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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Íàçâàíèå: Chemistry of the Elements
Àâòîðû: Greenwood N.N., Earnshaw A.
Àííîòàöèÿ: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Ðóáðèêà: Õèìèÿ /
Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Èçäàíèå: second edition
Ãîä èçäàíèÿ: 1997
Êîëè÷åñòâî ñòðàíèö: 1340
Äîáàâëåíà â êàòàëîã: 18.02.2007
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Hafnium see also “Group 4 elements”
Hafnium, abundance 955
Hafnium, alkyls and aryls 973
Hafnium, carbonyls 973
Hafnium, complexes, +3 oxidation state 969
Hafnium, complexes, +4 oxidation state 967—969
Hafnium, complexes, lower oxidation states 971
Hafnium, compounds with oxoanions 966 967
Hafnium, cyclopentadienyls 973—975
Hafnium, dioxide 962
Hafnium, discovery 954
Hafnium, halides 964—966
Hafnium, neutron absorber 965 1258
Hafnium, organometallic compounds 973—975
Hafnium, production and uses 956
Hafnium, sulfides 962
Hahnium see “Dubnium”
Halates, 862—866
Halates, , astatate 885
Halates, , disproportionation 855
Halic acids, 862—863
Halides 819—824
Halides, astatide 886
Halides, intercalation into graphite 294 295
Halides, synthesis of 819—823
Halides, trends in properties 823
Halites, 859—862
Hall effect 258 549 552 1017
Halogen cations, 842—844 (see also “Polyhalonium cations”)
Halogen(I) fluorosulfates, 883—885
Halogen(I) nitrates, XONO 883 884
Halogen(I) perchlorates, 883 884
Halogens (F, Cl, Br, I, At) 784—887 (see also “Interhalogen compounds”)
Halogens (F, Cl, Br, I, At), abundance and distribution 795 796
Halogens (F, Cl, Br, I, At), atomic and physical properties 800—804
Halogens (F, Cl, Br, I, At), charge-transfer complexes 806—809
Halogens (F, Cl, Br, I, At), history (time charts) 790 791
Halogens (F, Cl, Br, I, At), origin of name 789 790
Halogens (F, Cl, Br, I, At), production and uses 796 800
Halogens (F, Cl, Br, I, At), reactivity towards graphite 296
Halogens (F, Cl, Br, I, At), stereochemistry 806
Halous acids, HOXO 859 861
Hammett acidity function 51 52
Hapticity, classification of organometallic compounds 925
Hapticity, distinction from connectivity 925 928
Hassium 1281 1283
Hausmannite 1041 1049
Heat of vaporization, influence of H bonding 54
Heavy water 39
Helium see also “Noble gases”
Helium, abundance in universe 3
Helium, atomic and physical properties 891 890
Helium, discovery 888
Helium, production and uses 889 890
Helium, thermonuclear reactions in stars 10
Hemimorphite 348
Hertzsprung — Russell diagrams 6
Heteropoly blues 1015
Heteropolymolybdates 1013 1015
Heteropolytungstates 1013 1015
Hexamethylphosphoramide 532
Hexathionates, , preparation and structure 717 718 851
High temperature superconductivity 945 1183 1232
High-alumina cement 251
High-spin complexes 923
Hittorf's allotrope of phosphorus 482
Holmium 1229 (see also “Lanthanide elements”)
Hume — Rothery rules 1178
Hydrargillite 243 245
Hydrazido complexes with metals 430 (see also “Dinitrogen as a ligand”)
Hydrazine 408 422 427—431
Hydrazine, acid-base properties 428
Hydrazine, as a bridging ligand 431
Hydrazine, hydrate 429 430
Hydrazine, industrial production 429
Hydrazine, methyl derivatives as fuels 429
Hydrazine, molecular structure and conformation 427 428
Hydrazine, oxidation of 434
Hydrazine, preparation 427
Hydrazine, properties of 427
Hydrazine, reaction with nitrous acid 432
Hydrazine, reducing properties 430
Hydrazine, uses 429
Hydrazine, water treatment using 429
Hydrides, binary 64—67
Hydrides, binary and periodic table 65
Hydrides, binary of boron see “Boranes”
Hydrides, binary of sulfur see “Sulfanes”
Hydrides, binary, acid strength of 48
Hydrides, binary, bonding in 64
Hydrides, binary, classificatidn of 64
Hydrides, binary, complex 67
Hydrides, binary, covalent 64 67
Hydrides, binary, interstitial 67
Hydrides, binary, ionic 64 65
Hydrides, binary, nonstoichiometric 66 67
Hydroboration see “Diborane”
Hydrochloric acid, HCl(aq) 790 792 809 812
