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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Íàçâàíèå: Chemistry of the Elements
Àâòîðû: Greenwood N.N., Earnshaw A.
Àííîòàöèÿ: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Ðóáðèêà: Õèìèÿ /
Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Èçäàíèå: second edition
Ãîä èçäàíèÿ: 1997
Êîëè÷åñòâî ñòðàíèö: 1340
Äîáàâëåíà â êàòàëîã: 18.02.2007
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Nonaqueous solvent systems, 561 655
Nonaqueous solvent systems, 664 700 759
Nonaqueous solvent systems, HCl 819
Nonaqueous solvent systems, HF 570 816—819
Nonaqueous solvent systems, ICl 827
Nonaqueous solvent systems, superacids 570
Nonstoichiometry in chalcogenides 765 766
Nonstoichiometry in oxides 642—644
Nonstoichiometry in sulfides 679
Nuclear fission 1256
Nuclear fission, products 1257 1260
Nuclear fission, spontaneous 1253 1262
Nuclear fuels 1257—1262
Nuclear fuels, breeding 1259
Nuclear fuels, enrichment 1259
Nuclear fuels, reprocessing 1097 1260—1262
Nuclear reactions in stars 7—13
Nuclear reactors 1256—1260
Nuclear reactors, different types 1258
Nuclear reactors, natural 1257
Nuclear structure of atoms 22
Nuclear waste, storage 1257 1261
Nucleic acid and H bonding 60 62
Nucleic acid, double helix structure of 474
Nucleogenesis 2ff
Nylon-6 and -66 422
Obsidian 342
Octahedral complexes 914—916 922—923
Octahedral complexes of octahedral ions 996
Octahedral complexes of octahedral ions 1089
Octahedral complexes of tetrahedral complexes of 1158
Octahedral complexes, distortions in 915—916 (see also “Jahn — Teller effect”)
Oddo's rule 3
Oklo phenomenon 1257
Oligomerization of acetylene 1172
Olivine 109 347
One-dimensional conductors 1156 1165
Onyx 342
Opal 342
Open-hearth process 1072
Optical activity 919 1125
Optical isomers 915 919 1125
Optical rotatory dispersion (ORD) 1125
Optically active metal cluster compound 667
Orbital contribution to magnetic moment of high-spin complexes of 1132
Orbital degeneracy 1244
Orbital quantum number, l 26
Orford process 1146
Organometallic compounds 924—943
Organometallic compounds, classification 924—925
Organometallic compounds, definition 924
Organometallic compounds, dihapto ligands 930—933
Organometallic compounds, heptahapto ligands 941
Organometallic compounds, hexahapto ligands 940—941
Organometallic compounds, monohapto ligands 925—930
Organometallic compounds, octahapto ligands 941—943
Organometallic compounds, pentahapto ligands 937—940
Organometallic compounds, tetrahapto ligands 935—937
Organometallic compounds, trihapto ligands 933—935
Orpiment see “Arsenic sulfide
Orthonitrate ion, 472
Orthoperiodic acid see “Periodic acids”
Orthophosphates 523—526
Orthophosphates, , structural analogy with 526
Orthophosphates, uses of 524—525
Orthophosphoric acid see “Phosphoric acid”
Osmates 1082
Osmiamates 1085
Osmium, abundance 1071
Osmium, anomalous atomic weight of in Re ores 19
Osmium, atomic and physical properties 1074—1075
Osmium, carbidocarbonyls 1107—1108
Osmium, carbonyl halides 1108
Osmium, carbonyl hydrides and carbonylate anions 1105—1108
Osmium, carbonyls 928 929 1104—1105
Osmium, chalcogenides 1081
Osmium, complexes with 702
Osmium, complexes, +2 oxidation state 1091—1098
Osmium, complexes, +3 oxidation state 1088—1089
Osmium, complexes, +4 oxidation state 1086—1088
Osmium, complexes, +5 oxidation state 1086
Osmium, complexes, +6 oxidation state 1085—1086
Osmium, complexes, +7 oxidation state 1085
Osmium, complexes, +8 oxidation state 1085
Osmium, coordination numbers and stereochemistries 1078
Osmium, cyclooctatetraene complex 943
Osmium, discovery 1070
Osmium, halides and oxohalides 1082—1083
Osmium, organometallic compounds 1104—1112
