Fuhrhop J., Penzlin G. — Organic Synthesis: Concepts, Methods, Starting materials :: Электронная библиотека попечительского совета мехмата МГУ

Главная Ex Libris Книги Журналы Статьи Серии Каталог Wanted Загрузка ХудЛит Справка Поиск по индексам Поиск Форум

Авторизация

Поиск по указателям

Fuhrhop J., Penzlin G. — Organic Synthesis: Concepts, Methods, Starting materials

Обсудите книгу на научном форуме

Нашли опечатку?
Выделите ее мышкой и нажмите Ctrl+Enter

Название: Organic Synthesis: Concepts, Methods, Starting materials

Авторы: Fuhrhop J., Penzlin G.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: second edition, rewise and enlarged

Год издания: 1994

Количество страниц: 432

Добавлена в каталог: 29.10.2005

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Carbocycles, 7-membered, pr.      191
Carbocycles, 7-membered, synthesis via bicyclo[4.1.0]heptanes      76 334
Carbocycles, 8-membered, pr.      191
Carbocycles, bridged      see “Oligocyclic compounds bridged”
Carbocycles, macrocyclic, pr.      191
Carbocycles, macrocyclic, synthesis by 1-alkyne coupling      40 155
Carbocycles, macrocyclic, synthesis by acyloin coupling      53—54
Carbocycles, macrocyclic, synthesis by allyl coupling with Ni      41—42
Carbocycles, macrocyclic, synthesis by butadiene cyclooligomerization      41
Carbocycles, macrocyclic, synthesis by fragmentation of fused systems      89—90
Carbocycles, macrocyclic, synthesis by sulfide contraction      38—39 338
Carbocycles, pr.      189—192
Carbocycles, retro-synthesis      207—211
Carbocycles, synthesis      71—87 90—94 “Ring “Ring
Carbodiimide, dicyclohexyl- (= N,N-meihanetetraylbis[cyclohexanamine]), Moffatt — Pfitzner oxidation with      133
Carbodiimide, dicyclohexyl- (= N,N-meihanetetraylbis[cyclohexanamine]), syntheses with, of aryl ethers      144—145
Carbodiimide, dicyclohexyl- (= N,N-meihanetetraylbis[cyclohexanamine]), syntheses with, of azlactones      48 231
Carbodiimide, dicyclohexyl- (= N,N-meihanetetraylbis[cyclohexanamine]), syntheses with, of esters and amides      144—146 326—327
Carbodiimide, dicyclohexyl- (= N,N-meihanetetraylbis[cyclohexanamine]), syntheses with, of peptides      231—236 240—241
Carbohydrates      see “Monosaccharides” “Oligosaccharides”
Carbohydrates, pr.      263—264 (table)
Carbon monoxide, carbonyl synthon      46—48
Carbon monoxide, photolytic elimination or extrusion      330 339
Carbon monoxide, thermal elimination      337
Carbon oxides $\mathrm{C_{8n}O_{2n}}$ , (n=3, 4, 5)      338—339
Carbon-carbon bonds      see “Alkanes” “Alkenes” “Alkynes”
Carbonates, alkali hydrogen, deprotonation of ct-acylthio ketones      60
Carbonates, alkali or alkaline-earth, $\beta$ -eliminations of halides      52 140
Carbonates, alkali or alkaline-earth, deblocking of O-acyl derivs.      157—158 273
Carbonates, alkali or alkaline-earth, deprotonation of 1,3-diones      10
Carbonates, alkali or alkaline-earth, deprotonation of alkylphosphonium salts      31
Carbonates, alkali or alkaline-earth, deprotonation of phenols      355
Carbonates, alkali or alkaline-earth, epimerization of $\alpha$ -oxy aldehydes      265
Carbonazidic acid, 1,1-dimethyl ester ( $\mathrm{BocN_{3}}$ ), protecting reagent      162—163
Carbonic acid diesters, carboxyln. with      49
Carbonitriles      see “Nitriles”
Carbonochloridic acid esters, protecting reagents      157—158 162—163 229
Carbonothioic acid, O,O'- (1,2-alkanediyl) cyclic ester, reductive elimination      142
Carbonothioic acid, O,O'-dialkyl esters, pyroiysis      138 140—141
Carbonyl compounds      see “Aldehydes” “Ketones”
Carbonyl compounds, $\alpha,\beta$ -unsaturated, $a^{3}$ -synthons      16 19
Carbonyl compounds, $\alpha,\beta$ -unsaturated, $\beta$ -alkylation of      20—21 22
Carbonyl compounds, $\alpha,\beta$ -unsaturated, cyclopropanation of      75—76
Carbonyl compounds, $\alpha,\beta$ -unsaturated, reduction of the C=C bond      73 103—104
Carbonyl compounds, $\alpha,\beta$ -unsaturated, reduction of the C=O bond      105—107 265
Carbonyl compounds, $\alpha,\beta$ -unsaturated, synthesis of, by $\alpha,\beta$ -dehydrogenation      122 138—140
