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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
Greenwood N.N., Earnshaw A. — Chemistry of the Elements



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Íàçâàíèå: Chemistry of the Elements

Àâòîðû: Greenwood N.N., Earnshaw A.

Àííîòàöèÿ:

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.

Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.


ßçûê: en

Ðóáðèêà: Õèìèÿ/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Èçäàíèå: second edition

Ãîä èçäàíèÿ: 1997

Êîëè÷åñòâî ñòðàíèö: 1340

Äîáàâëåíà â êàòàëîã: 18.02.2007

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Nonaqueous solvent systems, $SbCl_{3}$      561 655
Nonaqueous solvent systems, $SO_{2}$      664 700 759
Nonaqueous solvent systems, HCl      819
Nonaqueous solvent systems, HF      570 816—819
Nonaqueous solvent systems, ICl      827
Nonaqueous solvent systems, superacids      570
Nonstoichiometry in chalcogenides      765 766
Nonstoichiometry in oxides      642—644
Nonstoichiometry in sulfides      679
Nuclear fission      1256
Nuclear fission, products      1257 1260
Nuclear fission, spontaneous      1253 1262
Nuclear fuels      1257—1262
Nuclear fuels, breeding      1259
Nuclear fuels, enrichment      1259
Nuclear fuels, reprocessing      1097 1260—1262
Nuclear reactions in stars      7—13
Nuclear reactors      1256—1260
Nuclear reactors, different types      1258
Nuclear reactors, natural      1257
Nuclear structure of atoms      22
Nuclear waste, storage      1257 1261
Nucleic acid and H bonding      60 62
Nucleic acid, double helix structure of      474
Nucleogenesis      2ff
Nylon-6 and -66      422
Obsidian      342
Octahedral complexes      914—916 922—923
Octahedral complexes of octahedral $d^{2}$ ions      996
Octahedral complexes of octahedral $d^{4}$ ions      1089
Octahedral complexes of tetrahedral complexes of $Ni^{II}$      1158
Octahedral complexes, distortions in      915—916 (see also “Jahn — Teller effect”)
Oddo's rule      3
Oklo phenomenon      1257
Oligomerization of acetylene      1172
Olivine      109 347
One-dimensional conductors      1156 1165
Onyx      342
Opal      342
Open-hearth process      1072
Optical activity      919 1125
Optical isomers      915 919 1125
Optical rotatory dispersion (ORD)      1125
Optically active metal cluster compound      667
Orbital contribution to magnetic moment of high-spin complexes of $Co^{II}$      1132
Orbital degeneracy      1244
Orbital quantum number, l      26
Orford process      1146
Organometallic compounds      924—943
Organometallic compounds, classification      924—925
Organometallic compounds, definition      924
Organometallic compounds, dihapto ligands      930—933
Organometallic compounds, heptahapto ligands      941
Organometallic compounds, hexahapto ligands      940—941
Organometallic compounds, monohapto ligands      925—930
Organometallic compounds, octahapto ligands      941—943
Organometallic compounds, pentahapto ligands      937—940
Organometallic compounds, tetrahapto ligands      935—937
Organometallic compounds, trihapto ligands      933—935
Orpiment      see “Arsenic sulfide
Orthonitrate ion, $NO_{4}^{3—}$      
472
Orthoperiodic acid      see “Periodic acids”
Orthophosphates      523—526
Orthophosphates, $AlPO_{4}$, structural analogy with $SiO_{2}$      526
Orthophosphates, uses of      524—525
Orthophosphoric acid      see “Phosphoric acid”
Osmates      1082