Osmium, oxidation states 1077 1079
Osmium, oxides 1079 1081
Osmium, oxoanions 1082
Osmium, production and uses 1072—1074
Osmium, reactivity of element 1075
Osmium, relationship with other transition elements 1075—1079
Osmium, standard reduction potentials 1077
Osmocene 937 1111
Osmyl complexes 1085 1086
Outer-sphere reactions 1124
Oxidation state, periodic trends in 27—28
Oxidation state, variability of 27 905
Oxides 640—644
Oxides, acid-base properties 628 640 641
Oxides, classification 640—642
Oxides, nonstoichiometry in 642—644
Oxides, structure types 641 753
OXO process (hydroformylation) 309 1135 1140
Oxonium ion 48
Oxovanadium (vanadyl) ion 982 995
Oxygen see also “Dioxygen” “Ozone”
Oxygen carriers see also “Dioxygen”
Oxygen carriers, complexes of cobalt 1132
Oxygen carriers, haemocyanin 1199
Oxygen carriers, haemoglobin and synthetic models 1098—1101
Oxygen carriers, Vaska's compound 615 617 1136 1137
Oxygen, abundance 600 602
Oxygen, allotropes 607
Oxygen, atomic 611 612
Oxygen, atomic properties 604 605
Oxygen, chemical properties 612—615
Oxygen, coordination geometries 613—615
Oxygen, crown ether compounds 95—97 124 601
Oxygen, difluoride 638
Oxygen, fluoride 638—640
Oxygen, history 600 601 604
Oxygen, industrial production 604
Oxygen, industrial uses 604
Oxygen, isotopes, separation of 604
Oxygen, liquefaction 601 604
Oxygen, liquid 601 603—604 606
Oxygen, occurrence in atmosphere, hydrosphere and lithosphere 600 602 605
Oxygen, origin of blue colour in liquid 607
Oxygen, origin of, in atmosphere 602
Oxygen, oxidation states 613
Oxygen, physical properties 605
Oxygen, preparation 603 604
Oxygen, radioactive isotopes 605
Oxygen, reduction potential, pH dependence 628—629
Oxygen, roasting of metal sulfides 676—678
Oxygen, standard reduction potentials 628 629 737
Oxyhyponitrous acid see also“Hyponitric acid”
Ozone, see also “Chlorofluorocarbons”
Ozone, , bonding 607 608
Ozone, , chemical reactions 609—611 848 849
Ozone, , discovery 607
Ozone, , environmental implications 608 848
Ozone, , hole 608
Ozone, , molecular structure 607 608 708
Ozone, , physical properties 607 608
Ozone, , preparation 609 611
Ozonide ion, 610
Ozonides (organic) 610 611
Ozonolysis 610 611 849
P-N compounds 531— 542
p-process in stars 13
p-type semiconductors see “Semiconductor” “Transistor”
Palladium, -allylic complexes 953 1172
Palladium, absorption of hydrogen 1150 1151
Palladium, abundance 1145
Palladium, alkene and alkyne complexes 1170—1172
Palladium, alkyls and aryls 1167 1168
Palladium, atomic and physical properties 1148—1149
Palladium, carbonyl chloride 1168
Palladium, chalcogenides 1152
Palladium, complexes, +2 oxidation state 1156—1166
Palladium, complexes, +3 oxidation state 1154 1156
Palladium, complexes, +4 oxidation state 1154
Palladium, complexes, zero oxidation state 1166—1167
Palladium, coordination numbers and stereochemistries 1150
Palladium, discovery 1144
Palladium, halides 1152—1154
Palladium, organometallic compounds 1167—1172
Palladium, oxidation states 1150
Palladium, oxides 1151 1152
Palladium, production and uses 1146 1147
Palladium, reactivity of element 1149
Paraperiodic acid see “Periodic acids”
Parathion 509
Patronite 977
Pauli exclusion principle 22 P
Pearlite 1075
Pentaborane, 154 159 163
Pentaborane, , Bronsted acidity 171 172
Pentaborane, , chemical reactivity 171
Pentaborane, , metalloborane derivatives 171—173
Pentaborane, , preparation 165
Pentaborane, , properties 170
Pentaborane, , structure 171
Pentagonal bipyramidal complexes 916
Pentathionates, , preparation and structure 717 718 851
Pentlandite 1145
Perbromates, 871—872
Perbromates, , discovery 789 871
Perbromates, , radiochemical synthesis 871
Perbromates, , redox systematics 854 855 872