Carbonyl compounds, $\alpha,\beta$ -unsaturated, synthesis of, by 3-eliminations      57 72—73 140
Carbonyl compounds, $\alpha,\beta$ -unsaturated, synthesis of, by aldol type reactions      55—59
Carbonyl compounds, $\alpha,\beta$ -unsaturated, synthesis of, by dimsylation of esters      65
Carbonyl compounds, $\alpha,\beta$ -unsaturated, synthesis of, by oxidation of allylic $\mathrm{CH_{2}}$       119—120
Carbonyl compounds, protection      see “Protection of carbonyl groups”
Carboperoxoic acids, oxidation with, Baeyer — Villiger type      80 136—137 165 276 319—320
Carboperoxoic acids, oxidation with, of alkenes to oxiranes      18 34 88 117 123—127 156—157
Carboperoxoic acids, oxidation with, of thioethers to sulfones      80
Carboperoxoic acids, oxidation with, of thioethers to sulfoxides      315
Carboperoxoic acids, relative reactivity of      123
Carbosulfenylation of alkenes (Reetz)      21
Carbothioic acids, S-(2-oxoalkyl) esters, S extrusion      59—60
Carbothioic acids, S-(2-pyridyl) or S-(2-imidazolyl) esters, macrocyclic lactones from      146
Carbothioic acids, S-alkyl esters, $d^{2}$ -synthons      62 322—323
Carbothioic acids, S-alkyl esters, aldol addition with chiral boron enolates      62
Carbothioic acids, S-alkyl esters, Wittig oleflnation of      32
Carbothioic acids, thionolactones, cyclic ethers from      110—111
Carboxamides, $\alpha,\beta$ -unsaturated, Michael addn. to      72
Carboxamides, alcoholysis      303
Carboxamides, hydrolysis (mild)      312—313
Carboxamides, N,N-dialkyl-, adducts with $\mathrm{POCl_{3}}$ (Vilsmeier reagents)      16 18 255 293
Carboxamides, N-alkylation (Mitsunobu)      160—161
Carboxamides, O-alkylation      111—112
Carboxamides, reduction, to aldehydes      98 105
Carboxamides, reduction, to amines      98 111—112 247 291
Carboxamides, synthesis      see “Peptides”
Carboxamides, synthesis by acylation of amines      144—145
Carboxamides, synthesis by acylation of amines with carboxylic acid azides      237—241
Carboxamides, synthesis by acylation of amines with carboxylic acid esters      66 112 234 291 297 299 354
Carboxamides, synthesis by acylation of amines with carboxylic acid halides or mixed anhydrides      247 291 312—313
Carboxamides, synthesis by acylation of amines with carboxylic acids (DCC)      144—145 231—236 240—241 326—327
Carboxamides, synthesis by acylation of amines, catalysts for      144—145 231 234
Carboxamides, synthesis by hydrolysis of nitriles      66 302—304
Carboximidic acids, esters, reactions, as $a^{1}$ -synthons      260
Carboximidic acids, esters, reactions, as $d^{2}$ -synthons      18—19 22—23 63—64 197—198
Carboximidic acids, esters, reduction of, to aldehydes      13 22—23 63—64 298
Carboximidic acids, esters, reduction of, to sec. amines      111—112
Carboximidic acids, esters, synthesis from carboxamides      111—112 260
Carboximidic acids, esters, synthesis from nitriles      22—23 298
Carboximidoyl chlorides, N-alkyl-, nitrile ylides from      153
Carboximidoyl chlorides, N-hydroxy-, nitrile N-oxides from      153
Carboxylic acids, $\alpha$ -alkyl- $\beta$ -hydroxy-, stereosel. synth.      27 62
Carboxylic acids, $\alpha$ -alkyl-, synthesis      13 22—23 199—201 299
Carboxylic acids, $\alpha$ -amino-      see “ $\alpha$ -Amino acids”
Carboxylic acids, $\alpha$ -hydroxy-, synthesis by $\alpha$ -oxn. of acids      120—122
Carboxylic acids, $\alpha$ -hydroxylation      120—121
Carboxylic acids, $\alpha,\beta$ -unsaturated $\alpha$ -acylamino-, enantioselective hydrogenation      102—103
Carboxylic acids, $\alpha,\beta$ -unsaturated, esters, Michael addition to      65—66 351
Carboxylic acids, $\alpha,\beta$ -unsaturated, esters, red. coupling with carbonyl compounds      69
Carboxylic acids, $\alpha,\beta$ -unsaturated, oxidative decarboxylation ( $\rightarrow$ ketones)      143
Carboxylic acids, $\alpha,\beta$ -unsaturated, synthesis by aldol type condensations      56
Carboxylic acids, $\alpha,\beta$ -unsaturated, synthesis from 2-alkynoic acids by $\beta$ -alkylation      64
