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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
Greenwood N.N., Earnshaw A. — Chemistry of the Elements



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Íàçâàíèå: Chemistry of the Elements

Àâòîðû: Greenwood N.N., Earnshaw A.

Àííîòàöèÿ:

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.

Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.


ßçûê: en

Ðóáðèêà: Õèìèÿ/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Èçäàíèå: second edition

Ãîä èçäàíèÿ: 1997

Êîëè÷åñòâî ñòðàíèö: 1340

Äîáàâëåíà â êàòàëîã: 18.02.2007

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Stannocene      402
Starch/iodine reaction      790 864
Stars, spectral classification of      5
Stars, temperatures of      5
Steel      1072—1075
Stellar evolution      5
Stereochemical non-rigidity (fluxional behaviour), $Al(BH_{4})_{3}$, ${\{}Al(BH_{4})_{2}H_{\mu}{\}}_{2}$      230
Stereochemical non-rigidity (fluxional behaviour), $Fe(CO)_{5}$      914 1104
Stereochemical non-rigidity (fluxional behaviour), $PF_{5}$      498
Stereochemical non-rigidity (fluxional behaviour), $SF_{4}$      684
Stereochemical non-rigidity (fluxional behaviour), 5-coordinate compounds      914
Stereochemical non-rigidity (fluxional behaviour), 8-coordinate compounds      995
Stereochemical non-rigidity (fluxional behaviour), allyl complexes      934
Stereochemical non-rigidity (fluxional behaviour), Berry pseudorotation mechanism      474 499
Stereochemical non-rigidity (fluxional behaviour), iron cyclopentadienyl complexes      1111
Stereochemical non-rigidity (fluxional behaviour), titanium cyclopentadienyl      974
Stibinidene complexes      597
Stibnite      see “Antimony sulfide” “Sb_{2}S_{3}”
Stishovite      342
Strength of oxoacids, Pauling's rules      50
Strontium      see also “Alkaline earth metals”
Strontium, history      108
Strontium, organometallic compounds      136
Strontium, polysulfides      681
Styx numbers      see “Boranes”
Sulfamic acid, $H[H_{2}NSO_{3}]$      408 741 742
Sulfamide $(H_{2}N)_{2}SO_{2}$      742 743
Sulfanes      682—683 (see also “Hydrogen sulfide”)
Sulfanes, nonexistence of $SH_{4}$ and $SH_{6}$      685
Sulfanes, physical properties      683
Sulfanes, preparation      682
Sulfanes, synthesis of polythionic acids from      716
Sulfate ion as ligand (${\eta}^{1}$, ${\eta}^{2}$, $\mu$)      712
Sulfates      711 712
Sulfide minerals, geochemical classification      648
Sulfide minerals, names and formulae      649
Sulfides, $S_{n} ^{2—}$ structures      631 681
Sulfides, anionic polysulfides      678 681 682
Sulfides, applications and uses      677—679
Sulfides, electrical properties      681
Sulfides, hydrolysis      678 679 682
Sulfides, industrial production      678
Sulfides, magnetic properties      681
Sulfides, preparation (laboratory)      677
Sulfides, roasting in air      676—678
Sulfides, solubility in water      678 679
Sulfides, structural chemistry      679—681
Sulfinates      703
Sulfites, $SO_{3}^{2—}$      705 719
Sulfites, $SO_{3}^{2—}$ in paper manufacture      652
Sulfites, $SO_{3}^{2—}$, protonation to $HSO_{3}^{—}$      719
Sulfoxylates, MS(O)OR      703
Sulfur      see also “Chalcogenides”
Sulfur as ligands      701—703
Sulfur chloride pentafluoride $SF_{5}Cl$, photoJytic reduction to $S_{2}F_{10}$      687
Sulfur chloride pentafluoride $SF_{5}Cl$, reaction with $O_{2}$      640
Sulfur chloride pentafluoride $SF_{5}Cl$, synthetically useful reactions of      688 689
Sulfur dioxide      698—701 (see also “Wackenroder's solution” “Sulfuric
