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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Íàçâàíèå: Chemistry of the Elements
Àâòîðû: Greenwood N.N., Earnshaw A.
Àííîòàöèÿ: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Ðóáðèêà: Õèìèÿ /
Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Èçäàíèå: second edition
Ãîä èçäàíèÿ: 1997
Êîëè÷åñòâî ñòðàíèö: 1340
Äîáàâëåíà â êàòàëîã: 18.02.2007
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Phosphoric triamide 532
Phosphorus acid, 512 514
Phosphorus oxoacids 510—531 (see also “Phosphoric acid” “Phosphates”)
Phosphorus oxoacids, lower oxoacids 516—517
Phosphorus oxoacids, nomenclature 511—512 517
Phosphorus oxoacids, standard reduction potentials 513
Phosphorus oxoacids, structural principles 510—512 517
Phosphorus oxoacids, volt-equivalent diagram 513
Phosphorus pentahalides 495 498—501
Phosphorus pentahalides, ammonolysis of with liquid 535
Phosphorus pentahalides, fluxionality of 498
Phosphorus pentahalides, industrial production of 500
Phosphorus pentahalides, ionic and covalent forms 498—501 537
Phosphorus pentahalides, mixed pentahalides 499
Phosphorus pentahalides, organo derivatives 499—501
Phosphorus pentahalides, reactions of with -diphosphazenes 535
Phosphorus pentahalides, structural isomerism 499 500
Phosphorus tribromide 496 497 500
Phosphorus trichloride, chemical reactions 497
Phosphorus trichloride, hydrolysis to phosphates 514
Phosphorus trichloride, industrial production 496
Phosphorus trichloride, organophosphorus derivatives 496 497 514
Phosphorus trifluoride 495 496
Phosphorus trifluoride as a poison 1101
Phosphorus trifluoride, similarity to CO as ligand 496
Phosphorus triiodide 495 497
Phosphorus, abundance and distribution 475
Phosphorus, allotropes 473 474 479—483
Phosphorus, alloys 492
Phosphorus, atomic propertie 482—483
Phosphorus, black allotropes 481—483 551
Phosphorus, bond energies 483
Phosphorus, catenation 473 483 485
Phosphorus, chemical reactivity 483 578
Phosphorus, cluster anions 491 588
Phosphorus, coordination geometries 483
Phosphorus, disproportionation in aqueous solutions 511—513
Phosphorus, encapsulated 554
Phosphorus, fertilizers 474 477—479 520 604
Phosphorus, halides 495
Phosphorus, history 473 474
Phosphorus, Hittorf's violet allotrope 481
Phosphorus, hydrides 492—495 (see also “Phosphine”)
Phosphorus, mixed halides 495
Phosphorus, multiple bond formation 473
Phosphorus, organic compounds 542—546
Phosphorus, oxides 503—506 (see also “Phosphorus trioxide” “Phosphorus
Phosphorus, oxohalides 501 502
Phosphorus, oxosulfides 507
Phosphorus, pentaphenyl 545
Phosphorus, peroxide, 506
Phosphorus, production and uses 479 480 520 525
Phosphorus, pseudohalides 495 501
Phosphorus, radioactive 482
Phosphorus, red, amorphous 481 482 483
Phosphorus, stereochemistry 485—486
Phosphorus, sulfides 506—509
Phosphorus, sulfides, industrial uses of 509
Phosphorus, sulfides, organic derivatives 509
Phosphorus, sulfides, physical properties 507
Phosphorus, sulfides, stoichiometry 506
Phosphorus, sulfides, structures 507
Phosphorus, sulfides, synthesis 506 508
Phosphorus, thiohalides 498 501—503 508
Phosphorus, triangulo- - species 587 588
Phosphorus, white, - 480—481 483 551
Phosphorus, ylides 545
Phosphoryl, halides, 502
Phosphoryl, pseudohalides 501
Photographic image intensification with 662
Photographic process 790 1185—1187
Photosynthesis see also “Chlorophylls”
Photosynthesis as origin of atmospheric 602
Photosynthesis, tracer experiments 601 602
Photosynthesis, manganese in 1061
Photosynthesis, NADP in 125
Photosystem II 1056 1061
Phyllo-silicates 347 349—354
Physical properties, periodic trends in 23
Piezoelectricity 58 345
Pig-iron 1072
Pitchblende 1250 1255
Plagioclase see “Feldspars”
Plaster of Paris 122
Platinum metals, definition 1070