Perbromates, , structure 871
Perbromic acid, 871
Perbromyl fluoride, 881
Perchlorates, 865—871
Perchlorates, , bridging ligand 791 868—871
Perchlorates, , chelating ligand 868—871
Perchlorates, , coordinating ability 791 868—871 1020
Perchlorates, , monodentate ligand 791 868—871
Perchlorates, , production and uses 865 867
Perchlorates, , redox systematics 854 855
Perchlorates, , structure 868
Perchloric acid, 865—868
Perchloric acid, , chemical reactions 867 868
Perchloric acid, , hydrates 867
Perchloric acid, , physical properties 865 866
Perchloric acid, , preparation 865 866
Perchloric acid, , structure 868
Perchloryl fluoride, 876 879 880
Perhalates, 854 855 865—875
Perhalic acids, 865—875
Periodates 872—875
Periodates, reaction schemes 874
Periodates, redox systematics 854 855
Periodates, structural relations 873
Periodates, synthesis 872 873
Periodates, transition metal complexes 875
Periodic acids 872—875
Periodic acids, acid-base systematics 874
Periodic acids, nomenclature 872
Periodic acids, preparation 873
Periodic acids, redox systematics 854 855
Periodic acids, structural relations 873
Periodic reactions, Belousov — Zhabotinskii reactions 865 865
Periodic reactions, Bray's reaction 865
Periodic table and atomic structure 20—23
Periodic table and predictions of new elements 29—31
Periodic table, history of 20 21
Permanganates 1050 1051
Perosmate 1082 1085
Perovskite structure 963
Perovskite structure in ternary sulfides 681
Peroxo anions 638
Peroxo complexes of 616
Peroxo compounds, fluorinated 639 640
Peroxochromium complexes 637 1024
Peroxodiphosphoric acid, 512
Peroxodisulfates, 713
Peroxodisulfuric acid, 713
Peroxomonophosphoric acid, 512
Peroxomonosulfuric acid, 705 712
Peroxonitric acid, 458
Peroxonitrous acid, HOONO 459
Peroxoselenous acid 783
Peroxotellurates 783
Perrhenates 1050
Perruthenates 1082
Pertechnetate ion 1050
Perxenates, 901
pH scale 32 49
Phase rule 676
Phase-transfer catalysis 97
Phenacite 347
Phlogiston theory 30 600 601 793
Phlogopite see “Micas”
Phosgene 305
Phospha-alkenes 545
Phospha-alkynes 545
Phosphate cycles in nature 475—479
Phosphate rock, occurrence and reserves 476
Phosphate rock, phosphorus production from 480 520 525
Phosphate rock, statistics of uses 525
Phosphates see “Chain phosphates” “Cyclophosphates” “Orthophosphates” “Superphosphates” “Tripolyphosphates”
Phosphatic fertilizers 474 477—479 520 524—526
Phosphazenes 534—536
Phosphides 489—492
Phosphine, , chemical reactions 492 493
Phosphine, , comparison with , , , 557
Phosphine, , inversion frequency 493
Phosphine, , Lewis base activity 493—495
Phosphine, , molecular structure 492 493
Phosphine, , preparation 492
Phosphine, , tertiary phosphine ligands 494
Phosphinic acid see “Hypophosphorous acid”
Phosphinoboranes 211
Phosphites 513 514
Phosphonic acid see “Phosphorous acid”
Phosphonitrilic chloride 408 (see also “Polyphosphazenes”)
Phosphoramidic acid 532
Phosphorescence of arsenic 550
Phosphorescence of phosphorus 474 485
Phosphoric acid, 516 517 518—522
Phosphoric acid, , autoprotolysis 518
Phosphoric acid, , hemihydrate 518—521
Phosphoric acid, , in colas and soft drinks 520
Phosphoric acid, , industrial production 521—522
Phosphoric acid, , industrial uses 520
Phosphoric acid, , polyphosphoric acids in 522
Phosphoric acid, , proton-switch conduction in 518 598
Phosphoric acid, , self-dehydration to diphosphoric acid 518
Phosphoric acid, , self-ionization 518
Phosphoric acid, , structure 518
Phosphoric acid, , successive replacement of H in 519 521
Phosphoric acid, , trideutero 518
Phosphoric acid, , “thermal” process 521 522
Phosphoric acid, , “wet” process 520 521
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