Sulfur dioxide as ligand      701—703
Sulfur dioxide in M—S—O phase diagrams      677
Sulfur dioxide, atmospheric pollution by      646 698—700 699
Sulfur dioxide, chemical reactions      700
Sulfur dioxide, clathrate hydrate      700
Sulfur dioxide, industrial production      698 708
Sulfur dioxide, insertion into M—C bonds      702 703
Sulfur dioxide, molecular and physical properties      700 780
Sulfur dioxide, solvent for chemical reactions      662 701
Sulfur dioxide, toxicity      700
Sulfur dioxide, uses      700
Sulfur imides, $S_{8—n}(NH)_{n}$      735—735
Sulfur in biological complexes      667
Sulfur trioxide      see also “Sulfuric acid production”
Sulfur trioxide, chemical reactions      703 704
Sulfur trioxide, molecular and physical properties      703 704
Sulfur trioxide, monomeric      703 704
Sulfur trioxide, polymeric      703 704
Sulfur trioxide, polymorphism      703 704
Sulfur trioxide, preparation by catalytic oxidation of $SO_{2}$      700 708
Sulfur trioxide, reaction with $F_{2}$      640
Sulfur trioxide, reaction with $SF_{6}$      695
Sulfur trioxide, trimeric      703 704
Sulfur, $S_{19}^{2+}$      see “Polyatomic cations”
Sulfur, $S_{2}$      656 661
Sulfur, $S_{3}$      656 661
Sulfur, $S_{4}$      661
Sulfur, $S_{4}^{2+}$      see “Polyatomic cations”
Sulfur, $S_{8}$      see “Cyclo-$S_{8}$
Sulfur, $S_{8}^{2+}$      see “Polyatomic cations”
Sulfur, $S_{n}$      see “Cyclo-$S_{n}$
Sulfur, $\lambda$ point      660
Sulfur, abundance      647
Sulfur, allotropes      646 652—661
Sulfur, atomic properties      661
Sulfur, atomic S      664
Sulfur, atomic weight, variability of      18 661 662
Sulfur, bromides $S_{n}Br_{2}$      691
Sulfur, catenation      652 656ff 681—683 689 690 716—718
Sulfur, chemical reactivity      662—664
Sulfur, chiral helices      660
Sulfur, chlorides      689—692 716
Sulfur, chlorides, $SCl_{7}I$      693
Sulfur, chlorides, $[SCl_{3}]^{+}$      691 693
Sulfur, chlorides, industrial applications of $SCl_{2}$ and $S_{2}Cl_{2}$      690
Sulfur, chlorides, preparation      690 691
Sulfur, chlorides, properties of $S_{n}Cl_{2}$      690 691
Sulfur, chlorofluorides      640 686—689
Sulfur, conformations (c, dt, lt)      656 659 665
Sulfur, conversion to $SO_{2}/SO_{3}$ for $H_{2}SO_{4}$      see “Sulfuric acid”
Sulfur, coordination geometries      663
Sulfur, Crystex      659
Sulfur, dihedral angles in $S_{n}$      654 655
Sulfur, fibrous ($\psi$, $\phi$)      659—660
Sulfur, fluorides      683—689
Sulfur, fluorides, chemical reactions      685—689
Sulfur, fluorides, fluxionality of $SF_{4}$      685
Sulfur, fluorides, isomeric $S_{2}F_{2}$      684
Sulfur, fluorides, physical properties      685 687
Sulfur, fluorides, stoichiometries      684
Sulfur, fluorides, structures      684—685
Sulfur, fluorides, synthesis      685—688
Sulfur, gaseous species      661
Sulfur, halides      683—693
Sulfur, hexafluoride      685 687
Sulfur, hexafluoride, applications as a dielectric gas      687
Sulfur, hexafluoride, reaction with $SO_{3}$      695
Sulfur, history      645 646
Sulfur, iodides      691—693
Sulfur, iodides, $SCl_{7}I$      693
Sulfur, iodides, $[S_{14}I_{3}]^{3+}$      692
Sulfur, iodides, $[S_{2}I_{4}]^{2+}$      692 693
Sulfur, iodides, $[S_{7}I]^{+}$      692
Sulfur, iodides, bond energy relations in      691
Sulfur, ligand properties of $S_{2}^{2—}$      665—669 668 671
Sulfur, ligand properties of chelating $—S_{n}—$      665 670 672
Sulfur, ligand properties of S atom      665—666
Sulfur, liquid      654 660
Sulfur, monoxide      698
Sulfur, nitrides      722—729
