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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Íàçâàíèå: Chemistry of the Elements
Àâòîðû: Greenwood N.N., Earnshaw A.
Àííîòàöèÿ: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Ðóáðèêà: Õèìèÿ /
Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Èçäàíèå: second edition
Ãîä èçäàíèÿ: 1997
Êîëè÷åñòâî ñòðàíèö: 1340
Äîáàâëåíà â êàòàëîã: 18.02.2007
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Stannocene 402
Starch/iodine reaction 790 864
Stars, spectral classification of 5
Stars, temperatures of 5
Steel 1072—1075
Stellar evolution 5
Stereochemical non-rigidity (fluxional behaviour), , 230
Stereochemical non-rigidity (fluxional behaviour), 914 1104
Stereochemical non-rigidity (fluxional behaviour), 498
Stereochemical non-rigidity (fluxional behaviour), 684
Stereochemical non-rigidity (fluxional behaviour), 5-coordinate compounds 914
Stereochemical non-rigidity (fluxional behaviour), 8-coordinate compounds 995
Stereochemical non-rigidity (fluxional behaviour), allyl complexes 934
Stereochemical non-rigidity (fluxional behaviour), Berry pseudorotation mechanism 474 499
Stereochemical non-rigidity (fluxional behaviour), iron cyclopentadienyl complexes 1111
Stereochemical non-rigidity (fluxional behaviour), titanium cyclopentadienyl 974
Stibinidene complexes 597
Stibnite see “Antimony sulfide” “Sb_{2}S_{3}”
Stishovite 342
Strength of oxoacids, Pauling's rules 50
Strontium see also “Alkaline earth metals”
Strontium, history 108
Strontium, organometallic compounds 136
Strontium, polysulfides 681
Styx numbers see “Boranes”
Sulfamic acid, 408 741 742
Sulfamide 742 743
Sulfanes 682—683 (see also “Hydrogen sulfide”)
Sulfanes, nonexistence of and 685
Sulfanes, physical properties 683
Sulfanes, preparation 682
Sulfanes, synthesis of polythionic acids from 716
Sulfate ion as ligand ( , , ) 712
Sulfates 711 712
Sulfide minerals, geochemical classification 648
Sulfide minerals, names and formulae 649
Sulfides, structures 631 681
Sulfides, anionic polysulfides 678 681 682
Sulfides, applications and uses 677—679
Sulfides, electrical properties 681
Sulfides, hydrolysis 678 679 682
Sulfides, industrial production 678
Sulfides, magnetic properties 681
Sulfides, preparation (laboratory) 677
Sulfides, roasting in air 676—678
Sulfides, solubility in water 678 679
Sulfides, structural chemistry 679—681
Sulfinates 703
Sulfites, 705 719
Sulfites, in paper manufacture 652
Sulfites, , protonation to 719
Sulfoxylates, MS(O)OR 703
Sulfur see also “Chalcogenides”
Sulfur as ligands 701—703
Sulfur chloride pentafluoride , photoJytic reduction to 687
Sulfur chloride pentafluoride , reaction with 640
Sulfur chloride pentafluoride , synthetically useful reactions of 688 689
Sulfur dioxide 698—701 (see also “Wackenroder's solution” “Sulfuric
Sulfur dioxide as ligand 701—703
Sulfur dioxide in M—S—O phase diagrams 677
Sulfur dioxide, atmospheric pollution by 646 698—700 699
Sulfur dioxide, chemical reactions 700
Sulfur dioxide, clathrate hydrate 700
Sulfur dioxide, industrial production 698 708
Sulfur dioxide, insertion into M—C bonds 702 703
Sulfur dioxide, molecular and physical properties 700 780
Sulfur dioxide, solvent for chemical reactions 662 701
Sulfur dioxide, toxicity 700
Sulfur dioxide, uses 700
Sulfur imides, 735—735
Sulfur in biological complexes 667
Sulfur trioxide see also “Sulfuric acid production”
Sulfur trioxide, chemical reactions 703 704
Sulfur trioxide, molecular and physical properties 703 704
Sulfur trioxide, monomeric 703 704
Sulfur trioxide, polymeric 703 704
Sulfur trioxide, polymorphism 703 704
Sulfur trioxide, preparation by catalytic oxidation of 700 708
Sulfur trioxide, reaction with 640
Sulfur trioxide, reaction with 695
Sulfur trioxide, trimeric 703 704
Sulfur, see “Polyatomic cations”
Sulfur, 656 661
Sulfur, 656 661
Sulfur, 661
