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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
Greenwood N.N., Earnshaw A. — Chemistry of the Elements



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Íàçâàíèå: Chemistry of the Elements

Àâòîðû: Greenwood N.N., Earnshaw A.

Àííîòàöèÿ:

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.

Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.


ßçûê: en

Ðóáðèêà: Õèìèÿ/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Èçäàíèå: second edition

Ãîä èçäàíèÿ: 1997

Êîëè÷åñòâî ñòðàíèö: 1340

Äîáàâëåíà â êàòàëîã: 18.02.2007

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Cadmium iodide structure type, relation to NiAs      556 680 680
Cadmium, abundance      1204
Cadmium, chalcogenides      1208 1210
Cadmium, coordination chemistry      1215—1217
Cadmium, discovery      1201
Cadmium, halides      1211—1212
Cadmium, organometallic compounds      1221
Cadmium, oxides      1211 1212
Cadmium, production and uses      1202—120
Cadmium, toxicity      1224 see
Caesium, abundance      70
Caesium, compounds with oxygen      83—86
Caesium, discovery      69
Calamine (smithsonite)      1202
Calcite      109
Calcium      see “Alkaline earth metals” “Lime” etc.
Calcium in biochemical processes      125
Calcium, carbide      297 298 320
Calcium, carbonate      see “Limestone”
Calcium, cyclopentadienyl      136 137
Calcium, history of      108
Calcium, organometallic compounds      136 137
Calcium, phosphates      524—526
Caliche (Chilean nitre)      796
Californium      1252 1262 see
Calomel      1213
Capped octahedral complexes      916
Capped trigonal prismatic complex      916
Caprolactam, for nylon—6      422
Carat      272 1176
Carbaboranes      see “Carboranes”
Carbene ligands      929
Carbides      297—301
Carbides, silicon (SiC)      334
Carbido complexes      927 1107—1108
Carbohydrates, photosyntheses of      125
Carbon dioxide      305 314
Carbon dioxide in photosynthesis      125
Carbon dioxide, aqueous solutions (acidity of)      309 310
Carbon dioxide, asaligand      312 313
Carbon dioxide, atmospheric      273—274
Carbon dioxide, coordination chemistry      312
Carbon dioxide, industrial importance      307 308
Carbon dioxide, insertion into M-C bonds      134 312
Carbon dioxide, physical properties      305
Carbon dioxide, production and uses of      311
Carbon dioxide, use in $\mathrm{^{l4}C}$ syntheses      310
Carbon monoxide      305—310
Carbon monoxide, as a ligand      926—929
Carbon monoxide, bonding in      926 927
Carbon monoxide, chemical reactions      306 308
Carbon monoxide, industrial importance      307
Carbon monoxide, physical properties      306
Carbon monoxide, poisoning effect of      306 1101
Carbon monoxide, preparation of pure      306
Carbon monoxide, similarity to $\mathrm{PF_3}$ as a ligand      496
Carbon, abundance      270
Carbon, allotropes      274—278 see
Carbon, atomic properties      276 372—372
Carbon, chalcogenides      314—319
Carbon, chemical properties      289
Carbon, coordination numbers      290. 291 292
Carbon, cycle (global)      273
Carbon, disulfide      313—318 653
Carbon, halides      301 304
Carbon, history of      268—270
Carbon, hond lengths (interatomic distances)      290 292
Carbon, hydrides of      301
Carbon, interatomic distances in compounds      290—292
Carbon, occurrence and distribution      270—274
Carbon, oxides      305 see “Carbon
Carbon, radioactive $\mathrm{^{14}C}$      276
Carbon, suboxides      305
Carbon, “monofluoride”      289
Carbonates, terrestrial distribution      274 273
Carbonic acid      310
Carbonic anhydrase      1225
Carbonyl fluoride, reaction with OF2      640