Carboxylic acids, $\alpha,\beta$ -unsaturated, synthesis from 2-alkynoic acids by cis-hydrogenation      64
Carboxylic acids, $\beta$ -hydroxy-, erythro- $\alpha$ -alkylation      27 325—326
Carboxylic acids, $\beta$ -hydroxy-, synthesis, aldol type addition      59 61—62
Carboxylic acids, $\beta$ -hydroxy-, synthesis, enantioselective (Noyorl) hydrogenation of $\beta$ -oxo acids      102—103 325—326
Carboxylic acids, $\beta$ -hydroxy-, synthesis, Reformatsky reaction      44—45 301
Carboxylic acids, $\beta$ -oxo-, esters, $\alpha$ -acidity      10
Carboxylic acids, $\beta$ -oxo-, esters, cyclopentanes from      83
Carboxylic acids, $\beta$ -oxo-, esters, decarboxylation      81 82—83 139 195 205 209—210
Carboxylic acids, $\beta$ -oxo-, esters, enantiosel, hydrogenation      102—103 325—326
Carboxylic acids, $\beta$ -oxo-, esters, reduction to satd. esters      114—115
Carboxylic acids, $\beta$ -oxo-, esters, synthesis by ester condensation      55 58—59
Carboxylic acids, $\beta$ -oxo-, esters, synthesis, $\beta$ -enol ethers from 2-alkynoic acids      63
Carboxylic acids, $\beta,\gamma$ -unsaturated, synthesis from enones by Favorskii rearrangement      84
Carboxylic acids, $\gamma$ -hydroxy- (and $\gamma$ -lactones)      63 64—65 69
Carboxylic acids, $\gamma$ -oxo-, esters, synthesis from enol ether + diazoacetic ester      69—70
Carboxylic acids, $\gamma$ -oxo-, esters, synthesis from nitroalkane + 2-enoic acid      65—66
Carboxylic acids, $\gamma$ -oxo-, esters, synthesis from Trost’s reagent + ketone      79
Carboxylic acids, $\omega$ -hydroxy, lactones from cyclic ketones      80 136—137 206 319—320
Carboxylic acids, $\omega$ -oxo-, synthesis, hydroformylation of co-enoic acids      47—48
Carboxylic acids, $\omega$ -oxo-, synthesis, reduction of cyclic anhydrides      46—47
Carboxylic acids, $\varepsilon$ -oxo-, synthesis by oxidative ring opening from cyclohexanol ethers      87—88 206
Carboxylic acids, $\varepsilon$ -oxo-, synthesis by oxidative ring opening from cyclohexanones      137
Carboxylic acids, $\varepsilon$ -oxo-, synthesis by oxidative ring opening from cyclopentanone + RCOCl      88
Carboxylic acids, $\varepsilon$ -oxo-, synthesis by oxidative ring opening from tm-cyclohexanols      136
Carboxylic acids, azides, peptide synthesis with      237—241
Carboxylic acids, azides, preparation      143 237—241 301
Carboxylic acids, azides, racemization of, lack of      231
Carboxylic acids, azides, rearr. to isocyanates      143 301
Carboxylic acids, conversion to functional derivs.      143—146 (see also “Carboxamides” etc.)
Carboxylic acids, conversion to ketones with RLi      45—46 283
Carboxylic acids, degradation to amines      139 143 301 308 331
Carboxylic acids, derivatives      143—146
Carboxylic acids, dianions, prepn.      63
Carboxylic acids, esters      see “Lactones”
Carboxylic acids, esters, $\alpha$ -acidity      10
Carboxylic acids, esters, $\alpha$ -alkylation      22 27 319—320
Carboxylic acids, esters, $\alpha$ -hydroxylation      121—122
Carboxylic acids, esters, $\alpha,\alpha$ -dialkylation (asym.)      22
Carboxylic acids, esters, hydrazides and azides from      239—240 301
Carboxylic acids, esters, hydrolysis      see “Deblocking”
Carboxylic acids, esters, methylenation with Tebbe’s reagent      110 272
Carboxylic acids, esters, O-silylation of enolates      325
Carboxylic acids, esters, oxidation to $\alpha,\beta$ -unsaturated esters      139
Carboxylic acids, esters, pyroiysis      140—141
Carboxylic acids, esters, reaction with DMSO anion      50—51 65
Carboxylic acids, esters, reduction to aldehydes      105—106 159 165 203 272—273 276 283 321 322
Carboxylic acids, esters, reduction to ethers      110—111
Carboxylic acids, esters, reduction to prim. alcohols      98 325 326 349
Carboxylic acids, esters, reductive coupling (acyloin coupling)      53—54
Carboxylic acids, esters, synthesis, carboxylation with $\mathrm{Et_{2}CO_{3}}$       49
Carboxylic acids, esters, synthesis, esterification of alcohols      144—146 347
Carboxylic acids, esters, synthesis, esterification of alcohols, inversion-esterification      160—161 286