Sulfur, see “Polyatomic cations”
Sulfur, see “Cyclo- ”
Sulfur, see “Polyatomic cations”
Sulfur, see “Cyclo- ”
Sulfur, point 660
Sulfur, abundance 647
Sulfur, allotropes 646 652—661
Sulfur, atomic properties 661
Sulfur, atomic S 664
Sulfur, atomic weight, variability of 18 661 662
Sulfur, bromides 691
Sulfur, catenation 652 656ff 681—683 689 690 716—718
Sulfur, chemical reactivity 662—664
Sulfur, chiral helices 660
Sulfur, chlorides 689—692 716
Sulfur, chlorides, 693
Sulfur, chlorides, 691 693
Sulfur, chlorides, industrial applications of and 690
Sulfur, chlorides, preparation 690 691
Sulfur, chlorides, properties of 690 691
Sulfur, chlorofluorides 640 686—689
Sulfur, conformations (c, dt, lt) 656 659 665
Sulfur, conversion to for see “Sulfuric acid”
Sulfur, coordination geometries 663
Sulfur, Crystex 659
Sulfur, dihedral angles in 654 655
Sulfur, fibrous ( , ) 659—660
Sulfur, fluorides 683—689
Sulfur, fluorides, chemical reactions 685—689
Sulfur, fluorides, fluxionality of 685
Sulfur, fluorides, isomeric 684
Sulfur, fluorides, physical properties 685 687
Sulfur, fluorides, stoichiometries 684
Sulfur, fluorides, structures 684—685
Sulfur, fluorides, synthesis 685—688
Sulfur, gaseous species 661
Sulfur, halides 683—693
Sulfur, hexafluoride 685 687
Sulfur, hexafluoride, applications as a dielectric gas 687
Sulfur, hexafluoride, reaction with 695
Sulfur, history 645 646
Sulfur, iodides 691—693
Sulfur, iodides, 693
Sulfur, iodides, 692
Sulfur, iodides, 692 693
Sulfur, iodides, 692
Sulfur, iodides, bond energy relations in 691
Sulfur, ligand properties of 665—669 668 671
Sulfur, ligand properties of chelating 665 670 672
Sulfur, ligand properties of S atom 665—666
Sulfur, liquid 654 660
Sulfur, monoxide 698
Sulfur, nitrides 722—729
Sulfur, organic thio ligands 673
Sulfur, origin in caprock of salt domes 647
Sulfur, oxidation state diagram of species 706
Sulfur, oxidation states 664
Sulfur, oxides 695—704 (see also “Sulfur dioxide” “Sulfur
Sulfur, oxides, higher, , 704
Sulfur, oxides, lower dioxides 695—698
Sulfur, oxides, lower oxides 695—698
Sulfur, oxoacids 706—721
Sulfur, oxofluorides 688 (see also “Thionyl fluorides” “Sulfuryl
Sulfur, peroxofluorides 689
Sulfur, plastic ( ) 659
Sulfur, polyatomic cations 664 665
Sulfur, polymeric ( ) 659
Sulfur, production 649—652
Sulfur, production, Frasch process 649—650
Sulfur, production, from pyrite 651
Sulfur, production, from sour gas and crude oil 651
Sulfur, production, statistics 762 768
Sulfur, radioactive isotopes 661
Sulfur, reserves 651
Sulfur, rhombohedral see
Sulfur, rubbery S 659
Sulfur, S-S bonds 652 654 662 667 681—683 716—718
Sulfur, schematic classification 707
Sulfur, singlet state 661
Sulfur, SN compounds 686 721—746 “ “ “S—N—X “Sulfur “S—N—O “Sulfur-nitrogen “Sulfur-nitrogen
Sulfur, standard reduction potentials of S species 706
Sulfur, table of 705
Sulfur, terrestrial distribution 647
Sulfur, thermodynamic interrelations 706
Sulfur, triplet state 661
Sulfur, uses 651 653
Sulfur, uses of radioactive 661 714
Sulfur, volt-equivalent diagram of S species 706
Sulfur-nitrogen anions, 733—734
Sulfur-nitrogen cations, 730—733
Sulfur-nitrogen-halogen compounds 736—740
Sulfur-nitrogen-halogen compounds, 738
Sulfur-nitrogen-halogen compounds, 738
Sulfur-nitrogen-halogen compounds, and 739
Sulfur-nitrogen-halogen compounds, cyclo- 736—738
Sulfur-nitrogen-halogen compounds, thiazyl halides NSX 736—738
Sulfur-nitrogen-oxygen compounds 740
Sulfur-nitrogen-oxygen compounds, amides of 741 (see also “Sulfamic acid” “Sulfamide”)
Sulfur-nitrogen-oxygen compounds, hydrazine derivatives of 743
Sulfur-nitrogen-oxygen compounds, hydroxylamine derivatives of 743—746
Sulfur-nitrogen-oxygen compounds, imido and nitrido derivatives of 743
Sulfur-nitrogen-oxygen compounds, sulfur-nitrogen oxides 740 741
Sulfuric acid 706 712
Sulfuric acid, 710 711