Platinum, -elimination in alkyls and aryls 926
Platinum, -allylic complexes 934 1172
Platinum, abundance 1145
Platinum, alkene and alkyne complexes 1170—1172
Platinum, alkyls and aryls 1167—1168
Platinum, anti-tumour compounds 1163
Platinum, atomic and physical properties 1148—1149
Platinum, black 1148
Platinum, blues 1165
Platinum, carbonylate anions 1169
Platinum, catalytic uses 466 467 1145
Platinum, chalcogenides 1152
Platinum, complexes, +2 oxidation state 1156—1166
Platinum, complexes, +3 oxidation state 1155—1156
Platinum, complexes, +4 oxidation state 1154—1155
Platinum, complexes, +6 and +5 oxidation states 1154
Platinum, complexes, with 702
Platinum, complexes, with S 666
Platinum, complexes, zero oxidation state 1166—1167
Platinum, coordination numbers and stereochemistries 1150
Platinum, halides 1152—1154
Platinum, optical resolution of 670
Platinum, organometallic compounds 931 932 1167—1172
Platinum, oxidation states 1150
Platinum, oxides 1151 1152
Platinum, production and uses 1146 1147
Platinum, reactivity of element 1149
Platinum, sulfide, structure 679
Plutonium see also “Actinide elements”
Plutonium economy 1259
Plutonium, bis(cyclooctatetraene) 942
Plutonium, critical mass 1261
Plutonium, discovery 1252
Plutonium, extraction from irradiated nuclear fuel 1260 1261
Plutonium, natural abundance 1253
Plutonium, redox behaviour 1265—1267
Plutonium, self-heating 1264
Plutonium, “breeding” 1259
Point groups 1290—1292
Pollution, atmospheric by 646 698—699 710 “Water”)
Polonium, abundance 747
Polonium, allotropy 751
Polonium, atomic and physical properties 753 754 890
Polonium, chemical reactivity 754—759
Polonium, coordination geometries 756
Polonium, dioxide 780
Polonium, discovery 747
Polonium, halides 767 768 769 770
Polonium, hydride, 766 767
Polonium, hydroxide 781
Polonium, nitrate 786
Polonium, oxides 779—780
Polonium, polonides 765 766
Polonium, production and uses 750
Polonium, radioactivity 748 750
Polonium, redox properties 755
Polonium, selenate 786
Polonium, sulfate 786
Polonium, toxicity 757—759
Polyethene (polythene) 261 262 972
Polyhalide anions 827 829—831 834—839
Polyhalide anions, bonding 838 839
Polyhalide anions, containing astatine 887
Polyhalide anions, structural data 836—839
Polyhalonium cations 827 829—831 833—835
Polyhalonium cations, stoichiometries 839
Polyhalonium cations, structures 840
Polyiodides 806 835—839
Polymetaphosphoric acid 512
Polypeptide chains 61 62
Polyphosphates, factors affecting rate of degradation 523 (see also “Chain polyphosphates” “Cyclo-polyphosphates”)
Polyphosphazenes 536
Polyphosphazenes, analogy with silicones 536
Polyphosphazenes, applications 542—543
Polyphosphazenes, basicities 540
Polyphosphazenes, bonding in 537—540
Polyphosphazenes, hydrolysis 541
Polyphosphazenes, melting points of 538
Polyphosphazenes, pentameric 538
Polyphosphazenes, preparation 536 537
Polyphosphazenes, reactions 540—542
Polyphosphazenes, structure 536—538
Polyphosphazenes, tetrameric 537 538
Polyphosphazenes, trimeric 537
Polyphosphoric acid 511
Polyphosphoric acid, catalyst for petrochemical processes 52
Polysulfanes see “Sulfanes”
Polysulfates, 712
Polysulfides of chlorine see “Sulfur chlorides”
Polysulfides of hydrogen see “Sulfanes”
Polysulfides, use in Na/S batteries 678
Polythiazyl see
Polythionates, 705 714 716—718
Polythionates, , seleno- and telluro- derivatives 717 782
Polythionic acids, 705 716
Polyurethane 305 422
Polywater 632 633
Porphin 126
Porphyrin complexes of Mg see “Chlorophylls”
Portland cement see also “High-alumina cement”
Portland cement, constitution of 252
Portland cement, manufacture of 252
Potassium see also “Alkali metals”
Potassium chlorate, thermal decomposition to give 603
Potassium compounds as fertilizers 73
Potassium compounds, production and uses of 73 74
Potassium permanganate, thermal decomposition to give 603
