Chiral pool”, low-cost reagents (”chirons”), alkaloids      290
“Chiral pool”, low-cost reagents (”chirons”), hydroxy acids      176 183 185 191
“Chiral pool”, low-cost reagents (”chirons”), steroids      284
“Chiral pool”, low-cost reagents (”chirons”), sugars      263—264
“Chiral pool”, low-cost reagents (”chirons”), terpenes      174 182 185 189—192 282
“Chiramt”, chiral copper chelates from      20—21
“Inverted DNA”      345—346
“Ox” protection      see “Protection of amino groups”
“Picket fence” porphyrin      253
“Recombinant bacteria”      241—246
“Redox glycosidation”      272
“R” synthons      see “Radical synthons”
“Sticky end” method      225—226 242—244
“Stien” = 1,2-diphenyl-1,2-ethanediamine, (R,R)- and (S,S)-, chiral auxiliaries      68—69
“Trimethylenemethane” (TMM) synthon      84
“Zip” reaction      249—250

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