Osmiamates      1085
Osmium, abundance      1071
Osmium, anomalous atomic weight of in Re ores      19
Osmium, atomic and physical properties      1074—1075
Osmium, carbidocarbonyls      1107—1108
Osmium, carbonyl halides      1108
Osmium, carbonyl hydrides and carbonylate anions      1105—1108
Osmium, carbonyls      928 929 1104—1105
Osmium, chalcogenides      1081
Osmium, complexes with $SO_{2}$      702
Osmium, complexes, +2 oxidation state      1091—1098
Osmium, complexes, +3 oxidation state      1088—1089
Osmium, complexes, +4 oxidation state      1086—1088
Osmium, complexes, +5 oxidation state      1086
Osmium, complexes, +6 oxidation state      1085—1086
Osmium, complexes, +7 oxidation state      1085
Osmium, complexes, +8 oxidation state      1085
Osmium, coordination numbers and stereochemistries      1078
Osmium, cyclooctatetraene complex      943
Osmium, discovery      1070
Osmium, halides and oxohalides      1082—1083
Osmium, organometallic compounds      1104—1112
Osmium, oxidation states      1077 1079
Osmium, oxides      1079 1081
Osmium, oxoanions      1082
Osmium, production and uses      1072—1074
Osmium, reactivity of element      1075
Osmium, relationship with other transition elements      1075—1079
Osmium, standard reduction potentials      1077
Osmocene      937 1111
Osmyl complexes      1085 1086
Outer-sphere reactions      1124
Oxidation state, periodic trends in      27—28
Oxidation state, variability of      27 905
Oxides      640—644
Oxides, acid-base properties      628 640 641
Oxides, classification      640—642
Oxides, nonstoichiometry in      642—644
Oxides, structure types      641 753
OXO process (hydroformylation)      309 1135 1140
Oxonium ion      48
Oxovanadium (vanadyl) ion      982 995
Oxygen      see also “Dioxygen” “Ozone”
Oxygen carriers      see also “Dioxygen”
Oxygen carriers, complexes of cobalt      1132
Oxygen carriers, haemocyanin      1199
Oxygen carriers, haemoglobin and synthetic models      1098—1101
Oxygen carriers, Vaska's compound      615 617 1136 1137
Oxygen, abundance      600 602
Oxygen, allotropes      607
Oxygen, atomic      611 612
Oxygen, atomic properties      604 605
Oxygen, chemical properties      612—615
Oxygen, coordination geometries      613—615
Oxygen, crown ether compounds      95—97 124 601
Oxygen, difluoride      638
Oxygen, fluoride      638—640
Oxygen, history      600 601 604
Oxygen, industrial production      604
Oxygen, industrial uses      604
Oxygen, isotopes, separation of      604
Oxygen, liquefaction      601 604
Oxygen, liquid      601 603—604 606
Oxygen, occurrence in atmosphere, hydrosphere and lithosphere      600 602 605
Oxygen, origin of blue colour in liquid      607
Oxygen, origin of, in atmosphere      602
Oxygen, oxidation states      613
Oxygen, physical properties      605
Oxygen, preparation      603 604
Oxygen, radioactive isotopes      605
Oxygen, reduction potential, pH dependence      628—629
Oxygen, roasting of metal sulfides      676—678
Oxygen, standard reduction potentials      628 629 737
Oxyhyponitrous acid      see also“Hyponitric acid”
Ozone, $O_{3}$      see also “Chlorofluorocarbons”
Ozone, $O_{3}$, bonding      607 608
Ozone, $O_{3}$, chemical reactions      609—611 848 849
Ozone, $O_{3}$, discovery      607
Ozone, $O_{3}$, environmental implications      608 848
Ozone, $O_{3}$, hole      608
Ozone, $O_{3}$, molecular structure      607 608 708
Ozone, $O_{3}$, physical properties      607 608