Hydrochloric acid, HCl(aq), azeotrope 815
Hydrofluoric acid, HF(aq) 790
Hydrofluoric acid, HF(aq), acid strength of 814
Hydrofluoric acid, HF(aq), azeotrope 815
Hydrofluoric acid, HF(aq), preparation of fluorides using 820—821
Hydroformylation of alkenes 309 1135 1140
Hydrogen see also “Dihydrogen”
Hydrogen as the essential element in acids 32
Hydrogen azide, 432 433
Hydrogen bond 33 52—64
Hydrogen bond and ferroelectricity 57
Hydrogen bond and proton nmr 56
Hydrogen bond and vibrational spectroscopy 56
Hydrogen bond in ammonia 423
Hydrogen bond in aquo complexes 625
Hydrogen bond in DNA 61 62
Hydrogen bond in HF 812 813
Hydrogen bond in proteins and nucleic acids 61 62
Hydrogen bond in water 623
Hydrogen bond, bond lengths (table) 60
Hydrogen bond, comparison with BHB bonds 64
Hydrogen bond, influence on properties 53
Hydrogen bond, influence on structure 59
Hydrogen bond, strength of X-ray and neutron diffraction 56
Hydrogen bond, theory of 63
Hydrogen bromide, HBr, azeotrope 815
Hydrogen bromide, HBr, hydrates 815
Hydrogen bromide, HBr, physical properties 813
Hydrogen bromide, HBr, production and uses 811 812
Hydrogen chloride, HCl see also “Hydrochloric acid”
Hydrogen chloride, HCl, hydrates 813 814
Hydrogen chloride, HCl, nonaqueous solvent properties 813
Hydrogen chloride, HCl, physical properties 813
Hydrogen chloride, HCl, production and uses 811—812
Hydrogen dinitrate ion, 468
Hydrogen fluoride, HF 809—810 (see also “Hydrofluoric acid”)
Hydrogen fluoride, HF, H bonding in 52—53 812
Hydrogen fluoride, HF, hydrates 814
Hydrogen fluoride, HF, nonaqueous solvent properties 816—818
Hydrogen fluoride, HF, physical properties 812 813
Hydrogen fluoride, HF, preparation of fluorides using 820
Hydrogen fluoride, HF, production and uses 809—811
Hydrogen fluoride, HF, skin burns, treatment of 810
Hydrogen halides, HX 809—819
Hydrogen halides, HX, chemical reactivity 813—816
Hydrogen halides, HX, nonaqueous solvent properties 816—819
Hydrogen halides, HX, physical properties 812 813
Hydrogen halides, HX, preparation and uses 809—812
Hydrogen iodide, HI, azeotrope 815
Hydrogen iodide, HI, hydrates 815
Hydrogen iodide, HI, physical properties 812
Hydrogen iodide, HI, production and uses 811 812
Hydrogen peroxide 633
Hydrogen peroxide, acid-base properties 636—638
Hydrogen peroxide, chemical properties 634 638
Hydrogen peroxide, physical properties 633 634 635
Hydrogen peroxide, preparation 633
Hydrogen peroxide, production statistics 634
Hydrogen peroxide, redox properties 634—637
Hydrogen peroxide, structure 635
Hydrogen peroxide, uses of 633—634
Hydrogen sulfate ion, 705 706 711—713
Hydrogen sulfide, see also “Sulfanes” “Wackenroder's
Hydrogen sulfide, as ligand 665 673
Hydrogen sulfide, , chemistry 682
Hydrogen sulfide, , molecular properties 682 767
Hydrogen sulfide, , occurrence in nature 646—648 651 771
Hydrogen sulfide, , physical properties 682 767
Hydrogen sulfide, , preparation (laboratory) 682
Hydrogen sulfide, , protonated 683
Hydrogen sulfite ion, 705 719
Hydrogen, abundance (terrestrial) 32
Hydrogen, abundance in universe 2
Hydrogen, atomic properties 34
Hydrogen, chemical properties 43
Hydrogen, cyanide, H bonding in 55
Hydrogen, history of 32 33
Hydrogen, industrial production 38
Hydrogen, ionized forms of 36
Hydrogen, isotopes of 34 (see also “Deuterium” “Tritium”)
Hydrogen, ortho- and para- 32 35
Hydrogen, physical properties of 34
Hydrogen, portable generator for 39
Hydrogen, preparation 38
Hydrogen, stereochemistry of 44
Hydrogen, thermonuclear reactions in stars 9
Hydrogen, variable atomic weight of 17
Hydrogen-ion concentration see “pH scale”
Hydrometalation 926
Hydronitrous acid see “Nitroxylic acid”
Hydroperoxides 636
Hydroxonium ion, 628—631 814 815
Hydroxyl ion, hydration of 630 632
Hydroxylamine 422 431—432
Hydroxylamine, configurational isomers 432 432
Hydroxylamine, hydroxylamides of sulfuric acid 744—746
Hydroxylamine, preparation 495 431 432
Hydroxylamine, properties 495 431 432