Carbonyl halides      see “Carhon oxohalides”
Carbonyls      see “Carbon monoxide as a ligand” see
Carboplatin      1165
Carborundum      see “Silicon carhide”
Carbosilanes      362
Carbyne ligands      928—930
Carhoranes      161 181
Carhoranes, bonding      181
Carhoranes, chemical reactions      186 189
Carhoranes, isomerization      185—187
Carhoranes, preparation      181—185
Carhoranes, structures      181 185
Carhoxypeptidase A      1224
Carnotite      977
Caro's acid      see “Peroxomonosulfuric acid”
Cassiterite      see “Tin dioxide”
Cast-iron      1071
Castner — Kellner process (chlor-alkali)      790 1203
Catalysis      see “Catalysts”
Catalysis, $\mathrm{CS_2}$, chlorination by $\mathrm{Fe/FeCl_3}$ and by $\mathrm{I_2}$      317
Catalysis, $\mathrm{CS_2}$, chlorination by $\mathrm{Fe/FeCl_3}$ and by $\mathrm{I_2}$ synthesis by $\mathrm{SiO_2}$ or $\mathrm{Al_2O_3}$      317
Catalysis, $\mathrm{C_6O}$, hydroxylation by base      284
Catalysis, $\mathrm{H_2}$, ortho-para conversion by paramagnetic species      35
Catalysis, $\mathrm{O_2}$, preparation from $\mathrm{H_2O_2}$      603
Catalysis, $\mathrm{S_4N_4}$, depolymenzation to $\mathrm{2S_2N_2}$ by $\mathrm{Ag_2S}$      725
Catalysis, ammonia(1)/metal solutions, effects of impurities      78
Catalysis, ammonia, oxidation to NO, $\mathrm{NO_2}$      423 465 466
Catalysis, C-H bonds, homogeneous catalytic activity of      494
Catalysis, C-N-o cycle in stars      9
Catalysis, carhonylation of $\mathrm{B_{12}H_{12}^{2-}}      180
Catalysis, chlorination of organic compounds hy CuCl      798
Catalysis, chlorination of organic compounds hy CuCl, $\mathrm{SO_2}$ to $\mathrm{O_2SCl_2}$ by c or $\mathrm{PeCl_3}$      694
Catalysis, chlorination of organic compounds hy CuCl, $\mathrm{S_2Cl_2}$ to $\mathrm{SCl_2}$ hy $\mathrm{FeCl_3}$      689
Catalysis, chlorination of organic compounds hy CuCl, SiC to $\mathrm{SiCl_4}$ by $\mathrm{NiCl_2}$      811
Catalysis, claus process for recovery of S from $\mathrm{H_2S}$      651 699
Catalysis, CO, organic reactions of      309
Catalysis, conjuncto boranes, preparation of      162
Catalysis, contact process for $\mathrm{H_2SO_4}$      646 700 708 981
Catalysis, Fischer-Tropsch process      309 1106
Catalysis, fluorination of ammonia by Cu      439
Catalysis, fluorination of ammonia by Cu $\mathrm{SOF_2}$ by CsF      685
Catalysis, fluorination of ammonia by Cu $\mathrm{SO_3}$ by AgF      640
Catalysis, fluorination of ammonia by Cu graphite by acid      289
Catalysis, graphite$\to$diamond transition by molten metals      278
Catalysis, HCN, production of      321
Catalysis, hydrazine, decomposition by heavy metals      428
Catalysis, hydrodesulfurization (HDS) by Mo compounds      1005
Catalysis, hydroformylation of alkenes      309 593 1135 1140
Catalysis, hydrogen ation by metal hydrides      47
Catalysis, hydrogen peroxide, decomposition of      635
Catalysis, hydrogen peroxide, production of      634
Catalysis, hydrogenation of alkenes      1134—1135
Catalysis, hydrogenation of alkenes, NO by Pt/charcoal      431
Catalysis, hydrogenation of alkenes, unsaturated organic compounds      38 43 1146
Catalysis, hypohalous acids, decomposition of      858
Catalysis, hyponitrous acid (HONNOH), base decomposition of      460
Catalysis, nitramide ($\mathrm{H_2HNO_2}$), base decomposition of      459
Catalysis, organotin compounds, synthesis of      399
Catalysis, oxidation of $\mathrm{SF_4}$ by $\mathrm{O_2/NO_2}$      687
Catalysis, oxidation of $\mathrm{SF_4}$ by $\mathrm{O_2/NO_2}$, $\mathrm{SO_2}$      700 708
Catalysis, phase transfer catalysis by Br-containing, compounds      794
Catalysis, phase transfer catalysis by Br-containing, cryptands      97