Ozone, $O_{3}$, preparation      609 611
Ozonide ion, $O_{3}^{—}$      610
Ozonides (organic)      610 611
Ozonolysis      610 611 849
P-N compounds      531— 542
p-process in stars      13
p-type semiconductors      see “Semiconductor” “Transistor”
Palladium, $\pi$-allylic complexes      953 1172
Palladium, absorption of hydrogen      1150 1151
Palladium, abundance      1145
Palladium, alkene and alkyne complexes      1170—1172
Palladium, alkyls and aryls      1167 1168
Palladium, atomic and physical properties      1148—1149
Palladium, carbonyl chloride      1168
Palladium, chalcogenides      1152
Palladium, complexes, +2 oxidation state      1156—1166
Palladium, complexes, +3 oxidation state      1154 1156
Palladium, complexes, +4 oxidation state      1154
Palladium, complexes, zero oxidation state      1166—1167
Palladium, coordination numbers and stereochemistries      1150
Palladium, discovery      1144
Palladium, halides      1152—1154
Palladium, organometallic compounds      1167—1172
Palladium, oxidation states      1150
Palladium, oxides      1151 1152
Palladium, production and uses      1146 1147
Palladium, reactivity of element      1149
Paraperiodic acid      see “Periodic acids”
Parathion      509
Patronite      977
Pauli exclusion principle      22 P
Pearlite      1075
Pentaborane, $B_{5}H_{9}$      154 159 163
Pentaborane, $B_{5}H_{9}$, Bronsted acidity      171 172
Pentaborane, $B_{5}H_{9}$, chemical reactivity      171
Pentaborane, $B_{5}H_{9}$, metalloborane derivatives      171—173
Pentaborane, $B_{5}H_{9}$, preparation      165
Pentaborane, $B_{5}H_{9}$, properties      170
Pentaborane, $B_{5}H_{9}$, structure      171
Pentagonal bipyramidal complexes      916
Pentathionates, $S_{5}O_{6}^{2—}$, preparation and structure      717 718 851
Pentlandite      1145
Perbromates, $BrO_{4}^{—}$      871—872
Perbromates, $BrO_{4}^{—}$, discovery      789 871
Perbromates, $BrO_{4}^{—}$, radiochemical synthesis      871
Perbromates, $BrO_{4}^{—}$, redox systematics      854 855 872
Perbromates, $BrO_{4}^{—}$, structure      871
Perbromic acid, $HBrO_{4}$      871
Perbromyl fluoride, $FBrO_{3}$      881
Perchlorates, $ClO_{4}^{—}$      865—871
Perchlorates, $ClO_{4}^{—}$, bridging ligand      791 868—871
Perchlorates, $ClO_{4}^{—}$, chelating ligand      868—871
Perchlorates, $ClO_{4}^{—}$, coordinating ability      791 868—871 1020
Perchlorates, $ClO_{4}^{—}$, monodentate ligand      791 868—871
Perchlorates, $ClO_{4}^{—}$, production and uses      865 867
Perchlorates, $ClO_{4}^{—}$, redox systematics      854 855
Perchlorates, $ClO_{4}^{—}$, structure      868
Perchloric acid, $HClO_{4}$      865—868
Perchloric acid, $HClO_{4}$, chemical reactions      867 868
Perchloric acid, $HClO_{4}$, hydrates      867
Perchloric acid, $HClO_{4}$, physical properties      865 866
Perchloric acid, $HClO_{4}$, preparation      865 866
Perchloric acid, $HClO_{4}$, structure      868
Perchloryl fluoride, $FClO_{3}$      876 879 880
Perhalates, $XO_{4}^{—}$      854 855 865—875
Perhalic acids, $HOXO_{3}$      865—875
Periodates      872—875
Periodates, reaction schemes      874
Periodates, redox systematics      854 855
Periodates, structural relations      873
Periodates, synthesis      872 873
Periodates, transition metal complexes      875
Periodic acids      872—875
Periodic acids, acid-base systematics      874
Periodic acids, nomenclature      872
Periodic acids, preparation      873