Carboxylic acids, esters, synthesis, hydration of 1-alkoxy-1-alkynes      64—65 325 327—328
Carboxylic acids, esters, synthesis, oxidation of aldehydes      134—135
Carboxylic acids, esters, synthesis, oxidation of ethers      118 134—135
Carboxylic acids, esters, synthesis, oxidative rearrangement, Baeyer — Villiger      136—137 282 283
Carboxylic acids, esters, synthesis, oxidative rearrangement, skeletal rearr. of ketones      136
Carboxylic acids, halides, conversion to $\alpha$ -functionalized ketones      50—51
Carboxylic acids, halides, conversion to azides      143
Carboxylic acids, halides, conversion to esters      144
Carboxylic acids, halides, conversion to ketones      46—47
Carboxylic acids, halides, preparation      143
Carboxylic acids, halides, reduction to aldehydes      46 96—98
Carboxylic acids, halides, umpolung with $\mathrm{Na_{2}Fe(CO)_{4}}$       17 46—47
Carboxylic acids, protection      see “Protection of carboxy groups”
Carboxylic acids, reduction to prim. alcohols      98
Carboxylic acids, synthesis by oxidation of alcohols      134 319—320
Carboxylic acids, synthesis by oxidation of aldehydes      134
Carboxylic acids, synthesis by oxidative cleavage of $\alpha$ -hydroxy ketones      62
Carboxylic acids, synthesis by oxidative cleavage of alkynes      117 132
Carboxylic acids, synthesis by retro-aldol type cleavage      88 207
Carboxylic acids, synthesis from anions with $\mathrm{CO_{2}}$       49 64 200
Carboxylic acids, synthesis via propanediol acids      139 199—200
Carcerand      356
Cardenolides, glycosylation      267
Cardenolides, synthesis      286—287
Carotenoids, synthesis      30—31 40—41
Carvone 1,2-oxide, $[(1S)-1\alpha,2\alpha,4\beta]$ -, chiral educt      282
Carvone, (-)-(R)- and (+)-(S)-, pr.      191
Cascade-branched polymers      354—356
Catalysts      see “Hydrogenation” “Lewis “Sulfonic
Catalysts, aldol addition, stereoselective      61
Catalysts, amidation/esterification      144—146 231 234
Catalytic hydrogenation      see “Hydrogenation”
Catechol derivatives      see “1
Catecholborane = 1,3,2-benzodioxaborole      131
Cation-exchange resins      see “Sulfonic acids”
Cavitands      355
Cbz (benzyloxycarbonyl)      162 163
cDNA = copy DNA      242
Ce (2-cyanoethyl), phosphate protecting group      166—167 216 218 220—224 342
Cephalexin      312—313
Cephalosporanic acid, 7-amino-      312—313
Cephalosporin C      312—313
Cephalosporin syntheses, partial      312—313
Cephalosporin syntheses, total      313—315
Ceramide, glycosylation of      271
Cerate(2-), hexanitrato-, diammonium (CAN, ceric ammonium nitrate, $\mathrm{(NH_{4})_{2}Ce(NO_{3})_{6}}$ ), oxn. of (4-methoxyphenyl)methyl ethers      157
Cerate(2-), hexanitrato-, diammonium (CAN, ceric ammonium nitrate, $\mathrm{(NH_{4})_{2}Ce(NO_{3})_{6}}$ ), oxn. of iron(0) complexes      78
Cerebrosides      271
Cerium(3+) chloride + $\mathrm{NaBH_{4}}$ , reduction with      105—106 107
Chelation stereocontrol      60—62 66—67
Chichibabin reaction, amination of pyridine derivs.      306
Chiral auxiliaries      see “Enantioselective syntheses”
Chiral bilayer effect      352
Chiral hydrogenation catalysts      102—103
Chiral induction      see “Asymmetric induction”
Chirality, self-reproduction of      299
Chloranil      see “Cyclohexadienedione tetrachloro-”
Chlordiazepoxide      307
Chlorins      257—259
Chloro-acetoxylation of diols      160
Chloroalkanes      see “Haloalkanes”
Chlorochromate, pyridinium      see “Chromate(1-)”
Chlorophyll a      257
Chlorophyll a, synthesis      258—259
Chlorophyll b, formula      257