Catalysis, propene, dimerization by $\mathrm{AlPr_3^n}      260
Catalysis, Reppe synthesis by $\mathrm{Ni^{II}}$ complexes      309 1167 1172
Catalysis, silanes, formation by Cu      338 363
Catalysis, silanes, formation by Cu, hydrolysis by base      339
Catalysis, silanes, formation by Cusilicone polymers, cross linking of      365
Catalysis, steam-hydrocarbon reforming process      39 421
Catalysis, synthesis (Haher-Bosch)      43 421—422
Catalysis, Wacker process by $\mathrm{PdCl_2/CuCl_2}$      1172
Catalysis, water-gas shift reaction      38—39 311 421 1106
Catalysis, “clock” reactions, autocatalysis      864
Catalysts      see “Catalysis”
Catalysts, $\mathrm{BF_3}$      199 200 686
Catalysts, $\mathrm{I_2}$      317 508 800
Catalysts, $\mathrm{MoS_2}$ in hydrogenations      1018
Catalysts, $\mathrm{N_2O_5}$ in decomposition of ozone      458
Catalysts, $\mathrm{Ph_3PO}$ as an o atom transfer catalyst      504
Catalysts, $\mathrm{SbFCl_4}$ in fluorinations      304
Catalysts, $\mathrm{V_2O_5}$      708 981
Catalysts, alumina (activated)      243 245
Catalysts, carbon (activated)      274 305 321 694
Catalysts, carbonyl complexes of metals      309 593 1106 1135 1142
Catalysts, crown ethers in synthesis of organoantimony compounds      596
Catalysts, dithiolato complexes in polymerizations and oxidations      674
Catalysts, Friedel Crafts      171 176 186 199 235—236 338 385
Catalysts, HBr      812
Catalysts, HCl in hydrolysis of glucose      812
Catalysts, heteropolymetallates in petrochemical industry      1014
Catalysts, HF      200 810
Catalysts, Ir      321 1115
Catalysts, lanthanide oxides      1232
Catalysts, metalloenzymes in biological systems      1138
Catalysts, NEt3 in malathion production      509
Catalysts, Ni, Pd, Pt      43 321 421 431 603 634 646 810 1148
Catalysts, NO complexes in homogeneous catalysis      450 452
Catalysts, nonstoichiomeiric oxides in heterogeneous catalysis      644
Catalysts, organotin compounds for polyurethanes      400
Catalysts, Pi/Re for lead-free petroleum products      1043
Catalysts, polymerization catalysts      105 200 229
Catalysts, polyphosphoric acid in petrochemical processes      520
Catalysts, Rh      321 1115
Catalysts, tin oxide systems      385
Catalysts, Vaska's compound      615 1135—1136
Catalysts, Wilkinson's catalyst      43 1134—1135
Catalysts, zeolites      309 359
Catalysts, Zielgter — Natta catalysts      260 261 972
Catalysts, “magic acid” in organic catalytic processes      570
Catena-$\mathrm{S_8}$ diradical      660 662
Catena-$\mathrm{S_x}$      656 659
Catena-$\mathrm{S_x}$, formation at $\lambda$ point      660
Catenation in Group 14 elements      374 402
Caustic soda      see “Sodium hydroxide”
Cellophane      317
Cement      251 252
Cementite      1075
Cerium      1229 see
Cerium, +4 oxidation state      1236 1239 1244
Cerium, diiodide      1240
Cerium, production      1230
Chabazite      see “Zeolites”
Chain polyphosphates      526—529 see “Sodium “Graham's “Kurrol's “Maddrell's
Chain polyphosphates, diphosphates      526
Chain polyphosphates, tripolyphosphates      528 528
Chain reactions, nuclear      1256 1261
Chalcocite (copper glance)      1174
Chalcogens, group trends      754—759 see Se Te Ðo
Chalcophile elements      646. 648
Chalcopyrite (copper pyrite) $\mathrm{CuFeS_2}$      649 1174 1365
Chaoite      275 276
Chelate effect      910—911
Chelation      906 910
Chemical periodicity      20
Chemical properties of the elements, periodic trends in      23
Chemical shear structures      644 see Mo W Re etc.
Chemiluminebcence of phosphorus      483
Chernobyl, nuclear reactor disaster      146
Chevrel phases      1018 1031
