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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Íàçâàíèå: Chemistry of the Elements
Àâòîðû: Greenwood N.N., Earnshaw A.
Àííîòàöèÿ: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Èçäàíèå: second edition
Ãîä èçäàíèÿ: 1997
Êîëè÷åñòâî ñòðàíèö: 1340
Äîáàâëåíà â êàòàëîã: 18.02.2007
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Cadmium iodide structure type, relation to NiAs 556 680 680
Cadmium, abundance 1204
Cadmium, chalcogenides 1208 1210
Cadmium, coordination chemistry 1215—1217
Cadmium, discovery 1201
Cadmium, halides 1211—1212
Cadmium, organometallic compounds 1221
Cadmium, oxides 1211 1212
Cadmium, production and uses 1202—120
Cadmium, toxicity 1224 see
Caesium, abundance 70
Caesium, compounds with oxygen 83—86
Caesium, discovery 69
Calamine (smithsonite) 1202
Calcite 109
Calcium see “Alkaline earth metals” “Lime” etc.
Calcium in biochemical processes 125
Calcium, carbide 297 298 320
Calcium, carbonate see “Limestone”
Calcium, cyclopentadienyl 136 137
Calcium, history of 108
Calcium, organometallic compounds 136 137
Calcium, phosphates 524—526
Caliche (Chilean nitre) 796
Californium 1252 1262 see
Calomel 1213
Capped octahedral complexes 916
Capped trigonal prismatic complex 916
Caprolactam, for nylon—6 422
Carat 272 1176
Carbaboranes see “Carboranes”
Carbene ligands 929
Carbides 297—301
Carbides, silicon (SiC) 334
Carbido complexes 927 1107—1108
Carbohydrates, photosyntheses of 125
Carbon dioxide 305 314
Carbon dioxide in photosynthesis 125
Carbon dioxide, aqueous solutions (acidity of) 309 310
Carbon dioxide, asaligand 312 313
Carbon dioxide, atmospheric 273—274
Carbon dioxide, coordination chemistry 312
Carbon dioxide, industrial importance 307 308
Carbon dioxide, insertion into M-C bonds 134 312
Carbon dioxide, physical properties 305
Carbon dioxide, production and uses of 311
Carbon dioxide, use in syntheses 310
Carbon monoxide 305—310
Carbon monoxide, as a ligand 926—929
Carbon monoxide, bonding in 926 927
Carbon monoxide, chemical reactions 306 308
Carbon monoxide, industrial importance 307
Carbon monoxide, physical properties 306
Carbon monoxide, poisoning effect of 306 1101
Carbon monoxide, preparation of pure 306
Carbon monoxide, similarity to as a ligand 496
Carbon, abundance 270
Carbon, allotropes 274—278 see
Carbon, atomic properties 276 372—372
Carbon, chalcogenides 314—319
Carbon, chemical properties 289
Carbon, coordination numbers 290. 291 292
Carbon, cycle (global) 273
Carbon, disulfide 313—318 653
Carbon, halides 301 304
Carbon, history of 268—270
Carbon, hond lengths (interatomic distances) 290 292
Carbon, hydrides of 301
Carbon, interatomic distances in compounds 290—292
Carbon, occurrence and distribution 270—274
Carbon, oxides 305 see “Carbon
Carbon, radioactive 276
Carbon, suboxides 305
Carbon, “monofluoride” 289
Carbonates, terrestrial distribution 274 273
Carbonic acid 310
Carbonic anhydrase 1225
Carbonyl fluoride, reaction with OF2 640
Carbonyl halides see “Carhon oxohalides”
Carbonyls see “Carbon monoxide as a ligand” see
Carboplatin 1165
Carborundum see “Silicon carhide”
Carbosilanes 362
Carbyne ligands 928—930
Carhoranes 161 181
Carhoranes, bonding 181
Carhoranes, chemical reactions 186 189
Carhoranes, isomerization 185—187
Carhoranes, preparation 181—185
Carhoranes, structures 181 185
Carhoxypeptidase A 1224
Carnotite 977
Caro's acid see “Peroxomonosulfuric acid”
Cassiterite see “Tin dioxide”
Cast-iron 1071
Castner — Kellner process (chlor-alkali) 790 1203
Catalysis see “Catalysts”
Catalysis, , chlorination by and by 317
Catalysis, , chlorination by and by synthesis by or 317
Catalysis, , hydroxylation by base 284
Catalysis, , ortho-para conversion by paramagnetic species 35
Catalysis, , preparation from 603
Catalysis, , depolymenzation to by 725
Catalysis, ammonia(1)/metal solutions, effects of impurities 78
Catalysis, ammonia, oxidation to NO, 423 465 466
Catalysis, C-H bonds, homogeneous catalytic activity of 494
Catalysis, C-N-o cycle in stars 9
Catalysis, carhonylation of $\mathrm{B_{12}H_{12}^{2-}} 180
Catalysis, chlorination of organic compounds hy CuCl 798
Catalysis, chlorination of organic compounds hy CuCl, to by c or 694
Catalysis, chlorination of organic compounds hy CuCl, to hy 689
Catalysis, chlorination of organic compounds hy CuCl, SiC to by 811
Catalysis, claus process for recovery of S from 651 699