Periodic acids, redox systematics      854 855
Periodic acids, structural relations      873
Periodic reactions, Belousov — Zhabotinskii reactions      865 865
Periodic reactions, Bray's reaction      865
Periodic table and atomic structure      20—23
Periodic table and predictions of new elements      29—31
Periodic table, history of      20 21
Permanganates      1050 1051
Perosmate      1082 1085
Perovskite structure      963
Perovskite structure in ternary sulfides      681
Peroxo anions      638
Peroxo complexes of $O_{2}$      616
Peroxo compounds, fluorinated      639 640
Peroxochromium complexes      637 1024
Peroxodiphosphoric acid, $H_{4}P_{2}O_{8}$      512
Peroxodisulfates, $S_{2}O_{8}^{2—}$      713
Peroxodisulfuric acid, $H_{2}S_{2}O_{8}$      713
Peroxomonophosphoric acid, $H_{3}PO_{5}$      512
Peroxomonosulfuric acid, $H_{2}SO_{5}$      705 712
Peroxonitric acid, $HOONO_{2}$      458
Peroxonitrous acid, HOONO      459
Peroxoselenous acid      783
Peroxotellurates      783
Perrhenates      1050
Perruthenates      1082
Pertechnetate ion      1050
Perxenates, $XeO_{6}^{4—}$      901
pH scale      32 49
Phase rule      676
Phase-transfer catalysis      97
Phenacite      347
Phlogiston theory      30 600 601 793
Phlogopite      see “Micas”
Phosgene      305
Phospha-alkenes      545
Phospha-alkynes      545
Phosphate cycles in nature      475—479
Phosphate rock, occurrence and reserves      476
Phosphate rock, phosphorus production from      480 520 525
Phosphate rock, statistics of uses      525
Phosphates      see “Chain phosphates” “Cyclophosphates” “Orthophosphates” “Superphosphates” “Tripolyphosphates”
Phosphatic fertilizers      474 477—479 520 524—526
Phosphazenes      534—536
Phosphides      489—492
Phosphine, $PH_{3}$, chemical reactions      492 493
Phosphine, $PH_{3}$, comparison with $NH_{3}$, $AsH_{3}$, $SbH_{3}$, $BiH_{3}$      557
Phosphine, $PH_{3}$, inversion frequency      493
Phosphine, $PH_{3}$, Lewis base activity      493—495
Phosphine, $PH_{3}$, molecular structure      492 493
Phosphine, $PH_{3}$, preparation      492
Phosphine, $PH_{3}$, tertiary phosphine ligands      494
Phosphinic acid      see “Hypophosphorous acid”
Phosphinoboranes      211
Phosphites      513 514
Phosphonic acid      see “Phosphorous acid”
Phosphonitrilic chloride $(NPCl_{2})_{X}$      408 (see also “Polyphosphazenes”)
Phosphoramidic acid      532
Phosphorescence of arsenic      550
Phosphorescence of phosphorus      474 485
Phosphoric acid, $H_{3}PO_{4}$      516 517 518—522
Phosphoric acid, $H_{3}PO_{4}$, autoprotolysis      518
Phosphoric acid, $H_{3}PO_{4}$, hemihydrate      518—521
Phosphoric acid, $H_{3}PO_{4}$, in colas and soft drinks      520
Phosphoric acid, $H_{3}PO_{4}$, industrial production      521—522
Phosphoric acid, $H_{3}PO_{4}$, industrial uses      520
Phosphoric acid, $H_{3}PO_{4}$, polyphosphoric acids in      522
Phosphoric acid, $H_{3}PO_{4}$, proton-switch conduction in      518 598
Phosphoric acid, $H_{3}PO_{4}$, self-dehydration to diphosphoric acid      518
Phosphoric acid, $H_{3}PO_{4}$, self-ionization      518
Phosphoric acid, $H_{3}PO_{4}$, structure      518
Phosphoric acid, $H_{3}PO_{4}$, successive replacement of H in      519 521
Phosphoric acid, $H_{3}PO_{4}$, trideutero      518
Phosphoric acid, $H_{3}PO_{4}$, “thermal” process      521 522
Phosphoric acid, $H_{3}PO_{4}$, “wet” process      520 521
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