Sulfur, organic thio ligands      673
Sulfur, origin in caprock of salt domes      647
Sulfur, oxidation state diagram of species      706
Sulfur, oxidation states      664
Sulfur, oxides      695—704 (see also “Sulfur dioxide” “Sulfur
Sulfur, oxides, higher, $SO_{3+X}$, $SO_{4}$      704
Sulfur, oxides, lower dioxides      695—698
Sulfur, oxides, lower oxides $S_{n}O$      695—698
Sulfur, oxoacids      706—721
Sulfur, oxofluorides      688 (see also “Thionyl fluorides” “Sulfuryl
Sulfur, peroxofluorides      689
Sulfur, plastic ($\chi$)      659
Sulfur, polyatomic cations      664 665
Sulfur, polymeric ($\mu$)      659
Sulfur, production      649—652
Sulfur, production, Frasch process      649—650
Sulfur, production, from pyrite      651
Sulfur, production, from sour gas and crude oil      651
Sulfur, production, statistics      762 768
Sulfur, radioactive isotopes      661
Sulfur, reserves      651
Sulfur, rhombohedral      see $Cyclo-{\alpha}-S_{8}$
Sulfur, rubbery S      659
Sulfur, S-S bonds      652 654 662 667 681—683 716—718
Sulfur, schematic classification      707
Sulfur, singlet state $S_{2}$      661
Sulfur, SN compounds      686 721—746 “S—N—X “Sulfur “S—N—O “Sulfur-nitrogen “Sulfur-nitrogen
Sulfur, standard reduction potentials of S species      706
Sulfur, table of      705
Sulfur, terrestrial distribution      647
Sulfur, thermodynamic interrelations      706
Sulfur, triplet state $S_{2}$      661
Sulfur, uses      651 653
Sulfur, uses of radioactive $^{35}S$      661 714
Sulfur, volt-equivalent diagram of S species      706
Sulfur-nitrogen anions, $S_{X}N_{Y}^{—}$      733—734
Sulfur-nitrogen cations, $S_{X}N_{Y}^{+}$      730—733
Sulfur-nitrogen-halogen compounds      736—740
Sulfur-nitrogen-halogen compounds, $N_{3}S_{3}Cl_{3}$      738
Sulfur-nitrogen-halogen compounds, $N_{3}S_{3}X_{3}O_{3}$      738
Sulfur-nitrogen-halogen compounds, $S_{4}N_{3}Cl$ and $S_{4}N_{4}Cl_{2}$      739
Sulfur-nitrogen-halogen compounds, cyclo-$(NSF)_{n}$      736—738
Sulfur-nitrogen-halogen compounds, thiazyl halides NSX      736—738
Sulfur-nitrogen-oxygen compounds      740
Sulfur-nitrogen-oxygen compounds, amides of $H_{2}SO_{4}$      741 (see also “Sulfamic acid” “Sulfamide”)
Sulfur-nitrogen-oxygen compounds, hydrazine derivatives of $H_{2}SO_{4}$      743
Sulfur-nitrogen-oxygen compounds, hydroxylamine derivatives of $H_{2}SO_{4}$      743—746
Sulfur-nitrogen-oxygen compounds, imido and nitrido derivatives of $H_{2}SO_{4}$      743
Sulfur-nitrogen-oxygen compounds, sulfur-nitrogen oxides      740 741
Sulfuric acid      706 712
Sulfuric acid, $D_{2}SO_{4}$      710 711
Sulfuric acid, amides of      741—743
Sulfuric acid, autoprotolysis in anhydrous      710
Sulfuric acid, contact process      646 700 708—710 981
Sulfuric acid, history      646 708
Sulfuric acid, hydrates      710
Sulfuric acid, hydrazine derivatives of      744
Sulfuric acid, hydroxylamine derivatives of      744—746
Sulfuric acid, imido derivatives of      743 744
Sulfuric acid, ionic dissociation equilibria in anhydrous      711
Sulfuric acid, lead chamber process      646 708
Sulfuric acid, nitrido derivatives of      743 744
Sulfuric acid, production from sulfide ores      708
Sulfuric acid, production from sulfur      652—652 708
Sulfuric acid, production statistics      407 708 710
Sulfuric acid, solvent system      711
Sulfuric acid, uses      710
Sulfurous acid, $H_2SO_3$      652 700 705 717 718
Sulfuryl chloride      694 695
Sulfuryl fluoride      688 694
Sulfuryl fluoride, mixed fluoride halides      694
Superconductivity in Chevrel phases      1018 1031