Catalysis, CO, organic reactions of 309
Catalysis, conjuncto boranes, preparation of 162
Catalysis, contact process for 646 700 708 981
Catalysis, Fischer-Tropsch process 309 1106
Catalysis, fluorination of ammonia by Cu 439
Catalysis, fluorination of ammonia by Cu by CsF 685
Catalysis, fluorination of ammonia by Cu by AgF 640
Catalysis, fluorination of ammonia by Cu graphite by acid 289
Catalysis, graphite diamond transition by molten metals 278
Catalysis, HCN, production of 321
Catalysis, hydrazine, decomposition by heavy metals 428
Catalysis, hydrodesulfurization (HDS) by Mo compounds 1005
Catalysis, hydroformylation of alkenes 309 593 1135 1140
Catalysis, hydrogen ation by metal hydrides 47
Catalysis, hydrogen peroxide, decomposition of 635
Catalysis, hydrogen peroxide, production of 634
Catalysis, hydrogenation of alkenes 1134—1135
Catalysis, hydrogenation of alkenes, NO by Pt/charcoal 431
Catalysis, hydrogenation of alkenes, unsaturated organic compounds 38 43 1146
Catalysis, hypohalous acids, decomposition of 858
Catalysis, hyponitrous acid (HONNOH), base decomposition of 460
Catalysis, nitramide ( ), base decomposition of 459
Catalysis, organotin compounds, synthesis of 399
Catalysis, oxidation of by 687
Catalysis, oxidation of by , 700 708
Catalysis, phase transfer catalysis by Br-containing, compounds 794
Catalysis, phase transfer catalysis by Br-containing, cryptands 97
Catalysis, propene, dimerization by $\mathrm{AlPr_3^n} 260
Catalysis, Reppe synthesis by complexes 309 1167 1172
Catalysis, silanes, formation by Cu 338 363
Catalysis, silanes, formation by Cu, hydrolysis by base 339
Catalysis, silanes, formation by Cusilicone polymers, cross linking of 365
Catalysis, steam-hydrocarbon reforming process 39 421
Catalysis, synthesis (Haher-Bosch) 43 421—422
Catalysis, Wacker process by 1172
Catalysis, water-gas shift reaction 38—39 311 421 1106
Catalysis, “clock” reactions, autocatalysis 864
Catalysts see “Catalysis”
Catalysts, 199 200 686
Catalysts, 317 508 800
Catalysts, in hydrogenations 1018
Catalysts, in decomposition of ozone 458
Catalysts, as an o atom transfer catalyst 504
Catalysts, in fluorinations 304
Catalysts, 708 981
Catalysts, alumina (activated) 243 245
Catalysts, carbon (activated) 274 305 321 694
Catalysts, carbonyl complexes of metals 309 593 1106 1135 1142
Catalysts, crown ethers in synthesis of organoantimony compounds 596
Catalysts, dithiolato complexes in polymerizations and oxidations 674
Catalysts, Friedel Crafts 171 176 186 199 235—236 338 385
Catalysts, HBr 812
Catalysts, HCl in hydrolysis of glucose 812
Catalysts, heteropolymetallates in petrochemical industry 1014
Catalysts, HF 200 810
Catalysts, Ir 321 1115
Catalysts, lanthanide oxides 1232
Catalysts, metalloenzymes in biological systems 1138
Catalysts, NEt3 in malathion production 509
Catalysts, Ni, Pd, Pt 43 321 421 431 603 634 646 810 1148
Catalysts, NO complexes in homogeneous catalysis 450 452
Catalysts, nonstoichiomeiric oxides in heterogeneous catalysis 644
Catalysts, organotin compounds for polyurethanes 400
Catalysts, Pi/Re for lead-free petroleum products 1043
Catalysts, polymerization catalysts 105 200 229
Catalysts, polyphosphoric acid in petrochemical processes 520
Catalysts, Rh 321 1115
Catalysts, tin oxide systems 385
Catalysts, Vaska's compound 615 1135—1136
Catalysts, Wilkinson's catalyst 43 1134—1135
Catalysts, zeolites 309 359
Catalysts, Zielgter — Natta catalysts 260 261 972
Catalysts, “magic acid” in organic catalytic processes 570
Catena- diradical 660 662
Catena- 656 659
Catena- , formation at point 660
Catenation in Group 14 elements 374 402
Caustic soda see “Sodium hydroxide”
Cellophane 317
Cement 251 252
Cementite 1075
Cerium 1229 see
Cerium, +4 oxidation state 1236 1239 1244
Cerium, diiodide 1240
Cerium, production 1230
Chabazite see “Zeolites”
Chain polyphosphates 526—529 see “Sodium “Graham's “Kurrol's “Maddrell's
Chain polyphosphates, diphosphates 526
Chain polyphosphates, tripolyphosphates 528 528
Chain reactions, nuclear 1256 1261
Chalcocite (copper glance) 1174
Chalcogens, group trends 754—759 see Se Te Ðo
Chalcophile elements 646. 648
Chalcopyrite (copper pyrite) 649 1174 1365
Chaoite 275 276
Chelate effect 910—911
Chelation 906 910
Chemical periodicity 20
Chemical properties of the elements, periodic trends in 23
Chemical shear structures 644 see Mo W Re etc.