Chlorothiazide      310
Chlorpheniramine, ( $\pm$ )-      303
Cholecalciferol (vitamin $\mathrm{D_{3}}$ )      31—32
Cholecalciferol (vitamin $\mathrm{D_{3}}$ ), $1\alpha,25$ -dihydroxy-      281—283
Cholest-5-en-3-ol, $(3\beta)$ - (cholesterol), 17-fluorination      118—119 156—157
Cholest-5-en-3-ol, $(3\beta)$ - (cholesterol), degradation of the $17\beta$ side-chain      118—119
Cholest-5-en-3-ol, $(3\beta)$ - (cholesterol), pr.      284
Cholesta-5,7-dien-3-ol, $(3\beta)$ - (provitamin $D_{3}$ ), electrocyclic ring opening      289
Cholesta-5,7-dien-3-ol, $(3\beta)$ - (provitamin $D_{3}$ ), pr.      284
Cholestan-3-ol, $(3\beta,5\alpha)$ -, remote oxidation      285—286
Chromate(1-), chlorotrioxo-, pyridinium ( $\mathrm{Py\cdot CrClO_{3}H=Py\cdot HCl\cdot CrO_{3}}$ , PCC), oxn. of sec. alcohols to ketones      283
Chromate(2-), potassium ( $\mathrm{K_{2}CrO_{4}}$ ), oxidation of allylic $\mathrm{CH_{2}}$       120
Chromic acid bis(1,1-dimethylethyl) ester, oxidation with, of alcohols to aldehydes      133—135
Chromic acid bis(1,1-dimethylethyl) ester, oxidation with, of allylic $\mathrm{CH_{2}}$       116 120
Chromium(2+) acetate, reduction of oxiranes      274—275
Chromium(6+) oxide with acetic acid, oxidative cleavage of tert. alcohols      136
Chromium(6+) oxide with sulfuric acid (Jones’ reagent), oxn. with, of alkanes      118—119
Chromium(6+) oxide with sulfuric acid (Jones’ reagent), oxn. with, of enol ethers      285
Chromium(6+) oxide with sulfuric acid (Jones’ reagent), oxn. with, of sec. alcohols      109 111 117 133—135 276—277 337
Chromium, trioxobis(pyridine)- (Collins’ reagent, $\mathrm{CrO_{3}Py_{2}}$ , $\mathrm{CrO_{3}\cdot 2Py}$ ), allylic oxidation of alkenes      116 120
Chromium, trioxobis(pyridine)- (Collins’ reagent, $\mathrm{CrO_{3}Py_{2}}$ , $\mathrm{CrO_{3}\cdot 2Py}$ ), oxn. of prim, alcohols      125
Chromium, trioxobis(pyridine)- (Collins’ reagent, $\mathrm{CrO_{3}Py_{2}}$ , $\mathrm{CrO_{3}\cdot 2Py}$ ), oxn. of sec. alcohols (selective)      135
Chugaev pyroiysis of thioesters      138 140—141
Cinchona alkaloids, chiral $\mathrm{OsO_{4}}$ -oxidation catalysts from      129
Cinchona alkaloids, pr.      290
cis/trans-Isomerization of alkenes      30—31 100—101 142 282 296 332
cis/trans-Selective reactions      see “Inversion” “Retention”
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, $\alpha$ -alkylation of cyclic ketones      12 82
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, $\alpha$ -alkylation of lactones      321 322 327—328
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, $\alpha$ -hydroxyln. of carbonyl compds      120—122
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, acid-catalysed cyclization of 1,5-dienes      91—92 279—280
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, allylsilane addn. to 2-enones (Sakurai)      90
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, chloro-acetoxylation of diols      160
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, halohydrination      117 275—276 287
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, halolactonization      275 319—320
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, Heck coupling      43
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, hydration of cyclic enones      274—275
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, hydroboration      131
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, Ireland — Claisen rearr.      87 324—325
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, iron-cyclohexadienyl complexes      44