Potassium, abundance 69
Potassium, compounds with oxygen 84—85
Potassium, discovery 68
Potassium, graphite intercalates 293—295
Potassium, nitrate, thermolysis of 468 469 541
Potassium, orthonitrate 474
Potassium, phosphates 524
Potassium, polysulfides 681 682
Potassium, polythionates, preparation and structure 717
Potassium, production of metal 73 74
Potassium, silyl 339 340
Potassium, terrestrial distribution of 70
Powder metallurgy 1005 1144
Praseodymium 1229 (see also “Lanthanide elements”)
Praseodymium, +4 oxidation state 1237 1239 1244
Praseodymium, diiodide 1441
Praseodymium-oxygen system, ordered defects and nonstoichiometry in 643—644
Principal quantum number n 22
Promethium 1228 (see also “Lanthanide elements”)
Protactinium see also “Actinide elements”
Protactinium, abundance 1253
Protactinium, bis(cyclooctatetraene) 942
Protactinium, discovery 1250
Protactinium, redox behaviour 1265—1267
Proton, hydration of 951 952 ionized and
Proton-switch conduction in 623
Proton-switch conduction in 843
Proton-switch conduction in 518
Protoporphyrin IX (PIX) 1099
Prout's hypothesis 888
Prussian blue 1094
Pseudohalogen concept 319 324
PTFE see “Teflon”
Purex process 1261
Purple of Cassium 1177
PVC plastics, organotin stabilizers for 409
Pyrite structure 555 557 680
Pyrochlore 977
Pyrophosphoric acid see “Diphosphoric acid”
Pyrophosphoryl halides 502 503 506
Pyrophyllite 352—355 413
Pyrrhotite 649
Quadruple metal-metal bonds 1031—1035
Quantum numbers 22
Quartz 342—344
Quartz, enantiomorphism 342
Quartz, uses 346
Quaternary arsonium compounds 594
Quaternary bismuth cations, 599
Quaternary phosphonium cations 485 495 498—501 545 546
r-process in stars 12
Racah parameter see “Interelectronic repulsion parameter”
Radial functions 1285—1287
Radioactive decay series 1254
Radioactive elements, discovery 21
Radioactive elements, varying atomic weights of 18
Radiocarbon dating 277
Radium, history of 108 (see also “Alkaline earth elements”)
Radius ratio rules 80
Radon see also “Noble gases”
Radon, atomic and physical properties 890 891
Radon, difluoride 903
Radon, discovery 889
Radon, fluoro complexes 903
Rare earths see “Lanthanide elements”
Raschig synthesis of hydrazine 427 428
Rayon 317 422 653
Realgar see “Arsenic sulfide” “
Red cake 977
Red lead, 385 388
Reduction potentials see “Standard reduction potentials”
Reinecke's salt 1028
Relativistic effects 599 1180
Reppe synthesis 309 1167 1172
Rhenates 1051
Rhenium, abundance 1041
Rhenium, alkyls 1062 1068—1069
Rhenium, carbidocarbonyls 1065—1066
Rhenium, carbonyls 928 1062—1064
Rhenium, chalcogenides 1049
Rhenium, complexes, +2 oxidation state 1058
Rhenium, complexes, +3 oxidation state 1057—1058
Rhenium, complexes, +4 oxidation state 1056
Rhenium, complexes, +5 oxidation state 1055
Rhenium, complexes, +6 oxidation state 1055
Rhenium, complexes, +7 oxidation state 1054
Rhenium, complexes, lower oxidation states 1061
Rhenium, compounds with metal-metal multiple bonds 1057 1058 1230
Rhenium, cyclopentadienyls 1067—1068
Rhenium, discovery 1040
Rhenium, halides and oxohalides 1051—1054
Rhenium, nine-coordinate hydrido complex 1046 1054
Rhenium, organometallic compounds 1062—1068
Rhenium, oxides 1045—1049
Rhenium, production and uses 1041
Rhenium, trioxide 1047
Rhenium, trioxide, structure of 1047
Rhodium, abundance 1113
Rhodium, atomic and physical properties 1114—1115
Rhodium, carbidocarbonyls 1141—1142
Rhodium, carbonyls 928 1140—1143
Rhodium, complexes, +1 oxidation state 1133—1136
Rhodium, complexes, +2 oxidation state 1129
Rhodium, complexes, +3 oxidation state 1122—1129
Rhodium, complexes, +4 oxidation state 1121
Rhodium, complexes, lower oxidation states 1137
Rhodium, complexes, with 702
Rhodium, coordination numbers and stereochemistries 1117
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