Superconductivity of metal sulfides      680
Superconductivity, high temperature      945 1182—1183 1232
Superconductivity, use of Nb/Zr in magnets      978
Superheavy elements      30 1253
Supernucleophiles      1139
Superoxo complexes of $O_2$      616 1127
Superphosphate fertilizer      474 525
Swarts reaction      560
Symmetry elements      1290—1292
Symmetry operations      1290—1292
Synergic bonding      see also “Back ($\pi$) bonding”
Synergic bonding in alkene complexes      926 927
Synergic bonding in CO and $CN^{—}$ complexes      931
Synergic bonding in cobalt cyanides      1122
Synthesis gas      1106
Talc      109
Tanabe — Sugano diagrams for $d^2$ ions      997
Tanabe — Sugano diagrams for $d^3$ ions      1029
Tanabe — Sugano diagrams for $d^6$ ions      1096 1128
Tanabe — Sugano diagrams for $d^8$ ions      1156
Tanabe — Sugano diagrams for $Mn^{II}$      1156
Tantalates      987
Tantalite      977
Tantalum      see also “Group 5 elements”
Tantalum, abundance      977
Tantalum, alkyls and aryls      999
Tantalum, carbene complex      926
Tantalum, carbonylate anions      999—1000
Tantalum, chalcogenides      987
Tantalum, complexes, +4 oxidation state      944—996
Tantalum, complexes, +5 oxidation state      994
Tantalum, compounds with oxoanions      993
Tantalum, cyclopentadienyls      1000—1001
Tantalum, discovery      976
Tantalum, halides and oxohalides      988—999
Tantalum, oxides      929 982 983 999—1000
Tantalum, production and uses      977
Technetates      1050
Technetium      see also “Group 7 elements”
Technetium, abundance      1041
Technetium, carbonyls      928 1062—1063
Technetium, chalcogenides      1049
Technetium, complexes, +2 oxidation state      1058
Technetium, complexes, +3 oxidation state      1057—1058
Technetium, complexes, +4 oxidation state      1056
Technetium, complexes, +5 oxidation state      1055
Technetium, complexes, +6 oxidation state      1055
Technetium, complexes, +7 oxidation state      1054
Technetium, complexes, lower oxidation states      1061
Technetium, cyclopentadienyls      1067—1068
Technetium, discovery      1040
Technetium, halides and oxohalides      1051—1054
Technetium, nuclear medicine, role in      1042
Technetium, organometallic compounds      1062—1067
Technetium, oxides      1045
Technetium, production and uses      1041
Tectites      394
Tecto-silicates      414—416 347
Teflon (PTFE)      304 791
Tellurates      782
Telluric acid, $Te(OH)_6$      782
Tellurides      765 766
Tellurites      781
Tellurium, abundance      748
Tellurium, allotropy      751
Tellurium, atomic and physical properties      753 754
Tellurium, chemical reactivity      754—759
Tellurium, coordination geometries      756—757
Tellurium, dioxide      779 780
Tellurium, discovery      747
Tellurium, halide complexes      776
Tellurium, halides      767—776
Tellurium, hydride, $H_2Te$      759 766
Tellurium, nitrate      786
Tellurium, nitride, $Te_3N_4$      783
Tellurium, organo compounds      786—788
Tellurium, oxides      779—780
Tellurium, oxoacids      781—783
Tellurium, oxohalides      777
Tellurium, polyatomic anions      762—765
Tellurium, polyatomic cations, $Te_{n}^{m+}$      759 761
Tellurium, polyatomic cations, $[Te_{n}Se_{4—n}]^{2+}$      761
Tellurium, production and uses      748 749
Tellurium, redox properties      755—756
Tellurium, sulfide, $TeS_7$      783
Tellurium, toxicity      759
Tellurium, trioxide      780
Tellurocyanate ion, $TeCN^{—}$      779
Telluropolythionates      783
Tellurous acid      781
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