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, lactonization (diastereosel.)      168 327—328
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, pinacol coupling of dioxo compds      53—54
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, redn. of cyclic ketones      106—107 274—275
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, [1+2]cycloadditions      74—76
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, [2+2]cycloadditions      29—30 78
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, [2+3]cycloadditions      84
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, [2+4]cycloadditions      84—86 280—281 297
cis/trans-Selective reactions, $\alpha/\beta$ -selectivity, “ene” reactions      282—283 297—298
cis/trans-Selective reactions, anti/syn-Selectivity, 1,2-diols from alkenes      81—82 117 123—129
cis/trans-Selective reactions, anti/syn-Selectivity, reduction of alkenes by Birch reduction      73 103—104 278
cis/trans-Selective reactions, anti/syn-Selectivity, reduction of alkenes with boranes      89—90 107—108 130—131
cis/trans-Selective reactions, anti/syn-Selectivity, reduction of alkenes with diazene      102
cis/trans-Selective reactions, anti/syn-Selectivity, reduction of alkenes with hydrogen      96—97 101—102 209
cis/trans-Selective reactions, E/Z-Selectivity, enolate formation      12—13 22—23 26 27 57—58 60—62
cis/trans-Selective reactions, E/Z-Selectivity, fragmentation of fused ring systems      89—90
cis/trans-Selective reactions, E/Z-Selectivity, Heck coupling      43
cis/trans-Selective reactions, E/Z-Selectivity, hydrozirconation/bromination      132 325
cis/trans-Selective reactions, E/Z-Selectivity, Julia — Lythgoe olefination      34
cis/trans-Selective reactions, E/Z-Selectivity, reduction of alkynes by Birch reduction      97 100—101
cis/trans-Selective reactions, E/Z-Selectivity, reduction of alkynes with boranes      37—38
cis/trans-Selective reactions, E/Z-Selectivity, reduction of alkynes with DIBAL      100
cis/trans-Selective reactions, E/Z-Selectivity, reduction of alkynes with hydrogen      64 96—97 100—102
cis/trans-Selective reactions, E/Z-Selectivity, reductive coupling of alkynes via $\mathrm{R_{3}B}$       37—38
cis/trans-Selective reactions, E/Z-Selectivity, reductive coupling of vinylic halides via $\mathrm{R_{2}CuLi}$       20 277
cis/trans-Selective reactions, E/Z-Selectivity, ring opening of cyclopropanes      70—71 76—77
cis/trans-Selective reactions, E/Z-Selectivity, sulfur extrusion      39 261
cis/trans-Selective reactions, E/Z-Selectivity, Wittig/Horner olefinations      29—31 273 276 281 283 329
Citronellal, pr.      174
Citronellal, synthesis starting from      206
Claisen condensation      see “Ester condensation”
Claisen rearrangement, Ireland-      87 325
Clathrochelates      247—248
Cleavage      see “Decarboxylation” “Retro-...”
Cleavage of rings      see “Ring cleavage” “Ring
Cleavage, oxidative      see “Oxidative cleavage”
Cleavage, reductive      see “Hydrogenolysis” “Reductive
Cleavage, site-specific, of DNA, by restriction endonucleases      243
Cleavage, site-specific, of DNA, by synthetic “scissors”      343—344
Clemmensen reduction      109
Clidinium bromide, $(\pm)$ -      309
Cloning of genes      241—246
Cobalt(2+) chloride, catalyst for the reduction of prim. amides with $\mathrm{NaBH_{4}}$       111—112
Cobalt, $dicarbonyl(\eta^{5}-2,4-cyclopentadien-1-yl)$ -, alkyne cyclotrimerization catalyst      80 281
Cobyrinic acid      259
Cobyrinic acid, synthesis      261—262

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15

О проекте