Sulfuric acid, amides of 741—743
Sulfuric acid, autoprotolysis in anhydrous 710
Sulfuric acid, contact process 646 700 708—710 981
Sulfuric acid, history 646 708
Sulfuric acid, hydrates 710
Sulfuric acid, hydrazine derivatives of 744
Sulfuric acid, hydroxylamine derivatives of 744—746
Sulfuric acid, imido derivatives of 743 744
Sulfuric acid, ionic dissociation equilibria in anhydrous 711
Sulfuric acid, lead chamber process 646 708
Sulfuric acid, nitrido derivatives of 743 744
Sulfuric acid, production from sulfide ores 708
Sulfuric acid, production from sulfur 652—652 708
Sulfuric acid, production statistics 407 708 710
Sulfuric acid, solvent system 711
Sulfuric acid, uses 710
Sulfurous acid, 652 700 705 717 718
Sulfuryl chloride 694 695
Sulfuryl fluoride 688 694
Sulfuryl fluoride, mixed fluoride halides 694
Superconductivity in Chevrel phases 1018 1031
Superconductivity of metal sulfides 680
Superconductivity, high temperature 945 1182—1183 1232
Superconductivity, use of Nb/Zr in magnets 978
Superheavy elements 30 1253
Supernucleophiles 1139
Superoxo complexes of 616 1127
Superphosphate fertilizer 474 525
Swarts reaction 560
Symmetry elements 1290—1292
Symmetry operations 1290—1292
Synergic bonding see also “Back ( ) bonding”
Synergic bonding in alkene complexes 926 927
Synergic bonding in CO and complexes 931
Synergic bonding in cobalt cyanides 1122
Synthesis gas 1106
Talc 109
Tanabe — Sugano diagrams for ions 997
Tanabe — Sugano diagrams for ions 1029
Tanabe — Sugano diagrams for ions 1096 1128
Tanabe — Sugano diagrams for ions 1156
Tanabe — Sugano diagrams for 1156
Tantalates 987
Tantalite 977
Tantalum see also “Group 5 elements”
Tantalum, abundance 977
Tantalum, alkyls and aryls 999
Tantalum, carbene complex 926
Tantalum, carbonylate anions 999—1000
Tantalum, chalcogenides 987
Tantalum, complexes, +4 oxidation state 944—996
Tantalum, complexes, +5 oxidation state 994
Tantalum, compounds with oxoanions 993
Tantalum, cyclopentadienyls 1000—1001
Tantalum, discovery 976
Tantalum, halides and oxohalides 988—999
Tantalum, oxides 929 982 983 999—1000
Tantalum, production and uses 977
Technetates 1050
Technetium see also “Group 7 elements”
Technetium, abundance 1041
Technetium, carbonyls 928 1062—1063
Technetium, chalcogenides 1049
Technetium, complexes, +2 oxidation state 1058
Technetium, complexes, +3 oxidation state 1057—1058
Technetium, complexes, +4 oxidation state 1056
Technetium, complexes, +5 oxidation state 1055
Technetium, complexes, +6 oxidation state 1055
Technetium, complexes, +7 oxidation state 1054
Technetium, complexes, lower oxidation states 1061
Technetium, cyclopentadienyls 1067—1068
Technetium, discovery 1040
Technetium, halides and oxohalides 1051—1054
Technetium, nuclear medicine, role in 1042
Technetium, organometallic compounds 1062—1067
Technetium, oxides 1045
Technetium, production and uses 1041
Tectites 394
Tecto-silicates 414—416 347
Teflon (PTFE) 304 791
Tellurates 782
Telluric acid, 782
Tellurides 765 766
Tellurites 781
Tellurium, abundance 748
Tellurium, allotropy 751
Tellurium, atomic and physical properties 753 754
Tellurium, chemical reactivity 754—759
Tellurium, coordination geometries 756—757
Tellurium, dioxide 779 780
Tellurium, discovery 747
Tellurium, halide complexes 776
Tellurium, halides 767—776
Tellurium, hydride, 759 766
Tellurium, nitrate 786
Tellurium, nitride, 783
Tellurium, organo compounds 786—788
Tellurium, oxides 779—780
Tellurium, oxoacids 781—783
Tellurium, oxohalides 777
Tellurium, polyatomic anions 762—765
Tellurium, polyatomic cations, 759 761
Tellurium, polyatomic cations, 761
Tellurium, production and uses 748 749
Tellurium, redox properties 755—756
Tellurium, sulfide, 783
Tellurium, toxicity 759
Tellurium, trioxide 780
Tellurocyanate ion, 779
Telluropolythionates 783
Tellurous acid 781
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