Chemiluminebcence of phosphorus 483
Chernobyl, nuclear reactor disaster 146
Chevrel phases 1018 1031
Chile saltpetre 407 see
Chlorates, 862—865
Chlorates, , redox properties 1001 1002
Chloric acid, 863
Chlorides, synthesis of 821 822 see
Chlorin 126
Chlorine see “Halogens”
Chlorine, abundance and distribution 795
Chlorine, atomic and physical properties 800—804
Chlorine, cations , 842 843
Chlorine, dioxide, cÞ2 844 845 846—848
Chlorine, history 790—793
Chlorine, hleaching power 790 793
Chlorine, hydrate 790
Chlorine, monofluorides 824—827 832
Chlorine, oxide fluorides 875—880
Chlorine, oxides 844—850
Chlorine, oxoacids and oxoacid salts 853
Chlorine, oxoacids and oxoacid salts, nomenclature 853
Chlorine, oxoacids and oxoacid salts, redox properties 853—855 see “Hypochlorous “Hypochlorites” “Chlorous etc.
Chlorine, penrafluoride 832—834
Chlorine, production and uses 797—798
Chlorine, radioactive isotopes 801 802
Chlorine, reactivity 805
Chlorine, standard reduction potentials 850
Chlorine, stereochemistry 806
Chlorine, toxicity 793
Chlorine, trifluoride 827—830 852
Chlorine, volt equivalent diagram 855
Chlorite 355 357 413
Chlorites, 854 855 859—862 1002 1007—1009
Chlorofluorocarbons 608 793 848
Chlorophylls 109 125—127
Chloroplatinic acid 1154
Chlorosulfanes see “Sulfur chlorides”
Chlorous acid, 854. 855 859 861
Chromate alum 1028
Chromateion 1009 1024 1193
Chrome ochre 1003
Chromic acid 1007
Chromite 1003
Chromium, abundance 1003
Chromium, bis(cyclopentadienyl) 939. 1038
Chromium, borazine complex 210
Chromium, carbonyls 928—929 1037
Chromium, carbyne complexes 929
Chromium, chalcogenides 680 1017 1018
Chromium, complexes, +2 oxidation state 1031—1035
Chromium, complexes, +3 oxidation state 1027—1031
Chromium, complexes, +4 oxidation state 1025—1027
Chromium, complexes, +5 oxidation state 1024—1025
Chromium, complexes, +6 oxidation state 1023—1024
Chromium, complexes, with S 666
Chromium, compounds with quadruple metal-metal bonds 1032—1034
Chromium, cyclooctatetraene complex 943
Chromium, cyclopentadienyls 939 1037
Chromium, dibenzene “sandwich” compound 940 1039
Chromium, discovery 1002
Chromium, dithiolene complex redox series 675
Chromium, halides and oxohalides 1019—1023
Chromium, hexacarhonyl 928. 1037
Chromium, importance of in early coordination chemistry 914 1027
Chromium, organometallic compounds 371 373—375 1207—1210
Chromium, oxides 1007—1009
Chromium, peroxo complexes 636. 637
Chromium, polynuclear complexes in dyeing and tanning 1030
Chromium, production and uses 1003
Chromium, sulfides, nonstoic biometry in 679 see
Chromium, “polyphenyl” compounds 940
Chromocene 1038
Chrysotile 351 352 357
Cinnabar (vermillion}, HgS 649 1202 1210
Circular dichroism (CD) 1125
Cisplalin 1164
Class-a and class-b metal ions 909 see
Clathrate compounds 893 1161
Claus process (S from ) 651 652 699
Claus process (S from ), uses of 356
Clock reaction (H. Landolt) 864
Cluster and cage structure 918 see
Cluster compounds of germanium, tin and lead 383 392 396 455—458
Cluster compounds of indium 256—257
Cluster compounds, 161 761
Cluster compounds, boranes incorporating P, As or Sh 212
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