Chile saltpetre      407 see
Chlorates, $\mathrm{ClO_3^-}$      862—865
Chlorates, $\mathrm{ClO_3^-}$, redox properties      1001 1002
Chloric acid, $\mathrm{HclO_3}$      863
Chlorides, synthesis of      821 822 see
Chlorin      126
Chlorine      see “Halogens”
Chlorine, abundance and distribution      795
Chlorine, atomic and physical properties      800—804
Chlorine, cations $\mathrm{Cl_2^+}$, $\mathrm{cl_3^+}$      842 843
Chlorine, dioxide, cÞ2      844 845 846—848
Chlorine, history      790—793
Chlorine, hleaching power      790 793
Chlorine, hydrate      790
Chlorine, monofluorides      824—827 832
Chlorine, oxide fluorides      875—880
Chlorine, oxides      844—850
Chlorine, oxoacids and oxoacid salts      853
Chlorine, oxoacids and oxoacid salts, nomenclature      853
Chlorine, oxoacids and oxoacid salts, redox properties      853—855 see “Hypochlorous “Hypochlorites” “Chlorous etc.
Chlorine, penrafluoride      832—834
Chlorine, production and uses      797—798
Chlorine, radioactive isotopes      801 802
Chlorine, reactivity      805
Chlorine, standard reduction potentials      850
Chlorine, stereochemistry      806
Chlorine, toxicity      793
Chlorine, trifluoride      827—830 852
Chlorine, volt equivalent diagram      855
Chlorite      355 357 413
Chlorites, $\mathrm{CLO_2^-}$      854 855 859—862 1002 1007—1009
Chlorofluorocarbons      608 793 848
Chlorophylls      109 125—127
Chloroplatinic acid      1154
Chlorosulfanes      see “Sulfur chlorides”
Chlorous acid, $\mathrm{HClO_2}$      854. 855 859 861
Chromate alum      1028
Chromateion      1009 1024 1193
Chrome ochre      1003
Chromic acid      1007
Chromite      1003
Chromium, abundance      1003
Chromium, bis(cyclopentadienyl)      939. 1038
Chromium, borazine complex      210
Chromium, carbonyls      928—929 1037
Chromium, carbyne complexes      929
Chromium, chalcogenides      680 1017 1018
Chromium, complexes, +2 oxidation state      1031—1035
Chromium, complexes, +3 oxidation state      1027—1031
Chromium, complexes, +4 oxidation state      1025—1027
Chromium, complexes, +5 oxidation state      1024—1025
Chromium, complexes, +6 oxidation state      1023—1024
Chromium, complexes, with S      666
Chromium, compounds with quadruple metal-metal bonds      1032—1034
Chromium, cyclooctatetraene complex      943
Chromium, cyclopentadienyls      939 1037
Chromium, dibenzene “sandwich” compound      940 1039
Chromium, discovery      1002
Chromium, dithiolene complex redox series      675
Chromium, halides and oxohalides      1019—1023
Chromium, hexacarhonyl      928. 1037
Chromium, importance of $\mathrm{Cr^{III}}$ in early coordination chemistry      914 1027
Chromium, organometallic compounds      371 373—375 1207—1210
Chromium, oxides      1007—1009
Chromium, peroxo complexes      636. 637
Chromium, polynuclear complexes in dyeing and tanning      1030
Chromium, production and uses      1003
Chromium, sulfides, nonstoic biometry in      679 see
Chromium, “polyphenyl” compounds      940
Chromocene      1038
Chrysotile      351 352 357
Cinnabar (vermillion}, HgS      649 1202 1210
Circular dichroism (CD)      1125
Cisplalin      1164
Class-a and class-b metal ions      909 see
Clathrate compounds      893 1161
Claus process (S from $\mathrm{H_2S}$)      651 652 699
Claus process (S from $\mathrm{H_2S}$), uses of      356
Clock reaction (H. Landolt)      864
Cluster and cage structure      918 see
Cluster compounds of germanium, tin and lead      383 392 396 455—458
Cluster compounds of indium      256—257
Cluster compounds, $\mathrm{Te_6^{4+}}$      161 761
Cluster compounds, boranes incorporating P, As or Sh      212
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