Hypersensitive bands in spectra of lanthanides 1244
Hypobromous acid, HOBr 853 855 857 858
HypochJorous acid, HOCl 853—859
HypochJorous acid, HOCl, preparation 857
HypochJorous acid, HOCl, reactions 858—859
HypochJorous acid, HOCl, uses 860
Hypochlorite, 854 855 857—859
Hypochlorite, , molecular hypochlorites 859
Hypofluorites (covalent) 639 688
Hypofluorous acid, HOF 638 639
Hypofluorous acid, HOF, preparation 791 853 856
Hypohalates, 853—859
Hypohalous acids, HOX 853—859
Hypoiodous acid, HOI 853—859
Hyponitric acid, 530 459
Hyponitrites 459—461
Hyponitrous acid, 459—459
Hypophosphites 513 516
Hypophosphoric acid (diphosphoric(IV) acid), 512 515—516
Hypophosphoric acid (diphosphoric(IV) acid), , isomerism to isohypophosphoric acid 515
Hypophosphorous acid, 512 513
Icosagens 227
Icosahedron, symmetry elements of 141
Ilmenite 955 960 963
Inclusion compounds 985 (see also “Clathrate compounds”)
Indium see also “Group 13 elements”
Indium, abundance 218
Indium, chalcogenides 252—254
Indium, discovery 216
Indium, III—V compounds 255—258
Indium, lower halides 240
Indium, organometallic compounds 262
Indium, oxide 247
Indium, production and uses 219
Indium, trihalides 237 238
Industrial chemicals, production statistics 407
Industrial Revolution 1070 1072
Inert-pair effect 27
Inert-pair effect in Al, Ga, In, Tl 226
Inert-pair effect in Ge, Sn, Pb 374
Inert-pair effect in P, As, Sb, Bi 553 566 568
Inner-sphere reactions 1124
Ino-silicates 347 349—351
Interelectronic repulsion parameter for hexaquochromium(III) 1029
Interelectronic repulsion parameter for hexaquovanadium(III) 996
Interelectronic repulsion parameter for high-spin complexes of cobalt(II) 1132
Interelectronic repulsion parameter for high-spin complexes of cobalt(III) 1127
Interhalogen compounds 824—828 (see also “Pojyhalide anions” “Polyhalonium
Interhalogen compounds, diatomic, XY 824—828 833
Interhalogen compounds, first preparation 790 791
Interhalogen compounds, hexa-atomic, 832—835
Interhalogen compounds, octa-atomic, 832—835
Interhalogen compounds, tetra-atomic, 828—831 833
Invar 1146
Iodates, 862 863
Iodates, , reaction scheme 866
Iodates, , redox systematics 854—856
Iodides, synthesis of 822
Iodine trichloride, complex and 568
Iodine, abundance and distribution 795 (see also “Halogens”)
Iodine, atomic and physical properties 800—804
Iodine, cations 842—844
Iodine, charge-transfer complexes 806—809
Iodine, colour of solutions 806—809
Iodine, crystal structure 803
Iodine, goitre treatment 790 794
Iodine, heptafluoride 832—835
Iodine, history 790 791 793
Iodine, Karl Fischer reagent for 627
Iodine, monohalides 824—828 833
Iodine, oxide fluorides 881—883
Iodine, oxides 851—853
Iodine, oxoacids and oxoacid salts 853 (see also “Iodic acid” “Iodates” “Periodic “Periodates”)
Iodine, oxoacids and oxoacid salts, nomenclature 853
Iodine, oxoacids and oxoacid salts, redox properties 854—856
Iodine, pentafluoride 832—834
Iodine, production and uses 799 800
Iodine, radioactive isotopes 801 802
Iodine, reactivity 805
Iodine, standard reduction potentials 854
Iodine, stereochemistry 806
Iodine, trichloride 828—829 831 833
Iodine, trifluoride 828 830 831 833
Iodine, volt equivalent diagram 855
Iodine, “pentoxide”, 851—853
Iodyl fluorosulfate, 882
Ionic radii 80 81
Ionic radii, table of 1295
Ionic-bond model 79—81 963
Ionic-bond model, deviations from 81
Ionization energy, periodicity of 24
Iridium, abundance 1113
Iridium, atomic and physical properties 1115—1116
Iridium, carbonyls 928 1140—1143
Iridium, complexes, +1 oxidation state 1133—1137
Iridium, complexes, +2 oxidation state 1129—1130
Iridium, complexes, +3 oxidation state 1121 1127 1129
Iridium, complexes, +4 oxidation state 1121—1122
Iridium, complexes, +5 oxidation state 1121
Iridium, complexes, lower oxidation states 1137
Iridium, complexes, with 702
Iridium, coordination numbers and stereochemistries 1117
Iridium, cyclopentadienyls 1143
Iridium, discovery 1113
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